Диссертация (1155365), страница 30

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Валентные углы ω (град.) в структуре(C6H8N2)3Н4[SiW12O40].9H2OУголO8-W1-O13O13-W1-O7O13-W1-O39O8-W1-O24O7-W1-O24O8-W1-O1O7-W1-O1O24)-W1-O1O26-W2-O9O26-W2-O25O9-W2-O25O18-W2-O27O25-W2-O27O18-W2-O4O25-W2-O4O34-W3-O14O14-W3-O10O14-W3-O38O34-W3-O32O10-W3-O32O34-W3-O2O10-W3-O2O32-W3-O2O21-W4-O19O21-W4-O16O19-W4-O16O12-W4-O35O16-W4-O35O12-W4-O3O16-W4-O3O37-W5-O16O16-W5-O11O16-W5-O36O37-W5-O25O11-W5-O25O37-W5-O4O11-W5-O4O25-W5-O4O31-W6-O9O31-W6-O13O9-W6-O13O36-W6-O6O13-W6-O6O36-W6-O4O13-W6-O4O20-W7-O39O39-W7-O18ω104.1(4)86.5(3)90.1(3)97.0(4)90.6(3)167.9(2)84.2(3)73.2(3)102.9(4)100.8(3)89.7(4)85.2(4)88.3(3)83.7(3)74.4(3)102.3(3)90.2(4)85.3(4)99.3(3)88.9(4)172.5(2)75.1(2)73.9(2)98.9(4)102.2(3)158.9(4)157.9(4)90.1(3)83.7(3)85.5(3)101.3(4)85.9(4)158.0(3)100.8(3)157.6(3)171.8(3)83.9(2)73.8(2)103.7(4)100.7(4)86.8(3)90.4(4)84.4(3)73.3(3)83.5(3)100.3(4)89.9(4)УголO8-W1-O7O8-W1-O39O7-W1-O39O13-W1-O24O39-W1-O24O13-W1-O1O39-W1-O1O26-W2-O18O18-W2-O9O18-W2-O25O26-W2-O27O9-W2-O27O26-W2-O4O9-W2-O4O27-W2-O4O34-W3-O10O34-W3-O38O10-W3-O38O14-W3-O32O38-W3-O32O14-W3-O2O38-W3-O2O21-W4-O12O12-W4-O19O12-W4-O16O21-W4-O35O19-W4-O35O21-W4-O3O19-W4-O3O35-W4-O3O37-W5-O11O37-W5-O36O11-W5-O36O16-W5-O25O36-W5-O25O16-W5-O4O36-W5-O4O31-W6-O36O36-W6-O9O36-W6-O13O31-W6-O6O9-W6-O6O31-W6-O4O9-W6-O4O6-W6-O4O20-W7-O18O20-W7-O40ω103.4(4)98.7(4)157.8(4)158.8(4)84.7(3)85.6(3)73.7(3)101.4(3)87.9(4)157.7(4)100.4(4)156.6(4)174.0(2)73.8(3)83.2(3)102.0(4)101.0(4)157.1(3)158.1(3)87.0(4)84.7(2)82.1(2)101.9(4)88.8(3)85.9(4)100.2(4)87.3(3)170.7(3)73.7(3)74.3(3)101.6(3)100.6(4)88.5(4)89.7(4)87.5(4)85.0(2)73.2(2)102.6(4)89.2(4)156.6(4)98.9(4)156.9(4)174.4(3)72.7(3)85.1(3)103.8(3)98.0(3)225УголO39-W7-O40O20-W7-O5O18-W7-O5O20-W7-O1O18-W7-O1O5-W7-O1O29-W8-O27O29-W8-O35O27-W8-O35O5-W8-O30O35-W8-O30O5-W8-O3O35-W8-O3O28-W9-O24O24-W9-O14O24-W9-O23O28-W9-O40O14-W9-O40O28-W9-O1O14-W9-O1O40-W9-O1O17-W10-O33O17-W10-O6O33-W10-O6O7-W10-O10O6-W10-O10O7-W10-O2O6-W10-O2O22-W11-O23O23-W11-O38O23-W11-O19O33-W12-O12O11-W12-O32O12-W12-O32O11-W12-O2O12-W12-O2O4-Si1-O2O2-Si1-O3O2-Si1-O1Si1-O1-W7Si1-O1-W9W7-O1-W9Si1-O2-W3Si1-O2-W10W3-O2-W10W8