Окислительное обессеривание углеводородного сырья пероксидом водорода в присутствии солей переходных металлов (1105643), страница 27
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Модифицированныйсинтез бромида 1-бутил-3-метил-N,N’-имидазола // 2009. Т. 52. № 10. С. 94– 97.1676 ПриложениеПриложение 1Хроматомасс-спектрометрический анализ прямогонной бензиновой фракциидо и после окислительного обессериванияХроматограмма образца №1 (обессеренный)3e+0072.5e+0072e+0071.5e+0071e+0075e+006Time (s)200300400500TIC600700800Хроматограмма образца №2 (исходный)3e+0072.5e+0072e+0071.5e+0071e+0075e+006Time (s)200300400TIC500600700Хроматограммы образцов №1 + №24e+0073.5e+0073e+0072.5e+0072e+0071.5e+0071e+0075e+006Time (s)200300400TIC naphta#1:1168500TIC naphta#2:1600700Фрагмент хроматограмм образцов №1 и №2, построенных похарактеристическому иону для алкилбензо[b]тиофенов m/z 16110000900080007000600050004000300020001000Time (s)615620625630161 naphta#2:1635640161 naphta#1:1645650Содержание серосодержащих соединений в образцах бензина относительнонафталинаPeak #NameR.T.
(s)QuantMasses№2(исх)№1(очищ)1Thiophene, tetrahydro-2,5-dimethyl-, trans-311.71013.6-2Thiophene, tetrahydro-2,5-dimethyl-, cis-314.91013.8-3trans-2-Ethyl-3-methylthiophane381.210110.2-4cis-2-Ethyl-3-methylthiophane384.0191019.0-5Naphthalene493.1128100.0100.06Benzo[b]thiophene, -ethyl-5991472.6-7Benzo[b]thiophene, C3622.3691610.3-8Benzo[b]thiophene, C3625.4861610.2-9Benzo[b]thiophene, C3628.9031610.4-10Benzo[b]thiophene, C3631.221610.3-11Benzo[b]thiophene, C3635.41612.0-12Benzo[b]thiophene, C3641.81611.2-Образец №2 (исходный)Peak #1NameCyclopentane, 1,3-dimethyl-169R.T.
(s)%%180.40.0022Cyclopentane, 1,2,3-trimethyl-185.80.0263Hexane, 2,3-dimethyl-192.20.1964Pentane, 3-ethyl-2-methyl-193.50.05553-Heptene, 2-methyl-195.30.0226Heptane, 2-methyl-198.31.4037Toluene201.81.7798Hexane, 2,3,4-trimethyl-205.70.4019Hexane, 3,4-dimethyl-206.71.44110Cyclohexane, 1,4-dimethyl-210.91.18511Cyclohexane, 1,2-dimethyl-2120.80912Cyclohexane, 1,3-dimethyl-216.30.62613Cyclohexane, 1,1-dimethyl-218.80.15414Cyclopentane, 1-ethyl-3-methyl-221.30.04615Cyclopentane, 1-ethyl-2-methyl-225.10.27816Cyclohexane, 1,2-dimethyl-230.60.36317Octane234.63.274181-Hexene, 5,5-dimethyl-238.72.611193-Hexene, 2,3-dimethyl-2430.339202,4-Dimethyl-1-heptene249.30.07321Hexane, 2,2,3-trimethyl-252.90.04522Cyclohexane, ethyl-255.80.01023Heptane, 2,4-dimethyl-2570.15224Cyclopentane, 1,1,3,3-tetramethyl-259.90.03925Cyclohexane, 1,4-dimethyl-262.40.04226Heptane, 2,6-dimethyl-263.50.69327Cyclohexane, ethyl-2671.49428Heptane, 2,5-dimethyl-2702.22129Cyclopentane, 1,1,3,4-tetramethyl-270.32.23430Cyclohexane, 1,1,3-trimethyl-2741.15231trans-1,3-Diethylcyclopentane276.30.31832Hexane, 