А.Н. Кост, Р.С. Сагитуллин, А.П. Терентьев - Упражнения и задачи по органической химии (1125895), страница 42
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7. Y 2- II 4-MeTllJ1 X1l HOJlflHOB eCTb C06c TBeHHble H3313alili Sl22.B. 1-, 2- II4-t<:eTII JlllMJ I Aa3OJl bl (3-M eTIVlHIIIHA3SOJ1 flAellT II'Iella 4 - MeTIiMI MI1,ll H30.l1 HAe lllw~eH 5-MeTHJJIfMlJjlaaoJlY) ,1-..%1 . 1-. 2- Ii 3- aMIIH Omlp pOJlbl .22.12. 6) 2,3- AIlMenwcYI(UH n aJlblleru.ll.""- 0n-~ (II-~" CHO0/-~"0/()N1-1,0*rI!T pafll,1lpo'¢ YlJiI " CH, O':22 . 19 , CaC z - -.... HC=CH.--~*0"-nllppoJlII.lll"'**HOCH zC= CCli 20 H22 . 42.
Bc-1(a t tll Aoq,06HOCTb)~) + (CHaCOhO ~1!... 1-1""-0 N/~O'lUPPOJlllAOlI22 .22. a)#[1 IU"22 . 23 .CHIINNH,922.44. B)I- 1 /""-N/Ol)CH,N (CH,),e) np eJino'l1'lr'l'e1JbllOK011L U.O.BnOJlOlKetfHIl5n8,T . e. B O' U3OJlbllCle'"I6-1~ CoB.22.47. B) nap H- ; r)22 .50. PaCKJlhlTHe5-IIMeTa-:KOIIbUa11<) 2-1i: II) I-Ii n 3-ltC06pa3011SllneMrnyroKOHOBOr!i8.%AernAaOHCCH=GflCH.CHO22 .51. oj Jl,eik TBne N8NH~: 33TeM CHaJ;6) 8SaltMOneHCToHe c CtH.CHO n p "7- MI'T OKCHXIIIIOJllttIOB.22.24. 2-Men l .n - 5-~TIlJlTlHp"JU!H.22 26.
a) 2. -1 ,O-T}l IIMeTfI'lXJlIl0Jl11H;It) l -cpeUIIJl - 3 . 5 -AH MeTllJInHp a 90J1.22 . 27. a) 2 , 3 -JUlMenIJHtrlAOJl;220(lJlK3JlOHJI, r pSMlnIOl:CHSHN/"-ClI 3nOJlYI;ae1 r 11 CMeCb"A. -KHCJl OTa .8) B 06bl'lllhiX VCJlODllllX CIIJlTe3 ¢lIIWl'pa c alleT3JlbAerll.llOM lie ~tJl,eT. PeaKuHfi 11111: r llrp~3 CT8Amo .nerHilp 3TIIUIi H r m H.\eplIU8 .!l,O 8I1POJle}lH8.6)N.H.- --+KOH- -->""-OAC-C li~c"H./l/H, ----+22 .43. )1""-0 \.COCl-Ia-~-II~ H-~ * _ N-CftH.22.20 .
r) 5 -III1 TPOJ1 HJ.\0JI -2-Kap(50HoBsII Kllc.~ OTa.22 .21. B) O.ro.~IIJl nIApa 3 I1 H II 5-oKcoreKC3110 lJalitH.N)"C2 H&e) ,neK8 p 601(t. llJUlpOB8Hlle COOTBeTCTBYIOIIl.efr 2-Kap6mIOBOH '\IIC,10TbI.OTJl I11.JHe OT 111O¢ eH8 !jlYPfH n p8lC'T.Il'lE:CKH u e YASe-rCJI npliMo anKHmrpoBan.I-Me THJlfI MIIAa 30J1Y ,II 4-Mcu ln nH p aso-~I"N/"C2H, ¢YP<PypOJI (n3 t1eIl T031l1IOB) - -K,)lc.1JOTa - --+ 3!jmp:B) BOCCT811 0BJlelllle 3 - 8UeTltJlTl!o<Pe1l8 IfJill 'lepe3 TneIUIJIManlJliirsJlOreIlH,n;3-H¢ypaJl<jlyJX\JypoJJ•NII~ N/"-CH.C2H 622.32. 8)(cOOTBeTcmeHHo, lI:HHaJl bnemIlIHIJ) .r)-A~'"C2H~ IlwJl~!-I6ICijJ l~H22.J6.CtH6r)R)IAIHI 1\n"pS,1OJ1/0NH~0)nH830MeT3u --~If)I~ IIJ1R ZnCI~;0) OlmC.llellHe JlOKlICJJOTHOIol K8TBJlI18e (nanpllMepnllKOIIIIHonoll KIICJJOThI.Jl,eKapOOKClI.irnpooanlieC.Hr.COC I" BOCCTallOOneHlle, nO./lY'leHJIe mmepltJU1J1.B nnKarutHOBOJi KIICJJOTbI.~22122.5223.40.
