Анализ, классификация и прогноз свойств гумусовых кислот (1098260), страница 31
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Yin et al, 1997@ ih ijbqbgZf hibkZgguf \h[ahj_ebl_jZlmjujZa^ 1.5.1).234LZ[ebpZ7.3Ebl_jZlmjgu_^Zggu_ihdhgklZglZfmklhcqb\hklbdhfie_dkh\]mfmkh\uodbkehlkHg(II)\i_j_kq_l_gZHg(II)-wd\b\Ze_glgmxdhgp_gljZpbx]mfmkh\uodbkehlIj_iZjZljG I OJD=ND 0=ND ωJKP OJDJKP)]fhev ffhev]Fhjkdb_=ND 8J_qgu_=NDHa_jgu_=NDNDlhjnZ4600320003.7*3.7*3.7*2.3**16.0-16.9 Mantoura et17.1-18.5 al., 197816.3-18.916.2-17.11141003.7*10.2*** <ZjrZeb;mZqb^a_ 1983–––18.119.3-19.718.4-20.118.3NDFhkd\u- 6.5 0.1j_db=D³$OGULFK´7??Bklhqgbd13.7-15.0 Heiden&Aikens,1983* –^ey\h^guo]mfmkh\uodbkehl\jZkq_l_gZ[_aahevgucij_iZjZl** –^eylhjnyguo]mfmkh\uodbkehl*** –^hihegbl_evghi_j_kqblZghgZ, = ihmjZ\g_gbx>w\bkZDZd \b^gh ba ^Zgguo ijb\_^_gguo \ lZ[e ihemq_ggu_ gZfbj_amevlZlu ohjhrh kh]eZkmxlky k >+HLGHQ and Aikens, @ LZd ^eyij_iZjZlZ=D$OGULFKihgZrbf^ZggufOJ.JKP = 14.0±J = Zba^Zgguo [Heiden and Aikens, 1983] – 13.7- \ aZ\bkbfhklb hl khhlghr_gby+J,,=ND Gm`gh aZf_lblv qlh mdZaZggu_ Z\lhju lZd`_ hij_^_eyebdhgklZglumklhcqb\hklbdhfie_dkh\]mfmkh\uodbkehlkHg(IIba^ZgguoihZ^khj[pbb+J,,gZihebwlbe_g_\ijbkmlkl\bb]mfmkh\uodbkehlqlh[ebadhf_lh^mbkihevah\Zgghfm\gZklhys_cjZ[hl_AgZq_gbydhgklZglgZc^_ggu_\>Mantoura et al., 1978@hdZaZebkvgZ-4ihjy^dZ \ur_ q_f \ gZklhys_c jZ[hl_ Z ijb\h^bfu_ \ [<ZjrZe b;mZqb^a_ 1983] – gZ ihjy^dZ gb`_ JZkoh`^_gb_ k [<ZjrZe b;mZqb^a_ @ fh`_l [ulv h[mkeh\e_gh ijbgpbibZevgh bguf f_lh^hf\u^_e_gby]mfmkh\uodbkehl–khj[pb_cgZZdlb\bjh\Zgghfm]e_qlhfh]ehkdZaZlvky gZ bo k\hckl\Zo < hlghr_gbb jZ[hlu >Mantoura et al., 1978]ijbqbgujZkoh`^_gbykgZrbfb^Zggufbfh`ghh[tykgblvbkihevah\Zgb_f[he__\ukhdbojGijbdhlhjhfjZ[hlZebZ\lhju***GZ hkgh\Zgbb ijh\_^_gguo kbkl_fZlbq_kdbo bkke_^h\Zgbc ihemq_gudhebq_kl\_ggu_ oZjZdl_jbklbdb dhfie_dkhh[jZamxsbo k\hckl\ ]mfmkh\uodbkehl ih hlghr_gbx d Hg(II) (kh^_j`Zgb_ jlmlv-k\yau\Zxsbo p_gljh\ bdhgklZglu mklhcqb\hklb dhfie_dkh\ ]mfmkh\uo dbkehl k Hg(II)) ^ey235ij_^klZ\bl_evghc \u[hjdb ij_iZjZlh\ jZaebqgh]h ijhbkoh`^_gby bnjZdpbhggh]h khklZ\Z < dZq_kl\_ dhgklZglu mklhcqb\hklb