Диссертация (1155365), страница 28
Текст из файла (страница 28)
Валентные углы в соединении [NH4]6Н6[Cа4V12O40]·12H2OУголω, градУголω, градO(4)V(1)O(3)103.58(11)O(2)#1Ca(1)Ca(1)#290.53(5)O(3)V(1)O(3)#192.9(2)O(2)#1Ca(1)Ca(1)#3117.90(5)O(4)V(1)O(2)102.03(14)Ca(1)#2Ca(1)Ca(1)#360.0O(3)V(1)O(2)152.91(12)O(2)#1Ca(1)Ca(1)#157.95(5)O(2)#2V(1)O(2)76.56(15)O(2)#2Ca(1)V(1)136.43(8)O(2)V(1)O(1)#375.56(11)O(2)#3Ca(1)V(1)89.05(2)O(4)V(1)V(1)#291.84(12)O(2)Ca(1)V(1)38.65(6)O(3)V(1)V(1)#2129.79(10)O(1)#1Ca(1)V(1)91.366(19)O(2)V(1)V(1)#240.26(6)O(1)#3Ca(1)V(1)50.08(8)O(4)V(1)Ca(1)138.93(9)O(1)Ca(1)V(1)135.27(9)O(3)V(1)Ca(1)117.42(8)O(2)#1Ca(1)V(1)122.19(6)O(2)V(1)Ca(1)37.16(9)Ca(1)#2Ca(1)V(1)62.51(2)O(2)Ca(1)O(1)170.92(16)Ca(1)#2Ca(1)V(1)122.49(2)O(1)#3Ca(1)O(1)85.21(16)Ca(1)#3Ca(1)V(1)#162.51(2)O(2)#2Ca(1)O(2)#340.33(10)V(1)Ca(1)V(1)#3119.757(4)O(2)#1Ca(1)O(2)#3137.99(7)Ca(1)#2O(1)Ca(1)94.59(15)O(2)Ca(1)O(2)#192.95(5)Ca(1)#3O(1)V(1)#391.02(4)O(1)#2Ca(1)O(2)#347.83(8)Ca(1)O(1)V(1)#3171.71(19)O(1)#3Ca(1)O(2)#3132.90(11)V(1)#3O(1)V(1)#182.78(12)O(1)Ca(1)O(2)#187.12(5)Ca(1)O(2)V(1)104.19(13)O(2)#2Ca(1)Ca(1)#2130.80(8)V(1)#2O(2)V(1)99.48(13)O(2)Ca(1)Ca(1)#284.25(10)V(1)O(3)V(1)#2119.30(15)O(1)#2Ca(1)Ca(1)#242.70(7)H(51)O(5)H(52)97.70(0)O(1)Ca(1)Ca(1)#286.68(11)Координаты симметрически эквивалентных атомов:#1 y+1,-z,-x+1; #2 x,-y,-z; #3 -x+2,-y,z.204Приложение Д.Валентные углы (ω, град) в соединении (NН4)4[Mo8O26]•4H2OУголО(6)-Mo(1)-O(7)О(6)-Mo(1)-O(5)О(7)-Mo(1)-O(5)О(6)-Mo(1)-O(2)О(7)-Mo(1)-O(2)O(5)-Mo(1)-O(2)O(6)-Mo(1)-O(1)O(7)-Mo(1)-O(1)O(5)-Mo(1)-O(1)O(2)-Mo(1)-O(1)O(6)-Mo(1)-O(1)#1O(7)-Mo(1)-O(1)#1O(5)-Mo(1)-O(1)#1O(2)-Mo(1)-O(1)#1O(1)-Mo(1)-O(1)#1O(8)-Mo(2)-O(9)O(8)-Mo(2)-O(3)O(9)-Mo(2)-O(3)O(8)-Mo(2)-O(2)O(9)-Mo(2)-O(2)O(3)-Mo(2)-O(2)O(8)-Mo(2)-O(1)O(9)-Mo(2)-O(1)O(3)-Mo(2)-O(1)O(2)-Mo(2)-O(1)O(8)-Mo(2)-O(5)#1O(9)-Mo(2)-O(5)#1O(3)-Mo(2)-O(5)#1O(2)-Mo(2)-O(5)#1O(1)-Mo(2)-O(5)#1O(11)-Mo(3)-O(10)Mo(2)-O(1)-Mo(4)Mo(1)-O(1)-Mo(1)#1Mo(2)-O(1)-Mo(1)#1Mo(4)-O(1)-Mo(1)#1Mo(1)-O(1)-Mo(3)Mo(2)-O(1)-Mo(3)Mo(4)-O(1)-Mo(3)Mo(1)#1-O(1)-Mo(3)Mo(1)-O(2)-Mo(2)Mo(1)-O(2)-Mo(4)#1Mo(2)-O(2)-Mo(4)#1Mo(2)-O(3)-Mo(3)H(2A)-N(2)-H(2B)H(2A)-N(2)-H(2C)H(2B)-N(2)-H(2C)ω, град