3-ethyl-2-methyl-280.80.07133cis-1,3-Diethylcyclopentane2820.12817034Cyclohexane, 1,2,4-trimethyl-284.40.34835Cyclopropane, butyl-287.20.01336Cyclohexane, 1,3,5-trimethyl-287.40.02237Hexane, -ethyl-289.70.37338Hexane, -ethyl-292.10.11239Ethylbenzene2950.46340Octane, -methyl-297.41.34741Pentalene, octahydro-299.10.17242Octane, -methyl-299.50.17243p+m-Xylene301.61.76644Octane, -methyl-3032.26845Decene304.31.20046Cyclohexane, 1,2,3-trimethyl-304.50.73047Decane, 2,5-dimethyl-304.90.56748Phenylethyne307.60.01549Cyclohexane, 1,2,4-trimethyl-308.30.00950Cyclohexane, 1,1,2-trimethyl-310.20.07451Thiophene, tetrahydro-2,5-dimethyl-, trans-311.70.00152Cyclopentane, 1-ethyl-3-methyl-, trans-313.40.26853Thiophene, tetrahydro-2,5-dimethyl-, cis314.90.00154Cyclohexane, 1-ethyl-4-methyl-, trans-316.70.51155Cyclohexane, 1-ethyl-4-methyl-, cis-318.40.18556o-Xylene320.10.77957Nonane325.13.12158Octane, 2-methyl-326.72.229594-Nonene, 2,3,3-trimethyl-328.20.329603,5-Dimethyl-3-heptene329.60.44061Cyclohexane, C3331.80.04162Alkene333.20.03363Decane, 4-methyl-333.50.033641H-Indene, octahydro-338.60.78165Cyclohexane, propyl-339.10.36017166Cyclohexane, 1,1,3,5-tetramethyl-341.10.02167Hexane, 4-ethyl-2-methyl-343.10.26668Benzene, C3343.50.26669Heptane, 2,4,6-trimethyl-3460.90170Cyclohexane, propyl-346.30.90171Octane, 2,6-dimethyl-349.31.96372Cyclohexene, 3-(2-methylpropyl)-352.40.00773Octane, 2,6-dimethyl-353.10.04274Alkane354.30.99375Cyclooctane, 1,4-dimethyl-, cis-354.60.99376Pentalene, octahydro-1-methyl-357.70.19477Benzene, propyl-363.50.45078Cyclooctane, 1,4-dimethyl-, trans-364.21.21579Alkane3680.85380Benzene, 1-ethyl-3-methyl-368.91.67481Benzene, 1-ethyl-4-methyl-369.42.30282Benzene, 1,2,3-trimethyl-373.20.85983Alkane3741.27784Dihydromyrcene375.50.64785Menthene376.30.25586Decene377.70.09987Benzene, C3380.70.19288trans-2-Ethyl-3-methylthiophane381.20.00389Cyclohexane, C4381.70.61590Cyclohexane, C4383.21.00091Cyclohexane, C4383.91.00092cis-2-Ethyl-3-methylthiophane384.0190.00393Alkene384.40.324941,1,3,3,5-Pentamethylcyclohexane384.80.22595Cyclohexene,C3385.70.08996Benzene, C3389.11.52897Cyclohexane, C4390.50.10217298Decane392.14.24999Decene3930.912100Diisoamylene395.50.035101Benzene, C4397.70.079102Dodecadiene3980.079103Benzene, C4399.60.1801049-Methylbicyclo[3.3.1]nonane402.40.002105Alkane405.41.345106Benzene, C44061.401107Benzene, C3406.70.925108Alkane408.40.190109Cyclohexane, C4411.40.704110Alkane411.90.704111Cyclopentane, C5413.50.114112Alkane414.60.797113Benzene, C4415.90.1221141,9-Tetradecadiene416.40.060115Cyclohexane, C3418.90.215116Alkane421.70.078117Benzene, C44220.135118Benzene, C4422.80.509119Cyclohexane, C2423.30.078120Alkane424.80.240121Benzene, C4425.30.734122Benzene, C4425.60.627123Alkane426.50.741124Benzene, C4426.80.739125Alkane428.40.655126Benzene, C4431.80.498127Alkane433.60.0041281,4-Undecadiene435.70.0261294-Decene, 