Диссертация (1150306), страница 4
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+%/)&'*F%4%)*'%/&)5*F, & F +"#1,.&3 +*#5%)#)%J 7–10 )&9'T5&'*+( "* 5F& )&9*.& +%/)&'*F F+**,)*S#)%% 1:1, +**,F#,+,F:TM%3 )%,.%': % %4%)*'%/&)5:. R&.&1,#.)*J 0#.,*J +"#1,.*FAOG1- 1*4"'#1+*F 7–17 2F'2#,+2 )&'%0%# 5F:3 :S%.#))H3 "%1*F F +'&9*4 "*'# ++**,)*S#)%#4 *,)*+%,#'()H3 %),#/.&'()H3 %),#)+%F)*+,#J 1:2, +**,F#,+,F:TM%3 ".*,*)&4%4%)*/.:""H % &4%5)*J /.:""H. -#+4*,.2 )& ,*, 0,* +"#1,.H 9H'% +)2,H F .&I'%0)H3.&+,F*.%,#'23 [CDCl3, (CD3)2CO % (CD3)2SO], F )%3 ".*+'#Y%F&#,+2 *5)& *9M&2 0#.,&: F+"#1,.&3 9, 10, 15–17 +%/)&' &,*4& F*5*.*5& %4%)*/.:""H +4#MU) )& ~2.5–4.0 4.5.!25!!*,)*+%,#'()* +**,F#,+,F:TM#/* +%/)&'& &,*4& F*5*.*5& NH F &'1%'- % &.%'1&.9*)%,.%'()H3".*%IF*5)H3 7, 8, 11–14 (;<ZH7=< 1).100100!(C–()!(C–()) (%)) (%)0!(N=C)"#$%&!(N–()!(N=C)"#$%&!(N=C)%&%'!(N–()!(N=C)%&%'0 36003600$&–1600–1600$&1*4"'#1+& 15.(78?AED 3.
>C +"#1,.100100) (%)) (%)!(N≡C)!(C–()!(C–()!(N–()!(N–()0!(N≡C)!(N=C)"#$%&!(N=C)"#$%&0 3600$&–13600$&–1!(N=C)%&%'!(N=C)%&%'600600(78?AED 4. >C +"#1,. 1*4"'#1+& 8.=&))*# .&I'%0%# F 3%4%0#+1%3 +5F%/&3 +F%5#,#'(+,F:#, * .&I'%0)*J 1*)K%/:.&$%%%4%)*'%/&)5*F F "*':0H3 1*4"'#1+&3. ; 8-%I*4#.&3 &,*4 F*5*.*5& %4%)*/.:""H:0&+,F:#, F *9.&I*F&)%% F*5*.*5)*J +F2I%, % #/* +%/)&' F +"#1,.&3 AOG 1- +4#M&#,+2 F!26!!+'&9*"*'():T *9'&+,( *,)*+%,#'()* "*5*9)*/* +%/)&'& F Z-%I*4#.&3, )# %4#TM%3 5&))*JF*5*.*5)*J +F2I% [16, 21, 24, 25, 27].;"*'*Y%,#'()*4.#Y%4#Z!>-O!-;G5'2+*#5%)#)%J+7–17+*1&I&'%+(+3&.&1,#.%+,%0)H4% "%1% "+#F5*4*'#1:'2.)H3 %*)*F [M + H] , [M + Na] % [M + K] . 8*4%4*^,*/*, F +"#1,.&3 ,&1Y# )&9'T5&'%+( "%1% K.&/4#),)H3 %*)*F [M – Cl]+, [M – 2Cl – H]+ % [M –3Cl – 2H]+,5&))HJ,%"K.&/4#),&$%%3&.&1,#.%+,%0#)5'23'*.%5)H31*4"'#1+*F"'&,%)H(IV) [88].
G#I:'(,&,H ^'#4#),)*/* &)&'%I& 5'2 F+#3 "*':0#))H3 1*4"'#1+*F+*/'&+:T,+2 + .&+0U,)H4% 5&))H4% 5'2 ".#5"*'&/H3 +,.:1,:..O*'#1:'2.)H# +,.:1,:.H +*#5%)#)%J 8, 11 % 13–17 :+,&)*F'#)H + "*4*M(T 4#,*5&G!7. C**.5%)&$%*))HJ "*'%^5. 1*4"'#1+*F %4##, ,%"%0):T *1,&^5.%0#+1:T /#*4#,.%T +5F:42 %4%)*'%/&)5&4%, )&3*52M%4%+2 F 1$",+-"*'*Y#)%%. ;+# :/'H F*1.:/ 4#,&''*$#),.&9'%I1% 1 90º. G&++,*2)%2 Pt–Cl, )&3*52M%#+2 F 5%&"&I*)# 2.3102(9)–2.3240(13) Å, 2F'2T,+23&.&1,#.%+,%0)H4% 5'2 +F2I#J PtIV–Cl [16, 21, 24, 89], & 5'%)H +F2I#J Pt–N –3&.&1,#.%+,%0)H4% 5'2 +F2I#J Pt–N%4%) [16, 21, 24, 81].
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