Анализ, классификация и прогноз свойств гумусовых кислот (1098260), страница 33
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b keZ[h\ujZ`_ggu_ ]b^jhnh[gu_ k\hckl\Z(lgKOW = 2.7) [Devitt and Weisner, 1998].&O1+&1+11&+1+&+Jbk 7.11. KljmdlmjgZynhjfmeZZljZabgZ>ey hij_^_e_gby dhgklZgl k\yau\Zgby ZljZabgZ ]mfmkh\ufb dbkehlZfbbkihevah\Zeb lhl `_ ih^oh^ qlh b ^ey I:M jZkkqblu\Zy __ dZd dhgklZglmkhj[pbb ih mjZ\g_gbx 1.26 >ZggZy qZklv jZ[hlu ih^jh[gh baeh`_gZ \khhl\_lkl\mxs_cim[ebdZpbb[Kulikova et al., 2000]>eywdki_jbf_glZevgh]hgZoh`^_gby^ZgghcdhgklZglug_h[oh^bfhhij_^_eylv^hexk\h[h^ghjZkl\hj_ggh]hZljZabgZα\ijbkmlkl\bb]mfmkh\uodbkehlLh]^ZbamjZ\g_gbybf__f(7.47)+ 1 = . 2& × K =NDα:ljZabg \ hlebqb_ hl I:M g_ nemhj_kpbjm_l qlh ^_eZ_lg_ijbf_gbfuf bkihevah\Zgb_ f_lh^Z lmr_gby nemhj_kp_gpbb Ihwlhfm248ijb[_]Zeb d ^jm]hfm kihkh[m hkgh\Zgghfm gZ jZa^_e_gbbk\h[h^ghjZkl\hj_ggh]h b k\yaZggh]h ]mfmkh\ufb dbkehlZfb ZljZabgZf_lh^hf mevljZnbevljZpbb >ey jZa^_e_gby bkihevah\Zeb f_f[jZgu kij_^_ehf ijhimkdZgby >Z Hij_^_e_gb_ k\h[h^ghjZkl\hj_ggh]hZljZabgZ \ nbevljZl_ hkms_kl\eyeb f_lh^hf h[jZs_ggh-nZah\hc <W@O kMN-^_l_dlbjh\Zgb_fijb gfK\yau\Zxsb_ k\hckl\Z ]mfmkh\uo dbkehl ih hlghr_gbx d ZljZabgmijh\h^beb k bkihevah\Zgb_f \u[hjdb khklhys_c ij_bfms_kl\_ggh baij_iZjZlh\ ihq\ lZd dZd ijh[e_fZ aZ]jyag_gby ]_j[bpb^Zfb gZb[he__ZdlmZevgZ^eyihq\_gguokj_^>eyjZkrbj_gby^bZiZahgZbamqZ_fuok\hckl\\ \u[hjdm [ueb \dexq_gu b ^jm]b_ ij_iZjZlu <k_]h \ g__ \hreh ij_iZjZlh\ =D NDb =NDihq\=ND=DbJH<lhjnZ =Dm]eyWdki_jbf_glu ih k\yau\Zgbx ZljZabgZ ]mfmkh\ufb dbkehlZfbijh\h^beb ijb ke_^mxsbo mkeh\byo dhgp_gljZpby ZljZabgZ K: 10–5 Fdhgp_gljZpby ]mfmkh\uo dbkehl K=ND = (1.5-6.5)×10-4 d] Ke jG \j_fy\aZbfh^_ckl\by – 24 q DhgklZglm k\yau\Zgby ZljZabgZ ]mfmkh\ufbdbkehlZfb gZoh^beb dZd lZg]_gk m]eZ gZdehgZ aZ\bkbfhklb α hldhgp_gljZpbb ]mfmkh\uo dbkehl Lbibqgu_ ]jZnbdb mdZaZgghc aZ\bkbfhklb^eyij_iZjZlh\]mfmkh\uodbkehljZaebqguodeZkkh\ijb\_^_gugZjbk 7.12.α&+$$*.6+$3J6)$3SDhgp_gljZpby]mfmkh\uodbkehl× d]HKeJbk 7.12.
