Анализ, классификация и прогноз свойств гумусовых кислот (1098260), страница 36
Текст из файла (страница 36)
>bZiZahglhdkbqghklbZljZabgZ^ey\h^hjhkebChlorellavulgarisGme_\Zywdkihabpby< wdki_jbf_glZo k -qZkh\hc wdkihabpb_c \ dZq_kl\_ l_kl-hldebdZbkihevah\ZebihdZaZl_ev)v/Fm>bZiZahglhdkbqghklbZljZabgZijb-qZkh\hcwdkihabpbb\h^hjhkebijb\_^_ggZjbk 7.23.< ij_^\Zjbl_evguo wdki_jbf_glZo [ueh mklZgh\e_gh qlh ijbbkihevah\Zgbb dhgp_gljZpbb ZljZabgZ \uau\Zxs_c kgb`_gb_ihdZaZl_ey )v/Fm (1.5×10–6 F \g_k_gb_ ]mfmkh\uo dbkehl \iehlv ^hdhgp_gljZpbb f] Ke^_lhdkbpbjmxs_]h^_ckl\byg_hdZau\ZehIjbwlhffZdkbfZevgh_khhlghr_gb_fZkkKZljZabg : ]mfmkh\u_dbkehlukhklZ\eyeh1 : l_ ij_\urZeh lZdh\h_ ^ey wdki_jbf_glh\ k gme_\uf \j_f_g_fwdkihabpbb M\_ebqblv dhgp_gljZpbx ]mfmkh\uo dbkehl [ueh g_evay ba-aZf_rZxs_]h \ebygby gZ j_]bkljZpbx nemhj_kp_gpbb oehjhnbeeZ ihwlhfm^ey mklZgh\e_gby khhlghr_gby ZljZabg : ]mfmkh\u_ dbkehlu jZ\gh]h mf_gvrbeb dhgp_gljZpbx ZljZabgZ < dZq_kl\_ jZ[hq_c gZfb [ueZ \u[jZgZdhgp_gljZpby ZljZabgZ ×10–7 F ijb\h^ysZy d m]g_l_gbxnhlhkbgl_aZChlorella vulgaris.271)Y)Phldhgljheym]g_l_gby Dhgp_gljZpbyZljZabgZ× fheveJbk 7.23.
>bZiZahglhdkbqghklbZljZabgZ^ey\h^hjhkebChlorellavulgaris<j_fywdkihabpbbqZkZ7.6.2 Hij_^_e_gb_dhgklZgl^_lhdkbdZpbbZljZabgZ]mfmkh\ufbdbkehlZfb>ey bkke_^h\Zgby ^_lhdkbpbjmxsbo k\hckl\ ]mfmkh\uo dbkehl ihhlghr_gbx d ZljZabgm ijh\h^beb k_jbx wdki_jbf_glh\ k -o qZkh\uf\j_f_g_f wdkihabpbb k \g_k_gb_f \hajZklZxsbo dhebq_kl\ ]mfmkh\uodbkehl -5. f] Ke ijb ihklhygghc dhgp_gljZpbb ZljZabgZ ×10–6 F\u[jZgghcgZhkgh\ZgbbmklZgh\e_ggh]h^bZiZahgZlhdkbqghklb>ey ijh\_^_gby wdki_jbf_glh\ ih ^_lhdkbdZpbbZljZabgZbkihevah\Zeb\u[hjdm l_o `_ ij_iZjZlh\ ]mfmkh\uo dbkehl qlh b ^ey k\yau\Zgby =D3 NDb =NDihq\ =ND =Db JH<lhjnZ =Dm]ey\\h^y\g___s_ljb ij_iZjZlZ – =ND ihq\_ggh]h jZkl\hjZ Bo \u^_e_gbx m^_eyehkv hkh[h_\gbfZgb_ \ jZ[hl_ =eZ\Z Ij_^iheZ]Zehkv qlh wlb ij_iZjZluij_^klZ\eyxsb_ kh[hc kZfmx gbadhfhe_dmeyjgmx njZdpbx ihq\_gguo]mfmkh\uodbkehlfh]mlh[eZ^Zlv\ukhdhcnbabheh]bq_kdhcZdlb\ghklvxIjh\_^_ggu_ wdki_jbf_glu ihdZaZeb qlh ]mfmkh\u_ dbkehlu kgb`Zeblhdkbqghklv ZljZabgZ \h \k_f bkke_^h\Zgghf ^bZiZahg_ dhgp_gljZpbc GZhkgh\Zgbb ihemq_gguo ^Zgguo aZ\bkbfhklb ihdZaZl_ey )v/Fm hldhgp_gljZpbb]mfmkh\uodbkehlkh]eZkgh^eydZ`^hcbkihevah\Zgghcdhgp_gljZpbb]mfmkh\uodbkehl[uebjZkkqblZguagZq_gbydhwnnbpb_glZ'Lbibqgu_djb\u_^_lhdkbdZpbbijb\_^_gugZjbk 7.24.272'JH<lhjnZ=NDlhjnZ=DI>iZo=NDihq\=DI>e_k=DI>h]Dhgp_gljZpby]mfmkh\uodbkehl×d]&eJbk 7.24.
