Диссертация (1150167), страница 19
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Спектр ЯМР 1H (500 MГц, CDCl3) соединения 2zeH3COC1F 3HF2zeС249.0(ppm)9089(ppm)С110Рис. 51. Спектр ЯМР 13C (125 MГц, CDCl3) соединения 2ze13603.78014.36594.35364.32184.30925.37025.35845.34635.33455.32205.28055.26735.25575.24345.23076.86436.85047.25397.23757.22151.00000.9616IntegralH3CO-73.0CF3-73.5-74.08.0Д1-74.5-75.05.30(ppm)7.06.0-75.55.0(ppm)-76.0-76.5(ppm)6.15733.05315.401.00001.01025.20(ppm)4.0-200.2-77.0-77.53.05316.15731.00004.34964.33364.29274.27675.32705.32095.27435.26945.25915.25415.24385.23855.22865.22295.21335.2072Hb(Д1+Д2)3.0Д1-200.4-78.0-200.7386-200.7602-200.7845-200.8088-200.8332-200.8575-200.8818-200.9061-200.9304-200.9548-200.2252-200.2495-200.2711-200.2955-200.3198-200.3441-200.3684-200.3927-200.4171-200.43879.01.0102Integral3.78253.84773.8439CF3HbF-76.1673-76.1808-76.1916-76.2051-76.2673-76.2808-76.2916-76.305110.05.02971.8135H3CO-76.2673-76.2808-76.2916-76.3051-76.1673-76.1808-76.1916-76.2051Ha0.96161.0000IntegralH3COД1HbД2OCH32zf3.80(ppm)2.01.0F-200.6-78.5-200.8-79.00.0Рис.52.
Спектр ЯМР 1H (400 MГц, CDCl3) соединения 2zfH3COД2CFД2OCH32zf(ppm)-201.0-76.2(ppm)-79.5Рис. 53. Спектр ЯМР 19F (470 MГц, CDCl3) соединения 2zf1375.38805.38265.37275.36745.35755.35175.34185.33615.32705.32095.27435.26945.25915.25415.24385.23855.22865.22295.21335.20724.34964.33364.29274.27673.84773.84393.78257.26007.24137.22006.89706.87606.86876.86616.84666.83026.82496.80926.80396.77806.7730200125.3514138(ppm)190131180170130160150129(ppm)140130126120110CF3124(ppm)100(ppm)9080702.060501.02zh51.0(ppm)4021302019.2417C221.361521.225919.855519.241712.0021.03571.34852.43081.29502.4464Integral2.4(ppm)19.8555C321.361521.2259C1F 350.75993.050.99184.051.2238H51.45225.0(ppm)55.156451.452251.223850.991850.759943.52986.0120.91207.0113.9996113.6962138.7016137.3241130.8934130.6329129.8693129.6159128.4632128.1492127.9065127.7138125.3514123.1317120.91208.0128.1492127.9065127.7138128.4632129.8693129.6159130.8934130.63299.0123.1317137.3241138.701612.0021.03573.78113.7624CF3MeBr2zh3.8(ppm)2.20.0Рис.54.
Спектр ЯМР 1H (500 MГц, CDCl3) соединения 2zhHBrCH3C2128122C3CF320(ppm)19100Рис. 55. Спектр ЯМР 13С (125 MГц, CDCl3) соединения 2zh1382.38712.36092.32422.28382.38712.36092.32422.28383.78113.76244.95634.94474.92564.90587.21667.19947.14967.03487.01986.98116.96616.94376.92936.85166.83446.82266.806010.09.08.07.06.04.4(ppm)(ppm)5.0Д22.42893.82133.8181Br4.01.11944.52663.80(ppm)3.02.4289-67.701.11945.1(ppm)0.34104.46724.45314.43894.42484.41084.35154.34464.33704.32993.82133.8181-67.604.52667.04.41084.35154.34464.33704.3299-67.501.00665.10885.10205.05505.04092zh1.00660.34100.33851.00007.2-67.405.05505.04097.33857.32137.30857.29126.92596.92226.90876.9050-67.301.0000H3CO5.10885.10206.92596.92226.90876.90507.33857.32137.30857.2912HO0.33852.94072.8989-67.202.94072.8989IntegralCF3BrCF3(ppm)-67.80-67.902.0-68.00Рис.
56. Спектр ЯМР 19F (470 MГц, CDCl3) соединения 2zhCF3Д14Д1Д2OH2.5(ppm)(ppm)1.00.0Рис. 57 Спектр ЯМР 1H (500 MГц, CDCl3) соединения4139-67.5965-67.6100-65.6180170HOH3CO-66.055.049354.817354.581870.3338(ppm)128(ppm)160150-66.4140-66.8(ppm)130120CF3-67.2110100(ppm)-67.690-68.080Br-68.470114.0068113.8534HC360-68.8Д2(ppm) (ppm)(ppm)50404-69.230H3H3CO-69.651.676951.444951.213050.981055.274173.0245120127.2430120.1128128.3671124.5522124.3738126.7719122.3325122.1541H3CO122-69.1745-69.1907160.0(ppm)131.0150131.1578124(ppm)-67.4695-67.4830190159.8497160.0781126CF31.00002.8695IntegralHOC 1F 3C3C2BrC2H4OCH3C2Д155.0(ppm)51(ppm)CF32010Рис.
