А.Н. Кост, Р.С. Сагитуллин, А.П. Терентьев - Упражнения и задачи по органической химии (1125895), страница 25
Текст из файла (страница 25)
10.KHCs alim:15.9. Kalme COe)lHHetlHR 06p aS}'1OTcRLUux sew,eCTB:a) a KpHJlOBaflr) YKCYCHbli'l aarH)lpH.n;;Jl) 3T3Hon (B npncYTCTBlHie) aSOTliCT3R I<UCnOTa .e~Koro Kami;CO;'lSlHafl ImCJlOTa;nOAHCTblll MeTItJl;B) CHa- CH--CH-CH,- COOI-l *HarullDIlTe ypaBHennR pea RUIHl O:-Br-11lnOnp0nlIOHOBOH(aJlaRllHa) co CJl(!Jl,ylOliUn.m Bew,CCTBar.IH:15.13.JlOThllIarpeorulll"B - --tr15.20. B30In a.ll1 -Ta 6.lII u e CJIeBa )K3331lb1 nCXOAHhle COe)lHHerHlR, no r opu·p ea r eH Thl HamHlJllTe B CBo60JlllblX K.'1eTK8 X <t>or\lJJlLJ no.'ll'qeJmhlx opr3H IY'lecl{1{X coeAH Heflll fI.I I IaMHHOK!l CJlOT, liCXO.n;51N"OHHCIC,Ii,OIl1 ,,~u· 1 H 'fl"'''l\Il.~a) HOOCC H~CH" 'COO HIa -OKCII:'lac..1 JIll UH KIICJlOT8~.OKCJt~lBCJ1f1l1aSl Kllt.1 OJ aNH21.0KclI~aCJIIll!all(5) HOCH.CHl1 COO HJH120fillt.~OTaa .
A"\IItto~~aCJIllllaH KIlC/lOTa~ . AMlIllo."aCJIRlla ll KII{'.~OTalll -AMlIIIO'daC1lHlI!lH K!lCJlOT a"f("12115.21. H allu w HTe cJ>oP MYJlLl npoMe*YTO'lHbIXHHJ:i B CiJe,1{)'1OUUI x cxe~la x:a) l,2,3-TpHMeTHJ1ItHKJIOrrponaH;6) 1,3-,!{fiXJIopUFlKJJorreHTaH;B) 1.1 ,3' TpHMeTIfJIUIIKJIOreKcaB;r) ~-Ull KJlOr e1<CHJla1<pOJIeJIH;H KOHe'!H blX coe:UlHe-) NH2-CH~-COOH C1i,CI1I3rCOBt~ A lI:H,_6CICH,COCI--+6) CH.,-Cf-I-CH-COOHICI-I(.IMl2!\J IA '.
Bt 6.4.HaSOBI1Te npoJljl KTbl peal<uuii.. 5. 22. YCTaJlOBHTe CTpoeHHe sem.eCTsa C3lJ 70 llN, KOTopoe o 6.FJaJlaeT8MQxnepHblM H cBoiicTBaMH, npu peaKIU11J C a30TIICTOii KJICIIOTOil BbJ,J.eJI fl eTa301', C 3TIMOBbiM CfllfPTOM o6p a3YeT COe.ll.fUleHrfe C H 0 N, a ripu Habu 2rpenaHHH nepeXOJlHT B BemecTBo COCTaBa COHt002N2'C~HIIO:!N,OnpeJleJlliTe CTp oeHire BelQeCTBa c 6PYTTO-CPOPMYJlOHeCJIH 113BeCTHO, 'ITO OHO paCTBOpHeTCH B KHCJIOTax H IIl.e.nO'la x, C 3THJl OBbJMCrIHpTOl\1 06pa3 y eT BelQe<;TBO COCTaBa C 7 H 150 zN, a n pH Ha rpeBa Hl111 BbIlteJIHeT aMMH aK H nep eXOltHT B COeltHHeJUI e, n pH OKHCJleHHH KOToporoo6pa3YIOTc5I aUeTOR H Ul.a Be.1JeBaH K/i CJlOTa.15.23.r) 16.1.II6) (CH 2)8B)(CH 2h CH Cl-!3 .I\)(CH2)eCHCH 2C(CH,l)2Cf-12CI I-Ir) (CH a)i:(CH 2 'eCHC 2 H&• e) (CH2l2CHhC(CH3)C2HblK)OnfeThTe Te 113 HII X, KOTOpbJe HMelOT aCH MMeTpHlJeCKJU'j aTOM yrJlepOlta.16.2.