Djb\u_^_lhdkbdZpbbZljZabgZjZaebqgufb]mfmkh\ufbdbkehlZfb.GZ hkgh\Zgbb ihemq_gguo aZ\bkbfhkl_c dhwnnbpb_glZ ' hldhgp_gljZpbb ]mfmkh\uo dbkehl [ueb jZkkqblZgu dhgklZglu ^_lhdkbdZpbbKOCDZljZabgZ]mfmkh\ufbdbkehlZfblZ[e 7.12).LZ[ebpZ 7.12DhgklZglu^_lhdkbdZpbbZljZabgZ]mfmkh\ufbdbkehlZfbjZaebqgh]hijhbkoh`^_gbybnjZdpbhggh]hkhklZ\Zn = 9, P = 0.95)Ij_iZjZlKOCDed]K=NDlhjnZPHF-T494(8.9±1.4)×105PHF-TH94(5.7±0.9)×105PHF-TT94(1.3±0.2)×106JH<lhjnZPDOM-TH(5.8±0.8)×105PDOM-TT(4.5±0.7)×105NDihq\SFA-Pw96(5.0±0.7)×104SFA-Pp96(5.0±0.8)×104SFA-Pg94(1.4±0.2)×105SFA-Pg96(6.0±0.8)×104SFA-Gw94(5.3±0.8)×105=NDihq\SHF-Co94(7.1±1.1)×105=Dm]e_cCHA-AGK(7.4±1.1)×105Ij_iZjZlKOCDed]K=Dihq\SHA-Pw94(1.2±0.3)×105SHA-Pw96(5.6±0.7)×105SHA-Pp94(1.4±0.4)×105SHA-Pp96(5.5±0.7)×105SHA-Pg94(1.0±0.2)×104SHA-Gw94(2.0±0.3)×105SHA-Gw96(1.4±0.2)×105SHA-Cm94(2.9±0.4)×105SHA-CtV94(3.7±0.6)×105=NDihq\_ggh]hjZkl\hjZSDHF-Pw96(2.1±0.3)×106SDHF-Pp96(1.8±0.2)×106SDHF-Pg96(1.9±0.2)×106=NDijbjh^guo\h^AHF-RMX2(2.9±0.5)×105273DZd \b^gh ba lZ[e =ND \h^guo \uly`_d ihq\ h[eZ^ZebgZb[hevr_c ^_lhdkbpbjmxs_c kihkh[ghklvx ih hlghr_gbx d ZljZabgm;ebadbfb d gbf agZq_gbyfb KHKD oZjZdl_jbah\Zebkv =D m]ey q_jgha_fZ bg_dhlhjuo I> ihq\ H< \h^gh]h wdkljZdlZ lhjnh\ b ij_iZjZlu ND ihq\ijZdlbq_kdbg_kgb`ZeblhdkbqghklvZljZabgZ7.6.3 KjZ\g_gb_k\yau\Zxsbob^_lhdkbpbjmxsbok\hckl\]mfmkh\uodbkehlihhlghr_gbxdZljZabgmKjZ\g_gb_ ihemq_gguo KHKD ZljZabgZ k .HK hij_^_e_ggufb kbkihevah\Zgb_f nbabdh-obfbq_kdbo f_lh^h\ lZ[e 7.12b7.7,Dkhhl\_lkl\_gghihdZaZehqlhKHK \kj_^g_fgZ^\Z-ljbihjy^dZij_\urZebKHKijbwlhfdhwnnbpb_gldhjj_eypbbf_`^mgbfbkhklZ\eyeIjbwlhfZgZeba [ehdh\ ^Zgguo ih k\hckl\Zf ]mfmkh\uo dbkehl b dhgklZglZfbk\yau\Zgby b ^_lhdkbdZpbb ZljZabgZ \uy\be gZebqb_ l_kghc \aZbfhk\yabKHKD k kh^_j`Zgb_f gbadhfhe_dmeyjghc njZdpbb D>Z – ij_^_eijhgbpZ_fhklb de_lhqguo f_f[jZg [Del Agnola et al., 1986] dhwnnbpb_gldhjj_eypbb khklZ\be .