dhfie_dkh\]mfmkh\uodbkehlkHg(II) ij_^eh`_ghbkihevah\ZlvdZ`msmxkydhgklZglm\jZkq_l_ gZ jlmlv-wd\b\Ze_glgmx dhgp_gljZpbx ]mfmkh\uo dbkehlJZajZ[hlZgu f_lh^bdb hij_^_e_gby Hg(II)-wd\b\Ze_glghc dhgp_gljZpbb]mfmkh\uo dbkehl b dZ`msboky dhgklZgl mklhcqb\hklb dhfie_dkh\ k Hg(II).IhdZaZgh qlh ]mfmkh\u_ dbkehlu jZaebqgh]h ijhbkoh`^_gby bnjZdpbhggh]h khklZ\Z k\yau\Zxl +J,, \ ijhqgu_ dhfie_dku ijb wlhf^bZiZahg baf_g_gby gZc^_gguo dZ`msboky dhgklZgl mklhcqb\hklb ih \k_cbkke_^h\Zgghc\u[hjd_ij_iZjZlh\khklZ\eyeh^bgihjy^hd7.2 Bkke_^h\Zgb_k\yau\Zxsbok\hckl\]mfmkh\uodbkehlihhlghr_gbxI:MbZljZabgmIheby^_jgu_ ZjhfZlbq_kdb_ m]e_\h^hjh^u I:M h[jZamxl deZkkobfbq_kdbokh_^bg_gbchdZau\Zxsbo\ujZ`_ggu_lhdkbq_kdb_fmlZ]_ggu_b dZgp_jh]_ggu_ wnn_dlu gZ `b\u_ hj]Zgbafu [Neff, 1979; Lee et al., 1981].GZjy^m k iheboehjbjh\Zggufb m]e_\h^hjh^Zfb hgb hlghkylky d h^ghfm bagZb[he__ hiZkguo deZkkh\ aZ]jyagyxsbo \_s_kl\ – \ukhdh]b^jhnh[gufhj]Zgbq_kdbf kh_^bg_gbyf [Maruya et al., 1997] <ebygb_ ]mfmkh\uo dbkehlgZ nhjfu kms_kl\h\Zgby I:M \ \h^guo kj_^Zo b bo [bheh]bq_kdmxZdlb\ghklv [ueh ih^jh[gh h[km`^_gh \ khhl\_lkl\mxs_f jZa^_e_ h[ahjZebl_jZlmju(1.6) qlh iha\hebeh gZ]ey^gh ijh^_fhgkljbjh\Zlvg_h[oh^bfhklv mq_lZ wlh]h nZdlhjZ ijb ihkljh_gbb Z^_d\Zlguo fh^_e_c[bh]_hobfbq_kdbo pbdeh\ I:M b ijh]ghabjh\Zgbb bo hiZkghklb ^ey[bhlbq_kdhcdhfihg_gluijbjh^guokj_^?s_ h^gbf \Z`guf deZkkhf hj]Zgbq_kdbo wdhlhdkbdZglh\ y\eyxlky]_j[bpb^u Ijb wlhf hkh[h hiZkgh aZ]jyag_gb_ i_jkbkl_glgufb]_j[bpb^Zfbh^gbfbagZb[he__jZkijhkljZg_gguoij_^klZ\bl_e_cdhlhjuoy\ey_lky ZljZabg [AZoZj_gdh, 1990] <j_fy _]h `bagb \ ihq\_ khklZ\ey_l hlg_kdhevdbo g_^_ev ^h q_luj_o e_l b [he__ :ljZabg ijbgZ^e_`bl d deZkkmkbf-ljbZabgh\uo ]_j[bpb^h\ – kbevguo ki_pbnbq_kdbo bg]b[blhjh\nhlhkbgl_aZKh]eZkghfgh]hqbke_ggufbkke_^h\Zgbyfhkgh\gufnZdlhjhfhij_^_eyxsbf aZdj_ie_gb_ ZljZabgZ \ ihq\_gghf ijhnbe_ b mjh\_gvijhy\ey_fhc bf lhdkbqghklb y\ey_lky k\yau\Zgb_ k ]mfmkh\ufb dbkehlZfb[E_[_^_\Zb^jH\qbggbdh\Z]Wlhl\hijhkih^jh[ghhk\_s_g\h[ahj_ebl_jZlmjujZa^_eMdZaZggu_ ijbqbgu h[mkeh\beb \u[hj I:M b ZljZabgZ \ dZq_kl\_fh^_evguo hj]Zgbq_kdbo lhdkbdZglh\ ^ey hp_gdb k\yau\Zxsbo b^_lhdkbpbjmxsbok\hckl\]mfmkh\uodbkehl2367.2.1 