HanH llH1Te CTP YK1'YPHhle CPOPMYJlbl cJJeJlYIOIIl.nx coeltflHeHHii:na H; 6) I ,3-ltH3TH.1JQU K.lTo6YTaH;II) UMKJIOOKTaTeTpaeH-I,3,5;K) mpaJ-ic-l ,4-AHXJJOPI{11 KJlOreKcan;B) 1, I ,2·TpuMenfJJUH K.lTonea.Jl) 3TlfJllmemUflUIoneHT8rr;a J I, I ,·ltHMeTM.I)UHKJIOflPO_Tau;*r) I,3-ltrrMeTlfJlUHKJJOreI<cali(l(tIC- 11 mpaHc,)It) UHKJlOner-IT1i.'TQH l(JJoreKcall;e)1,2 -ltIlUII K.IJ OneHTII.IJ3Tau;>K) 3-MeTliJIUH KJlOreKceH ;". 3) 2,6-;J.IfMeTIIJIUHI<JJoreKca_ * M)* H)* 0)n) fl1111€1I; rUJKJlOreKCaH.lI.I10H_{ ,3; • c) KaMcpopa.p).lllleH·I,3; 16.3.f-Ia m1llulTeCTPYKTYPll brempaHc-H30MepoB COell.lIlleJUlH:CPOPMYJlbiBcexB03MO>KHblX'l'R}6H2~H-CHa¢4UOa6)q--cu,11)--ella11,)~An)QeRaH3C*e}·3) D-CH=CH-GH.c'J2U.16.5.J-MeTIlJl4-H30npOnTiJlUIIKJlOr eKcaH (1.leHTaH) ;JJll MOHea,MeHTO.'l; 1 ,2,3-TpHMeTH JII~HK.TIOnpOn8H;l,3-AUMeTnJIllIIK.1Jo6YTaH;I, I ,3-TpRMerHJlUH K.FJOrel<CaH;1,3-;mxJTopu nK.IJOneHTall.HH3C-CH~H3uaaBaHU1JHa30BHTe c.1JeltYI0Ul.He COeltHHeHHH:a) (CH 2) 4>1<)3)n)K)H16.
A.lUInIIKJIUQECK IIE Yl'JIEBOLJ.OPOLJ.b1 1,1 UX II POH3BOLJ.RLIECTpoeHueea-l,3;e) l,2-.lUIMerRJll.I.IIKJJOnpOnaH;Ha30BHTe CJIe;I,yIOlQHe COeAHHeHI1H:CH 2 a}.n) 1- MernJIUlfI{.IlOreKCa..'lH9:C2~b,H611)0CI-l--1Uj,r--f:ln Ha30BHTe Bee H30MepbJ B PH.ll.Y UJlKJT06YTaHa CC sHJ 6. 06paTHTe BlllIMalille ua lluc-mpaHc-u30Mepmo.HamtllilfTefipYTTO-CPOP~lyJlOH16.6. Hamllll1 Te JI lIa30BTITe l130Mepbl, OTJIuqalOIUlleCH pa3Jl1l tUlhlMnO.TI OiKeS1H!M .ll.BoClHofr CBH3U, .ll.JJR CJIe,.:1YIOUl.Hx coemmerulH: a) MerHJlUllK,lIo(5YTeJi; (5) MerllJlUHKJlOneHTeH; B) MenUlltIll<.TIOreKCeH; * r) MeTIVlUIIKnoreKcaAllell.
EeTb .tIlI Y H.HX cTepeo1l30MepbJ?16.7. HapneYliTe KOlIcpoPMaUHoHllbre cjJOPMYJJbl a, e-, e,a-, a,a- 1\e,e-l-MerlJ.rJ-3·3THJJUlIKJlOreKcaHa. KaKlfe 113 HIlX HBJllUOTCSl Ifuc-mpaflCH30Mepal.m?16.8. K81WH 113 1130MepoB 1,2-AIIMeTllJlUI!lUlOnpOnaHa 6y AeT 60neeycrOI1'IlIB - I~Uo- HJJU mpaHc?16.9. Hapl1cYllTe B03MO.m.Hble KOHcpoPMaInm )J)Ul mpaHc- nm1 IIUCI ,4-JlIf~leTHJTU UlUIOreKCaHa. KSKoe nO.IJOmeHIle aaiblYT 3aMecTUTeJlU B*J22123npOCTpaHCTBe nI)H BafIROo6pa3IlOii KOHqmrypaUHII KOJJbUa, ecJTll B ({peeJIOBI1.ll,Roil ORR ooa OWJIH 3KDaTOpIl2JIbHbIMH?16.10.