105.49(9)101.91(8)98.24(8)99.92(8)96.62(8)149.15(7)96.68(8)157.78(7)78.26(7)77.79(7)172.37(7)82.06(7)77.67(6)77.82(6)75.74(7)106.04(9)102.43(8)101.03(8)97.17(8)98.94(8)146.78(7)93.62(7)159.88(8)78.33(7)73.87(6)163.48(7)88.10(7)82.67(7)71.71(6)71.82(6)105.82(9)163.25(8)104.26(7)97.41(6)97.42(6)163.84(8)85.62(5)86.14(5)91.90(6)109.59(8)109.76(7)104.20(7)116.16(9)111.0103.9107.2СвязьO(11)-Mo(3)-O(4)O(10)-Mo(3)-O(4)O(11)-Mo(3)-O(3)O(10)-Mo(3)-O(3)O(4)-Mo(3)-O(3)O(11)-Mo(3)-O(7)#1O(10)-Mo(3)-O(7)#1O(4)-Mo(3)-O(7)#1O(3)-Mo(3)-O(7)#1O(11)-Mo(3)-O(1)O(10)-Mo(3)-O(1)O(4)-Mo(3)-O(1)O(3)-Mo(3)-O(1)O(7)#1-Mo(3)-O(1)O(13)-Mo(4)-O(12)O(13)-Mo(4)-O(4)O(12)-Mo(4)-O(4)O(13)-Mo(4)-O(5)O(12)-Mo(4)-O(5)O(4)-Mo(4)-O(5)O(13)-Mo(4)-O(1)O(12)-Mo(4)-O(1)O(4)-Mo(4)-O(1)O(5)-Mo(4)-O(1)O(13)-Mo(4)-O(2)#1O(12)-Mo(4)-O(2)#1O(4)-Mo(4)-O(2)#1O(5)-Mo(4)-O(2)#1O(1)-Mo(4)-O(2)#1Mo(1)-O(1)-Mo(2)Mo(1)-O(1)-Mo(4)Mo(4)-O(4)-Mo(3)Mo(1)-O(5)-Mo(4)Mo(1)-O(5)-Mo(2)#1Mo(4)-O(5)-Mo(2)#1Mo(1)-O(7)-Mo(3)#1H(14A)-O(14)-(14B)H(15A)-O(15)-(15B)H(1A)-N(1)-H(1B)H(1A)-N(1)-H(1C)H(1B)-N(1)-H(1C)H(1A)-N(1)-H(1D)H(1B)-N(1)-H(1D)H(2A)-N(2)-H(2D)H(2B)-N(2)-H(2D)H(2C)-N(2)-H(2D)ω, град103.73(8)99.09(8)102.19(8)99.35(8)142.52(7)90.47(8)163.71(8)76.81(7)76.38(7)159.58(8)94.59(8)73.18(6)73.05(6)69.12(6)104.38(9)100.58(8)102.04(8)100.26(8)95.88(8)148.06(7)160.49(7)94.83(7)78.29(7)74.01(6)88.56(7)163.58(7)85.11(7)71.51(6)71.93(6)92.11(6)91.76(6)117.32(9)109.24(8)110.10(8)104.16(7)116.89(9)109.5108.7114.0104.4114.0104.4114.0111.5111.5111.5205Приложение Е.Валентные углы (ω) в соединении (NH4)2[Co(H2O)4]2H2[Mo8O28].6H2OСвязьO(7)-Mo(1)-O(8)O(7)-Mo(1)-O(6)#1O(8)-Mo(1)-O(6)#1O(7)-Mo(1)-O(3)O(8)-Mo(1)-O(3)O(6)#1-Mo(1)-O(3)O(7)-Mo(1)-O(1)O(8)-Mo(1)-O(1)O(6)#1-Mo(1)-O(1)O(3)-Mo(1)-O(1)O(7)-Mo(1)-O(4)O(8)-Mo(1)-O(4)O(6)#1-Mo(1)-O(4)O(3)-Mo(1)-O(4)O(1)-Mo(1)-O(4)O(9)-Mo(2)-O(10)O(9)-Mo(2)-O(5)O(10)-Mo(2)-O(5)O(9)-Mo(2)-O(3)O(10)-Mo(2)-O(3)O(5)-Mo(2)-O(3)O(9)-Mo(2)-O(1)O(10)-Mo(2)-O(1)O(5)-Mo(2)-O(1)O(3)-Mo(2)-O(1)O(9)-Mo(2)-O(2)O(10)-Mo(2)-O(2)O(5)-Mo(2)-O(2)O(3)-Mo(2)-O(2)O(1)-Mo(2)-O(2)O(11)-Mo(3)-O(4)O(11)-Mo(3)-O(2)O(4)-Mo(3)-O(2)O(11)-Mo(3)-O(1)#1O(4)-Mo(3)-O(1)#1O(2)-Mo(3)-O(1)#1O(11)-Mo(3)-O(6)O(4)-Mo(