-O35-W4W3-O38-W11O8-W1-O13O13-W1-O7ω87.0(4)101.4(4)85.4(4)170.6(3)84.1(3)84.1(3)103.5(4)100.7(4)90.4(3)89.3(3)86.4(3)83.8(3)74.6(3)99.6(4)91.0(4)158.0(3)99.9(3)157.4(3)171.1(3)83.8(2)73.9(2)103.2(4)100.8(4)89.4(3)89.0(3)158.2(4)83.3(3)84.8(3)102.9(3)86.1(4)157.8(3)156.1(3)157.8(3)88.1(4)84.3(2)82.8(2)110.24(9)108.5(2)109.4(3)123.4(4)125.0(3)91.46(15)125.17(3)123.85(10)89.91(4)120.3(5)152.0(5)104.1(4)86.5(3)УголO18-W7-O40O39-W7-O5O40-W7-O5O39-W7-O1O40-W7-O1O29-W8-O5O5-W8-O27O5-W8-O35O29-W8-O30O27-W8-O30O29-W8-O3O27-W8-O3O30-W8-O3O28-W9-O14O28-W9-O23O14-W9-O23O24-W9-O40O23-W9-O40O24-W9-O1O23-W9-O1O17-W10-O7O7-W10-O33O7-W10-O6O17-W10-O10O33-W10-O10O17-W10-O2O33-W10-O2O10-W10-O2O22-W11-O38O22-W11-O19O38-W11-O19Si1-O3-W4Si1-O3-W11W4-O3-W11Si1-O4-W5Si1-O4-W6W5-O4-W6W10-O6-W6W6-O9-W2W12-O11-W5W1-O13-W6W5-O16-W4W4-O19-W11W9-O24-W1W8-O27-W2W3-O32-W12W3-O38-W11O8-W1-O7O8-W1-O39ω158.2(3)158.3(3)89.5(4)74.4(3)74.3(3)100.9(4)86.2(3)158.3(4)97.2(4)159.3(4)170.6(3)84.8(3)74.6(3)102.6(4)102.3(4)84.6(4)86.2(4)89.6(4)73.9(3)84.2(2)100.9(4)155.8(4)84.2(3)100.9(4)88.4(3)173.3(3)72.9(3)73.8(3)103.1(4)99.3(4)88.4(4)124.43(3)124.1(3)91.30(12)125.3(3)123.5(3)90.26(5)152.8(4)123.2(5)152.3(5)151.3(5)150.6(5)121.6(5)120.5(4)151.8(5)120.4(4)152.0(5)103.4(4)98.7(4)226УголO13-W1-O39O8-W1-O24O7-W1-O24O8-W1-O1O7-W1-O1O24)-W1-O1O26-W2-O9O26-W2-O25O9-W2-O25O18-W2-O27O25-W2-O27O18-W2-O4O25-W2-O4O34-W3-O14O14-W3-O10O14-W3-O38O34-W3-O32O10-W3-O32O34-W3-O2O10-W3-O2O32-W3-O2O21-W4-O19O21-W4-O16O19-W4-O16O12-W4-O35O16-W4-O35O12-W4-O3O16-W4-O3O37-W5-O16O16-W5-O11O16-W5-O36O37-W5-O25O11-W5-O25O37-W5-O4O11-W5-O4O25-W5-O4O31-W6-O9O31-W6-O13O9-W6-O13O36-W6-O6O13-W6-O6O36-W6-O4O13-W6-O4O20-W7-O39O39-W7-O18O39-W7-O40O20-W7-O5O18-W7-O5O20-W7-O1ω90.1(3)97.0(4)90.6(3)167.9(2)84.2(3)73.2(3)102.9(4)100.8(3)89.7(4)85.2(4)88.3(3)83.7(3)74.4(3)102.3(3)90.2(4)85.3(4)99.3(3)88.9(4)172.5(2)75.1(2)73.9(2)98.9(4)102.2(3)158.9(4)157.9(4)90.1(3)83.7(3)85.5(3)101.3(4)85.9(4)158.0(3)100.8(3)157.6(3)171.8(3)83.9(2)73.8(2)103.7(4)100.7(4)86.8(3)90.4(4)84.4(3)73.3(3)83.5(3)100.3(4)89.9(4)87.0(4)101.4(4)85.4(4)170.6(3)УголO7-W1-O39O13-W1-O24O39-W1-O24O13-W1-O1O39-W1-O1O26-W2-O18O18-W2-O9O18-W2-O25O26-W2-O27O9-W2-O