Анализ, классификация и прогноз свойств гумусовых кислот (1098260), страница 34
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2&K^_eZ_f ^hims_gb_ qlh lhdkbqghklv jZkl\hjZ ijyfh ijhihjpbhgZevgZdhgp_gljZpbbWLLh]^Zlhdkbqghklv\ijbkmlkl\bbWLaZibr_lkydZd(7.53)7WL = N × & WL]^_k –dhwnnbpb_glijhihjpbhgZevghklbLhdkbqghklv WL \ ijbkmlkl\bb ]mfmkh\uo dbkehl ZgZeh]bqgh fh`ghaZibkZlvdZd(7.54)TWL=ND = k×>WL@Ih^klZ\eyy7.53b7.53\mjZ\g_gb_7.50ihemqZ_f>WL@' = −(7.55)= − αK WL<ujZ`Zy ^hex g_k\yaZggh]h WL α q_j_a dhgp_gljZpbx ]mfmkh\uodbkehlgZhkgh\ZgbbaZ\bkbfhklbKOChlα (1.26ihemqZ_f'=. 2& ' × & =ND + . 2& ' × & =ND(7.56)Nb]mjbjmxsmx \ ^Zgghf mjZ\g_gbb dhgklZglm hij_^_ey_fmx \b^hfaZ\bkbfhklb wnn_dlZ ^_lhdkbdZpbb hl dhgp_gljZpbb ]mfmkh\uo dbkehl fugZa\ZebdhgklZglhc^_lhdkbdZpbb– KOCDHgZ[m^_lwd\b\Ze_glgZdhgklZgl_obfbq_kdh]hk\yau\ZgbyWL-=NDlhevdh\lhfkemqZ__keb\_ebqbgZwnn_dlZ^_lhdkbdZpbbD aZ\bkblhl_^bgkl\_ggh]hnZdlhjZ–dhgp_gljZpbbk\h[h^ghcnhjfu WL GZ ijZdlbd_ KOCD fh`gh jZkkqblZlv iml_f ZiijhdkbfZpbbwdki_jbf_glZevguo aZ\bkbfhkl_c ' hl dhgp_gljZpbb ]mfmkh\uo dbkehlmjZ\g_gb_f 7.56 Ihwlhfm j_amevlZlu \k_o lhdkbdheh]bq_kdbowdki_jbf_glh\ij_^klZ\eyeb\\b^_khhl\_lkl\mxsbodjb\uo^_lhdkbdZpbb253Bkihevah\Zgb_ ^Zggh]h bgl_jij_lZpbhggh]h ZiiZjZlZ ij_^ty\eyeh\iheg_dhgdj_lgu_lj_[h\ZgbydihklZgh\d_wdki_jbf_glh\ih^_lhdkbdZpbbLZd ^ey jZkq_lZ dZ`^hc lhqdb gZ djb\hc ^_lhdkbdZpbb g_h[oh^bfh [uehbaf_jblv l_kl-hldebd \ q_luj_o l_kl-kbkl_fZo dhgljhev WL ijbjZ[hq_cdhgp_gljZpbb\hlkmlkl\b_]mfmkh\uodbkehl]mfmkh\u_dbkehluijb l_klbjm_fhc dhgp_gljZpbb \ hlkmlkl\b_ WL WL jZ[hqZydhgp_gljZpby\ijbkmlkl\bbl_klbjm_fhcdhgp_gljZpbb]mfmkh\uodbkehl< k\yab k baeh`_gguf \k_ ^Zevg_crb_ wdki_jbf_glu ih ^_lhdkbdZpbbijh\h^bebkv\khhl\_lkl\bbkhibkZggufblj_[h\Zgbyfb7.4 Bkke_^h\Zgb_^_lhdkbpbjmxsbok\hckl\]mfmkh\uodbkehlihhlghr_gbxdHg(II)7.4.1 <u[hjmkeh\bc[bhl_klbjh\Zgby^eybamq_gby^_lhdkbdZpbb+J,,]mfmkh\ufbdbkehlZfb<hlebqb_hl[hevrbgkl\Z^jm]boly`_euof_lZeeh\jlmlvijZdlbq_kdbg_\klj_qZ_lky\ijbjh^guokj_^Zo\nhjf_k\h[h^gh]hbhgZHg2+Hkgh\gu_nhjfukms_kl\h\Zgbyjlmlb(II)\hlkmlkl\b_]mfmkh\uodbkehl– Hg(OH)2bHgCl2 Ijb wlhf khhlghr_gb_ +J2+2:HgCl2 aZ\bkbl hl jG b dhgp_gljZpbboehjb^-bhgh\jbk 7.13).S&O+J&O+J&O+J2++J&OS++JJbk 7.13.
