Диссертация (1150261), страница 21
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Сольватационные избытки водных растворов сульфоновых кислотпри 250С.система H 2O − CH 3SO3 Hmγ±Γ ++( H 2O )mγ±Γ ++( H 2O )mγ±Γ ++( H 2O )0,100,8130 -0,470,700,8160 -0,552,501,1230 -0,700,200,7920 -0,491,000,8490 -0,583,001,2340 -0,720,300,7890 -0,511,500,9130 -0,623,501,3800 -0,760,400,7940 -0,532,001,0000 -0,674,001,5800 -0,800,500,8040 -0,53система H 2O − C2 H 5 SO3 Hmγ±Γ ++( H 2O )mγ±Γ ++( H 2O )mγ±Γ ++( H 2O )0,100,7970 -0,470,700,7660 -0,542,500,9880 -0,680,200,7740 -0,481,000,7810 -0,573,001,0730 -0,700,300,7560 -0,491,500,8390 -0,623,501,1760 -0,730,400,7510 -0,512,000,9100 -0,654,001,2800 -0,740,500,7520 -0,52- 140 система H 2O − C6 H 5 SO3 Hmγ±Γ ++( H 2O )mγ±Γ ++( H 2O )mγ±Γ ++( H 2O )0,100,7840 -0,460,800,6800 -0,492,000,6680 -0,550,200,7450 -0,460,900,6760 -0,492,500,6770 -0,590,300,7220 -0,471,000,6730 -0,503,000,6940 -0,620,400,7080 -0,471,200,6690 -0,513,500,7170 -0,650,500,6970 -0,481,400,6680 -0,524,000,7460 -0,670,600,6900 -0,481,600,6670 -0,534,500,7790 -0,700,700,6850 -0,491,800,6670 -0,545,000,8180 -0,71система H 2O − (CH 3 )2 C6 H 3SO3 Hmγ±Γ ++( H 2O )mγ±Γ ++( H 2O )mγ±Γ ++( H 2O )0,100,7490 -0,440,800,4930 -0,282,000,3620 -0,320,200,6790 -0,410,900,4750 -0,272,500,3380 -0,360,300,6340 -0,381,000,4560 -0,263,000,3210 -0,400,400,5960 -0,361,200,4290 -0,273,500,3100 -0,450,500,5650 -0,341,400,4060 -0,284,000,3030 -0,500,600,5370 -0,321,600,3890 -0,305,000,2990 -0,540,700,5130 -0,311,800,3740 -0,314,500,3000 -0,57система H 2O − (CH 3 )3 C6 H 2 SO3 Hmγ±Γ ++( H 2O )mγ±Γ ++( H 2O )mγ±Γ ++( H 2O )0,100,7430 -0,450,400,5690 -0,290,700,4610 -0,100,200,6700 -0,380,500,5300 -0,230,800,4330 -0,050,300,6140 -0,340,600,4940 -0,170,900,4080 -0,01- 141 система H 2O − (CH 3 )3 C6 H 2 SO3 H (продолжение)mγ±Γ ++( H 2O )mγ±Γ ++( H 2O )mγ±Γ ++( H 2O )1,000,3860 0,021,800,2820 -0,083,500,2200 -0,441,200,3500 0,042,000,2680 -0,154,000,2150 -0,511,400,3220 0,022,500,2440 -0,274,500,2140 -0,571,600,2990 -0,023,000,2300 -0,365,000,2150 -0,62система H 2O − (CH 3 )3 C6 H 2 SO3 Limγ±Γ ++( H 2O )mγ±Γ ++( H 2O )mγ±Γ ++( H 2O )0,100,7730 -0,470,800,5560 -0,282,000,3860 -0,270,200,7240 -0,440,900,5340 -0,252,500,3580 -0,380,300,6890 -0,421,000,5140 -0,223,000,3440 -0,470,400,6600 -0,401,200,4770 -0,183,500,3390 -0,540,500,6320 -0,371,400,4450 -0,184,000,3390 -0,590,600,6050 -0,341,600,4210 -0,204,500,3450 -0,630,700,5800 -0,311,800,4020 -0,24Таблица 3.
