Диссертация (1150375), страница 22
Текст из файла (страница 22)
Chem. Soc., Faraday Trans. 1996. 92(11). 1869-1875.90.Marcus Y. Preferential solvation of silver(I), copper(I) and copper(II) ions in aqueous acetonitrile// J. Chem. Soc. Dalt. Trans. 1991. 9. 2265-2268.91.Rajendran G., Sreekumar T.K., Kalidas C.
Preferential solvation of copper (II) salts in water-pyridine and water-dimethylsulfoxide mixtures // Fluid Phase Eq. 1989. 46. 249-258.92.Tsierkezos N.G., Roithova J., Schwarz H., Schro1der D., Molinou I.E. Solvation of copper(II)sulfate in binary water/N,N-dimethylformamide mixtures: from the solution to the gas phase // J. Phys.Chem.
B. 2008. 112 (14). 4365-4371.93.Gill D.S., Kumari N., Chauhan M.S. Preferential solvation of ions in mixed solvents. Part 4. // J.Chem. Soc. Farad. Trans. I. 1985. 81. 687-693.94.Umebayashi Y., Matsumoto K., Watanabe M., Ishiguro S-I. Individual solvation number of first-row transition metal(II) ions in solvent mixtures of N,N-dimethylformamide and N,Ndimethylacetamide. Solvation steric effect // Phys. Chem.
Chem. Phys. 2001. 3. 5475–5481.95.Ishiguro S., Umebayashi Y., Komiya M. Thermodynamic and structural aspects on the solvationsteric effect of lanthanide(III) – dependence on the ionic size // Coord. Chem. Rev. 2002. 226. 103–111.96.Spaha M., Spah D.C., Jun S., Lee S., Song H-J., Won-Gun K., Park J-W.
Thermodynamicdetermination of solvation potentials of various metal chlorides by (1,4-dioxane + water) mixturesthrough EMF measurements // Fluid Phase Eq. 2009. 279. 17–27.97.Yokoyama H, Tada Y. 65th Annual Meeting of Electrochemical Society of Japan, Tokyo, 1998.98.Ohtaki H., Niwa Y., Perez F.R., Ozutsumi K., Alvarez J., Probst M., Bolado S. Anomaly of thebasicity of water in mixed solvents // J. of Mol.
Liq. 2006. 129. 49-56.99.Kamienska-Piotrowicz E. Analysis of the enthalpies of transfer of Co(II) ion in mixed solventsby means of the theory of preferential solvation // Therm. Acta. 2005. 427 (1-2). 1-7.100.Kimura T., Kato Y. Luminescence study on determination of the hydration number of Sm(III)and Dy(III) // J.
Alloys Comp. 1995. 225. 284-287.101.Chiavone-Filho O., Rasmussen P. Solubilities of salts in mixed solvents // J. Chem. Eng. Data.1993. 38 (3). 367-369.102.Eysseltova J., Malkova Z. Solubility in the systems MCl (M = Na, K)–1,4-dioxane–water at 25°C // J. Solut. Chem. 2006. 35 (9). 1329–1334.129103.Selikson B., Ricci J. E. The system sodium nitrate—dioxane—water at 25 °C // J. Am.
Chem.Soc. 1942. 64 (10). 2474–2476.104.Schott H., Lynch C. C. Ternary systems cobalt chloride-dioxane-water and nickel chloride-dioxane-water at 25° C // J. Chem. Eng. Data. 1966. 11 (2). 215–221.105.Бахшиев Н. Г. Введение в молекулярную спектроскопию. Л.: ЛГУ. 1987. 216 с.106.Ng S. S., Hassan Z., Abu H. Kramers-Kronig analysis of Infrared reflectance with a singleresonance // J.
Technol. 2006. 44. 67-76.107.Wakabayashi K., Maedo Y., Ozutsumi K., Ohtaki H. The structure of solvated halide ions indimethyl sulfoxide studied by Raman spectroscopy and X-ray diffraction // J. Mol. Liq. 2004. 110 (13). 43-50.108. Lechat, S., Khan, M.A., Bouet, G., Vierling, F. Spectrophotometric study of cobalt(II) chloridecomplexes in ethanol and propan-2-ol. // Inorg. Chim.
