А.Н. Кост, Р.С. Сагитуллин, А.П. Терентьев - Упражнения и задачи по органической химии (1125895), страница 13
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06bnCHIl Te XOA peaKUIiH . 5.26. KaKK'" o6pa30M. II cxoAn " 3 HOAIlCTOro npoflHna. OOJlY'UITb CJIeA}'JOUUie coe.D.HHeHHH :'1 CH:oOi.cH~a~CI-CH,-{: "ltCI6) CH, -CH, -CHBr, _a)CH,CH,CiCi) CH. -CH,b 6,B)roeCH 3 -CHC I,r) CHI-CHC!A) CH,-CCI,Ha30BHTC nOJlyqa!OUI.HecH aew;ecrsa.CH,-CH-<:H" 5.32.
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a npH AeHCTAHII 6POMIICToro BOAOpOJl8 06pa·'YCT 2.2-D.H6poMnponaH?5.37. H anHWHTe crpyKTypHylO cpopMyny BeU.[(.."CTBa CsHuBr. KOTopoenpH rH..!I.pOJl H3e ,naer Tperlf'lHbll1 cnHpT, a npH AefllJ1p06pOMHPOBaHII H TPHNeTHnmlneH.2H1-6_8IIIJI-IB,A - _A _6M,KOH(IO!Wrwftja..r.ep,B6 -H,O...... B6. CUHPTLI II lIX nPOH300JJ; UblE(I~))f()I(.Ot.ClllCH,CH, CHBr,c~HRr-A _cn"PTtIt>5.28. PaccMOTpHTC peaKQ1l1O OTu.I.cnJleHHfI Hel or 3-6POM-2-MemnneH.Talta (npH .lleACTBHH CII"pTOBOH w.eno'III).
KaKOH 113 H30MepOB yrneBO.ll"paM 06p83yercn npeJIMYUlecTBeHHO? .ll.aHTe 06bflClleIlHe.62~TpocHRe a paaaaBRnN.OH I..,AHMlI)...... S..6. 1.J)2)3}•H anHWHTe crpyKTyp Hble cpoPMYJlbl CJleJlYlOiUHX COCJlHHeltlll1:mpem-6YTH.'IOBblH CIlHPl';H30aMHJlOBblH cnKp'l;npona HOJI .. 2;4) 2-MC1'HnneH1'8HOJI-3;5) 5-NcTHnrenTaHon-3;6) 3-3THnreKcaHOJl-3;637) 2.3·.II,HWe<rIlJl6yraHOJJ_2;8) 2.2,4-rpHMe'l"HJJneH'raHOJJ-3;22) ~ -3THJlrenTHIIOBbln cnJtPl';"'23) reKcaMenllle llrllHKOJIb;24) 3TlIJlCHXJlOprHJ1.pHH;9) 4'XJlOpneliTaHon.2;10) aJlJJHIIOBI.di cUHpr;11) 2,2-.IlHMeTH.lrcnreH.4_-011-3;12) 3,3-.IlHMeTHllneHra.HOJI-2;13) 6YTlHlJtHOJl .
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1:H. 34) CH.-CH-CH,-O-CH_CH,CIHIO-~H,CH, CH,l 3)!oJ!,tH, II) CH, -CH-CH, _OH • 12) CH,-CH-CH-CH,_OH30)31, CHrl-o-CH,-GH-CH,10) CH,-l:H-CH, -OH tH,--<lH26) CH;r-O-CH,-CH,~e29) Ci"I.-CH-O-CH-CH,01'12,• 28) CH,-O-CH-CH.CH~-O-CH-CH,6) HCaC~-CH.mf 9) CHtDH-CHr-CH aH.6OHI7) CHt - CH-CH,- CHt_OH. B) CHt-CH-CH-CHt-CHa6H~H,-LCH--CH_CH • 241tH,--<lI·11:",011 ~27)C(l,CIi , CH.--CH,-OH C}-I.CH,OIi6H 1:H,25) CH,-CH-b-I-CH- tH-CH-CHa5j CH,=CH-CH,OHCHtCH.22) CH,-UH-LcH.-NO,CH~-t-CH_CH_LclCH,cHCH, 4) CI'h-CH - CH-CH, -CH_CH aBT C1CH.-CH,-OHCHa-LcH,-OH~H,-OH201 CH.-l--CH--LcH, 6H t l ~H'--<lH CII.CH I tH,tH,NO,-CH sINO, CH l 23)tH,tH,I~HiCH,.J:H-CH,CJCI-CH-CH.CH,~H.Jt1CH.-CH,-t-CH_~-CH.IB)CH.CHaCH,-W,,--LcH.I38) It30aMflJJIIHTPHT;'" 39) TPH6yrIlJlcfx>c¢ar.CH, OHCHr-CH-CH. CH,CH.-L~H--t-c.H,_CH,OH OHH830BIlTe CRCAYIOlltlle coe.!l,HlIeUIfR:.CH,17) CHs-CH-b.t--CH-CH._t-C IOH Ot-!J7) 6YTII.'ltlHrp8T;KapCillHolI;MeTH.'tnIlHHJlIl306YTH.IJ'K8p6IfHOJl:6.2.I1pOllIIJlCepll8Rb ~H,-OlltH.35) llIf3rllJlcYJJ!>¢aT;20) JtH~eTH"lau.eTll.'leHII.'1_~H.