6-methyl-436.10.058173130Benzene, C44370.410131Cyclohexane, alkyl437.30.224132Benzene, C4438.10.181133Benzene, -butenyl-439.80.065134Cyclohexane, C5440.30.215135Benzene, C4441.60.480136Benzene, -butenyl-442.90.109137Cyclohexane, C5443.30.063138Benzene, C4445.30.014139Undecane447.42.6801401H-Indene, 2,3-dihydro-1,1-dimethyl-448.10.438141Alkene448.50.173142Benzene, C5449.80.078143Benzene, C5451.40.0411441H-Indene, 2,3-dihydro-1,6-dimethyl-452.60.071145Benzene, C44530.071146Alkene453.30.071147Benzene, C5454.40.001148Alkene455.60.068149Alkane456.20.261150Benzene, C5456.90.026151Benzene, C5457.70.133152Benzene, C5458.30.040153Alkane459.20.034154Cyclohexane, alkyl459.50.068155Benzene, C54600.219156Benzene, pentyl-460.40.219157Alkane461.10.239158Dodecene463.50.0281591H-Indene, 1-ethyl-2,3-dihydro-1-methyl-4640.176160Alkene464.50.160161Benzene, C6464.80.033174162Cyclohexane, pentyl-466.50.1421634-tert-Butyltoluene467.40.024164Benzene, C5467.90.147165Cyclopentane, 2-propenyl-468.10.147166trans-1,3-Diethylcyclopentane468.30.1471671H-Indene, 1-ethyl-2,3-dihydro-1-methyl-469.40.0151681H-Indene, 2,3-dihydro-4-methyl-4700.007169Benzene, C5471.30.021170Benzene, C5471.80.104171Alkane472.10.094172Benzene, alkenyl472.30.095173Alkane474.30.070174Alkane474.90.236175Benzene, C5475.50.2511761H-Indene, 2,3-dihydro-4-methyl-475.80.081177Benzene, C5476.50.463178Alkane476.80.463179Naphthalene, 1,2,3,4-tetrahydro-C2477.20.081180Benzene, C54780.046181Alkane478.80.322182Benzene, C5479.90.021183Naphthalene, 1,2,3,4-tetrahydro-C2481.90.391184Benzene, C5482.90.086185Benzene, C5483.70.037186Benzene, C5486.50.040187Alkane489.80.097188Cyclohexane, C4491.10.112189Benzene, C6492.90.201190Naphthalene493.10.032191Benzene, C6494.80.079192Dodecane495.81.425193Alkene496.30.3391751941H-Indene, 2,3-dihydro-1,1-dimethyl-496.80.085195Benzene, C6497.60.019196Benzene, alkenyl498.70.044197Benzene, C6500.40.023198Naphthalene, 1,2,3,4-tetrahydro-1,8-dimethyl-500.60.023199Alkane502.20.359200Benzene, C6502.60.118201Benzene, C6503.20.0332021H-Indene, 2,3-dihydro-1,1,5-trimethyl-505.40.045203Alkane505.70.045204Naphthalene, 1,2,3,4-tetrahydro-2-methyl-507.40.049205Benzene, C6507.70.049206Cyclohexane, 2-butyl-1,1,3-trimethyl-509.50.118207Benzene, C65100.0322081H-Indene, 2,3-dihydro-1,1-dimethyl-511.70.045209Benzene, C5514.90.042210Cyclohexane, hexyl-515.50.192211Naphthene516.10.023212Cyclopentane, ethyl-516.40.049213Benzene, C65180.000214Alkane519.30.035215Naphthene519.60.008216Alkane520.20.122217Benzene, alkenyl520.60.023218Alkane522.20.066219Naphthene522.40.004220Alkane524.30.098221Benzene, C6524.90.026222Alkane528.30.294223Benzene, alkenyl528.60.294224Naphthalene, 