27O26-W2-O4O9-W2-O4O27-W2-O4O34-W3-O10O34-W3-O38O10-W3-O38O14-W3-O32O38-W3-O32O14-W3-O2O38-W3-O2O21-W4-O12O12-W4-O19O12-W4-O16O21-W4-O35O19-W4-O35O21-W4-O3O19-W4-O3O35-W4-O3O37-W5-O11O37-W5-O36O11-W5-O36O16-W5-O25O36-W5-O25O16-W5-O4O36-W5-O4O31-W6-O36O36-W6-O9O36-W6-O13O31-W6-O6O9-W6-O6O31-W6-O4O9-W6-O4O6-W6-O4O20-W7-O18O20-W7-O40O18-W7-O40O39-W7-O5O40-W7-O5O39-W7-O1ω157.8(4)158.8(4)84.7(3)85.6(3)73.7(3)101.4(3)87.9(4)157.7(4)100.4(4)156.6(4)174.0(2)73.8(3)83.2(3)102.0(4)101.0(4)157.1(3)158.1(3)87.0(4)84.7(2)82.1(2)101.9(4)88.8(3)85.9(4)100.2(4)87.3(3)170.7(3)73.7(3)74.3(3)101.6(3)100.6(4)88.5(4)89.7(4)87.5(4)85.0(2)73.2(2)102.6(4)89.2(4)156.6(4)98.9(4)156.9(4)174.4(3)72.7(3)85.1(3)103.8(3)98.0(3)158.2(3)158.3(3)89.5(4)74.4(3)227УголO5-W7-O1O29-W8-O27O29-W8-O35O27-W8-O35O5-W8-O30O35-W8-O30O5-W8-O3O35-W8-O3O28-W9-O24O24-W9-O14O24-W9-O23O28-W9-O40O14-W9-O40O28-W9-O1O14-W9-O1O40-W9-O1O17-W10-O33O17-W10-O6O33-W10-O6O7-W10-O10O6-W10-O10O7-W10-O2O6-W10-O2O22-W11-O23O23-W11-O38O23-W11-O19O33-W12-O12O11-W12-O32O12-W12-O32O11-W12-O2O12-W12-O2O4-Si1-O2O2-Si1-O3O2-Si1-O1Si1-O1-W7Si1-O1-W9W7-O1-W9Si1-O2-W3Si1-O2-W10W3-O2-W10W8-O35-W4ω84.1(3)103.5(4)100.7(4)90.4(3)89.3(3)86.4(3)83.8(3)74.6(3)99.6(4)91.0(4)158.0(3)99.9(3)157.4(3)171.1(3)83.8(2)73.9(2)103.2(4)100.8(4)89.4(3)89.0(3)158.2(4)83.3(3)84.8(3)102.9(3)86.1(4)157.8(3)156.1(3)157.8(3)88.1(4)84.3(2)82.8(2)110.24(9)108.5(2)109.4(3)123.4(4)125.0(3)91.46(15)125.17(3)123.85(10)89.91(4)120.3(5)УголO29-W8-O5O5-W8-O27O5-W8-O35O29-W8-O30O27-W8-O30O29-W8-O3O27-W8-O3O30-W8-O3O28-W9-O14O28-W9-O23O14-W9-O23O24-W9-O40O23-W9-O40O24-W9-O1O23-W9-O1O17-W10-O7O7-W10-O33O7-W10-O6O17-W10-O10O33-W10-O10O17-W10-O2O33-W10-O2O10-W10-O2O22-W11-O38O22-W11-O19O38-W11-O19Si1-O3-W4Si1-O3-W11W4-O3-W11Si1-O4-W5Si1-O4-W6W5-O4-W6W10-O6-W6W6-O9-W2W12-O11-W5W1-O13-W6W5-O16-W4W4-O19-W11W9-O24-W1W8-O27-W2W3-O32-W12ω100.9(4)86.2(3)158.3(4)97.2(4)159.3(4)170.6(3)84.8(3)74.6(3)102.6(4)102.3(4)84.6(4)86.2(4)89.6(4)73.9(3)84.2(2)100.9(4)155.8(4)84.2(3)100.9(4)88.4(3)173.3(3)72.9(3)73.8(3)103.1(4)99.3(4)88.4(4)124.43(3)124.1(3)91.30(12)125.3(3)123.5(3)90.26(5)152.8(4)123.2(5)152.3(5)151.3(5)150.6(5)121.6(5)120.5(4)151.8(5)120.4(4)228Приложение Л 2.