3)-O(6)O(2)-Mo(3)-O(6)O(1)#1-Mo(3)-O(6)O(11)-Mo(3)-O(1)Mo(3)-O(2)-Mo(2)Mo(4)-O(2)-Mo(2)Mo(1)-O(3)-Mo(2)Mo(3)-O(4)-Mo(1)Mo(2)-O(5)-Mo(4)ω, град103.6(2)104.11(19)98.2(2)104.8(2)95.33(18)144.06(19)156.03(19)100.40(19)71.99(16)72.88(17)84.84(19)171.10(17)82.33(18)79.49(16)71.23(15)103.7(2)100.4(2)102.8(2)99.99(19)90.77(19)152.00(17)92.72(18)158.72(18)87.25(17)72.82(16)166.73(19)89.46(18)74.25(16)81.58(16)75.07(15)103.4(2)104.43(19)102.42(19)103.1(2)96.72(19)141.51(17)99.1(2)157.01(19)76.40(17)73.15(16)177.79(18)109.7(2)92.13(14)112.3(2)116.38(19)116.2(2)Связьω, градO(4)-Mo(3)-O(1)76.35(17)O(2)-Mo(3)-O(1)77.75(16)O(1)#1-Mo(3)-O(1)74.77(17)O(6)-Mo(3)-O(1)81.03(15)O(13)-Mo(4)-O(14)106.2(2)O(13)-Mo(4)-O(12)100.62(16)O(14)-Mo(4)-O(12)97.80(15)O(13)-Mo(4)-O(5)93.7(2)O(14)-Mo(4)-O(5)91.7(2)O(12)-Mo(4)-O(5)159.80(11)O(13)-Mo(4)-O(6)91.29(18)O(14)-Mo(4)-O(6)161.6(2)O(12)-Mo(4)-O(6)83.97(12)O(5)-Mo(4)-O(6)81.50(16)O(13)-Mo(4)-O(2)157.29(19)O(14)-Mo(4)-O(2)92.93(19)O(12)-Mo(4)-O(2)88.43(11)O(5)-Mo(4)-O(2)73.27(16)O(6)-Mo(4)-O(2)68.80(16)O(15)-Co(1)-O(18)176.8(2)O(15)-Co(1)-O(8)#290.9(2)O(18)-Co(1)-O(8)#287.79(19)O(15)-Co(1)-O(17)90.8(2)O(18)-Co(1)-O(17)90.6(2)O(8)#2-Co(1)-O(17)177.2(2)O(15)-Co(1)-O(14)90.3(2)O(18)-Co(1)-O(14)86.75(19)O(8)#2-Co(1)-O(14)88.55(17)O(17)-Co(1)-O(14)93.6(2)O(15)-Co(1)-O(16)87.8(2)O(18)-Co(1)-O(16)95.08(19)O(8)#2-Co(1)-O(16)89.40(17)O(17)-Co(1)-O(16)88.5(2)O(14)-Co(1)-O(16)177.20(19)Mo(3)#1-O(1)-Mo(2)148.7(2)Mo(3)#1-O(1)-Mo(1) 102.24(16)Mo(2)-O(1)-Mo(1)96.93(17)Mo(3)#1-O(1)-Mo(3) 105.23(17)Mo(2)-O(1)-Mo(3)97.04(16)Mo(1)-O(1)-Mo(3)95.84(14)Mo(3)-O(2)-Mo(4)109.0(2)Mo(1)#1-O(6)-Mo(3) 108.25(17)Mo(1)#1-O(6)-Mo(4)147.5(2)Mo(3)-O(6)-Mo(4)103.82(19)Mo(1)-O(8)-Co(1)#3172.9(3)Mo(4)#4-O(12)-Mo(4)180.0206СвязьMo(4)-O(14)-Co(1)Co(1)-O(15)-H(15A)Co(1)-O(15)-H(15B)H(15A)-O(15)-H(15B)Co(1)-O(15)-H(15C)H(15A)-O(15)-(15C)H(15B)-O(15)-H(15C)Co(1)-O(17)-H(17B)H(17A)-O(17)-H(17B)Co(1)-O(18)-H(18A)Co(1)-O(18)-H(18B)H(18A)-O(18)-H(18B)H(19A)-O(19)-H(19B)H(1A)-N(1)-H(1D)H(1B)-N(1)-H(1D)ω, град176.7(3)118.7107.8107.7107.1107.6107.5105.0106.0103.0111.0111.2117.3108.0108.0СвязьCo(1)-O(16)-H(16A)Co(1)-O(16)-H(16B)H(16A)-O(16)-H(16B)Co(1)-O(16)-H(16C)H(16A)-O(16)-H(16C)H(16B)-O(16)-H(16C)Co(1)-O(17)-H(17A)H(20A)-O(20)-H(20B)H(21A)-O(21)-H(21B)H(21C)-O(21')-H(21D)H(1A)-N(1)-H(1B)H(1A)-N(1)-H(1C)H(1B)-N(1)-H(1C)H(1C)-N(1)-H(1D)ω, град117.0108.0108.0108.0107.8107.8105.5114.2107.9104.1117.3108.0108.0107.2207Приложение Ж1.