Диссертация (1150392), страница 23
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57. – P. 83–87.135ПРИЛОЖЕНИЕ8.28.07.67.47.27.06.86.66.46.23.90266.03706.15656.13710.99557.14797.12977.27861.00003.09067.86.05.8(ppm)5.65.45.25.04.885804.64.44.24.03.8706560553.6170165160155150145140135130125120115110105(ppm)10095907553.629377.422977.000076.577190.6907100.4368128.5517127.1377131.4722135.2980152.4709161.8337C ЯМР спектр (75 МГц, CDCl3) соединения 6c:166.3995132.0146Integral8.47.50867.48567.46997.44457.4227Н ЯМР спектр (300 МГц, CDCl3) соединения 6c:7.90577.8814150MeOHNHOCF 3CO 2Et13.8655.3363.0477.3277.0076.6890.7090.3990.0789.7698.76116.87113.88119.70122.54125.37N3.27128.92127.45H3.182.111.002.030.992.0213151.901.341.321.313.864.394.384.374.364.364.354.344.334.324.314.304.296.086.066.976.966.956.946.946.937.097.087.287.897.897.887.877.867.861164.37162.63161.00136Н ЯМР спектр (400 МГц, CDCl3) соединения 6h:HOCF 3CO 2EtMeOC ЯМР спектр (100 МГц, CDCl3) соединения 6h:1701601501401301201101004.5(ppm)90(ppm)4.0807013.83375.064.19475.577.423077.000076.57706.084.64316.5101.57117.0113.77417.5134.1580132.2365128.6730127.25348.0151.9679133.07642.04541.00000.84423.19461.46971.44621.42274.52024.49544.47194.44846.40416.38437.27997.21317.89227.86757.55207.52857.49277.46677.44321163.5687162.72982.0186137Н ЯМР спектр (300 МГц, CDCl3) соединения 6n:3.53.060502.5402.0301.5C ЯМР спектр (75 МГц, CDCl3) соединения 6n:20101701601501401301201101004.5(ppm)90(ppm)4.0803.5703.060502.5403017.13185.023.56325.553.53316.077.423077.000076.57706.590.18537.0115.88207.5134.3157130.2361128.6229127.7696158.2486132.88302.98246.04342.00003.0042Integral1.91011.89563.90627.09467.07407.38037.35617.33317.27861166.9170138Н ЯМР спектр (300 МГц, CDCl3) соединения 6s:2.01.5C ЯМР спектр (75 МГц, CDCl3) соединения 6s:20190180170160150140130120110100(ppm)4.090803.5706013.89824.5(ppm)55.63395.065.435064.84715.577.423077.200877.000076.57706.094.80996.5114.7851113.66667.0120.72897.5129.2108163.9989161.66878.0177.9800133.29173.00362.11711.00000.98212.13642.05311.40421.37941.35593.91034.43364.41014.38664.36315.56426.23717.04617.01647.28117.70307.67451185.7737Integral139Н ЯМР спектр (300 МГц, CDCl3) соединения 7m:3.02.550402.0301.5C ЯМР спектр (75 МГц, CDCl3) соединения 7m:2010NHCF3CO 2Et13.8664.11NH77.3277.0076.6873.0372.7472.4572.1799.28117.05119.87122.68125.50133.18129.27129.16126.99161.86H3.21O2.28H1.001.002.271.142.1013178.141.381.361.344.454.444.434.424.414.394.394.384.364.354.344.335.685.957.287.567.557.537.657.637.637.617.767.747.741187.61140Н ЯМР спектр (400 МГц, CDCl3) соединения 7i:OCF3CO 2EtC ЯМР спектр (100 МГц, CDCl3) соединения 7i:13.362.677.377.076.797.683.182.882.682.3122.4122.1125.4125.4125.1125.0126.4126.4126.4126.3131.0129.3128.9128.6128.5128.3127.9127.8127.3136.4141.33.102.041.001.005.062.052.0013163.8146.4146.40.960.940.924.104.094.094.074.074.064.054.044.036.076.067.537.527.517.507.487.487.477.457.286.916.897.687.657.947.921164.6141Н ЯМР спектр (400 МГц, CDCl3) соединения 23e:C ЯМР спектр (100 МГц, CDCl3) соединения 23e:13.5726.2562.2877.3277.0076.6887.7596.61127.27125.33128.42129.16130.55131.98136.78141.96141.91162.02168.683.163.082.191.001.032.062.403.382.16131.041.021.002.324.214.194.184.184.174.164.154.134.124.114.104.094.084.075.935.916.966.947.227.207.337.307.287.927.907.907.497.477.457.431202.85142Н ЯМР спектр (400 МГц, CDCl3) соединения 23j:C ЯМР спектр (100 МГц, CDCl3) соединения 23j:13.9251.5463.0777.2577.0076.75112.48114.65116.86119.08123.02121.30129.00128.71129.88132.80147.36147.07146.77146.48140.05154.01158.463.033.022.011.001.005.94131.311.291.273.734.324.304.284.275.815.846.006.037.287.377.417.407.461167.05143Н ЯМР спектр (400 МГц, CDCl3) соединения E,E-39d:C ЯМР спектр (100 МГц, CDCl3) соединения E,E-39d:13.7753.3863.4471.4971.2771.0570.8477.2577.0076.75118.08120.36122.63128.30124.91129.79131.91135.75132.68143.92162.08163.363.463.342.221.002.231.122.1513165.491.321.311.293.944.404.394.384.374.374.364.344.344.334.324.314.317.367.287.507.487.478.017.997.587.567.551175.66144Н ЯМР спектр (400 МГц, CDCl3) соединения 40d’:C ЯМР спектр (100 МГц, CDCl3) соединения 40d’:51.8255.6355.5777.3277.2077.0076.68107.38120.17124.30127.16128.42128.33127.97127.68132.02131.95131.73129.37129.19128.943.006.061.001.043.285.332.081.0113137.10136.843.523.984.005.925.915.915.906.546.546.536.537.467.447.427.427.417.417.417.407.337.327.317.317.297.287.277.727.727.7010.691163.94145Н ЯМР спектр (400 МГц, CDCl3) соединения 38b:C ЯМР спектр (100 МГц, CDCl3) соединения 38b:.
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