Сольватационные избытки водных растворов неорганическихоснований при 250С.система H 2O − LiOHmγ±Γ ++( H 2O )mγ±Γ ++( H 2O )mγ±Γ ++( H 2O )0,010,8951 -0,470,080,7550 -0,440,400,6000 -0,410,020,8583 -0,460,100,7349 -0,430,500,5791 -0,420,040,8116 -0,450,200,6683 -0,420,600,5627 -0,420,060,7796 -0,440,300,6281 -0,410,700,5495 -0,43- 142 система H 2O − LiOH (продолжение)mγ±Γ ++( H 2O )mγ±Γ ++( H 2O )mγ±Γ ++( H 2O )0,800,5387 -0,431,600,4939 -0,483,500,4634 -0,510,900,5297 -0,441,800,4884 -0,484,000,4568 -0,501,000,5221 -0,442,000,4840 -0,494,500,4490 -0,481,200,5100 -0,452,500,4757 -0,515,000,4396 -0,451,400,5009 -0,473,000,4694 -0,51система H 2O − NaOHmγ±Γ ++( H 2O )mγ±Γ ++( H 2O )mγ±Γ ++( H 2O )0,010,9017 -0,481,200,6776 -0,5410,003,2584 -0,890,020,8701 -0,471,400,6839 -0,5611,004,1454 -0,900,040,8322 -0,461,600,6922 -0,5712,005,2412 -0,910,060,8075 -0,461,800,7022 -0,5913,006,5560 -0,910,080,7893 -0,462,000,7139 -0,6014,008,0830 -0,910,100,7750 -0,462,500,7493 -0,6415,009,7964 -0,910,200,7311 -0,463,000,7937 -0,6716,0011,6525 -0,910,300,7079 -0,473,500,8474 -0,7017,0013,5955 -0,910,400,6938 -0,474,000,9114 -0,7318,0015,5670 -0,910,500,6847 -0,484,500,9871 -0,7519,0017,5173 -0,900,600,6790 -0,495,001,0762 -0,7825,0028,2626 -0,900,700,6756 -0,506,001,3023 -0,8126,0029,9565 -0,890,800,6738 -0,517,001,6086 -0,8427,0031,4759 -0,880,900,6733 -0,528,002,0184 -0,8628,0032,5740 -0,851,000,6739 -0,539,002,5586 -0,8829,0032,8617 -0,74- 143 система H 2O − KOHmγ±Γ ++( H 2O )mγ±Γ ++( H 2O )mγ±Γ ++( H 2O )0,010,9020 -0,481,000,7327 -0,578,003,6520 -0,870,020,8707 -0,471,200,7515 -0,599,004,7290 -0,890,040,8336 -0,461,400,7741 -0,6110,006,1097 -0,900,060,8098 -0,461,600,7998 -0,6311,007,8599 -0,900,080,7925 -0,461,800,8284 -0,6512,0010,0490 -0,910,100,7791 -0,462,000,8598 -0,6613,0012,7451 -0,920,200,7400 -0,472,500,9502 -0,7014,0016,0062 -0,920,300,7221 -0,483,001,0579 -0,7315,0019,8700 -0,920,400,7135 -0,493,501,1841 -0,7516,0024,3397 -0,920,500,7103 -0,514,001,3310 -0,7817,0029,3696 -0,920,600,7107 -0,524,501,5010 -0,8018,0034,8508 -0,920,700,7136 -0,535,001,6972 -0,8119,0040,6004 -0,920,800,7185 -0,546,002,1823 -0,8420,0046,3588 -0,920,900,7249 -0,567,002,8199 -0,86система H 2O − CsOHmγ±Γ ++( H 2O )mγ±Γ ++( H 2O )mγ±Γ ++( H 2O )0,010,9065 -0,480,200,7725 -0,480,800,7675 -0,540,020,8785 -0,470,300,7604 -0,490,900,7742 -0,550,040,8464 -0,470,400,7559 -0,501,000,7819 -0,560,060,8266 -0,470,500,7555 -0,511,100,7902 -0,570,080,8125 -0,470,600,7578 -0,521,200,7993 -0,580,100,8018 -0,470,700,7620 -0,53- 144 Таблица 4.