Валентные углы (ω, град) в соединении (C6H11NO)6Н3[PW12O40]УголO(25)-W(1)-O(9)O(25)-W(1)-O(1)O(9)-W(1)-O(1)O(25)-W(1)-O(3)O(9)-W(1)-O(3)O(1)-W(1)-O(3)O(25)-W(1)-O(4)O(9)-W(1)-O(4)O(1)-W(1)-O(4)O(3)-W(1)-O(4)O(25)-W(1)-O(37)O(9)-W(1)-O(37)O(1)-W(1)-O(37)O(3)-W(1)-O(37)O(4)-W(1)-O(37)O(26)-W(2)-O(6)O(26)-W(2)-O(5)O(6)-W(2)-O(5)O(26)-W(2)-O(1)O(6)-W(2)-O(1)O(5)-W(2)-O(1)O(26)-W(2)-O(2)O(6)-W(2)-O(2)O(5)-W(2)-O(2)O(1)-W(2)-O(2)O(26)-W(2)-O(37)O(6)-W(2)-O(37)O(5)-W(2)-O(37)O(1)-W(2)-O(37)O(2)-W(2)-O(37)O(27)-W(3)-O(7)O(27)-W(3)-O(8)O(7)-W(3)-O(8)O(27)-W(3)-O(3)O(7)-W(3)-O(3)O(8)-W(3)-O(3)O(27)-W(3)-O(2)O(7)-W(3)-O(2)O(8)-W(3)-O(2)O(3)-W(3)-O(2)O(27)-W(3)-O(37)O(7)-W(3)-O(37)O(8)-W(3)-O(37)ω103.9(5)101.4(5)154.6(5)101.1(5)89.4(5)87.9(5)103.7(5)85.0(4)86.9(5)155.2(5)168.4(4)84.8(4)70.5(4)71.0(4)84.4(4)104.1(5)103.5(5)84.4(4)101.2(5)154.7(5)89.4(5)99.9(5)88.0(4)156.6(5)88.1(5)168.0(5)84.0(4)85.9(4)71.0(4)71.3(4)105.7(5)102.6(5)86.2(5)100.3(5)154.0(5)87.5(4)101.6(5)87.8(5)155.8(5)87.7(4)168.5(4)83.1(4)85.2(4)УголO(35)-W(11)-O(23)O(19)-W(11)-O(23)O(35)-W(11)-O(22)O(19)-W(11)-O(22)O(23)-W(11)-O(22)O(35)-W(11)-O(18)O(19)-W(11)-O(18)O(23)-W(11)-O(18)O(22)-W(11)-O(18)O(35)-W(11)-O(39)O(19)-W(11)-O(39)O(23)-W(11)-O(39)O(22)-W(11)-O(39)O(18)-W(11)-O(39)O(36)-W(12)-O(23)O(36)-W(12)-O(24)O(23)-W(12)-O(24)O(36)-W(12)-O(20)O(23)-W(12)-O(20)O(24)-W(12)-O(20)O(36)-W(12)-O(21)O(23)-W(12)-O(21)O(24)-W(12)-O(21)O(20)-W(12)-O(21)O(36)-W(12)-O(40)O(23)-W(12)-O(40)O(24)-W(12)-O(40)O(20)-W(12)-O(40)O(21)-W(12)-O(40)O(39)-P(1)-O(40)O(39)-P(1)-O(37)O(40)-P(1)-O(37)O(39)-P(1)-O(38)O(40)-P(1)-O(38)O(37)-P(1)-O(38)W(2)-O(1)-W(1)W(2)-O(2)-W(3)W(3)-O(3)-W(1)W(4)-O(4)-W(1)W(5)-O(5)-W(2)W(2)-O(6)-W(6)W(3)-O(7)-W(7)W(3)-O(8)-W(8)ω104.6(5)87.2(5)105.7(5)154.3(5)85.3(4)101.5(5)87.6(4)153.9(5)88.4(4)168.1(5)71.3(4)83.5(4)83.4(4)70.6(4)103.1(5)102.4(5)85.6(4)103.1(4)89.4(5)154.4(5)102.7(5)154.2(5)88.5(4)85.2(4