Nhjfu kms_kl\h\Zgby +J,, \ aZ\bkbfhklb hl jG bdhgp_gljZpbboehjb^-bhgh\LZdbf h[jZahf lhdkbq_kdh_ ^_ckl\b_ fh]ml hdZau\Zlv k\h[h^guc bhgHg qlh fZeh\_jhylgh ihkdhevdm _]h ^hey \ ijbjh^guo kj_^Zo djZcg_g_agZqbl_evgZ +J2+2 beb +J&O2 ijbq_f bo lhdkbq_kdh_ ^_ckl\b_ fh`_ljZaebqZlvky[Mason et al., 1996]Ihwlhfm\i_j\mxhq_j_^vg_h[oh^bfh[uehmklZgh\blv dZdZy ba \ur_mdZaZgguo nhjf hdZau\Z_l gZb[hevr__lhdkbq_kdh_ ^_ckl\b_ k l_f qlh[u bkke_^h\Zlv ^_lhdkbpbjmxsb_ k\hckl\Z]mfmkh\uodbkehlihhlghr_gbxdwlhcnhjf_2+254Hij_^_e_gb_ ^bZiZahgh\ lhdkbqghklb +J2+2 b +J&O2 >eybkke_^h\Zgby ^_lhdkbpbjmxs_]h ^_ckl\by ]mfmkh\uo dbkehl ih hlghr_gbxd +J,, ijbf_gyeky f_lh^ Zev]heh]bq_kdh]h l_klbjh\Zgby L_kl-h[t_dlhfkem`beZ h^ghde_lhqgZy \h^hjhkev Chlorella pyrenoidosD \u[hj dhlhjhc [ueh[mkeh\e_g hljZ[hlZgghklvx khhl\_lkl\mxs_c f_lh^bdb [bhl_klbjh\Zgby>Iheugh\ @ < dZq_kl\_ l_kl-nmgdpbb bkihevah\Zeb hlghkbl_evguc\uoh^ i_j_f_gghc nemhj_kp_gpbb 5 = Fv/Fm oZjZdl_jbamxsbc ^hexih]ehs_gghc k\_lh\hc wg_j]bb gZijZ\ey_fmx gZ nhlhkbgl_a <j_fywdkihabpbbkhklZ\behqZkZL_kl-kj_^u ^ey bamq_gby lhdkbqghklb +J&O2 b +J2+2 ]hlh\beb gZhkgh\_kj_^uLZfby fF.123b fF0J624\ZjvbjmyjGbkh^_j`Zgb_.&O JZkij_^_e_gb_ Hg(II) ih nhjfZf kms_kl\h\Zgby \ l_kl-kj_^ZojZkkqblu\Zeb gZ hkgh\Zgbb ebl_jZlmjguo ^Zgguo ih khhl\_lkl\mxsbfdhgklZglZf mklhcqb\hklb >SCDB], mkj_^g_gguf b ijb\_^_gguf d bhgghckbe_ kj_^u ^ey [bhl_klbjh\Zgby ih mjZ\g_gbx >w\bkZ lZ[e <oh^_lhdkbdheh]bq_kdh]hwdki_jbf_glZjGg_kdhevdhbaf_gyeky\j_amevlZl_`bag_^_yl_evghklb \h^hjhke_c Ihwlhfm jZkij_^_e_gb_ Hg(II) jZkkqblu\Zebkmq_lhfjGjZkl\hjZ\dhgp_[bhl_klbjh\ZgbyLZ[ebpZ 7.8Kj_^u^eyl_klbjh\ZgbylhdkbqghklbjlmlbII)DhgpKCljG\gZqZe_dhgp_HgCl2:Hg(OH)2\dhgp_l_klbjh\Zgbyl_klbjh\Zgby107.3 / 6.9-7.50/01.6×10–8–1.6×10–920.01 F6.4 / 5.9-6.87200-1142.5×10–10[Hg2+]/C(Hg2+)DZd \b^gh ba lZ[ebpu \ kj_^_ hkgh\gZy nhjfZ jlmlb Hg(OH)2 \kj_^_ 2 – HgCl2 >hey k\h[h^gh]h bhgZ \ h[_bo kj_^Zo g_agZqbl_evgZJ_amevlZlu Zev]heh]bq_kdh]h l_klbjh\Zgby h[_bo kj_^ ijb\_^_gu gZjbk 7.14.2555hldhgljhey+J2++J&O&+JfdFJbk 7.14.
