Диссертация (1150164), страница 23
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N. Mikhaylov, V. N. Sorokoumov, K. A. Korvinson et al.// Organometallics – 2016. – Vol. 35, No. 11. – P. 1684–1697.127ПриложениеСпектры ЯМР2aBHA1281H–1H NOESY (400 MHz, CDCl3–ДМСО–d6 10:1) для 2aBHA1292bBHA1301H–1H NOESY (400 MHz, CDCl3) для 2bBHA1313aBHA1321H–1H NOESY (400 MHz, CDCl3) для 3aBHA1334aBHA1343bBHA1352aBA1362aMBA137150ppm (t1)1005013816.83017.6983.030.14329.58429.13028.8384.054.6245.055.88277.31777.00076.682128.269125.781125.615125.542125.480125.360128.866146.509150.648183.231182.7312b12b57%57%9.00191.762189.392Cl HNN C Pd CNN9.026.917.166.02.742.227.00.692001.522.511.263.560.908.0ppm (t1)5.5077.0117.0096.9917.2607.1727.1697.1647.1537.1467.1297.1267.1087.2807.6627.3187.3001.0951.4311.5591.4661.8951.925400.13 МГц, Растворитель - CDCl3300000000250000000NC HNCl Pd CNN2000000001500000001000000002b*12b*43%43%5000000002.01.0500000000400000000100.61 МГц, CDCl330000000020000000010000000000150100139502.029.63729.29328.98730.1683.055.10754.68855.8644.077.42477.00076.5775.0112.681112.624125.012124.821124.653126.3076.0126.814127.963128.584133.046132.723146.852151.324160.605160.35612c2c52%58%9.01179.531O9.006.636.637.05.100.638.0ppm (t1)3.41200ppm (t1)5.220.88189.602187.425Cl HNN C Pd CNN6.9596.6366.6246.6076.5955.5966.9837.0377.1567.1487.0637.1767.1997.2737.2607.2457.7627.3011.4721.1591.5111.5803.723300.13 МГц, CDCl3400000000NC HNCl Pd CNN300000000200000000O2c*12c*48%48%10000000001.050000000040000000075.47 МГц, CDCl33000000002000000001000000000ppm (t1)1005014022.50522.3255.023.79227.78527.26029.60129.29528.98130.16730.90554.73555.90777.31777.00076.682126.254126.210126.008125.781125.613125.235129.803129.490127.209127.166126.778130.796130.533132.691132.480142.4402.661.22148.18912d2d77%9.212.991.45188.098179.808Cl HNN C Pd CiPrNN9.003.693.701500.341.090.301.07190.1010.7340.7170.7001.0771.2521.2351.2221.2051.4871.5271.5812.1643.2053.1883.1713.1543.1373.1203.1033.3623.3453.3283.3113.2933.2763.2595.6357.0247.0057.1047.1007.0967.0807.2097.1977.1907.1707.2607.3327.3177.2997.2967.761400000000300000000400.13 МГц, CDCl3NC HNCl Pd CiPrNN20000000012d*2d*33%33%1000000000ppm (t1)0.00600000000500000000100.61 МГц, CDCl34000000003000000002000000001000000000ИК спектры:141ИК спектр 2aBHA@PS(30%) после реакции Соногоширы (условия шприц–реактора).1421431442aBA2aMBA1452aDBA@PS(30%)2aAm@PS(30%)14612b12c14712d148.
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