Термодинамические свойства кристаллических фаз, образующихся при получении глинозема методом Байера (1105756), страница 19
Текст из файла (страница 19)
С. 3–8.132. Grishchenko R.O., Emelina A.L., Makarov P.Y. Thermodynamic properties andthermal behavior of Friedel’s salt // Thermochim. Acta. 2013. V. 570. P. 74–79.133.KurdakovaS.V.,GrishchenkoR.O.,DruzhininaA.I.,OgorodovaL.P.Thermodynamic properties of synthetic calcium-free carbonate cancrinite // Phys.
Chem. Miner.2014. V. 41. № 1. P. 75–83.134. Buhl J.-C. Synthesis and characterization of the basic and non-basic members of thecancrinite-natrodavyne family // Thermochim. Acta. 1991. V. 178. P. 19–31.135. Werner P.-E., Eriksson L., Westdahl M. TREOR, a semi-exhaustive trial-and-errorpowder indexing program for all symmetries // J. Appl.
Crystallogr. 1985. V. 18. № 5.P. 367–370.136. Boultif A., Louër D. Indexing of powder diffraction patterns for low-symmetrylattices by the successive dichotomy method // J. Appl. Crystallogr. 1991. V. 24. № 6.P. 987–993. 110137. Крешков А.П., Ярославцев А.А. Курс аналитической химии. Количественныйанализ. 5-е изд. М.: Химия. 1982.
312 c.138. Малышев В.М., Мильнер Г.А., Соркин Е.Л., Шибакин В.Ф. Автоматическийнизкотемпературный калориметр // Приб. техн. экспер. 1985. № 6. P. 195–197.139. Stevens R., Boerio-Goates J. Heat capacity of copper on the ITS-90 temperaturescale using adiabatic calorimetry // J. Chem. Thermodyn. 2004. V.
36. № 10. P. 857–863.140. Press W.H. Numerical recipes. Cambridge: Cambridge University Press. 2007.1235 p.141. Bevington P.R., Robinson D.K. Data reduction and error analysis for the physicalsciences. Boston: McGraw-Hill. 2003. 336 p.142. Qiu G.F., Deng H.M., Zeng W.M., Chen N.Y. Composition and spectroscopicstudies of hydrated sodium aluminate compounds // Acta Metall. Sin. (English Lett.) 1996. V. 9.№ 3. P.
177–180.143. Watling H. Spectroscopy of concentrated sodium aluminate solutions // Appl.Spectrosc. 1998. V. 52. № 2. P. 250–258.144. Höhne G.W.H., Hemminger W., Flammersheim H.-J. Differential scanningcalorimetry. 2nd ed. Berlin: Springer. 2003. 298 p.145. Finegold L., Phillips N. Low-Temperature heat capacities of solid argon and krypton// Phys.
Rev. 1969. V. 177. № 3. P. 1383–1391.146. Murch L.E., Giauque W.F. The thermodynamic properties of sodium hydroxide andits monohydrate. Heat capacities to low temperatures. Heats of solution // J. Phys. Chem. 1962.V. 66. № 10. P. 2052–2059.147. Hemingway B.S., Robie R.A., Fisher J.R., Wilson W.H.
Heat capacities of gibbsite,Al(OH)3, between 13 and 480 K and magnesite, MgCO3, between 13 and 380 K and theirstandard entropies at 289.15 K, and the heat capacities of calorimetry conference benzoic acidbenween 12 and 316 K // J. Res. US Geol.
Surv. 1977. V. 5. № 6. P. 797–806.148. Pöllmann H., Kuzel H.-J. Synthesis and polymorphic transformations of solidsolutions in the system 3CaO·Al2O3·CaCl2·nH2O – 3CaO·Al2O3·Ca(OH)2·nH2O – H2O // NeuesJb. Miner. Monat. 1988. № 5. P. 193–202.149. Ben Yair M. Studies on stability of calcium chloroaluminate // Isr. J. Chem. 1971.V. 9. P. 529–536.150. Vieira A.C., Moreira R.L., Dias A. Raman scattering and Fourier transform infraredspectroscopy of Me6Al2(OH)16Cl2·4H2O (Me = Mg, Ni, Zn, Co, and Mn) andCa2Al(OH)6Cl·2H2O hydrotalcites // J. Phys. Chem. 2009. V.