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klbfmebjmxsbf^_ckl\b_f ]mfmkh\uo dbkehl Ihwlhfm ^ey jZkq_lZ ^_lhdkbpbjmxs_ckihkh[ghklb ij_iZjZlh\ ]mfmkh\uo dbkehl [ue \\_^_g hkh[uc ihdZaZl_ev –dhwnnbpb_gl ^_lhdkbdZpbb ' ?]h ih^jh[gh_ hibkZgb_ ijb\_^_gh \ gZrbokhhl\_lkl\mxsbo im[ebdZpbyo [Perminova et al., 1996; Steinberg et al., 1999].>hklhbgkl\hf ^Zggh]h ihdZaZl_ey y\ey_lky lh qlh hg hljZ`Z_l baf_g_gb_mjh\gy lhdkbqghklb WL \ ijbkmlkl\bb ]mfmkh\uo dbkehl LWL=ND ihkjZ\g_gbx k lhdkbqghklvx WL \ bo hlkmlkl\b_ LWL mqblu\Zy ijb wlhf\hafh`gh_ baf_g_gb_ l_kl-hldebdZ ih^ \ebygb_f kh[kl\_ggh]h \ha^_ckl\by]mfmkh\uodbkehlIjbgbfZyqlh5 −5WL(7.48)=L WL5bL WL + =ND =5=ND−55WL =ND=ND]^_ R0 – l_kl-hldebd\dhgljhe_[_aWLb=NDRWL – l_kl-hldebd\ijbkmlkl\bbWLR=ND –l_kl-hldebd\ijbkmlkl\bb=NDRWL=ND – l_kl-hldebd\ijbkmlkl\bbWLb=NDihemqZ_fL −LLWL + =ND' = WL= 1 − WL + =NDLLWL(7.49),(7.50)WLIjb mkeh\bb qlh qm\kl\bl_evghklv l_kl-hj]Zgbafh\ d kh[kl\_gghfm^_ckl\bx]mfmkh\uodbkehlg_baf_gy_lky\ijbkmlkl\bbWLbkihevah\Zgb_dhwnnbpb_glZ ' iha\hey_l hoZjZdl_jbah\Zlv ^_lhdkbpbjmxsbc wnn_dl]mfmkh\uo dbkehl h[mkeh\e_gguc lhevdh k\yau\Zgb_f WL \ g_lhdkbqgu_252dhfie_dkugZnhg_boklbfmebjmxs_]h\ha^_ckl\bygZl_kl-h[t_dlIhwlhfmagZy aZ\bkbfhklv dhwnnbpb_glZ ' hl dhgp_gljZpbb ]mfmkh\uo dbkehl lgdjb\mx ^_lhdkbdZpbb fh`gh jZkkqblZlv dhgklZglm ^_lhdkbdZpbb .OCD.Ij_bfms_kl\h ^Zggh]h iZjZf_ljZ ijb hp_gd_ ^_lhdkbdZpbb ih kjZ\g_gbx kdhwnnbpb_glhf ' khklhbl \ lhf qlh _keb ihke_^gbc iha\hey_l ihemqblvlhq_qgmx hp_gdm ^_lhdkbdZpbb lh .OCD y\ey_lky oZjZdl_jbklbdhc^_lhdkbpbjmxs_c kihkh[ghklb ]mfmkh\uo dbkehl \h \k_f ^bZiZahg_dhgp_gljZpbcIjbwlhf_]hnbabq_kdbckfukeZgZeh]bq_g.OC.>ey\u\h^ZmjZ\g_gby^ZgghcdhgklZgluaZibr_fmjZ\g_gb_k\yau\ZgbyWL]mfmkh\ufbdbkehlZfbWL + =ND 5 WL-=ND(7.51)Lh]^Z ^hex WL gZoh^ys_]hky \ k\h[h^ghf khklhygbb α) fh`gh\ujZablvq_j_akhhl\_lkl\mxsmxdhgklZglmk\yau\Zgby[WL](7.52)α==[WL] + [WL =ND ] + K =ND × .
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