)169.4(4)84.6(4)85.2(4)69.4(4)69.8(4)111.0(5)108.4(6)110.1(6)108.4(6)110.6(6)108.2(5)128.7(6)127.4(6)128.3(6)149.5(5)150.6(5)153.1(6)152.7(7)149.8(7)208УголO(3)-W(3)-O(37)O(2)-W(3)-O(37)O(28)-W(4)-O(4)O(28)-W(4)-O(15)O(4)-W(4)-O(15)O(28)-W(4)-O(16)O(4)-W(4)-O(16)O(15)-W(4)-O(16)O(28)-W(4)-O(10)O(4)-W(4)-O(10)O(15)-W(4)-O(10)O(16)-W(4)-O(10)O(28)-W(4)-O(38)O(4)-W(4)-O(38)O(15)-W(4)-O(38)O(16)-W(4)-O(38)O(10)-W(4)-O(38)O(29)-W(5)-O(11)O(29)-W(5)-O(5)O(11)-W(5)-O(5)O(29)-W(5)-O(17)O(11)-W(5)-O(17)O(5)-W(5)-O(17)O(29)-W(5)-O(10)O(11)-W(5)-O(10)O(5)-W(5)-O(10)O(17)-W(5)-O(10)O(29)-W(5)-O(38)O(11)-W(5)-O(38)O(5)-W(5)-O(38)O(17)-W(5)-O(38)O(10)-W(5)-O(38)O(30)-W(6)-O(12)O(30)-W(6)-O(6)O(12)-W(6)-O(6)O(30)-W(6)-O(11)O(12)-W(6)-O(11)O(6)-W(6)-O(11)O(30)-W(6)-O(18)O(12)-W(6)-O(18)O(6)-W(6)-O(18)O(11)-W(6)-O(18)O(30)-W(6)-O(39)O(12)-W(6)-O(39)O(6)-W(6)-O(39)ω71.2(4)70.8(4)101.8(6)103.9(6)87.4(4)101.8(5)156.4(4)88.2(4)99.9(6)88.5(5)156.2(4)86.3(4)168.1(5)85.1(4)86.0(4)71.5(4)70.3(4)104.7(5)103.6(5)85.5(5)101.4(5)88.8(5)155.1(5)99.8(5)155.6(5)88.4(5)86.8(5)167.7(5)84.9(4)84.6(4)70.7(4)70.9(4)101.3(5)102.9(5)89.7(4)103.9(5)154.8(5)84.6(5)103.0(5)86.9(4)154.0(5)87.6(4)170.8(4)71.4(4)83.0(4)УголW(1)-O(9)-W(9)W(5)-O(10)-W(4)W(5)-O(11)-W(6)W(6)-O(12)-W(7)W(8)-O(13)-W(7)W(9)-O(14)-W(8)W(9)-O(15)-W(4)W(10)-O(16)-W(4)W(5)-O(17)-W(10)W(11)-O(18)-W(6)W(11)-O(19)-W(7)W(12)-O(20)-W(8)W(9)-O(21)-W(12)W(10)-O(22)-W(11)W(12)-O(23)-W(11)W(12)-O(24)-W(10)P(1)-O(37)-W(2)P(1)-O(37)-W(3)W(2)-O(37)-W(3)P(1)-O(37)-W(1)W(2)-O(37)-W(1)W(3)-O(37)-W(1)P(1)-O(38)-W(5)P(1)-O(38)-W(4)W(5)-O(38)-W(4)P(1)-O(38)-W(10)W(5)-O(38)-W(10)W(4)-O(38)-W(10)P(1)-O(39)-W(6)P(1)-O(39)-W(7)W(6)-O(39)-W(7)P(1)-O(39)-W(11)W(6)-O(39)-W(11)W(7)-O(39)-W(11)P(1)-O(40)-W(9)P(1)-O(40)-W(12)W(9)-O(40)-W(12)P(1)-O(40)-W(8)W(9)-O(40)-W(8)W(12)-O(40)-W(8)C(1)-O(41)-H(41O)C(1)-N(1)-C(6)C(1)-N(1)-H(1)C(6)-N(1)-H(1)O(41)-C(1)-N(1)ω152.3(6)127.8(5)150.9(7)128.8(7)152.5(5)129.6(6)149.5(6)128.1(5)129.5(6)128.8(6)129.2(5)132.0(5)130.0(6)150.7(6)152.1(5)150.2(6)126.0(6)125.3(5)90.3(4)125.0(6)89.6(3)89.4(4)126.8(6)124.8(6)90.9(3)123.7(5)90.1(3)89.6(3)128.0(5)125.1(6)89.1(3)125.6(6)88.9(4)87.9(3)125.8(5)125.4(6)