А.Н. Кост, Р.С. Сагитуллин, А.П. Терентьев - Упражнения и задачи по органической химии (1125895), страница 39
Текст из файла (страница 39)
Cf/(CHOH).tA 0H+ It + 3NaOH _(6HOH)t+ 2Nal + 2H,D&\lOH2'20113 .21.CO'°13.37. BoceMb.13.38. a)I'-H(CHOH),ICH 313 .22.HH=F" HHeao:to"HnHHCH}OHHL-"pHTP03"CHO~HH~onD- SplI l'\103a13.23. ~ R~HORL -T))l:oJaHat13 .46.HITH°HCH 20R~.D·ranaJCTosa2 . 3.6-Tp HMeTUn rJlJOK038 II 2.3.4.
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TaJ<13.31. 4aCTlf Qna5J13.35.HCH 20H HCH2 0 HHvHD- TpeDaaH:!:H "+ OH )HCH20HCHOH--L--oH~OKHOH'HIKHOH." . I.n apbl (a) 11 ( B). 110 He (r) cn o.II) ClI~=CH -CH . - NH 2e)CH:lCHzCH1-NH-CH(CHs),II) NH ~CH2CJ\.!~Il~NJ-l~Ii)l(CHa),N}OHp) (CZH6 )~ -NOHOH°-r-Hn,..H!r)H)('''NIJzIl~HNH3 CElsx)~-r-HeRaH;l0H.L-3PIfT posa14 _2. . r )13 .36. OISere T p03b1 ,l{aIOT o,zam 11C n OTepeA aCHMMeTpHlJllOCTH TOT }f(e 03B30R. TaR RDR oOpa30nall1le ero CS5J 3alloy yrJJepO~Horo 8TOMa. oOyc.nOBJIIfBaJOUlero pa3 Jl1I QUE' MelK,lty 9TH/11K ,l{BYMlI reTpo3BMH:cnoyH- N- NHC;;HGH*OH- -f-NHc,H,HonC't.!OllHORC~20H~H0-=t=H.OR,IIC~OHD-"PIfTPDaa:?O2D·rjle03aMeT I1 J1~''HJ13MIlIl; 4 _aMlIDo - 2 - MeTl4Jlren Tall; N -!>IefllJlaueT 8M 1J.n .05a arO\13 830TS SClIMMe-rpHIUlbi • nM~Ol'Te-rp3aAplI'leCKoe CTpDelllle (Sp3.[,lI6pH)l,H3aJ.l.
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1. r)(CHshCHCHP-\COOHI14.28. 4 10 a.NHtCI-IsNH~ + CH sCOOH14 .30. a)2CH 3 NH 2--.+ CH ,COC I~ CH;JCONHCH s14.31. 0 6pa60TJ(oil CMeCH UJ,enO'lblO14.33. ~H.NH2+ 4H6 502C IIt3) 1I00CCH~CHsCHCOOHI+ CH"NH, • HCInOCJleAYlO u\t!1l neperoHKoa C BOAllll biM napoM.NdOH---- C sH aS0 2NIIC,ll.+ C6H.SO!!CI(C2 HI)~NH rNH.1CHKJcH~COON~OH+ HCI--+ C 61-I.S02N(C~H5 h+ HCI14 . 35. nC p'8H'IHO o6pa3YIomeecli N - lIInpo30coeAlmeHlle T3yroMepHo Kpaiille lleYCTofi ·'11l11<lM )' a.ijKIIJlJlH a3OCoellllHe.tIllIO . KOTopoe pacn aJl3eTcli c rtlTCpOJInTfl'leCKHMpa3p bl BoM CB1I311. o6pa3YSl MOJIelly.ny a30'ra. 11011 rUApoKclIJla It COOT l1el C1 BYIO'Ul ull K3HIOJf.
nOC.ijcJlfmil cnoco6en JlJI60 n\lllcOe.llltHIl'T L ItO H rllApOKclma. 06·pa3yll CTTll pT C lIell9MelffibiM CKeJleTOM. .llJf60 TCpMb npoT(JIj (06pa30B8J11leOJle<\luHa) . JlUOO Il00Meplf30aaTbc ll c nepeMemeHllelrt CI~Sl311 y r Jle poA-yrJlepo.ll, .nOCJl e.!ll UIR npouecc MOlKeT npUBeCTl-1 I( Kap6KanlOHY It3OCTpoeUH lI . CTpyKTypa/ · 3¢<t'eK'Ta Tpex a,lKllnb·KOToporo llecKOJIbKO 6o.,1Jee cTz 6111l1l30Balla 3a C'IeTflblX rpynll.Ta Koi'! KanlOn.
npnCOE'lllmSlll ru.nPOKCI1JI (06paTIlMo) . n peapa·maeTCll 6 rpeTlt411b1H cn llpT .NH~11)NII~CH2CHsCH~CH2CH2COOH T) CH:{-\-lCONIICl-lCOOH I16.2. II) <1. Me'fIlJl.(l· aMlIlIon pOITIIOIIOS31l KIICJlo,. a;)1) 6pO\ll l1AP8T 3'111J10(loro 3t\Jupa 2· aMKIl0t-.laCJIsmoi\ KIICJ\OThI . a) CH3CI-l ~NCl-IuCHJ1NO14. 38 .( Cl I3)~CHNH COCI .14 .42. r)(CH.hCIINHCONHCH(Cf-1 3 )206pa 3l:BaHIJ~1130HIlTpltJl a (0 npncYTcTBHIt 1I1eJIO'lH Jl)111 CBH3blBaitHII HC l):lK) paCK pblTlte 3nOKCH.II,HOrO KOJlbUa C o6pa30BBIllleM a ~II-I IIOCl1 l1 pTa.H<JiilUlTe B YQe61lJlKe npaw lJlo KpacyccKo ro ;3) Bmllllllle Ka p60llllJlbHOR r pynnhl lIa cOn plliKeJlHYlO AI}OHIfYIO COll3b yrne·pOA-y r .lepoA peSKO nOJlllpu3yeT n OC1lE'AIlI010.
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