Lhdkbq_kdh_ ^_ckl\b_ HgCl2 b Hg(OH)2 gZ \h^hjhkevChlorella pyrenoidosa ^ey HgCl2 ijb\_^_gu kj_^gb_agZq_gbyih^\mfbaf_j_gbyfDZd \b^gh ba jbk lhdkbqghklv +J,, \ h[_bo kj_^Zo aZf_lghjZaebqZ_lkyKhhl\_lkl\mxsb_^bZiZahgulhdkbqghklbijb\_^_gu\lZ[e 7.9.LZ[ebpZ 7.9>bZiZahgulhdkbqghklb+J(OH)2bHgCl2NhjfZHg(OH)2HgCl2WD0fdF+J,,WD50fdF+J,,WD100fdF+J,,416g_^hklb]gmlZ0.30.60.8DZd\b^ghbalZ[e ^eybkke_^m_fh]hl_kl-h[t_dlZ+J&O2[he__q_fgZ ihjy^hd lhdkbqg__ q_f +J2+2 Wlh ]h\hjbl h lhf qlh mjh\_gvlhdkbqghklbkj_^uij_bfms_kl\_ggh[m^_lh[mkeh\e_gkh^_j`Zgb_f+J&O2.MdZaZggh_ jZaebqb_ \ lhdkbq_kdhf ^_ckl\bb +J&O2 b +J2+2 fh`_l[ulv h[mkeh\e_gh eb[h khj[pb_c +J2+2 gZ kl_gdZo dmevlb\ZlhjZkhijh\h`^Zxs_cky kgb`_gb_f _]h dhgp_gljZpbb \ l_kl-kbkl_f_ eb[hjZaebqb_flhdkbq_kdh]h^_ckl\by+J&O2b+J2+2.>ey ijh\_jdb ^Zgguo ij_^iheh`_gbc [ueh bamq_gh jZkij_^_e_gb_+J,, f_`^m [bhfZkkhc \h^hjhkeb kj_^hc ^ey [bhl_klbjh\Zgby b kl_gdZfbdmevlb\ZlhjZ >ey wlh]h \h \k_o lj_o mdZaZgguo dhfihg_glZo l_kl-kbkl_fuhij_^_eyeb kh^_j`Zgb_ +J,, ih hdhgqZgbb lhdkbdheh]bq_kdh]hwdki_jbf_glZ Ihemq_ggu_ ^Zggu_ ih jZkij_^_e_gbx +J,, \ l_kl-kbkl_fZoijb\_^_gugZjbk bjbk 7.16.Dhebq_kl\h+J,,gfhev256jjkl_gdZ&KOBkoh^gh_dhebq_kl\h+J,,gfhevDhebq_kl\h+J,,gfhevJbk 7.15.