89.7(3)125.5(6)89.6(3)89.5(3)109.5128.6(4)115.7115.7118.2(4)209УголO(11)-W(6)-O(39)O(18)-W(6)-O(39)O(31)-W(7)-O(13)O(31)-W(7)-O(19)O(13)-W(7)-O(19)O(31)-W(7)-O(7)O(13)-W(7)-O(7)O(19)-W(7)-O(7)O(31)-W(7)-O(12)O(13)-W(7)-O(12)O(19)-W(7)-O(12)O(7)-W(7)-O(12)O(31)-W(7)-O(39)O(13)-W(7)-O(39)O(19)-W(7)-O(39)O(7)-W(7)-O(39)O(12)-W(7)-O(39)O(32)-W(8)-O(13)O(32)-W(8)-O(20)O(13)-W(8)-O(20)O(32)-W(8)-O(14)O(13)-W(8)-O(14)O(20)-W(8)-O(14)O(32)-W(8)-O(8)O(13)-W(8)-O(8)O(20)-W(8)-O(8)O(14)-W(8)-O(8)O(32)-W(8)-O(40)O(13)-W(8)-O(40)O(20)-W(8)-O(40)O(14)-W(8)-O(40)O(8)-W(8)-O(40)O(33)-W(9)-O(15)O(33)-W(9)-O(21)O(15)-W(9)-O(21)O(33)-W(9)-O(14)O(15)-W(9)-O(14)O(21)-W(9)-O(14)O(33)-W(9)-O(9)O(15)-W(9)-O(9)O(21)-W(9)-O(9)O(14)-W(9)-O(9)O(33)-W(9)-O(40)O(15)-W(9)-O(40)O(21)-W(9)-O(40)ω83.5(4)71.5(4)104.3(5)101.5(5)89.8(5)105.1(5)84.0(5)153.5(4)100.5(5)155.1(4)87.3(5)87.6(5)168.5(5)85.1(4)71.5(4)82.3(4)70.5(4)103.5(5)103.3(5)88.4(5)102.5(5)154.0(4)86.4(4)103.1(6)85.2(5)153.6(4)88.3(4)169.4(5)84.1(4)69.1(4)70.2(4)84.8(4)102.4(5)102.2(5)89.5(4)102.2(5)155.3(5)86.5(4)103.7(5)85.1(4)154.2(5)88.0(4)169.5(4)85.2(4)70.4(4)УголO(41)-C(1)-C(2)N(1)-C(1)-C(2)C(1)-C(2)-C(3)C(1)-C(2)-H(2A)C(3)-C(2)-H(2A)C(1)-C(2)-H(2B)C(3)-C(2)-H(2B)H(2A)-C(2)-H(2B)C(4)-C(3)-C(2)C(4)-C(3)-H(3A)C(2)-C(3)-H(3A)C(4)-C(3)-H(3B)C(2)-C(3)-H(3B)H(3A)-C(3)-H(3B)C(3)-C(4)-C(5)C(3)-C(4)-H(4A)C(5)-C(4)-H(4A)C(3)-C(4)-H(4B)C(5)-C(4)-H(4B)H(4A)-C(4)-H(4B)C(4)-C(5)-C(6)C(4)-C(5)-H(5A)C(6)-C(5)-H(5A)C(4)-C(5)-H(5B)C(6)-C(5)-H(5B)H(5A)-C(5)-H(5B)N(1)-C(6)-C(5)N(1)-C(6)-H(6A)C(5)-C(6)-H(6A)N(1)-C(6)-H(6B)C(5)-C(6)-H(6B)H(6A)-C(6)-H(6B)C(7)-N(2)-C(12)C(7)-N(2)-H(2)C(12)-N(2)-H(2)O(42)-C(7)-N(2)O(42)-C(7)-C(8)N(2)-C(7)-C(8)C(7)-C(8)-C(9)C(7)-C(8)-H(8A)C(9)-C(8)-H(8A)C(7)-C(8)-H(8B)C(9)-C(8)-H(8B)H(8A)-C(8)-H(8B)C(8)-C(9)-C(10)ω122.6(4)119.2(3)113.0(6)109.0109.0109.0109.0107.8114.1(8)108.7108.7108.7108.7107.6114.1(3)108.7108.7108.7108.7107.6117.0(8)108.1108.1108.1108.1107.3111.6(6)109.3109.3109.3109.3108.0129.8(7)115.1115.1121.4(5)126.2(5)112.4(3)113.4(4)108.9108.9108.9108.9107.7114.4(3)210УголO(14)-W(9)-O(40)O(9)-W(9)-O(40)O(34)-W(10)-O(22)O(34)-W(10)-O(24)O(22)-W(10)-O(24)O(34)-W(10)-O(16)O(22)-W(10)-O(16