< lh \j_fy ^ey .OC gZb[he__ l_kgZy dhjj_eypbygZ[ex^ZeZkv k kh^_j`Zgb_f ZjhfZlbq_kdbo njZ]f_glh\ &Ar \ ]mfmkh\uodbkehlZoKe_^h\Zl_evgh kjZ\g_gb_ \_ebqbg .HK b KHKD mdZau\Z_l gZ lh qlhk\yau\Zgb_ ZljZabgZ ]mfmkh\ufb dbkehlZfb g_ fh`_l kem`blv hkgh\gufnZdlhjhfhij_^_eyxsbf\_ebqbgm^_lhdkbdZpbbIh-\b^bfhfm\mkeh\byo\g_k_gby ZljZabgZ ij_h[eZ^Zxsbf nZdlhjhf y\ey_lky klbfmebjmxs__^_ckl\b_ ]mfmkh\uo dbkehl ijhy\eyxs__ky lhevdh ijb g_[eZ]hijbylguomkeh\byo kj_^u dhlhjh_ h[km`^Zehkv \ur_ jZa^_e >ZggZy ]bihl_aZih^l\_j`^Z_lkybj_amevlZlZfbwdki_jbf_glh\ih\ebygbx]mfmkh\uodbkehlgZ khklhygb_ nhlhkbgl_lbq_kdh]h ZiiZjZlZ \h^hjhke_c \ mkeh\byo\ha^_ckl\by^jm]bog_]Zlb\guonZdlhjh\kj_^u–ihgb`_gghcl_fi_jZlmjuLZd \ oh^_ ijh\_^_gby lhdkbdheh]bq_kdbo wdki_jbf_glh\ [uehmklZgh\e_gh qlh ijb hilbfZevghc l_fi_jZlmj_ dmevlb\bjh\Zgby \h^hjhkeb(35HK ]mfmkh\u_ dbkehlu g_ h[eZ^Zeb nbabheh]bq_kdhc Zdlb\ghklvx ihhlghr_gbxdoehj_ee_<lh`_\j_fy\ujZ`_ggh_klbfmebjmxs__^_ckl\b_]mfmkh\uo dbkehl hlf_qZehkv ijb ijh\_^_gbb wdki_jbf_glh\ k -qZkh\hcwdkihabpb_c \ g_[eZ]hijbylguo mkeh\byo dmevlb\bjh\Zgby oehj_eeu LZdaZf_lgh_m\_ebq_gb_ihdZaZl_ey)v/FmgZ[ex^Zehkvijb\g_k_gbb]mfmkh\uodbkehl m oehj_eeu \ujZsb\Z_fhc ijb ihgb`_gghc l_fi_jZlmj_ °K\f_klh °K J_amevlZlu ^ey ^\mo ij_iZjZlh\ ijb\_^_gu gZ jbk 7.25.:gZeh]bqgu_ ^Zggu_ [ueb ihemq_gu b ^ey jy^Z ^jm]bo bkke_^h\Zgguoij_iZjZlh\6+$-Pw96, SHA-Pp96, SHA-Pg96, SHA-CtV94, SHA-Gw94).274)Y)PhldhgljheyIjb[eZ]hijbylguomkeh\byo6'+)3Z6'+)3JIjbg_[eZ]hijbylguomkeh\byo6'+)3Z6'+)3Jdhgp_gljZpby=NDf]KeJbk 7.25.