Hapllcyihe !j1oPMy.rJW H30MepHbTx yrJJeBo.nopo.nOB CsH ' RatoKoil 1f3 H30MepoB uaH60JJce HanpSI}f{CIIHLlIf?ucm16. J1. KaKoH li 3 4 - paHc,u30MCPOB 1,3-.nI1-mpem-6YTIl.1mIK.n06yTaR a Ran60Jlee CTa6lfJletf?J6.12• .M olKeT .IHI CYUJ.ecTBOB8Tb COeJl.IIHelHfe C meCTlP'IneJlHbTM yrJJenTlKJlOM, KOTopoe uo.lJee YCroll'tllBO B <PoPMe aaHHbl, qeM B ¢;opMeJ<peCJJa'Mil'B) BrCH~CH ~CH~CH 2COOCH3 - - + ?($rp)';' 16.2 t. KaKlie BeI.U.£ClB8 Mor YT 06pB30BaTbcR npu .IleiiCTBlH1 a30mc'fo ii KIJC.110Thl fla CJle.nyroIlJ,lle aMIlHbf (neper pynmlpOBKa H. 51.
neMbHH(}OBai:pO,L\Hb~116.13. Hapucyihe Bee 1f30Mepw 1.2,3,4,5,6-reI\C8XJJopUlIl\JIOreKC8HaB KomtmrypaL(IIH <cr.-pec.'lo» (HcnO.lJI,3YliTe JlJlJf 9Tora MO.:teJllI). lIJll'1 Ka.Koro B30Mepa 6o.1JbUIa$l qaCTb aTO~1OB rBJlOrella HaXOllHTC$! B aKCHa.'lbHOMnO.?lO.iKe.HIIII?16. 14. Hail,L\HTe B },'1eOHJlKe ¢oPMY.lJY XpJf33HTeMoBoH KHCJlOTbJ (coc.TaBHa H tJBCTb Tll1 perpYMa) . Ha mlIllllTe JJ.JUI Hee 4uc-mPaHC-H 30Me pbl. .LIa».Te JIM CHCTeMaTfftleCKOe Ha 3Ba Hue.lIonyqeHUe15. 06pa30saIJRe UHKJlOaJlKaHa (CH~n no peaKUI,," Br (CH:Jn BrnpOHCXO.llHT KOHKypellTHO C pea KlUlSlMH m n a2Br(CH :Jll B rZn -+ 2B r (CHa)n( CH :Jn Br06'hHCHHTe: 16..+ Zn+6) KaK .uOJliKeH 3aBHceTb BbJXOJl UR I<JTOaJT Kana OT BeJJHqHHhl o6pa3YroIlleroCR u flK.TJa?.16.16.
nOJIY4BTeB3 cooTBeTcTsYJOUJ.JIX) l\IeTHJJUH1<.lJOn pOn aH;B)6) 1,2-.nH~lernJlIJ.H KJlo6YTaH,.ll.HraJJOrelfn p OH 3BO.llHblX1.2~.lnI MenIJlUJlK.rlonponaH; 1') ! ,3-.ll.HM7T11JJilllKJlo6yraH. .LIaiiTe 06ocHoBaHHe Bbl60py .lUl r aJJOrel'lH.Ila.16.17. npe.LtJJO)f{JITe CUHTes IJ.HKJlOrenTB Ha U UHJ<)]OOKTBffa 0 nOMOUl.blOMaJlOnOBoro sq)JJ pa.16.18. OpellJJO>l<lITe nynl ClfllTe3a a) ./lll3T1.JJTall,HnaT -+ llIIJWOneHTaH; 6) .IlUSTIlJla.lll·m aT -+ 6)Trf.'l ul1 KJTO neHTBu; s) lUI3T1iJ1cYI\IJ.IITJaT llHK.lJOreKCaH.IlliOu-I.4. HCDOJIb3yj.jTe CJTO>l<H03qm PHYIO KOH.IleHCarniIO. .;c 16. 19.
I(aKH M crroco60hl113 IJ.HKJlOreKCanOJlaMO}l(HO nO.TJyqllTbt{UC-UHKJlOreKcallJU:lOJI'! ,2? KaK nOJJytHlTb mpaH.C-I/30Mep?16.20. H alHlIlJI1Te $oPMYJTbl nponYIlJ,emn"x, COC.!l.lIffellJltl B CJT~}10IlJ,IfXpea KllIH1X:a) UIlKJlOreKC3ROHuftJ;JlOreKCt!.IJ+H,OA ~ 6 _+ Sr ~~ A -- H,O B - --+ 1 -31 U.~UHKJlO.reIlCeH KOH--+ 5(CIIII'pT )124- ,,-/11'-/"-NII:6),,/H< - - ' /"-1\11~B)2I,,-/1-1/"-Cl-leNH t-* 16.22.