JZkij_^_e_gb_jlmlbf_`^mdhfihg_glZfbl_kl-kbkl_fu\kj_^_k+J2+)2.jjkl_gdZ&KOBkoh^gh_dhebq_kl\h+J,,gfhevJbk 7.16.JZkij_^_e_gb_ jlmlb f_`^m dhfihg_glZfb l_klkbkl_fu\kj_^_k+J&O2.Ba ijb\_^_gguo ^Zgguo \b^gh qlh \ h[_bo l_kl-kj_^Zo gZ kl_gdZokhj[bjm_lky g_ [he__ hl \\_^_ggh]h +J,, ihwlhfm jZaebqb_ \lhdkbqghklb +J2+2 b +J&O2 g_ fh`_l [ulv h[mkeh\e_gh jZaebqghckhj[pb_cgZkl_gdZodmevlb\ZlhjZDjhf_lh]hgZdhie_gb_+J,,\[bhfZkk_\h^hjhkeb kms_kl\_ggh aZ\bk_eh hl gZebqby oehjb^-bhgh\ \ kj_^_ LZd \hlkmlkl\b_ oehjb^h\ ^\_ lj_lb \k_c h[gZjm`_gghc +J,, gZoh^behkv \[bhfZkk_ oehj_eeu \ lh \j_fy dZd \ ijbkmlkl\bb oehjb^h\ wlZ \_ebqbgZkhklZ\eyeZ f_g__ iheh\bgu Ke_^m_l aZf_lblv qlh ^ey +J&O2 ijb WD0(0.3 fdF oehj_eeZ gZdZieb\ZeZ jlmlb hl kmohc fZkku < lh `_ \j_fy^ey +J2+2 ijb WD0 (3 fdF \h^hjhkev gZdZieb\Z_l jlmlb hl kmohcfZkku Wlh ]h\hjbl h lhf qlh jZaebqb_ \ lhdkbq_kdhf ^_ckl\bb +J&O2 b257Hg(OH)2 h[mkeh\e_gh jZaebqguf mjh\g_f lhdkbqghklb wlbo kh_^bg_gbc ^eybkke_^m_fh]hl_kl-h[t_dlZIjb khihklZ\e_gbb dhebq_kl\Z \\_^_gghc b gZc^_gghc +J,, [uehh[gZjm`_gh qlh dZd \ kj_^_ k +J2+2 lZd b k +J&O2 \ oh^_lhdkbdheh]bq_kdh]hwdki_jbf_glZijhbkoh^ylihl_jbjlmlb<i_j\hfkemqZ_hgb khklZ\eyxl ± \h \lhjhf ± lh _klv g_^hhij_^_e_ggh_dhebq_kl\h +J,, \ h[_bo kj_^Zo kh\iZ^Z_l k lhqghklvx ^h hrb[dbwdki_jbf_glZ Ki_pbZevguo bkke_^h\Zgbc h ijbqbgZo wlbo ihl_jv g_ijh\h^beb h^gZdh fh`gh ij_^iheZ]Zlv qlh \ mkeh\byo wdki_jbf_glZ qZklv+J,, \hkklZgZ\eb\Z_lky \h^hjhkevx ^h we_f_glZjghc b \u^m\Z_lky ijb[Zj[hlbjh\Zgbb\ha^moZq_j_al_kl-kbkl_fmLZdbfh[jZahfihdZaZghqlhlhdkbqghklvHgCl2^ey\h^hjhkeb Chlorellapyrenoidosa gZ ihjy^hd \ur_ q_f Hg(OH)2 Wlhl nZdl \Z`_g ^eyij_^kdZaZgbylhdkbqghklbHg,,\\h^guokj_^ZoihkdhevdmihdZau\Z_lqlhlhdkbqghklv h^gbo b l_o `_ dhgp_gljZpbc Hg,, fh`_l jZaebqZlvky \aZ\bkbfhklbhlkhklZ\Zijbjh^guo\h^>eyihemq_gby^hklh\_jghcaZ\bkbfhklblhdkbq_kdh]hwnn_dlZHgCl2hldhgp_gljZpbb HgCl2 g_h[oh^bfh [ueh mq_klv dhe_[Zgby qm\kl\bl_evghklb\h^hjhkeb \ jZaguo wdki_jbf_glZo K wlhc p_evx baf_j_gguc lhdkbq_kdbcwnn_dl ghjfbjh\Zeb lZdbf h[jZahf qlh[u ijb hij_^_e_gghc dhgp_gljZpbblhdkbdZglZ \ ^Zevg_cr_f [m^_f gZau\Zlv __ jZ[hq_c agZq_gb_hlghkbl_evghc lhdkbqghklb khklZ\eyeh Z \ hlkmlkl\b_ lhdkbdZglZ >eywlh]hhlghkbl_evgmxlhdkbqghklv\ujZ`Zebke_^mxsbfh[jZahf7=50 −5W,50 −5E(7.57)]^_ 5t – l_kl-hldebd \ ijbkmlkl\bb lhdkbdZglZ 5b – l_kl-hldebd \ijbkmlkl\bbjZ[hq_cdhgp_gljZpbblhdkbdZglZ50 –l_kl-hldebd\dhgljhe_>ey +J&O2 \ dZq_kl\_ jZ[hq_c [ueZ \u[jZgZ dhgp_gljZpby fdFWD100 Ihemq_ggZy aZ\bkbfhklv L hl dhgp_gljZpbb +J&O2 ihdZaZgZ gZjbk 7.17.Ihemq_ggmx aZ\bkbfhklv Ziijhdkbfbjh\Zeb k ihfhsvx ebg_cghcnmgdpbb r = Ijb ihkljh_gbb Ziijhdkbfbjmxs_c nmgdpbb ^ey \k_]h^bZiZahgZ dhgp_gljZpbc +J&O2 hl ^h jZ[hq_c mqblu\Zeb qlh lhdkbdZglgb`_g_dhcihjh]h\hcdhgp_gljZpbbg_ijhy\eyelhdkbq_kdh]h^_ckl\byl_L = < j_amevlZl_ ZiijhdkbfbjmxsZy nmgdpby ^ey hibkZgby lhdkbqkdh]h^_ckl\by+J&O2\^bZiZahg_dhgp_gljZpbchl^h fdFbf__lke_^mxsbc\b^(7.58)T = max(0, 2 × C(HgCl2) – 0.6)258LU &+J&OfdFJbk 7.17.
AZ\bkbfhklv hlghkbl_evghc lhdkbqghklb +J&O2 hldhgp_gljZpbb7.4.2 Hij_^_e_gb_dhgklZgl^_lhdkbdZpbb+JII)]mfmkh\ufbdbkehlZfbHp_gdm ^_lhdkbpbjmxsbo k\hckl\ ]mfmkh\uo dbkehl ijh\h^beb ihhlghr_gbx d gZb[he__ lhdkbqghfm +J&O2 Wdki_jbf_glu ih ^_lhdkbdZpbbijh\h^beb \ kj_^_ kh^_j`Zs_c F .&O b jZ[hqmx dhgp_gljZpbx +J&O20.8 fdF WD100 jbk >bZiZahg dhgp_gljZpbc ]mfmkh\uo dbkehlkhklZ\eye -25 f]e qlh oZjZdl_jgh ^ey ih\_joghklguo \h^ >EZibg bDjZkxdh\ 1991@<oh^_wdki_jbf_glh\baf_jyebbgl_gkb\ghklvnhlhkbgl_aZ\h^hjhkeb\mkeh\byoihklhygghc fdFdhgp_gljZpbb+J&O2bjZaebqguodhgp_gljZpbc ]mfmkh\uo dbkehl Qlh[u dhebq_kl\_ggh hoZjZdl_jbah\Zlvwnn_dl ^_lhdkbdZpbb jZkkqblu\Zeb dhwnnbpb_gl ' \ khhl\_lkl\bb k >ey wlh]h ko_fZ ijh\_^_gby lhdkbdheh]bq_kdbo wdki_jbf_glh\ \dexqZeZ \k_[y gZjy^m k dhgljhevguf \ZjbZglhf [_a +J&O2 b ]mfmkh\uo dbkehl\ZjbZglu k \g_k_gb_f +J&O2 b +J&O2]mfmkh\u_ dbkehlu <ZjbZgl \g_k_gby]mfmkh\uodbkehl[_a+J&O2himkdZeb\k\yabkmdZaZgguf\ur_hlkmlkl\b_fkh[kl\_ggh]h^_ckl\by]mfmkh\uodbkehlgZoehj_eem\\u[jZgguomkeh\byowdki_jbf_glZ< wdki_jbf_glZo ih ^_lhdkbdZpbb bkihevah\Zeb lm `_ \u[hjdmij_iZjZlh\ qlh b ijb bamq_gbb dhfie_dkhh[jZamxsbo k\hckl\ dhlhjZykhklhyeZ ba ij_iZjZlh\ jZaebqgh]h ijhbkoh`^_gby b njZdpbhggh]hkhklZ\ZJH<\h^=ND\h^=ND^hgguohleh`_gbc=Dm]ey=NDlhjnZ=Dihq\b=NDihq\Ijh\_^_ggu_ wdki_jbf_glu ihdZaZeb qlh ih^Z\eyxs__ [hevrbgkl\hij_iZjZlh\ ]mfmkh\uo dbkehl h[eZ^Zeh ^_lhdkbpbjmxsbf ^_ckl\b_f ih259hlghr_gbx d +J&O2 Lbibqgu_ djb\u_ ^_lhdkbdZpbb ^ey ij_iZjZlh\]mfmkh\uodbkehljZaebqgh]hijhbkoh`^_gbyijb\_^_gZgZjbk 7.18.'=NDlhjnZ=NDihq\=Dihq\=ND\h^=Dm]eyDhgp_gljZpby=NDf]eJbk 7.18.
