Rohsenow W., Hartnett J., Young Cho. Handbook of Heat Transfer (776121), страница 16
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1 4F i c k i a n D i f f u s i o n Coefficients [(m2/s) × 10 -4] at A t m o s p h e r i c P r e s s u r e (Continued)DqT(K)T(K)Carbon dioxideargon [26] (Continued)Carbon dioxidecarbon dioxide[19]13681383142714451495150315381676194.8273.2312.8362.62.592.132.532.662.652.843.083.21Carbon dioxidecarbon dioxide [7]194.72732983532.250.05000.09070.1130.153DijT(K)Dij0.05160.09700.12480.1644Carbon dioxidecarbon dioxide [5]2332530.06620.07942742933133333633930.09250.10870.12390.13950.16130.18764234534830.21640.24770.2892All the Dij values are in (m2/s) x 10-~.
For example, at 276.2 K theinterdiffusion coefficient for the air--carbon dioxide mixture is 1.420 x10-5 m2/s.For an extensive review with formula fits but no data tables, see Marrero and Mason, J. Phys. Chem. Ref. Data, 1:3-118 (1972). Interpolationfrom a graph of log D;j versus log T is often simple.References for Fickian interdiffusion coefficients1. R. E. Walker and A. A. Westenberg, "Molecular Diffusion Studiesin Gases at High Temperatures. II.
Interpretation of Results on the HeN2 and CO2-N2 Systems," J. Chem. Phys., 29:1147,1958.2. R. E. Walker and A. A. Westenberg, "Molecular Diffusion Studiesin Gases at High Temperatures. IV. Results and Interpretation of theCO2-O2, CH4-O2, H2-O2, CO-O 2 and H 2 0 - O 2 Systems," J. Chem.
Phys,32:436,1960.3. M. Trautz and W. MUller, "Die Reibung, W~irmeleitung und Diffusion in Gasmischungen. XXXIII. Die Korrektion der bisher mitder Verdampfungsmethode gemessenen Diffusionskonstanten," Ann.Physik, 22:333,1935.4. E A. Schwertz and J. E. Brow, "Diffusivity of Water Vapor in SomeCommon Gases," J. Chem. Phys., 19:.640, 1951.5. K. Sch~ifer and P. Reinhard, "Zwischenmolekulare Kr~ifte und dieTemperaturabh~ingigkeit der Selbstdiffusion von CO2," Z. Naturforsch,18:187,1963.6.
G. Ember, J. R. Ferron, and K. Wohl, "Self-Diffusion Coefficientsof Carbon Dioxide at 1180°-1680°K," J. Chem. Phys., 37:891,1962.7. E. B. Winn, "The Temperature Dependence of the Self-DiffusionCoefficients of Argon, Neon, Nitrogen, Oxygen, Carbon Dioxide, andMethane," Phys. Rev., 80:.1024, 1950.8. R. E. Walker and A.
A. Westenberg, "Molecular Diffusion Studiesin Gases at High Temperature. III. Results and Interpretation of theHe-A System," J. Chem. Phys., 31:319, 1959.9. A. A. Westenberg and G. Frazier, "Molecular Diffusion Studies inGases at High Temperature. V. Results for the H2-Ar System," J. Chem.Phys., 36:3499,1962.10. R. Paul and I. B. Srivastava, "Mutual Diffusion of the Gas PairsHE-Ne, HE-Ar, and HE-Xe at Different Temperatures," J. Chem.
Phys.,35:1621,1961.11. R. A. Strehlow, "The Temperature Dependence of the MutualDiffusion Coefficient for Four Gaseous Systems," J. Chem. Phys.,21:2101,1953.12. K. E Srivastava, "Mutual Diffusion of Binary Mixtures ofT(K)DijCarbon dioxidenitrogen [24]Carbon dioxidecarbon dioxide[6]29629811800.1090.1091.731.841218133014452.042.382.80145014871490152015762.862.562.882.982.783.121580166516803.333.293.502890.158Water-hydrogen [4]307.3328.6352.71.0201.1211.200Water-nitrogen [4]307.6328.6352.20.2560.3030.359X e n o n - x e n o n [13]194.7273.2293.0300.5329.9378.00.02570.04800.04430.05760.06840.0900Helium, Argon, and Xenon at Different Temperatures," Physica,25:571, 1959.13.
I. Amdur and T. E Schatzki, "Diffusion Coefficients of the Systems Xe-Xe and A-Xe," J. Chem. Phys., 27:1049,1957.14. K. P. Srivastava and A. K. Barua, "The Temperature Dependenceof Interdiffusion Coefficient for Some Pairs of Rare Gases," Indian J.Phys., 33:229,1959.15. B. N. Srivastava and K. P. Srivastava, "Mutual Diffusion of Pairsof Rare Gases at Different Temperatures," J. Chem. Phys., 30:.984,1959.16. R.