Acta. 1993. 211. 33-36.109.Åkerlöf G., Short O. A. The dielectric constant of dioxane—water mixtures between 0 and 80°// J. Am. Chem. Soc. 1936. 58 (7). 1241–1243.110. Ohtaki, H. Structural studies on solvation and complexation of metal ions in nonaqueous solutions// Pure Appl. Chem. 1987. 59. 1143-1150.111.Chmurzyński L., Kluczkowski M., Pilarczyk M.
Equilibria of copper(II) bromide indimethylsulphoxide solutions // Electrochim. Acta. 1984. 29 (3). 373-379. (1984).112.Biliskov N., Baranovic G. Infrared spectroscopy of liquid water-N,N-dimethylformamidemixtures // J. Mol. Liq. 2009. 144 (3). 155-162.113. Elleb, M., Meullemeestre, J., Schwing-Weill, M.-J., Vierling, F. Spectrophotometric study ofcopper(II) chloride complexes in propylene carbonate and in dimethyl sulfoxide // Inorg.
Chem. 1982.21. 1477-1483.114.Hu Z., Li H., Wang C., Wu T., Han S. Is the blue shift of C–H vibration in DMF–water mixturemainly caused by C–H⋯O interaction? // Chem. Phys. Let. 2004. 394. 405-409.115.Umebayashi Y., Matsumoto K., Watanabe M., Ishiguro S. Individual solvation numbers aroundthe nickel(II) ion in an N,N-dimethylformamide and N,N-dimethylacetamide mixture determined byRaman spectrophotometry // Anal. Sc. 2001.
2001. 17. 323-326.116.Lindqvist-Reis P., Persson I., Sandstrom M. Steric effects control the structure of the solvatedlanthanum(III) ion in aqueous dimethyl sulfoxide, and N,N′-dimethylpropyleneurea solution. AnEXAFS and Large-Angle X-ray Scattering study // Inorg. Chem. 2000. 39 (18). 4006-4011.117.Beuchat C., Hagberg D., Spezia R., Gagliardi* L. Hydration of lanthanide chloride salts: Aquantum chemical and classical molecular dynamics simulation study // J.
Phys. Chem. B. 2010. 114(47). 15590–15597.130118.Díaz-Moreno S., Ramos S., Bowron D.T. Solvation structure and ion complexation of La3+ in a1-molal aqueous solution of lanthanum chloride // J. Phys. Chem. A. 2011. 115. 6575–6581.119.Bunzli J-C.G., Milicic-Tang A. FT-IR and fluorometric investigation of rare-earth and metal ionsolvation part // Inorg. Chim. Acta. 1996.
252. 221-228.120.Fuchs A., Lundberg D., Warminska D., Persson I. On the structure and volumetric properties ofsolvated lanthanoid(III) ions in amide-solutions // J. Phys. Chem. B. 2013. 117. 8502−8511.121.Umebayashi Y., Matsumoto K., Watanabe M., Ishiguro S-I. Individual solvation number of first-row transition metal(II) ions in solvent mixtures of N,N-dimethylformamide and N,Ndimethylacetamide.
Solvation steric effect // Phys. Chem. Chem. Phys. 2001. 3. 5475–5481.122.Хрипун М.К., Червоненко К.Ю., Киселев А.А., Хрипун А.В. Структурные эффекты имикрогетерогенность в концентрированных растворах и их роль в образовании хлорокомплексовкадмия // Журн. общ. химии. 2001. 71 (1). 25 – 35.123.Хрипун М.К., Киселев А.А., Ефимов А.Ю., Мюнд Л.А., Петрановский В.П. Влияниеструктуры раствора на взаимную растворимость компонентов и процесс образования хлоридныхкомплексов цинка и кадмия в системах Zn(Cd)(NO3)2 — LiCl — H2O // Ж. Структ. Химии. 2004.45 (6). 1027 – 1033.131ПриложенияТаблица П1.