AZ\bkbfhklv wnn_dlZ ^_lhdkbdZpbb +J&O2 (0.8 fdF hldhgp_gljZpbb]mfmkh\uodbkehljZaebqgh]hijhbkoh`^_gbyIhemq_ggu_ aZ\bkbfhklb bkihevah\Zeb ^ey jZkq_lZ dhgklZgl^_lhdkbdZpbb H^gZdh \\b^m g_ebg_cghklb ^bZiZahgZ lhdkbqghklb HgCl2,ijb\_^_ggu_gZjbkaZ\bkbfhklbg_Ziijhdkbfbjh\Zebnmgdpb_c50),Z jZkkqblu\Zeb agZq_gby khhl\_lkl\mxsbo dhgklZgl ^_lhdkbdZpbb ^eydZ`^hcwdki_jbf_glZevghclhqdbbkihevamyhibkZggucgb`_ih^oh^Mqblu\Zeb qlh mf_gvr_gb_ lhdkbqghklb HgCl2 \ ijbkmlkl\bb]mfmkh\uodbkehlkhhl\_lkl\m_lkgb`_gbxjZ\gh\_kghcdhgp_gljZpbbHgCl2\j_amevlZl_ijhl_dZgbyj_ZdpbbHgCl2JKP4+JJKP&O–,lhdkbq_gg_lhdkbq_g(7.59)Lh]^Z ba ^Zgguo ih kgb`_gbx lhdkbqghklb HgCl2 fh`gh jZkkqblZlvdhgklZglmeb]Zg^gh]hh[f_gZ> +J3&P @ ⋅ > &O − @. 3&P &O => +J&O @ ⋅ > 3&P @−(7.60)>hfgh`Zy dhgklZglm gZ dhgklZglm mklhcqb\hklb HgCl2 ihemqZeb\ujZ`_gb_ ^ey jZkq_lZ dhgklZglu ^_lhdkbdZpbb HgCl2 ]mfmkh\ufbdbkehlZfb(7.61)KD(JKP) = K(JKP&O)⋅β(HgCl2).?keb kgb`_gb_ lhdkbqghklb h[mkeh\e_gh lhevdh k\yau\Zgb_f Hg(II) \g_lhdkbqgu_dhfie_dku.D(JKP)[m^_lwd\b\Ze_glgZ.(JKP).Qlh[u jZkkqblZlv dhgklZglu eb]Zg^gh]h h[f_gZ jZ\gh\_kgmxdhgp_gljZpbx [HgCl2] hij_^_eyeb ba ^bZiZahgZ lhdkbqghklb HgCl2 (7.58) Z260jZ\gh\_kgmx dhgp_gljZpbx Cl b JKP ijbjZ\gb\Zeb d h[s_c ihkdhevdmoehjb^-bhgu gZoh^ylky \ [hevrhf ba[uld_ JZ\gh\_kgmx dhgp_gljZpbxHgJKP hij_^_eyeb ba mjZ\g_gby fZl_jbZevgh]h [ZeZgkZ \ ij_^iheh`_gbbqlh\kyjlmlvjZkij_^_ey_lkyf_`^mdhfie_dkZfbk]mfmkh\ufbdbkehlZfbboehjb^hf–>+JJKP@ &+J– [HgCl2](7.62)Ih^klZ\eyy b \ ihemqZ_f nhjfmem ^ey jZkq_lZdhgklZglueb]Zg^gh]hh[f_gZbawdki_jbf_glZevguo^Zgguo.