Hij_^_e_gb_dhgklZglk\yau\Zgby]mfmkh\uodbkehlkI:MBamq_gb_ \aZbfh^_ckl\by ]mfmkh\uo dbkehl k I:M ijh\h^beb gZijbf_j_ lj_o ij_^klZ\bl_e_c wlh]h deZkkZ kh_^bg_gbc – ibj_gZ 3\nemhjZgl_gZ )OW b ZgljZp_gZ $Q <u[hj fh^_evguo I:M hkgh\u\Zeb gZjZaebqbb bo nbabdh-obfbq_kdbo k\hckl\ \ i_j\mx hq_j_^v ]b^jhnh[ghklbjZkl\hjbfhklb b ihl_gpbZeZ bhgbaZpbb qlh \Z`gh ^ey mklZgh\e_gbyf_oZgbafZkhhl\_lkl\mxs_]h\aZbfh^_ckl\byHkgh\gu_nbabdh-obfbq_kdb_oZjZdl_jbklbdbbkihevam_fuoI:Mijb\_^_gu\lZ[e 7.4.LZ[ebpZ 7.4Nbabdh-obfbq_kdb_oZjZdl_jbklbdbfh^_evguoI:Mih^Zgguf[Clar, 1964; Dbjkhb^j 1988]I:MKlj-jZTmp°K Tbp°CJZkl\hjb- >Z\e_gb lgKowfhklv\\h^_ _iZjh\fd]e°K (20°C),w<Ibj_g1493601356.85×10–7 5.187.55NemhjZgl_g110–2650.60×10–6 5.227.8:gljZp_g216340301.96×10–4 4.447.44<u[hjdZ ij_iZjZlh\ bkihevah\ZggZy ^ey bkke_^h\Zgby \aZbfh^_ckl\byk I:M \dexqZeZ h[jZaph\ =ND b JH< lhjnZ =D ND b =NDihq\ =ND \h^ b =D m]ey DhgklZglu k\yau\Zgby I:M ]mfmkh\ufbdbkehlZfb hij_^_eyeb f_lh^hf lmr_gby nemhj_kp_gpbb DZd mdZau\Zehkv \eblh[ahj_ jZa^_e ^Zgguc f_lh^ iha\hey_l hij_^_eylv dhgklZgluk\yau\Zgby I:M ]mfmkh\ufb dbkehlZfb iml_f baf_j_gby dhgp_gljZpbbk\h[h^ghc b k\yaZgghc nhjf I:M [_a bo ij_^\Zjbl_evgh]h jZa^_e_gbyDjhf_ lh]h bkihevah\Zgb_ wlh]h f_lh^Z g_ lj_[m_l hij_^_e_gby lhqghcdhgp_gljZpbbI:M\jZkl\hj_>Shlautman and Morgan, 1993@JZkq_ldhgklZglk\yau\Zgby I:M ]mfmkh\ufb dbkehlZfb KOC ijh\h^beb k ihfhsvxmjZ\g_gby Rl_jgZ-Nhevf_jZ 1.27).
Ih^jh[gh_ h[km`^_gb_ ihemq_gguoj_amevlZlh\ijb\_^_gh\[Perminova et al., 1999].>eyhij_^_e_gbyKOCbaf_jyebbgl_gkb\ghklbnemhj_kp_gpbbjZkl\hjh\I:M \ hlkmlkl\b_ )0 b \ ijbkmlkl\bb ) jZaebqguo dhgp_gljZpbc]mfmkh\uo dbkehl K wlhc p_evx ]hlh\beb dhgp_gljZpbhggu_ k_jbb]mfmkh\uo dbkehl ijb ihklhygghc dhgp_gljZpbb I:M dhlhjZy khklZ\eyeZ5×10–7, 6.4×10–7b×10–7F^ey3\)OWb$Qkhhl\_lkl\_gghDhgp_gljZpbb237]mfmkh\uo dbkehl mklZgZ\eb\Zeb \ ^bZiZahg_ -7×10–6 d] Ke GZ jbk 7.5ijb\_^_gu lbibqgu_ ki_dlju nemhj_kp_gpbb 3\ \ ijbkmlkl\bb jZaebqguodhgp_gljZpbc ]mfmkh\uo dbkehl Lbibqgu_ dhgp_gljZpbhggu_ aZ\bkbfhklblmr_gby nemhj_kp_gpbb I:M ]mfmkh\ufb dbkehlZfb bkihevah\Zggu_ ^eyjZkq_lZKHKijb\_^_gugZjbk 7.6.)λgfJbk 7.5.
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