<ha^_ckl\b_ ]mfmkh\uo dbkehl gZ nhlhkbgl_lbq_kdmxZdlb\ghklv Chlorella vulgaris ijb ihgb`_gghc °K bghjfZevghc °K l_fi_jZlmjZo dmevlb\bjh\Zgby<j_fywdkihabpbb–qZkZIh^h[gu_wnn_dlufh]mlkem`blvih^l\_j`^_gb_fba\_klgh]hl_abkZhkihkh[ghklb ]mfmkh\uo dbkehl ih\urZlv h[smx g_ki_pbnbq_kdmxkhijhlb\ey_fhklvhj]Zgbafh\knhjfmebjh\Zggh]hOjbkl_\hckkhljm^gbdZfb gZ hkgh\_ fgh]hqbke_gguo hiulh\ k jZkl_gbyfb [Ojbkl_\Z b^j 1968] <hafh`guf f_oZgbafhf h[tykgyxsbf klbfmebjmxs__\ha^_ckl\b_ ]mfmkh\uo dbkehl ijb g_[eZ]hijbylguo mkeh\byo kj_^uy\ey_lky m\_ebq_gb_ ijhgbpZ_fhklb de_lhqguo f_f[jZg dZd j_Zdpby gZ^_ckl\b_ klj_kkhjZ – \ gZrbo wdki_jbf_glZo ijb \g_k_gbb ZljZabgZ bebkgb`_gbb l_fi_jZlmju GZebqb_ l_kghc dhjj_eypbb f_`^m .OCD bkh^_j`Zgb_f \ ]mfmkh\uo dbkehlZo gbadhfhe_dmeyjghc njZdpbb D>Zk\b^_l_evkl\m_l\ihevam^Zggh]hij_^iheh`_gby>ey mklZgh\e_gby dhgdj_lgh]h f_oZgbafZ ^_lhdkbdZpbb ZljZabgZ]mfmkh\ufb dbkehlZfb gZijbf_j hij_^_e_gb_ ki_pbnbq_kdbo kZclh\^_ckl\by ]mfmkh\uo dbkehl g_h[oh^bfh ijh\_^_gb_ ^hihegbl_evguowdki_jbf_glh\ \dexqZxsbo ^_lZevgh_ bkke_^h\Zgb_ nbabheh]bq_kdhcZdlb\ghklb ]mfmkh\uo dbkehl Z lZd`_ \hafh`ghklv bo ihklmie_gby \ l_klhj]Zgbafu***LZdbf h[jZahf \ j_amevlZl_ \uiheg_ggh]h dhfie_dkZ wdki_jbf_glh\kbkl_fZlbq_kdb bkke_^h\Zgu k\yau\Zxsb_ b ^_lhdkbpbijmxsb_ k\hckl\Z]mfmkh\uo dbkehl ih hlghr_gbx d Hg(II) I:M b ZljZabgm ^eyij_^klZ\bl_evguo \u[hjhd ]mfmkh\uo dbkehl jZaebqgh]h ijhbkoh`^_gby bnjZdpbhggh]h khklZ\Z GZ hkgh\Zgbb ijbf_g_gby dhgp_ipbb275dhfie_dkhh[jZah\Zgby/k\yau\Zgby ^ey hibkZgby ijhp_kkh\ ^_lhdkbdZpbbly`_euo f_lZeeh\ b hj]Zgbq_kdbo wdhlhdkbdZglh\ ]mfmkh\ufb dbkehlZfbij_^eh`_g kihkh[ dhebq_kl\_gghc hp_gdb ^_lhdkbpbjmxsbo k\hckl\]mfmkh\uo dbkehl k ihfhsvx dhgklZgl ^_lhdkbdZpbb ?^bgucf_lh^heh]bq_kdbc ih^oh^ ^ey hp_gdb k\yau\Zxsbo b ^_lhdkbpbjmxsbok\hckl\ ]mfmkh\uo dbkehl bkihevah\Zg \i_j\u_ GZ hkgh\Zgbb kjZ\g_gbydhgklZgl k\yau\Zgby b ^_lhdkbdZpbb k^_eZg \u\h^ h dhfie_dkhh[jZah\Zgbbk\yau\Zgbb dZd hkgh\ghf f_oZgbaf_ ^_lhdkbdZpbb Hg(II) b I:M]mfmkh\ufb dbkehlZfb b h ijbgpbibZevgh bghc ijbjh^_ bo^_lhdkbpbjmxs_]h ^_ckl\by ih hlghr_gbx d ZljZabgm Knhjfbjh\Zgh[rbjguc fZkkb\ ijbagZdh\ k\hckl\ – dhgklZgl k\yau\Zgby mklhcqb\hklbdhfie_dkh\ b ^_lhdkbdZpbb qlh iha\hebeh i_j_clb d aZ\_jrZxs_fm wlZimjZ[hlu–ihemq_gbxijh]ghklbq_kdbofh^_e_c³kljh_gb_-k\hckl\h´2768.