3&P &O − =K +J − > +J&O @ ⋅ K &O.> +J&O @ ⋅ K 3&P (7.63)Kh]eZkgh ijb\_^_gghc ko_f_ ^ey dZ`^hc wdki_jbf_glZevghc lhqdbjZkkqblu\ZebdhgklZglumklhcqb\hklbdhfie_dkh\]mfmkh\uodbkehlkHg(II)ba ^Zgguo ih ^_lhdkbdZpbb .D(JKP) bo eh]Zjbnfbjh\Zeb mkj_^gyeb bdhjj_dlbjh\Zeb ih mjZ\g_gbx >w\bkZ gZ bhggmx kbem kj_^u ^ey[bhl_klbjh\Zgby fhev dhjj_dlbjmxsbc nZdlhj – Ihemq_ggu_agZq_gby .D(JKP) ijb\_^_gu \ lZ[e KhihklZ\e_gb_ .D(JKP) kK(JKP) gZc^_ggufb Z^khj[pbhgguf f_lh^hf lZ[e ihdZau\Z_l qlhhgb kh\iZ^Zxl ih ihjy^dm \_ebqbgu ijb wlhf agZqbfZy dhjj_eypby f_`^mgbfbhlkmlkl\m_lIhemq_ggu_ ^Zggu_ fh`gh jZkkfZljb\Zlv dZd k\b^_l_evkl\h lh]h qlhk\yau\Zgb_ Hg(II) \ g_lhdkbqgu_ ]mfZlu y\ey_lky hkgh\guf f_oZgbafhf^_lhdkbdZpbb Hg(II) ]mfmkh\ufb dbkehlZfb <Z`guf ke_^kl\b_f ^Zggh]haZdexq_gby y\ey_lky lh qlh \ wlhf kemqZ_ agZq_gby .(JKP) fh`ghbkihevah\Zlv^eyhp_gdblhdkbqghklbHg(II)\jZaguo\h^h_fZoIh^jh[ghwlZl_fZ h[km`^Z_lky \ khhl\_lkl\mxs_c im[ebdZpbb [@bebg b I_jfbgh\Z2000].>ey ihemq_gby ^hihegbl_evghc dhebq_kl\_gghc hp_gdb ijhp_kkZ^_lhdkbdZpbb +J,, ]mfmkh\ufb dbkehlZfb [ueh bamq_gh bo \ebygb_ gZgZdhie_gb_+J,,\[bhfZkk_\h^hjhke_c\ijbkmlkl\bboehjb^h\Ijbwlhfh`b^Zehkv qlh gZdhie_gb_ +J,, \ [bhfZkk_ \h^hjhke_c [m^_l dZd b \kemqZ_ lhdkbq_kdh]h wnn_dlZ hij_^_eylvky jZ\gh\_kghc dhgp_gljZpb_cHgCl2.>ey wlhc p_eb bamqZeb \ebygb_ ]mfmkh\uo dbkehl gZ jZkij_^_e_gb_+J,, \ kbkl_f_ oehjb^kh^_j`Zsbc jZkl\hj – [bhfZkkZ \h^hjhke_c Ijbbaf_j_gbb kh^_j`Zgby +J,, \ l_kl-jZkl\hj_ b [bhfZkk_ \h^hjhkeb ihhdhgqZgbb lhdkbdheh]bq_kdh]h wdki_jbf_glZ [ueh h[gZjm`_gh qlh \h \k_okemqZyo]mfmkh\u_dbkehluij_iylkl\h\ZebgZdhie_gbxjlmlb261LZ[ebpZ 7.10Eh]ZjbnfudhgklZgl^_lhdkbdZpbbb [bhgZdhie_gby Hg(II)]mfmkh\ufbdbkehlZfbjZaebqguodeZkkh\Q = 3, P = 