)O(24)-W(10)-O(16)O(34)-W(10)-O(17)O(22)-W(10)-O(17)O(24)-W(10)-O(17)O(16)-W(10)-O(17)O(34)-W(10)-O(38)O(22)-W(10)-O(38)O(24)-W(10)-O(38)O(16)-W(10)-O(38)O(17)-W(10)-O(38)O(35)-W(11)-O(19)N(2)-C(12)-H(12A)C(11)-C(12)-H(12A)N(2)-C(12)-H(12B)C(11)-C(12)-H(12B)H(12A)-C(12)-H(12B)C(13)-O(43)-H(43O)C(13)-N(3)-C(18)C(13)-N(3)-H(3)C(18)-N(3)-H(3)O(43)-C(13)-N(3)O(43)-C(13)-C(14)N(3)-C(13)-C(14)C(13)-C(14)-C(15)C(13)-C(14)-H(14A)C(15)-C(14)-H(14A)C(16)-C(17)-H(17B)H(17A)-C(17)-H(17B)N(3)-C(18)-C(17)N(3)-C(18)-H(18A)C(17)-C(18)-H(18A)N(3)-C(18)-H(18B)C(17)-C(18)-H(18B)H(18A)-C(18)-H(18B)C(19)-N(4)-C(24)C(19)-N(4)-H(4)C(24)-N(4)-H(4)O(44)-C(19)-N(4)ω70.5(4)83.9(4)103.5(5)103.3(5)85.8(4)101.2(5)155.3(5)90.0(4)101.4(5)87.1(4)155.2(5)86.5(4)167.9(4)84.6(4)86.1(4)70.8(4)69.6(4)100.0(5)110.4110.4110.4110.4108.6109.5127.8(8)116.1116.1117.0(5)126.5(6)116.3(5)114.9(3)108.5108.5108.7107.6116.1(4)108.3108.3108.3108.3107.4130.3(5)114.8114.8122.8(5)УголC(8)-C(9)-H(9A)C(10)-C(9)-H(9A)C(8)-C(9)-H(9B)C(10)-C(9)-H(9B)H(9A)-C(9)-H(9B)C(9)-C(10)-C(11)C(9)-C(10)-H(10A)C(11)-C(10)-H(10A)C(9)-C(10)-H(10B)C(11)-C(10)-H(10B)H(10A)-C(10)-H(10B)C(12)-C(11)-C(10)C(12)-C(11)-H(11A)C(10)-C(11)-H(11A)C(12)-C(11)-H(11B)C(10)-C(11)-H(11B)H(11A)-C(11)-H(11B)N(2)-C(12)-C(11)C(13)-C(14)-H(14B)C(15)-C(14)-H(14B)H(14A)-C(14)-H(14B)C(16)-C(15)-C(14)C(16)-C(15)-H(15A)C(14)-C(15)-H(15A)C(16)-C(15)-H(15B)C(14)-C(15)-H(15B)H(15A)-C(15)-H(15B)C(15)-C(16)-C(17)C(15)-C(16)-H(16A)C(17)-C(16)-H(16A)C(15)-C(16)-H(16B)C(17)-C(16)-H(16B)H(16A)-C(16)-H(16B)C(18)-C(17)-C(16)C(18)-C(17)-H(17A)C(16)-C(17)-H(17A)C(18)-C(17)-H(17B)C(21)-C(20)-H(20A)C(19)-C(20)-H(20B)C(21)-C(20)-H(20B)H(20A)-C(20)-H(20B)C(22)-C(21)-C(20)C(22)-C(21)-H(21A)C(20)-C(21)-H(21A)C(22)-C(21)-H(21B)ω108.7108.7108.7108.7107.6107.7(5)110.2110.2110.2110.2108.5112.4(7)109.1109.1109.1109.1107.9106.5(3)108.5108.5107.5113.8(5)108.8108.8108.8108.8107.7116.6(4)108.1108.1108.1108.1107.3114.1(7)108.7108.7108.7108.7108.7108.7107.6113.6(4)108.8108.8108.8211УголO(44)-C(19)-C(20)N(4)-C(19)-C(20)C(19)-C(20)-C(21)C(19)-C(20)-H(20A)C(21)-C(22)-H(22B)C(23)-C(22)-H(22B)H(22A)-C(22)-H(22B)C(24)-C(23)-C(22)C(24)-C(23)-H(23A)C(22)-C(23)-H(23A)C(25)