Длины связей r (Å) и валентные углы (град.)в структуре соединенияCoCl2(H2O)2(DMF)2СвязьRСвязьrCo1—O12.057(3)N3—C3A1.439(6)Co1—O1i2.057(3)N3—C3B1.455(4)Co1—O3i2.093(2)Co2—O42.021(3)Co1—O32.093(2)Co2—Cl12.231(1)Co1—O2i2.105(2)Co2—Cl22.245(1)Co1—O22.105(2)Co2—Cl32.246(3)O1—C11.246(3)O4—C41.239(4)C1—N11.301(3)C4—N41.316(5)N1—C1B1.447(3)N4—C4A1.442(5)N1—C1A1.452(4)N4—C4B1.465(5)O2—C21.196(4)H2A1—Cl3ii2.788(2)C2—N21.324(4)Cl3—H42.859(1)N2—C2A1.438(4)H4—Cl32.859(1)N2—C2B1.448(6)Cl3—C43.470(4)O3—C31.237(3)C4—Cl33.470(4)C3—N31.306(4)УголУголO1—Co1—O1i179.98(7)C2—N2—C2A119.28(26)O1—Co1—O3i2.66(7)C2—N2—C2B123.95(28)O1i—Co1—O387.34(7)C2A—N2—C2B116.74(31)O1—Co1—O387.34(7)C3—O3—Co1122.62(18)O1i—Co1—O392.66(7)O3—C3—N3125.75(27)O3i—Co1—O3180.00(7)C3—N3—C3A121.29(26)O1—Co1—O2i87.43(7)C3—N3—C3B120.94(27)O1i—Co1—O2i92.57(7)C3A—N3—C3B117.76(29)O3i—Co1—O2i90.42(7)O4—Co2—Cl1106.56(8)O3—Co1—O2i89.58(7)O4—Co2—Cl2105.53(9)O1—Co1—O292.57(7)Cl1—Co2—Cl2113.48(4)132O1i—Co1—O287.43(7)O4—Co2—Cl3104.28(8)O3i—Co1—O289.58(7)Cl1—Co2—Cl3111.26(4O3—Co1—O290.42(7)Cl2—Co2—Cl3114.76(5)O2i—Co1—O2179.99(7)C4—O4—Co2123.36(23)C1—O1—Co1126.50(18)O4—C4—N4123.97(29)O1—C1—N1123.26(25)C4—N4—C4A121.94(29)C1—N1—C1B121.53(22)C4—N4—C4B120.91(31)C1—N1—C1A121.42(21)C4A—N4—C4B117.14(31)C1B—N1—C1A117.03(23)Cl3—H4—C4124.36(21)C2—O2—Co1125.52(18)C4—H4—Cl3124.36(21)O2—C2—N2125.98(27)133Таблица П2.
Длины связей r (Å) и валентные углы (град.)в структуре соединенияCoCl2*8/3DMFСвязьRСвязьrCo1—O12.057(3)N2—C2BCo1—O1i2.057(3)O3—C31.237(3)Co1—O3i2.093(2)C3—N31.306(4)Co1—O32.093(2)N3—C3A1.439(6)Co1—O2i2.105(2)N3—C3B1.455(4)Co1—O22.105(2)Co2—O42.021(3)O1—C11.246(3)Co2—Cl12.231(1)C1—N11.301(3)Co2—Cl22.245(1)N1—C1B1.447(3)Co2—Cl32.246(3)N1—C1A1.452(4)O4—C41.239(4)O2—C21.196(4)C4—N41.316(5)C2—N21.324(4)N4—C4A1.442(5)N2—C2A1.438(4)N4—C4B1.465(5)Угол1.448(6)УголO1—Co1—O1i179.98(7)C2—N2—C2A119.28(26)O1—Co1—O3i2.66(7)C2—N2—C2B123.95(28)O1i—Co1—O387.34(7)C2A—N2—C2B116.74(31)O1—Co1—O387.34(7)C3—O3—Co1122.62(18)O1i—Co1—O392.66(7)O3—C3—N3125.75(27)O3i—Co1—O3180.00(7)C3—N3—C3A121.29(26)O1—Co1—O2i87.43(7)C3—N3—C3B120.94(27)O1i—Co1—O2i92.57(7)C3A—N3—C3B117.76(29)O3i—Co1—O2i90.42(7)O4—Co2—Cl1106.56(8)O3—Co1—O2i89.58(7)O4—Co2—Cl2105.53(9)O1—Co1—O292.57(7)Cl1—Co2—Cl2113.48(4)O1i—Co1—O287.43(7)O4—Co2—Cl3104.28(8)O3i—Co1—O289.58(7)Cl1—Co2—Cl3111.26(4O3—Co1—O290.42(7)Cl2—Co2—Cl3114.76(5)O2i—Co1—O2179.99(7)C4—O4—Co2123.36(23)C1—O1—Co1126.50(18)O4—C4—N4123.97(29)O1—C1—N1123.26(25)C4—N4—C4A121.94(29)134C1—N1—C1B121.53(22)C4—N4—C4B120.91(31)C1—N1—C1A121.42(21)C4A—N4—C4B117.14(31)C1B—N1—C1A117.03(23)Cl3—H4—C4124.36(21)C2—O2—Co1125.52(18)C4—H4—Cl3124.36(21)O2—C2—N2125.98(27)135Таблица П3.