Сольватационные избытки водных растворов солей магния при250С.система H 2O − MgCl2mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )0,100,5280 -0,600,800,5210 -0,762,001,0510 -0,880,200,4880 -0,640,900,5430 -0,772,501,5380 -0,900,300,4760 -0,661,000,5690 -0,793,002,3200 -0,920,400,4740 -0,681,200,6300 -0,813,503,5500 -0,930,500,4800 -0,701,400,7080 -0,834,005,5300 -0,940,600,4900 -0,721,600,8020 -0,854,508,7200 -0,950,700,5050 -0,741,800,9140 -0,875,0013,9200 -0,95система H 2O − MgBr2mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )0,100,5420 -0,610,800,6270 -0,792,001,5930 -0,890,200,5120 -0,660,900,6680 -0,802,502,5600 -0,920,300,5110 -0,691,000,7140 -0,813,004,2000 -0,930,400,5200 -0,711,200,8260 -0,843,507,0600 -0,940,500,5380 -0,731,400,9620 -0,854,0012,0000 -0,950,600,5640 -0,751,601,1280 -0,874,5020,8000 -0,960,700,5910 -0,771,801,3330 -0,885,0036,1000 -0,96- 145 система H 2O − MgJ 2mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )0,100,5710 -0,620,800,7420 -0,812,002,3900 -0,910,200,5500 -0,670,900,8050 -0,822,504,2700 -0,930,300,5580 -0,701,000,8790 -0,833,007,8100 -0,940,400,5750 -0,731,201,0530 -0,853,5014,8000 -0,950,500,6050 -0,751,401,2720 -0,874,0028,6000 -0,960,600,6430 -0,771,601,5560 -0,894,5056,7000 -0,960,700,6880 -0,791,801,9280 -0,905,00113,0000-0,97система H 2O − (MgClO4 )2mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )0,100,5770 -0,630,800,7800 -0,812,002,5900 -0,910,200,5650 -0,680,900,8490 -0,822,504,7800 -0,930,300,5760 -0,711,000,9250 -0,833,008,9900 -0,940,400,5990 -0,731,201,1120 -0,863,5017,2600 -0,950,500,6330 -0,751,401,3550 -0,874,0033,3000 -0,960,600,6730 -0,771,601,6670 -0,890,700,7230 -0,791,802,0800 -0,90система H 2O − (MgNO3 )2mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )0,100,5220 -0,600,500,4690 -0,700,900,5180 -0,760,200,4800 -0,640,600,4780 -0,711,000,5360 -0,770,300,4670 -0,660,700,4880 -0,731,200,5800 -0,790,400,4650 -0,680,800,5010 -0,741,400,6310 -0,81- 146 система H 2O − (MgNO3 )2 (продолжение)mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )1,600,6910 -0,822,501,0880 -0,884,002,5900 -0,921,800,7580 -0,843,001,4490 -0,904,503,5000 -0,932,000,8350 -0,853,501,9360 -0,915,004,7400 -0,93Таблица 5.
