Закономерности образования сополимеров из мономеров разной активности в условиях полимеризации с обратимой передачей цепи (1105567), страница 23
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Впервые проведено систематическое исследование закономерностей образованиясополимеров (стирола–бутилакрилатов, стирола–акриловой кислоты, винилацетата–бутилакрилатов) в присутствии тритиокарбонатов и установлено, что положениетритиокарбонатной группы в цепи зависит от природы мономеров. Во всех системахнаблюдаетсяэффективныйконтрольмолекулярно-массовыххарактеристиксополимеров.2.
Найдены условия для контролируемого синтеза узкодисперсных композиционнооднородных сополимеров, включая амфифильные, заданного состава, молекулярноймассы и распределения мономерных звеньев в цепи (статистических, градиентных,блок-градиентных, блок-статистических и блочных).3. Впервые установлены закономерности полимеризации винилацетата в присутствиитритиокарбонатов и основные причины замедления этого процесса (реакции обрыва сучастиеминтермедиатов),найденыусловиядлясинтезаузкодисперсногополивинилацетата.4.
Установлено влияние микроструктуры цепи и композиционной однородности нафизико-химическиесвойствасополимеров:поверхностнуюэнергиюпленоксополимеров стирола и н-бутилакрилата, поверхностную активность и способность кагрегации растворов сополимеров на основе стирола и акриловой кислоты.129СПИСОК ЛИТЕРАТУРЫ1.Odian G. Principles of Polymerization (4th ed.). New York: Wiley-Interscience, 2004.832 p.2.Matyaszewski K., Davis T.P.
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