Длины связей r (Å) и валентные углы (град.)в структуре соединенияCuCl2(ДМСО)2 аСвязьСвязьrrCu-O(1)1.9507(19)Cu-Cl(2)2.6961(9)Cu-O(1)#11.9507(19)S-O(1)1.5328(16)Cu-Cl(1)2.2805(9)S-C(1)1.767(3)Cu-Cl(2)#2.2865(8)S-C(2)1.768(3)УголУголO(1)-Cu-O(1)#1173.20(10)Cl(1)-Cu-Cl(2)101.28(3)O(1)-Cu-Cl(1)92.86(5)Cl(2)#2-Cu-Cl(2)112.618(19)O(1)#1-Cu-Cl(1)92.86(5)O(1)-S-C(1)104.48(12)O(1)-Cu-Cl(2)#288.65(4)O(1)-S-C(2)103.67(12)O(1)#1-Cu-Cl(2)#288.65(4)C(1)-S-C(2)100.34(17)Cl(1)-Cu-Cl(2)#2146.10(4)Cu#3-Cl(2)-Cu144.38(4)O(1)-Cu-Cl(2)87.63(5)S-O(1)-Cu118.09(10)O(1)#1-Cu-Cl(2)87.63(5)а) Примечание: операторы симметрии, использованные для получения эквивалентных атомов: #1x,y,-z+1/2#2 x+1/2,-y+1/2,-z+1/2#3 x-1/2,-y+1/2,-z+1/2136Таблица П4. Длины связей r (Å) и валентные углы (град.)в структуре соединенияCuBr2(ДМСО)3СвязьСвязьrrCu-O(2)1.951(6)S(2)-C(1)1.765(11)Cu-O(1)1.954(6)O(3)-S(3)1.504(7)Cu-O(3)2.059(6)S(3)-C(5)1.716(15)Cu-Br(2)2.4727(18)S(3)-C(6)1.740(14)Cu-Br(1)2.5895(16)S(1)-C(3)1.740(12)S(1)-O(2)1.521(6)S(2)-O(1)1.517(6)S(1)-C(2)1.741(13)S(2)-C(4)1.756(13)УголУголO(2)-Cu-O(1)166.4(3)S(2)-O(1)-Cu121.4(4)O(2)-S(1)-C(3)103.3(5)O(2)-Cu-Br(1)93.7(2)O(2)-Cu-O(3)85.0(3)S(1)-O(2)-Cu122.0(4)C(2)-S(1)-C(3)99.7(8)O(1)-Cu-Br(1)96.0(2)O(1)-Cu-O(3)83.1(2)S(3)-O(3)-Cu121.7(4)O(1)-S(2)-C(4)106.5(6)O(3)-Cu-Br(1)106.5(2)O(2)-Cu-Br(2)91.9(2)O(3)-S(3)-C(5)107.5(7)O(1)-S(2)-C(1)101.0(5)Br(2)-Cu-Br(1)109.80(6)O(1)-Cu-Br(2)93.8(2)O(3)-S(3)-C(6)101.9(6)O(3)-Cu-Br(2)143.7(2)C(5)-S(3)-C(6)97.6(11)137Таблица П5.
![](https://s.studizba.com/z.php?f=/templates/si/i/noavatar.png&w=100&h=100&t=1"){kind=avatar}