Paul and I. B. Srivastava, "Studies on Binary Diffusion of theGas Pairs O2-A, O2-Xe, and O:-He," Indian J. Phys., 35:465,1961.17. R. Paul and I. B. Srivastava, "Studies on the Binary Diffusion ofthe Gas Pairs N2-A, N2-Xe, and N2-He," Indian J. Phys., 35:523,1961.18. S. L. Seager, L. R. Geertson, and J. C. Giddings, "TemperatureDependence of Gas and Vapor Diffusion Coefficients," J. Chem. Eng.Data, 8:168, 1963.19.
I. Amdur, J. W. Irvine, Jr., E. A. Mason, and J. Ross, "DiffusionCoefficients of the Systems CO2-CO2 and CO2-N20," J. Chem. Phy&,20:436, 1952.20. J. N. Holsen and M. R. Strunk, "Binary Diffusion Coefficients inNonpolar Gases," Ind. Eng. Chem. Fund., 3:143,1964.21. C. R. Mueller and R. W. Cahill, "Mass Spectrometric Measurement of Diffusion Coefficients," J. Chem.
Phys, 40:651,1964.22. I. Amdur and L. M. Shuler, "Diffusion Coefficients of the Systems CO-CO and CO-N2," J. Chem. Phys., 38:188,1963.23. I. B. Srivastava, "Mutual Diffusion of Binary Mixtures of Ammonia with He, Ne and Xe," Indian J. Phys., 36:193, 1962.24. L. E. Boardman and N. E. Wild, "The Diffusion of Pairs of Gaseswith Molecules of Equal Mass," Proc. Royal Soc. A162:511,1937.25. L. Waldmann, "Die Temperaturerscheinungen bei der Diffusionin ruhenden Gasen und ihre messtechnische Anwendung," Z.
Phys.,124:2, 1947.26. T. A. Pakurar and J. R. Ferron, "Measurement and Prediction ofDiffusivities to 1700°K in Binary Systems Containing Carbon Dioxide,"Univ. of Delaware Tech. Rept. DEL-14-P, 1964.27. J.-W. Yang, "A New Method of Measuring the Mass DiffusionCoefficient and Thermal Diffusion Factor in a Binary Gas System,"doctoral dissertation, Univ. of Minnesota, 1966.28. R.
E. Walker, L. Monchick, A. A. Westenberg, and S. Favin,"High Temperature Gaseous Diffusion Experiments and Intermolecular Potential Energy Functions," Planet. Space Sci., 3:221,1961.2.26CHAPTER TWOTHERMOPHYSICAL PROPERTIES OF LIQUIDSTABLE 2.15Thermophysical Properties of Saturated Water and SteamLiquidT (°C)11" 107~-103010203040506070809017 52512 99210 0157 9706 5135 4404 6304 0053 5103 1135695866026176306436536626696751001101201301401501601701801902 7902 5222 3002 1101 9501 8101 6901 5851 4931 412200210220230240250260270280290300310320330340350360370Steamc,CpPr17.618.218.819.420.120.921.622.323.123.91.8641.8681.8741.8831.8941.9071.9241.9441.9691.9990.850.870.880.900.910.920.940.950.960.9812112412813213513914214614915324.825.826.727.828.830.031.332.634.135.72.0342.0752.1242.1802.2452.3202.4062.5042.6152.7410.991.001.021.041.051.081.091.121.141.170.910.880.860.850.850.840.850.860.890.9215616016316717117417818218719337.539.441.543.946.549.552.856.660.966.02.8833.0433.2233.4263.6563.9184.2214.5744.9965.511.201.241.271.301.341.381.421.471.531.610.961.011.091.191.341.622.418.9919820521422523825628233571.979.187.898.9113130150183PrTI • 1074.2174.1934.1824.1794.1794.1814.1854.1904.1974.20512.999.306.965.404.323.542.972.542.201.9480.484.588.592.696.61001051091131176806836856876876866846816766714.2164.2294.2454.2634.2854.3104.3394.3714.4084.4491.731.561.431.311.221.141.071.020.970.941 3381 2731 2151 1621 1141 0701 0309949619306646576486396296176045895735574.4974.5514.6144.6864.7704.8694.9855.135.305.519018658307907487006445645405225034824604354013385.776.126.597.258.2710.0814.9953.9~-1036.146.968.059.5911.9215.9526.79112.9Viscosity rl (N-s/m2), thermal conductivity ~, (W/m.deg), heat capacity Cp(kJ/kg.deg), Prandtl number Pr.Ref.