=eZ\Z8IJH=GHAK<HCKL<=MFMKH<UODBKEHLKBKIHEVAH<:GB?F>?KDJBILHJH<KHKL:<:< j_amevlZl_ \uiheg_gby ij_^u^ms_]h [ehdZ bkke_^h\Zgbc [uebkha^Zgu\k_g_h[oh^bfu_ij_^ihkuedb^eyj_r_gby\Z`ghcl_hj_lbq_kdhcbijZdlbq_kdhc aZ^Zqb – jZajZ[hldb ijh]ghklbq_kdbo fh^_e_c ³khklZ\ –k\hckl\h´ Kha^Zgb_ lZdbo fh^_e_c fh`_l kem`blv l_hj_lbq_kdbf [Zabkhf^ey jZajZ[hldb kbkl_fu kdjbgbg]Z ]mfmkh\uo dbkehl hkgh\Zggh]h gZhij_^_e_gbb bo khklZ\Z Wlh iha\hebl hkms_kl\eylv p_e_\hc ihbkdij_iZjZlh\h[eZ^ZxsbofZdkbfZevgufbk\yau\Zxsbfbb/beb^_lhdkbpbjmxsbfbk\hckl\Zfbihhlghr_gbxdjZaebqgufwdhlhdkbdZglZfg_ ijh\h^y wdki_jbf_glh\ ih k\yau\Zgbx beb ^_lhdkbdZpbb Ihy\e_gb_lZdbo fh^_e_c kihkh[kl\h\Zeh [u jZkrbj_gbx kn_ju ijbf_g_gbyijbjh^gh]h ]mfbgh\h]h kujvy m]hev lhjn kZijhi_ev \ p_eyoj_dmevlb\Zpbb aZ]jyag_gguo kj_^ Z lZd`_ y\behkv [u g_h[oh^bfhcij_^ihkuedhc ^ey jZajZ[hldb e_dZjkl\_gguo ij_iZjZlh\ gZ hkgh\_]mfbgh\uo\_s_kl\Ki_pbnbdhc ihemq_ggh]h \ jZ[hl_ fZkkb\Z ^Zgguo y\ey_lky \ukhdZyjZaf_jghklv fZljbpu ^_kdjbilhjh\ khklZ\Z qbkeh klhe[ph\ > bkjZ\gbfh_ k g_c qbkeh ij_iZjZlh\ \ \u[hjd_ (qbkeh kljhd -26 \aZ\bkbfhklb hl dhebq_kl\Z gZc^_gguo dhgklZgl k\yau\Zgby Kha^Zgb_ijh]ghklbq_kdbo fh^_e_c k bkihevah\Zgb_f lZdbo fZkkb\h\ ^Zgguo lj_[m_lijbf_g_gby f_lh^h\ iha\heyxsbo kgbablv jZaf_jghklv fZljbpug_aZ\bkbfuoi_j_f_gguo\gZr_fkemqZ_–^_kdjbilhjh\khklZ\Z>ey wlhc p_eb bkihevah\Zeb f_lh^ fgh`_kl\_gghc j_]j_kkbb FJ\\h^y h]jZgbq_gb_ gZ dhebq_kl\h qe_gh\ \ mjZ\g_gbb j_]j_kkbb bij_^mkfZljb\Zy\u[hjhilbfZevguo^_kdjbilhjh\iml_fboZ\lhfZlbq_kdh]hi_j_[hjZ Z\lhj Ze]hjblfZ b ijh]jZffu – : < Dm^jy\p_\ b f_lh^ufgh]hdhfihg_glgh]h ZgZebaZ – j_]j_kkbb gZ ]eZ\guo dhfihg_glZo J=D b^jh[gh]h f_lh^Z gZbf_gvrbo d\Z^jZlh\ >FGD