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13.CH ~-O-S -O-CH,J40) CH. -CH-CH. O-SO,HICH,CH,/ .....H- CHs-CH,-O-NO,__043) HO-CH. -t-CH1-OHtH,--OH6.3. HanHwHTe crPYKTYPHble¢loPMYJlbl Beex H30MepoBcnHpTa CloH,OH.Ha90BHTt HX pa3JIHlIHblMH cnoco6aMIi H YKa)t(HTe, HaKHe H3 HH X JlMJI.K>TCJI nepBH\{HblMH, BTOPHIIHblMlt H TpeTH'IHblMH .•6.4. HanHWH'Te CTpYKTypJll>le <PoPMYJlbI H30MepoB cnMpTa CsHIIOH.6. 14.
H3 KaKHX Henpe.n.eJlbHblX y r JleBOllOpoAOB npH rHllPanUH H woryr 06PS30BaTbCH CJlellYlOllllle cml PTbI:a) smop-6YTHII08b1A CnliJYr; 6) 2-MeTllJf6yrauOJI-2; • a) MeTHJlII S06y·THIIKap6HKOJJ.OrMeTbTe aCIlMMeTpIIlJecKHe yrllcp0,II,Hble 8TOMbi 8 HX MMcKyJle.6. 15. H uoBHTe P83J1H'IHblNH cnQCO(5aMH OAHOaTOMHble cnHpTbI , n olIy'lalOJ..UHecfl npl! BOCCTaHOSJIeH HH CJleAYlOUlHx Kap OOKHJlbHblX coe.IUfKeuKA :Ha30BHTe "X, OTMeTbll! BTOpH'lHble Ii TpeTHlJHble cnHJ)TbI, a T8K>Ke aeHN'a) CH~-C-CH lMeTPH'IecKHe 3TOMbi yrJlepOAa.6.5. HamlwH'Te crPYI(TYPBble <J!oPM ) JJbICsHuOH "BTOpll 'lHblXIIHa30BHTe " " .TpeY'H'JH bl X cnllpTooH H330BHTe liX no paUl tOHaJlb Hol1 lloMell KJI3Type.COCT8B3r)tH,l{eTbIPb~R yrJJepOJlHhlMH BroMaNH Ii Ha30BHTC li X.6.8.
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6.23. nOJlY"IHTe H3 MeT~IJ]OBOro cnHp-ra H HeopraHH'IecKHx peareHTOB:• a) npomtJJoBhlft CIlHp-r; 6) H30npOnHJJOBhlH CmtpT.6.24.Me'lelloro 3TIIJlOOOrO c nH p-r8 (14CH.,CH 20 H ) nOJIY'lHTe 3-Me-TllJlnCHT8IJo,'1-3, Me'leHhlil no DCeM TpC.'d r pynnaM C H,.6.25. HamlwHTe CXeMbi nOJly 'leuHH:'·13a) 3TIIJlell rJlH KOJUI 113 9TH~1eHa;6) r JllIuepHHa H3 nponilneHa ; a} rJlHuepHHa H3 aUeTJI.'ICHa;Jl(rra:a) ,ot·C I8 i-l 3,c1 6) CH ,-CH.-cc I(CH~ , 8) CH s-CHr-CHt-CHBr-CH. • 6.26. npH BOCCTaHOBJlemm KaKoro COe,ll,HHeH HII 06pa3Yet'cH cnHPT. KOTOpblrl MO)f(1I0 P83Jl.e.'IHTb Ha OnTH"IecKH AeffTeJlbHble H30Mepbl: lTHJlOSioln ~HP H30MBCJlHHOA KHCJIOTbf, MeTHJl3TliJiKerOH, TpHMeTIfJlaUeT3J1bn.erH]l, llHll30nponHJlKeroH?6.27.
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