2 with permission.Source"1.691.801.962.182.513.145.0420.66o"000J0I,M..I~DC~C~ O0 C~O0 0'~ C~ O0~C4 C-~ ~V.~ C~I ,~. (~r~TIc~"TTc~"TooT×"To2.272.28CHAPTER TWOTABLE 2.17Isobaric Specific Heat for Water and Steam at Various Temperatures and PressuresPressure, barT(°C)0.1110204060801000501001201401601802002202402602803003203403503603653703753803853903954004054104154204254304404504604805005205405605806006206406606807008004.2181.9291.9101.9131.9181.9261.9331.9441.9541.9641.9761.9871.9992.0112.0242.0302.0372.0402.0432.0462.0492.0522.0562.0592.0622.0662.0692.0722.0762.0792.0822.0892.0952.1022.1162.1292.1422.1562.1702.1842.1982.2122.2262.2402.2542.2682.3394.2174.1812.0382.0071.9841.9771.9741.9751.9791.9851.9932.0012.0102.0212.0322.0382.0442.0482.0502.0532.0562.0592.0612.0652.0682.0712.0742.0772.0802.0832.0862.0932.0992.1062.1192.1322.1462.1592.1732.1872.2002.2132.2272.2412.2552.2702.3414.2124.1794.2144.2434.2834.3372.6132.4332.3162.2422.1942.1632.1412.1262.1222.1252.1272.1282.1282.1272.1272.1262.1252.1252.1262.1272.1282.1292.1312.1322.1342.1382.1412.1462.1542.1642.1752.1852.1972.2082.2192.2302.2432.2562.2702.2832.3524.2074.1764.2114.2404.2804.3344.4034.4942.9392.6742.5052.3952.3212.2682.2392.2352.2312.2272.2222.2182.2122.2072.2022.2002.1972.1952.1932.1922.1922.1902.1902.1902.1912.1922.1962.2012.2082.2162.2262.2332.2402.2502.2602.2722.2862.2992.3644.1964.1724.2074.2354.2754.3274.3954.4834.6014.7633.5823.1162.8342.6492.5362.5042.4782.4622.4462.4282.4122.3962.3812.3692.3582.3492.3402.3342.3272.3212.3162.3072.3002.2942.2862.2812.2802.2802.2852.2852.2872.2912.2982.3072.3172.3302.3894.1864.1674.2024.2304.2694.3204.3864.4724.5864.7414.9644.5143.6793.2172.9432.8612.7932.7592.7252.6902.6572.6272.6002.5752.5532.5342.5172.5012.4872.4742.4622.4412.4242.4092.3852.3682.3572.3492.3492.3422.3362.3342.3372.3432.3522.3622.4144.1764.1634.1984.2264.2634.3134.3784.4614.5714.7204.9325.255.314.1183.5263.3503.2163.1343.0723.0182.9642.9132.8672.8262.7892.7562.7272.7002.6752.6532.6322.5962.5652.5382.4962.4643.4412.4232.4162.4012.3892.3812.3792.3812.3882.3982.4404.1654.1584.1944.2214.2584.3074.3704.4504.5574.7004.9025.205.705.794.4124.0433.7693.6553.5463.4463.3563.2743.2013.1373.0783.0252.9792.9362.8982.8632.8302.7732.7262.6842.6182.5692.5312.5022.4872.4652.4452.4312.4232.4212.4242.4292.465THERMOPHYSICAL PROPERTIESTABLE 2.172.29Isobaric Specific Heat for Water and Steam at Various Temperatures and Pressures(Continued)Pressure, barT (°C)1501752002102202252302400501001201401601802002202402602803003203403503603653703753803853903954004054104154204254304404504604805005205405605806006206406606807008004.1414.1484.1834.2094.2454.2914.3504.4254.5234.6534.8325.095.506.238.148.686.866.155.695.335.024.7504.5204.3254.1554.0073.8793.7643.6643.5733.4913.3503.2353.1382.9862.8752.7912.7262.6832.6382.5982.5662.5422.5282.5202.5182.5314.1294.1424.1784.2044.2384.2834.3404.4134.5084.6324.8015.045.416.057.459.2712.579.848.367.406.686.135.685.325.024.7704.5564.3714.2114.0694.9453.7343.5643.4243.2103.0562.9402.8522.7912.7332.6822.6402.6072.5852.5722.5652.5644.1174.1374.1734.1984.2324.2764.3314.4024.4924.6114.7724.9975.335.897.019.1011.3719.7218.3812.7110.198.687.656.906.335.875.505.194.9334.7114.5204.2053.9593.7613.4653.2573.1042.9892.9