-O(45)-H(45O)C(25)-N(5)-C(30)C(25)-N(5)-H(5)C(30)-N(5)-H(5)O(45)-C(25)-N(5)O(45)-C(25)-C(26)N(5)-C(25)-C(26)C(25)-C(26)-C(27)C(25)-C(26)-H(26A)C(27)-C(26)-H(26A)C(25)-C(26)-H(26B)C(27)-C(26)-H(26B)H(26A)-C(26)-H(26B)C(26)-C(27)-C(28)C(26)-C(27)-H(27A)C(28)-C(27)-H(27A)C(26)-C(27)-H(27B)C(28)-C(27)-H(27B)H(27A)-C(27)-H(27B)C(29)-C(28)-C(27)C(29)-C(28)-H(28A)C(27)-C(28)-H(28A)H(30A)-C(30)-H(30B)C(31)-N(6)-C(36)C(31)-N(6)-H(6)C(36)-N(6)-H(6)O(46)-C(31)-N(6)O(46)-C(31)-C(32)N(6)-C(31)-C(32)C(31)-C(32)-C(33)C(31)-C(32)-H(32A)C(33)-C(32)-H(32A)C(31)-C(32)-H(32B)C(36)-C(35)-H(35B)C(34)-C(35)-H(35B)ω120.4(5)116.2(3)114.1(4)108.7108.3108.3107.4115.4(5)108.4108.4109.5125.7(4)117.2117.2121.6(4)107.1(4)131.1(3)114.7(3)108.6108.6108.6108.6107.6121.4(3)107.0107.0107.0107.0106.7110.4(3)109.6109.6106.7126.4(4)116.8116.8121.0(5)123.2(5)115.9(3)112.6(4)109.1109.1109.1108.0108.0УголC(20)-C(21)-H(21B)H(21A)-C(21)-H(21B)C(21)-C(22)-C(23)C(21)-C(22)-H(22A)C(23)-C(22)-H(22A)C(24)-C(23)-H(23B)C(22)-C(23)-H(23B)H(23A)-C(23)-H(23B)N(4)-C(24)-C(23)N(4)-C(24)-H(24A)C(23)-C(24)-H(24A)N(4)-C(24)-H(24B)C(23)-C(24)-H(24B)H(24A)-C(24)-H(24B)C(29)-C(28)-H(28B)C(27)-C(28)-H(28B)H(28A)-C(28)-H(28B)C(28)-C(29)-C(30)C(28)-C(29)-H(29A)C(30)-C(29)-H(29A)C(28)-C(29)-H(29B)C(30)-C(29)-H(29B)H(29A)-C(29)-H(29B)N(5)-C(30)-C(29)N(5)-C(30)-H(30A)C(29)-C(30)-H(30A)N(5)-C(30)-H(30B)C(29)-C(30)-H(30B)C(33)-C(32)-H(32B)H(32A)-C(32)-H(32B)C(32)-C(33)-C(34)C(32)-C(33)-H(33A)C(34)-C(33)-H(33A)C(32)-C(33)-H(33B)C(34)-C(33)-H(33B)H(33A)-C(33)-H(33B)C(35)-C(34)-C(33)C(35)-C(34)-H(34A)C(33)-C(34)-H(34A)C(35)-C(34)-H(34B)C(33)-C(34)-H(34B)H(34A)-C(34)-H(34B)C(36)-C(35)-C(34)C(36)-C(35)-H(35A)C(34)-C(35)-H(35A)ω108.8107.7116.1(4)108.3108.3108.4108.4107.5117.2(4)108.0108.0108.0108.0107.2109.6109.6108.1123.9(4)106.3106.3106.3106.3106.4121.7(4)106.9106.9106.9106.9109.1107.8113.2(4)108.9108.9108.9108.9107.8110.0(4)109.7109.7109.7109.7108.2117.2(3)108.0108.0212УголH(35A)-C(35)-H(35B)N(6)-C(36)-C(35)N(6)-C(36)-H(36A)C(35)-C(36)-H(36A)ω107.2113.1(4)108.9108.9УголN(6)-C(36)-H(36B)C(35)-C(36)-H(36B)H(36A)-C(36)-H(36B)ω108.9108.9107.8Приложение Ж 2.
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