Сольватационные избытки водных растворов солей кальция при250С.система H 2O − CaCl2mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )0,100,5180 -0,600,900,4840 -0,753,001,4830 -0,910,200,4720 -0,631,000,5000 -0,773,502,0800 -0,920,300,4550 -0,651,200,5390 -0,794,002,9300 -0,930,400,4480 -0,671,400,5870 -0,814,504,1700 -0,940,500,4480 -0,691,600,6440 -0,835,005,8900 -0,940,600,4530 -0,701,800,7120 -0,855,508,1800 -0,940,700,4600 -0,722,000,7920 -0,866,0011,1100 -0,950,800,4700 -0,742,501,0630 -0,89система H 2O − CaBr2mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )0,100,5320 -0,600,500,4900 -0,710,900,5670 -0,780,200,4910 -0,650,600,5040 -0,731,000,5960 -0,790,300,4810 -0,670,700,5210 -0,751,200,6640 -0,820,400,4820 -0,690,800,5420 -0,761,400,7460 -0,84- 147 система H 2O − CaBr2 (продолжение)mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )1,600,8460 -0,853,002,5300 -0,925,0018,4300 -0,961,800,9680 -0,873,503,8800 -0,945,5031,7000 -0,962,001,1190 -0,884,006,2700 -0,956,0055,7000 -0,972,501,6540 -0,904,5010,6400 -0,95система H 2O − CaJ 2mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )0,100,5520 -0,610,600,5760 -0,751,200,8400 -0,840,200,5240 -0,660,700,6050 -0,771,400,9780 -0,850,300,5240 -0,690,800,6410 -0,791,601,1480 -0,870,400,5350 -0,710,900,6820 -0,801,801,3560 -0,880,500,5530 -0,731,000,7310 -0,812,001,6170 -0,89система H 2O − Ca(ClO4 )2mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )0,100,5570 -0,620,900,6950 -0,803,004,2100 -0,930,200,5320 -0,671,000,7430 -0,813,506,7600 -0,940,300,5320 -0,691,200,8530 -0,834,0010,7700 -0,940,400,5440 -0,711,400,9920 -0,854,5017,0200 -0,950,500,5640 -0,731,601,1610 -0,875,0026,7000 -0,950,600,5890 -0,751,801,3720 -0,885,5041,3000 -0,960,700,6180 -0,772,001,6340 -0,896,0063,7000 -0,960,800,6540 -0,782,502,6200 -0,91- 148 система H 2O − Ca(NO3 )2mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )0,100,4880 -0,590,900,3400 -0,663,000,3820 -0,790,200,4290 -0,601,000,3380 -0,673,500,4070 -0,810,300,3970 -0,601,200,3370 -0,694,000,4380 -0,830,400,3780 -0,611,400,3370 -0,704,500,4720 -0,840,500,3650 -0,621,600,3390 -0,715,000,5100 -0,850,600,3560 -0,631,800,3420 -0,735,500,5510 -0,860,700,3490 -0,642,000,3470 -0,746,000,5960 -0,870,800,3440 -0,652,500,3620 -0,77Таблица 6.
Сольватационные избытки водных растворов солей уранила при250С.система H 2O − UO2 (ClO4 )2mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )0,100,6040 -0,630,901,1830 -0,853,0029,8000 -0,950,200,6120 -0,701,001,3410 -0,863,5067,9000 -0,960,300,6460 -0,731,201,7410 -0,884,00154,6000-0,960,400,6980 -0,761,402,3000 -0,904,50345,0000-0,970,500,7620 -0,781,603,0600 -0,915,00724,0000-0,970,600,8410 -0,801,804,1400 -0,925,501 457,0000-0,970,700,9350 -0,822,005,7000 -0,930,801,0490 -0,842,5012,9000 -0,94- 149 система H 2O − UO2 (NO3 )2mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )mγ±Γ 2+2+( H 2O )0,100,5430 -0,610,900,6410 -0,793,002,0000 -0,860,200,5120 -0,661,000,6790 -0,803,502,3700 -0,860,300,5100 -0,681,200,7610 -0,814,002,6400 -0,840,400,5180 -0,711,400,8550 -0,834,502,8500 -0,840,500,5340 -0,721,600,9430 -0,845,003,0100 -0,830,600,5550 -0,741,801,0830 -0,855,503,2000 -0,830,700,5780 -0,762,001,2180 -0,860,800,6080 -0,782,501,6020 -0,87Таблица 7.