H[Z f_lh^Z iha\heyxlkgbablvjZaf_jghklvfZljbpubkoh^guo^ZgguojZaeZ]Zy__gZdhfihg_glug_ kgb`Zy ijb wlhf dhebq_kl\h bkoh^guo ^_kdjbilhjh\ < f_lh^_ J=DjZaeh`_gb_ bkoh^ghc fZljbpu ijh\h^yl lhevdh k mq_lhf __ \gmlj_gg_ckljmdlmju[>m[jh\b^j 2000]<f_lh^_>FGDhkms_kl\ey_lkykh\f_klgh_jZaeh`_gb_dZdfZljbpu^_kdjbilhjh\lZdbijh]ghabjm_fuok\hckl\ [Geladiand Kowalski, 1986, Gunst and Maston, 1980] Wlh ih\urZ_l gZ^_`ghklvihemqZ_fhcijh]ghklbq_kdhcfh^_eb [Lindberg at al, 1983].< ^Zevg_cr_c jZ[hl_ bkihevah\Zeb \k_ ljb f_lh^Z GZ \uoh^_ \k_ hgb^Zxl ijh]ghklbq_kdmx fh^_ev dhlhjZy ij_^klZ\ey_l kh[hc ebg_cgmx FJ277J=D b >FGD beb g_ebg_cgmx FJ nmgdpbhgZevgmx aZ\bkbfhklvijh]ghabjm_fh]hk\hckl\Zhl^_kdjbilhjh\8.1 Dhjj_eypbhggZy\aZbfhk\yav^_kdjbilhjh\khklZ\Zbijh]ghabjm_fuok\hckl\JZkq_l ijh]ghklbq_kdbo fh^_e_c ij_^\Zjyeb hp_gdhc gZebqbydhjj_eypbhgguo\aZbfhk\ya_cf_`^m^_kdjbilhjZfbkhklZ\ZgZ[hjdhlhjuo^ey \k_o \u[hjhd [ue klZg^Zjlguf b \dexqZe \k_ ljb mjh\gy ^_kdjbilhjh\aZbkdexq_gb_f\u[hjdb^eyI:M]^_gZ[hj^_kdjbilhjh\[ue^hiheg_gaZkq_l ε b ijh]ghabjm_fufb k\hckl\Zfb – dhgklZglZfb k\yau\Zgby b^_lhdkbdZpbbHg(II)I:MPy, Flt, An)bZljZabgZ ]mfmkh\ufbdbkehlZfbIjh\_^_gb_ dhjj_eypbhggh]h ZgZebaZ ihdZaZeh qlh l_kgu_dhjj_eypbhggu_ \aZbfhk\yab f_`^m dhgklZglZfb mklhcqb\hklb dhfie_dkh\Hg(II)k]mfmkh\ufbdbkehlZfbbbgl_]jZevgufb^_kdjbilhjZfbkhklZ\Z\k_omjh\g_chlkmlkl\mxl>ey dhgklZgl k\yau\Zgby b ^_lhdkbdZpbb I:M gZ[ex^Zehkv gZebqb_l_kghc dhjj_eypbhgghc \aZbfhk\yab k ijyfufb b dhk\_ggufb ihdZaZl_eyfbkh^_j`Zgby ZjhfZlbq_kdbo njZ]f_glh\ \ khklZ\_ ]mfmkh\uo dbkehl (CAr,∑CAr, H/C, ε* Ijbf_j lZdhc dhjj_eypbhgghc aZ\bkbfhklb ^ey dhgklZglk\yau\ZgbyI:Mijb\_^_ggZjbk 8.1.3\Dhk [ ed]Kr )OWU $QU &$U Jbk 8.1.