0.95)Ij_iZjZllgKD(JKP) lgKB(JKP)Ij_iZjZlJH<ijbjh^guo\h^lgKD(JKP) lgKB(JKP)=NDlhjnZADOM-SMu413.8±0.114.1±0.2PHF-T49414.3±0.114.3±0.5ADOM-SMu814.2±0.114.0±0.3PHF-T59414±114.5±0.1PHF-T69413.5±0.214.3±0.2=NDijbjh^guo\h^AHF-MMu7−14.2±0.1PHF-TH9413.8±0.514.3±0.1AHF-RND11−13.5±0.6PHF-TMu414.0±0.114.4±0.1AHF-RND1413.7±0.213.9±0.3PHF-TT9413±313±2AHF-SSH1−14.04±0.05AHF-SMu813.80±0.0413.6±0.7=ND^hgguohleh`_gbcBHF-RLuh13±614.3±0.5BHF-RND1313.9±0.514.4±0.4BHF-SMu214.4±0.314.6±0.4=Dm]e_cCHA-AGK13.9±0.114.0±0.4CHA-ALD13.4±0.214.1±0.4=Dihq\SHA-Gw9414.4±0.214.64±0.08SHA-Pw9414.3±0.314.9±0.3SHA-PwN−14.1±0.5=NDihq\SHF-Co9413.8±0.114.3±0.2SHF-TMu1214.0±0.115.3±0.1SHF-PMu914±214.8±0.4>Zgguc nZdl iha\hebe jZkkqblZlv dhgklZglu mklhcqb\hklb dhfie_dkh\]mfmkh\uo dbkehl k Hg(II) ba ^Zgguo ih __ [bhgZdhie_gbx KqblZy qlhgZdhie_gb_ +J,, \ [bhfZkk_ \h^hjhke_c dZd b \ kemqZ_ lhdkbq_kdh]hwnn_dlZ hij_^_ey_lky jZ\gh\_kghc dhgp_gljZpb_c +J&O2 l_ ]mfZlu g_ih]ehsZxlkyoehj_eehcijbq_fkhhl\_lkl\mxsZyaZ\bkbfhklvebg_cgZl_+J,, aZgbfZ_l g_agZqbl_evgmx ^hex p_gljh\ k\yau\Zgby gZ \h^hjhkebfh`ghaZibkZlvqlh(7.64)BCF/BCF0 = 1 – α,]^_BCF –nZdlhj[bhdhgp_gljbjh\Zgby+J,, \ijbkmlkl\bb]mfmkh\uodbkehlBCF0 –lh`_\hlkmlkl\b_]mfmkh\uodbkehlα –^hey+J,,k\yaZggh]h\dhfie_dkHgJKPLh]^Z dhgklZglu mklhcqb\hklb dhfie_dkh\ ]mfmkh\uo dbkehl k Hg(II)fh`gh gZclb ba ³djb\uo [bhgZdhie_gby´ – aZ\bkbfhklb hlghr_gbyBCF/BCF0 ZgZeh] hlghr_gbx lhdkbqghkl_c – wnn_dlm ^_lhdkbdZpbb D) hldhgp_gljZpbb]mfmkh\uodbkehlZiijhdkbfbjmybonmgdpb_c262KihfhsvxmdZaZgghcijhp_^mjugZoh^blky\_ebqbgZK(JKPCl)/[Cl–]2.Mqblu\Zyqlhoehjb^-bhgugZoh^ylky\[hevrhfba[uld_ihhlghr_gbxdhjlmlb jZ\gh\_kgmx dhgp_gljZpbx oehjb^h\ fh`gh ijbjZ\gylv d h[s_chldm^Z gZclb dhgklZglm eb]Zg^gh]h h[f_gZ b i_j_kqblZlv __ gZ dhgklZglmmklhcqb\hklbdhfie_dkh\]mfmkh\uodbkehlkHg(II)ZgZeh]bqghlhfmdZdwlh^_eZehkv^eylhdkbdheh]bq_kdbodhgklZglIhemq_ggu_ agZq_gby dhgklZgl h[hagZqZeb lgKBJKP lZ[e HgblZd`_ ohjhrh kh]eZkmxlky k dhgklZglZfb gZc^_ggufb Z^khj[pbhgguff_lh^hf ijbq_f f_`^m lgKJKP b lgKBJKP gZ[ex^Z_lky agZqbfZydhjj_eypby (r = 0.67 ijb n = 22).
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