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Èññëåäîâàíî êîíôîðìàöèîííîå ïîâåäåíèå ãèáêîé äèýëåêòðè÷åñêîé ïîëèìåðíîé öåïè â ïîñòîÿííîì îäíîðîäíîì ýëåêòðè÷åñêîìïîëå â ðåæèìàõ õîðîøåãî è ïëîõîãî ðàñòâîðèòåëåé. Ïðåäñêàçàí íîâûé êîíôîðìàöèîííûéïåðåõîä ãëîáóëà-êëóáîê, èíäóöèðîâàííûé ýëåêòðîñòðèêöèîííûì íàáóõàíèåì ïîëèìåðà âýëåêòðè÷åñêîì ïîëå. Ïîêàçàíà ïðèíöèïèàëüíàÿ âîçìîæíîñòü óïðàâëåíèÿ êîíôîðìàöèîííûì ñîñòîÿíèåì ïîëèìåðà èçìåíåíèåì íàïðÿæåííîñòè ýëåêòðè÷åñêîãî ïîëÿ. Ðàçðàáîòàíà ìîäåëü äèýëåêòðè÷åñêîé ïîëèìåðíîé öåïè ñ èçîòðîïíî ïîëÿðèçóåìûìè ìîíîìåðíûìè çâåíüÿìè â ñðåäå äèýëåêòðè÷åñêîãî ðàñòâîðèòåëÿ ñ ìàëîé äîáàâêîé èçîòðîïíî ïîëÿðèçóåìûõ ÷àñòèö íèçêîìîëåêóëÿðíîãî öåëåâîãî ñîåäèíåíèÿ âî âíåøíåì ýëåêòðè÷åñêîì ïîëå.
 ðàìêàõ ðàçðàáîòàííîé ìîäåëè èññëåäîâàíî ïîâåäåíèå ëîêàëüíîé êîíöåíòðàöèè íèçêîìîëåêóëÿðíûõ ÷àñòèö öåëåâîãî ñîåäèíåíèÿ âíóòðè îáúåìà ïîëèìåðà âçàâèñèìîñòè îò ñîîòíîøåíèÿ ìåæäó ïîëÿðèçóåìîñòÿìè ìîíîìåðíîãî çâåíà è ÷àñòèöûöåëåâîãî ñîåäèíåíèÿ.Ïðèëîæåíèå Ïðèëîæåíèè îïèñàíî ïðèìåíåíèå èíòåãðèðîâàíèÿ ïî òðàåêòîðèÿì ê âû÷èñëåíèþ ôóíêöèè ðàñïðåäåëåíèÿ ïî ðàäèóñó èíåðöèè ãàóññîâîé ïîëèìåðíîé öåïè â d-ìåðíîì ïðîñòðàíñòâå.Îñíîâûâàÿñü íà ïîëó÷åííûõ àñèìïòîòè÷åñêèõ ñîîòíîøåíèÿõ äëÿ ôóíêöèè ðàñïðåäåëåíèÿ ïðèáîëüøèõ è ìàëûõ ðàäèóñàõ èíåðöèè, ñêîíñòðóèðîâàíà èíòåðïîëÿöèîííàÿ ôîðìóëà äëÿ êîíôèãóðàöèîííîé ýíòðîïèè êàê ôóíêöèè ðàäèóñà èíåðöèè ãàóññîâîé ïîëèìåðíîé öåïè â d-ìåðíîìïðîñòðàíñòâå, èñïîëüçóåìàÿ â ãëàâàõ 4-5 äëÿ îïèñàíèÿ âêëàäà êîíôîðìàöèîííîé ýíòðîïèèïîëèìåðíîé öåïè äëÿ ñëó÷àÿ d = 3.Ñïèñîê ïóáëèêàöèé1.
Budkov Yu.A., Kolesnikov A.L. and Kiselev M.G. A modied Poisson-Boltzmann theory: Eectsof co-solvent polarizability // EPL. 2015. V.111. P. 28002. https://doi.org/10.1209/02955075/111/280022. Budkov Yu.A., Kolesnikov A.L., Kiselev M.G. On the theory of electric double layer withexplicit account of a polarizable cosolvent // J. Chem. Phys. 2016. V.144. P. 184703.https://doi.org/10.1063/1.4948634353.
Budkov Y., Kolesnikov A., Goodwin Z., Kiselev M., Kornyshev A. Theory of electrosorptionof water from ionic liquids // Electrochimica Acta. 2018. V. 284. P. 346-354.http://doi.org/10.1016/j.electacta.2018.07.1394. Budkov Y. Nonlocal statistical eld theory of dipolar particles in electrolyte solutions // Journalof Physics: Condensed Matter.
2018. V. 30. P. 344001-344009. http://doi.org/10.1088/1361648X/aad3ee5. Budkov Yu.A. and Kolesnikov A.L. Polarizable polymer chain under external electric eld:Eects of many-body electrostatic dipole correlations // Eur. Phys. J. E. 2016. V.39. P.110. http://doi.org/10.1140/epje/i2016-16110-x6.
Budkov Yu.A., Kalikin N.N. and Kolesnikov A.L. Polymer chain collapse inducedby many-body dipole correlations // Eur. Phys. J. E. 2017. V.40. P. 47.http://doi.org/10.1140/epje/i2017-11533-57. Gordievskaya Yu.D., Budkov Yu.A. and Kramarenko E.Y. An interplay of electrostaticand excluded volume interactions in the conformational behavior of a dipolar chain:theory and computer simulations // Soft Matter 2018. V.14. P. 3232.http://doi.org/10.1039/C8SM00346G8. Budkov Yu.A., Kolesnikov A.L. and Kiselev M.G.
Communication: Polarizable polymer chainunder external electric eld in a dilute polymer solution // J. Chem. Phys. 2015. V.143. P. 201102. http://doi.org/10.1063/1.49366619. Kolesnikov A.L., Budkov Yu.A., Basharova E. and Kiselev M.G. Statistical theory of polarizabletarget compound impregnation into a polymer coil under the inuence of an electric eld //Soft Matter 2017. V.13. P. 4363. http://doi.org/10.1039/C7SM00417F10. Budkov Yu.A.
and Kiselev M.G. Flory-type theories of polymer chains under dierent externalstimuli // J. Phys.: Condens. Matter. 2018. V.30. P. 043001. http://doi.org/10.1088/1361648X/aa9f5611. Budkov Yu.A. and Kolesnikov A.L. On a new application of the path integrals in polymerstatistical physics // J. Stat.
Mech. 2016. V.2016. P. 103211. http://doi.org/10.1088/17425468/2016/10/10321136.
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