062.8332.7702.7172.6752.6442.6252.6132.5984.1134.1354.1714.1964.2294.2734.3284.3974.4864.6034.7604.9795.315.846.877.8110.1813.7775.6719.0313.1410.498.907.837.066.465.995.615.295.024.7954.4244.1393.9123.5763.3433.1743.0462.9542.8752.8072.7092.7032.6692.6462.6322.6114.1084.1334.1694.1944.2274.2704.3244.3934.4814.5954.7494.9635.285.796.747.569.4011.6218.3852.719.1913.3810.689.067.977.186.576.095.705.375.104.6644.3334.0743.6953.4343.2473.1063.0032.9182.8442.7812.7312.6942.6692.6522.6254.1064.1324.1684.1934.2264.2684.3224.3904.4784.5914.7444.9555.265.766.687.459.1010.9415.5681.4925.7115.6211.889.848.537.606.906.365.925.565.264.7914.4354.1593.7563.4813.2843.1363.0282.9392.8632.7982.7462.7072.6802.6622.6324.1034.1314.1674.1924.2244.2674.3204.3884.4754.5884.7384.9475.255.746.637.358.8410.4013.8429.5240.9518.8813.4210.779.168.067.266.656.165.775.444.9274.5444.2473.8193.5293.3223.1673.0542.9612.8822.8142.7602.7192.6912.6722.6394.0994.1294.1654.1894.2224.2644.3174.3844.4694.5804.7284.9315.235.696.537.178.419.5811.7917.4468.433.418.2113.2910.769.208.127.326.716.225.835.224.774.433.953.633.403.233.103.012.922.852.792.752.712.692.652.30CHAPTER TWOTABLE 2.17Isobaric Specific Heat for Water and Steam at Various Temperatures and Pressures(Continued)Pressure, barT (°C)25027030040050060080010000501001201401601802002202402602803003203403503603653703753803853903954004054104154204254304404504604805005205405605806006206406606807008004.0954.1274.1634.1874.2204.2614.3134.3794.4644.5724.7174.9165.205.656.437.028.078.9910.5613.7623.3773.128.0417.3113.0210.679.178.127.356.746.265.545.024.6314.0893.7313.4813.2953.1583.0512.9602.8822.8192.7712.7362.7132.6664.0864.1234.1594.1834.2154.2554.3064.3714.4524.5584.6974.8865.165.576.276.767.568.189.1210.6713.5120.0738.0233.7121.1115.3212.2210.308.998.047.326.285.585.084.3893.9513.6503.4313.2683.1443.0402.9522.8802.8242.7832.7552.6944.0734.1171.1534.1774.2084.2474.2964.3584.4374.5374.6694.8455.095.466.076.457.037.437.988.769.9011.6814.6019.6825.7124.8519.5915.4512.7010.839.497.736.625.874.9024.3163.9263.6503.4423.2903.1653.0602.9742.9062.8552.8192.7364.0324.0984.1354.1564.1854.2204.2654.3194.3884.4744.5844.7284.9205.195.605.816.106.276.486.706.977.307.718.198.789.4710.2511.1212.0012.7313.1312.5410.899.287.085.815.024.4874.0953.8233.6143.4463.3083.1973.1103.0442.8793.9934.0804.1174.1374.1634.1964.2354.2844.3444.4194.5144.6334.7884.9965.305.455.645.735.845.966.106.266.436.616.817.047.297.577.878.188.509.089.489.528.557.206.135.374.7964.3874.0823.8453.6543.5003.3763.2793.0243.9564.0644.1004.1194.1434.1724.2084.2524.3054.3714.4534.5554.6834.8485.085.205.345.405.475.565.655.755.845.946.056.166.276.406.546.696.847.177.477.717.877.486.766.035.385.8904.5104.2163.9813.7913.6373.5133.1683.8824.0354.0684.0854.1054.1304.1594.1954.2374.2904.3544.4324.5244.6334.7664.8714.9544.9875.035.085.145.205.255.305.345.385.425.465.515.565.615.725.845.976.196.316.286.105.755.395.034.7244.4654.2494.0683.9163.4413.8004.0104.0394.0544.0714.0924.1164.1454.1804.2234.2764.3404.4114.4854.5524.6634.7194.7374.7644.8024.8434.8844.9194.9494.9744.9965.025.045.065.085.105.155.205.265.405.515.585.565.435.285.084.8714.6694.4854.3224.1783.669Source:Ref.
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