KaJ< U3 remaHa nonyqH Tb TOJTYO.TJ? ~l<ai!mTe ),CJlOBJlH .16.23. [(aKlie yr JleBO.llopO!lbl nOJJY'lalO'fCSI npll KaTaJlUTll tjec"O~1 rnllplipoBaHlIlI naqrraJlHHa?16.24. fIpH Kfl TaJl HTIl'leCKOM rI fJlPH pOBaHlHf pesopUl-J Ha, B OnFll1l1eaT 6eH30JJ a, npouecc OCTa uaBmlBaerCfl lIa cr8.lJl11 ,ll1lr1JAponpmI3B0..1HOr o.nOqeMY 3TO coe.!UIHeHH e YCTolttmBo? Kalwe COe,lU,HeHlfe nOJIY41fTCfI eCJl fI118 .l ll rH .Ilpope30pllll fl nO.lleikrBOaBTb rH.IlPBllOM.
HaTpHH, a aaTeM 6po~lIIc,TWill I5YTBJlOM?CaoiicTBa+a) nOtteMY pea KnrUI llHKJIH3aUIm TaKOra TBTIa OP" npOBe.lleflnH axB pa36aBJleHHblX p acTBopa x .uaJOT JJY'llIJfle BhIXO./lb1 u flJ<)]oaJlIUlHOB, 'leAfB KOHueHTpn p OBaltHblX pacTBopax;6)a)16.25. [(aK MeH HeTCH YCToil 'UlJ30CTh UJIl{JlOB B pfl.llY: IUlI\,lJOnponafl.UHKJlo6YT8H, UJlKJlOr eKCaH, UHKJIOOl(Taa?• 16.
26. npu IlponycK8HluI UHKJlOnpOnaHoBblx II IIHKJIo6yranoBblxy r JleBOllOpolloB Qepe3 lIa rp eTYlo OKHCb amOMlflUl R rrpOHCXO.llllT pa3MbTKaHHe UHKJJa C o6pa30B<lllHe1l! OJle<!mfloB. KaKHe O.nE$IiHbI Mor Yl OopB30BaTbB ::nux YCJlOBHSlX; a) MeTII JlIUlKJJOn ponaH. 6) 1.2-1UJMem.1)UHK.1orrponaH- u) I , l-llm..feTliJJUH KJlo6YTa H.J6.27.
HaIIIl w HTe ypaSHeHJISI peBKu llii c 6POMOM: * a) IUIKJJOnpona.Ha; 6) IIlfKJlOneHTaH8 , B) UIJKJlOreHcafiB .J6.28. 1\aKue YI'.'leBO.llOPOllbl o6pa3yJO'fCfJ B )C.'lOBIIHX Heo6p-aTHMoroKaTamf38 H .3 eJlUHCKOro H3: a) 1-MeTri.1IJ.IIKJlOreKcella-1; ,. 6) I -MemJl·4- 1l30npOnUJJ 1111 KJJOr eKCeHa- J, B) 1.2- JUHlenJ.'lTOII'JlOr eKca.nnella· 1,3?J6.29. K8KHe coe..n.HueHlfl1 o6pa3YToTcfl npll JtelicrBmt Ha UHKJJOnellTefl IlJ,e.lJOQ110r o p aCTBopa nepM8HraliaTa K8.tJJlfI npn 1<OI\tUBTHOif Tel>-tnepa.Type 11 npH aarpeB8HHlI?16.30. HanlllUine peaKWUJ 030110.!JUsa C,lJe.llYIOUl,II:< COe.lllllleftHl!:a J IllI KJlo6YTeH; 6) UHt<JJoreKCen; It B) !-MeTllJl-2-:mtmlll KJJOneHTeH'l.16.3t. HarmlIlTn e ypaBHeHIHI cne.n.YIOUllIX pea KUllli:a) !.2-.l\UMeTHJTllUIUlOneHTeH·!HCI _6) !-MeTII.'IUIIKJlOreKcen·jBr2Ha30afITe KOneqllbJC BemeCTBa . MorYT JIll nOJlY41lTbCSJ CTepeoH30Mepbl?J6.32. HarrnmlfTe peaKUIUl UIlJ(JlOnel/T8,'tlleHa co c.lJe.nY10IlJ,lIwt aeIlJ,eCTB<lIllH: a) UPOIll (1 AtOAb); 6) 6POMflCTblii BO)lOPOJJ.
![](https://s.studizba.com/z.php?f=/templates/si/i/noavatar.png&w=100&h=100&t=1"){kind=avatar}