58. Спектр ЯМР 13C (125 MГц, CDCl3)соединения 4OCH3C1F2ClCHД1FД16aД2Д2(ppm)-70.0Рис. 59. Спектр ЯМР 19F (470 MГц, CDCl3)соединения 414055.274155.049354.817354.581851.676951.444951.213050.981073.024570.819170.3338131.1578131.0150128.3671127.2430126.7719124.5522124.3738122.3325122.1541120.1128114.0068113.8534160.0781159.8497200159.0(ppm)190MeO(ppm)1801702CC1(ppm)160FH(ppm)15014013012055.209955.17786.01105.0(ppm)(ppm)100(ppm)901.00004.080706.0632Integral1.02214.4(ppm)6.06321.00001.02214.04843.01994.04843.0199Integral(ppm)55.209955.177849.589349.432394.522094.304394.086692.969692.755592.5378114.2065113.95327.0113.9532114.20658.0129.1198132.3423132.2745132.1996131.6964131.6643130.4652129.8978129.11985.43.0C2(ppm)93(ppm)605049.589349.43233C(ppm)92.969692.755592.537894.522094.304394.0866H129.8978MeO158.71099.0130.465210.0131.6964131.6643132.3423132.2745132.1996158.7109Integral7.25(ppm)4.40724.39154.46094.44535.35255.34955.33315.27245.25645.23965.23665.22023.77536.85736.83527.26007.24517.23647.22343.77534.46094.44534.40724.39155.38575.36935.35255.34955.33315.27245.25645.23965.23665.22026.85736.83527.26007.24517.23647.2234MeOCF2ClFMeO6b(ppm)2.01.04030200.0Рис.
60 Спектр ЯМР 1H (400 MГц, CDCl3) соединения 6bC1F2Cl6bC3(ppm)49.5(ppm)grease10Рис. 61. Спектр ЯМР 13C (125 MГц, CDCl3) соединения 6b141010.09.08.07.08.06.0-78(ppm)7.85.0(ppm)-807.6-827.4(ppm)4.06.90536.86526.83266.7935-761.0000-747.26007.21977.2038MeO0.2621-727.40667.3909-702.2068-681.9026-662.5915Cl-647.64557.62987.61757.60277.51987.50527.4904-62.8-62.7382-62.7545-62.7707-61.0765-61.0900-61.1116-61.1251-60.7279-60.7496-60.7631-63.0841-63.1003-63.1165-63.1327Fb0.15827.89937.8852(ppm)1.9257Integral-621.00007.89937.88527.64557.62987.61757.60277.51987.50527.49047.40667.39097.26007.21977.20386.90536.86526.83266.7935-600.26211.92570.15822.59151.90262.2068IntegralFaFa ClFb7.23.0-191.0383-191.0735-191.0843-191.1086-191.1194-191.1329-191.1545-191.1680-191.1788-191.2032-191.2140-191.2491MeOFF6b-191.10(ppm)-63.0(ppm)-84-867.0-887a2.0-90-921.0-94Рис.
62. Спектр ЯМР 19F (470 MГц, CDCl3) соединения 6bOFZ-E-/ZE-6.80.0Рис. 63. Спектр ЯМР 1H (400 MГц, CDCl3) соединения 7а142-62.7220-62.7382-62.7545-62.7707-63.0841-63.1003-63.1165-63.1327-61.0765-61.0900-61.1116-61.1251-119.0-119.2160-119.4118.5781118.5317129.0155(ppm)(ppm)140-119.6120Cl-119.8-120.0(ppm)-120.3182180-120.2408135.9752135.9466(ppm)130.01.0000200131.0(ppm)155.7561153.5757187.6704187.4384132.0-119.4518-119.376122016.084Integral133.0128.5025129.3696129.3411129.1805129.8371129.8050131.7820131.7142133.0346OFCl10080-120.2-120.47a118.5(ppm)(ppm)60-120.64020-120.8-121.00Рис. 64. Спектр ЯМР 13C (125 MГц, CDCl3) соединения 7aZOFE-/Z-7aE--121.2Рис. 65.
Спектр ЯМР 1F (470 MГц, CDCl3) соединения 7a143136.0073135.9752135.9466133.0346131.7820131.7142129.8371129.8050129.3696129.3411129.1805128.5025118.5781118.5317155.7561153.5757187.6704187.4384.
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