1,2,3,4-tetrahydro-5-methyl-529.80.024225Alkane531.30.007176226Benzene, C6531.70.007227Benzene, C6535.80.003228Cyclopentane, C4536.90.015229Tridecane540.10.692230Naphthalene, 1,2,3,4-tetrahydro-6-methyl-542.30.041231Naphthalene, 1,2,3,4-tetrahydro-1,1-dimethyl-542.60.057232Naphthalene, 2-methyl-543.30.083233Alkane544.90.021234Naphthalene, 1,2,3,4-tetrahydro-1,2-dimethyl-545.90.002235Alkane547.90.045236Naphthalene, 1-methyl-5510.060237Naphthalene, 1,2,3,4-tetrahydro-1,4-dimethyl-552.90.040238Benzene, C6553.80.0072391H-Indene, 2,3-dihydro-1,1,5-trimethyl-556.50.010240Benzene, C6558.60.001241Heptylcyclohexane560.50.035242Alkene560.90.087243Alkane561.20.087244Naphthalene, 1,2,3,4-tetrahydro-2,6-dimethyl-564.30.036245Alkane566.50.038246Alkane569.50.057247Naphthalene, 5-ethyl-1,2,3,4-tetrahydro-5700.016248Benzene, C7571.80.109249Alkane572.10.109250Biphenyl578.60.000251Tetradecane581.40.3432521H-Indene, 2,3-dihydro-1,1,3-trimethyl-583.90.006253Alkane587.70.006254Naphthalene, C2589.40.014255Benzene, C7594.50.003256Naphthalene, C2595.50.028257Naphthalene, C2596.90.029177258Diene5980.003259Benzo[b]thiophene, 7-ethyl-5990.0012601,1'-Biphenyl, 4-methyl-599.70.002261Alkane602.20.032262Cyclohexane, octyl-602.50.021263Naphthalene, C2603.70.003264Alkane604.30.011265Naphthalene, C26050.004266Naphthalene, C2605.40.015267Alkane6060.084268Alkane609.20.016269Naphthalene, C3609.60.016270Benzene, C66100.014271Benzene, octyl-610.50.008272Alkane613.30.007273Pentadecane620.20.179274Benzo[b]thiophene, C3622.3690.000275Benzo[b]thiophene, C3625.4860.000276Naphthalene, C3628.30.002277Benzo[b]thiophene, C3628.9030.000278Benzo[b]thiophene, C3631.220.000279Naphthalene, C3632.70.000280Benzo[b]thiophene, C3635.40.001281Naphthalene, C3636.50.003282Naphthalene, C3638.50.005283Benzo[b]thiophene, C3641.80.000284Alkane643.60.009285Naphthalene, C3644.70.014286Alkane646.30.007287Naphthalene, C36510.004288Benzene, C6651.10.004289Hexadecane656.70.073178290Alkane673.90.019291Alkane678.70.019292Heptadecane691.30.038293Alkane693.40.019294Octadecane724.20.014295Alkane727.50.009296Alkane744.10.006297Nonadecane755.50.009100.000179Приложение 2Хроматомасс-спектрометрический анализ бензиновой фракциикаталитического крекинга вакуумного газойля (35-225ОС)180181182183184Приложение 3Хроматомасс-спектрометрический анализ прямогонной дизельной фракции(240 - 345°C)Хроматограмма образца дизельного топлива8e+0077e+0076e+0075e+0074e+0073e+0072e+0071e+007Time (s)300400500600TICPeak#Name700800900R.T.
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