r)e)~I-O~O-.-0HOr~O~~~H oNk~!U3!H3Cto6aa23 .53.22 .54. 0) 2-HO,ll.TMO<jleBjr) IIHTpOBaHHe 0 DOJIOJl\:eliHee) 2 ,3 .4.5-TeTp anO,ll;nFlppon;6(op aellTamllo onpe,lleJl!reT aTOM aSOTa)iretc~::olK) DPO~Jq' .il.lleBoaol'O (:itHTe3a23 .60.II) BHa'l aJIe OKHCJleliHe rpyn m >f eHs AO C001-lj K) OKHCJ1eBHe 6eH8OJ1h}{0ro KOJIbUa )1,0 TIHPIUlHlJ-2, 3-)luK apOcmoBOR IUICJlOrbl; Jl) BOCC1'aHOB.lletiae DJrplI )lHIIOOOrO KClIlbua j If) apoMaTHsaUitli (06pa 30BauH e DlrpH;!llm a) .
rayroMepH8S123 . 61. C,I-l ~NH2 -23.2.23.3. 23 .9.23.13. 3)~CH2HCIHC+~CI-l~23.18. A) NI-l 2CONH 223.20./CoH.HC4 - I1HTpO- ] ,3-)lHME'1'OKCHOeH30J11B0;JTo -nOJlOlKeJllle 1\ aneT8MHHorpyn ne(Oo.nee cHJl.bH1oIiropHeHTa tlT) ;8) 8aMe.melllle B OPTO-DOJIO)KetIJle K MeT1\JlbHOil rpynrrE' (MeHbmlljj 06'beM rpyn llht) ;F) 3aMemeHne B opTo·nOJlO)K eJ!ne KB MlIf KllX yCJIOBH~ X 2 "JU1T po lPefJOJI -4,cyJlb¢oK~IC;{OTa , B Oo.neeyCJI OBll llX- 2 4 -.aHRllTpo¢eHOJI B ll8)f(e nllKpnHOeaH KllCJJOTa; e) 2.4. 5-TpItMeTRJl8uero¢eHoH;.JI\:) 2,4- ,IlJlX.n0PBHTp o6eHSOJI; Jl)23.69.23 .70.\IHC'COC)H+ HNO]l-H~O-H-CeHfiIIICH-COO I-lHC'CI-l ,+ CO + Nt + NH4ND,2(npOMelKYTO'IIlO 06pa3y eTCl3 HeeTollKa Sl KapOaMlfHonafl jWCJlorll ~yCOOH).8) cpoploIaJlbJlernA Tflrp yeTclI ll.(eJtOttblO (raK Kal{ lIJJ.eT peaKUIUl KammUl{apo)CH.O+ KOH- - + CHaOI-l+ HCOOK23.22.
a) CHaCO (CH e), COOHn) HOOC (CHah CH (COOH) CH2 COOH28.25. 3)S·MeTMJIJ!3OTll0MOl!eBIlHS;Ii) 0pTOMypaShllRbUl 9cpnp.28.26. flonO)KnrenbHYlo peaKUHlO22'2J).aJOT6) I )1,)Ii lK).CoH5 COCH 2 CsH~ COCH 2 CH 2 COOH (n) ; If) ... t - HlI'Tp onpoH3BO.llHoe . MOJ!. Bee = 136; CSH S02 1.
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