Неравновесные состояния и гистерезис сорбции-десорбции водорода в водородаккумулирующих материалах (1098242), страница 36
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Показано, что механохимическая обработка исходногосоединения с добавками катализатора диссоциативной хемосорбции водорода икарбонизированногосвязующегообеспечиваетсущественноеувеличениеводородсорбционной способности в области высоких давлений при сохранении полнойобратимости взаимодействия.9. Проведено исследование взаимодействия в системе H2O-H2 и тройных системахна ее основе, дополнительно содержащих компоненты, стабилизирующие гидратные фазы.Показано, что для бинарной системы гистерезис фазового перехода лед Ih↔клатратныйгидрат sII связан с выраженным объемным эффектом (до 15%), а в случае превращенияL↔sII - с механизмом формирования зародышей клатратной фазы в жидкости. В системахН2О-ТГФ-Н2 и Н2О-1,4-диоксан-Н2 в области давлений выше 1000 бар обнаруженонестабильное сверхнасыщенное водородом состояние, которое отвечает частичномудвойному заполнению молекулами Н2 пентагональных полостей-додекаэдров (512) вклатратном каркасе.2167. Список литературы1.
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