Геометрические параметры водородных связей вструктуре соединения (C6H8N2)3Н4[SiW12O40].9H2O (Å и °)D-HOW1-HW1AOW1-HW1BOW1-HW1BOW1-HW1BOW2-HW2AOW2-HW2BOW2-HW2BOW2-HW2BOW3-HW3AOW3-HW3AOW3-HW3BOW4-HW4AOW4-HW4BOW4-HW4BOW5-HW5AOW5-HW5BOW6-HW6AOW6-HW6BOW7-HW7AOW7-HW7BOW8-HW8AOW8-HW8BOW8-HW8BOW8-HW8BOW8-HW8COW9-HW9AOW9-HW9BN1A-H1A1N1A-H1A2N6A-H6A1N6A-H6A2D-HN6A-H6A3N1B-H1B1N1B-H1B1N1B-H1B2N1B-H1B3N6B-H6B1N6B-H6B2N1C-H1C2N6C-H6C1N6C-H6C2d(D-H)0.820.820.820.820.820.820.820.820.820.820.820.820.820.820.820.820.820.820.820.820.820.820.820.820.820.820.820.890.890.890.89d(D-H)0.890.890.890.890.890.890.890.890.890.89d(H...A)1.8062.5242.5512.5522.3132.6182.6182.6842.4192.5482.1211.8552.4112.6462.1272.4852.2302.5621.9301.8782.0662.4772.5602.6252.2082.3712.0642.3132.4332.1062.317d(H...A)2.1092.3372.6282.0582.0812.5492.0222.5332.1212.047<DHA178.47115.73129.88164.75136.44125.87125.87114.41139.04135.08179.50164.42124.43116.08148.29145.19156.13117.46179.79162.69144.98113.61155.24118.65161.69134.01143.64143.50125.41139.53133.32<DHA130.16120.23111.76145.87165.98110.40167.95123.43153.40164.67d(D...A)2.6542.9723.1403.3492.9613.1693.1693.1143.0853.1812.9692.6542.9533.0962.8583.1932.9983.0292.7782.6712.7782.9043.3223.1032.9982.9992.7683.0753.0452.8402.999d(D...A)2.7692.8893.0712.8392.9532.9772.9043.1142.9422.914AOW4O12O19O38O28O17O17N1CO26OW5OW6OW1N1BOW1N6BO26OW8O17OW8OW1OW7N6BO20O5OW6N6AO39OW2O19O24OW9AOW4OW7OW6OW3OW4O29OW8OW2OW9O37Операция симметрии------------------x, -y-1, -z+1-x, -y-1, -z+1-x, -y-1, -z+1-------------------x, -y, -z+1-x, -y, -z+1-x, -y, -z+1------------------x, -y, -z-x, -y, -z-----------------x, y, z+1-x, -y-1, -z+1x-1, y, z-x, -y, -zx-1, y, z------------------x-1, y-1, z------------------x+1, y+1, z-x+1, -y, -z---------------------------------------x+1, y, z-------------------x, y-1, z-x+1, -y, -z+1------------------x, y-1, z------------------Операция симметрии-x, -y-1, -z+1-x, -y-1, -z-x, -y, -z------------------x, y, z-1-x+1, -y, -z-x+1, -y, -z-x, -y, -z+1x-1, y, z-x-1, -y-1, -z229.

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