113C. № 30. P. 13358–13368. 111151. Zhang P., Qian G., Cheng H., Yang J., Shi H., Frost R.L. Near-infrared and midinfrared investigations of Na-dodecylbenzenesulfate intercalated into hydrocalumite chloride(CaAl-LDH-Cl) // Spectrochim. Acta. 2011. V. 79A. № 3. P. 548–553.152. Zhang P., Shi H., Xiuxiu R., Guangren Q., Frost R.L. Na-dodecylsulfatemodification of hydrocalumite and subsequent effect on the structure and thermal decomposition// J. Therm.
Anal. Calorim. 2011. V. 104. № 2. P. 743–747.153. Vieille L., Rousselot I., Leroux F., Besse J., Taviot-Guého C. Hydrocalumite and itspolymer derivatives. Part 1. Reversible thermal behavior of Friedel’s salt: A direct observationby means of high-temperature in situ powder X-ray diffraction // Chem. Mater. 2003. V. 15.№ 23. P. 4361–4368.154. Houtepen C.J.M., Stein H.N. The dehydration of some calcium aluminate hydrates,with univalent anions // J. Colloid Interf.
Sci. 1976. V. 56. № 2. P. 370–376.155. Helgeson H.C., Delany J.M., Nesbitt H.W., Bird D.K. Summary and critique of thethermodynamic properties of rock forming minerals // Am. J. Sci. 1978. V. 278-A. P. 1–229.156. Ederová J., Šatava V. Heat capacities of C3AH6, C4AS̄ H12 and C6AS̄ 3H32 //Thermochim. Acta. 1979.
V. 31. № 1. P. 126–128.157. Mercury L., Vieillard P., Tardy Y. Thermodynamics of ice polymorphs and ‘icelike’ water in hydrates and hydroxides // Appl. Geochem. 2001. V. 16. № 2. P. 161–181.158. Allada R.K., Navrotsky A., Boerio-Goates J. Thermochemistry of hydrotalcite-likephases in the MgO – Al2O3 – CO2 – H2O system: A determination of enthalpy, entropy, and freeenergy // Am. Mineral.
2005. V. 90. № 2–3. P. 329–335.159. Расцветаева Р.К., Пеков И.В., Чуканов Н.В., Розенберг К.А., Олысыч Л.В.Кристаллическиеструктурынизкосимметричныхразновидностейканкринитаиканкрисилита // Кристаллография. 2007. Т. 52. № 5. С. 840–846.160. Hermeler G., Buhl J.-C., Hoffmann W. The influence of carbonate on the synthesisof an intermediate phase between sodalite and cancrinite // Catal. Today. 1991.
V. 8.P. 415–42.161.KhomyakovA.P.,CamaraF.,SokolovaE.Carbobystrite,Na8[Al6Si6O24](CO3)·4H2O, a new cancrinite-group mineral species from the Khibina alkalinemassif, Kola Peninsula, Russia: description and crystal structure // Can. Mineral. 2010. V. 48.P.
291–300.162. Брек Д. Цеолитовые молекулярные сита. М.: Мир. 1976. 782 с.163. Эмиралиев А., Ямзин И.И. Уточнение структуры карбонат-канкринита понейтронографическим данным // Кристаллография. 1982. V. 27. №. 1. P. 51–55. 112164. Галицкий В.Ю., Грешучников Б.Н., Соколов Ю.А.
О форме нахождения водыв канкрините // Журн. Неорг. Хим. 1978. Т. 23. № 11. С. 3152–3154.165. Ballirano P., Maras A. The crystal structure of a ‘disordered’ cancrinite // Eur. J.Mineral. 2004. V. 16. №. 1. P. 135–141.166. Kanepit V.N., Rieder E.E. Neutron diffraction study of cancrinite // J. Struct. Chem.1995.
V. 36. № 4. P. 694–696.167. Rastsvetaeva R.K., Pekov I.V., Chukanov N.V., Rozenberg K.A., Olysych L.V.Crystal structures of low-symmetry cancrinite and cancrisilite varieties // Crystallogr. Reports.2007. V. 52. № 5. P. 811–818.168. Zhou D., Schmitt E.A., Zhang Z., Law D., Wight C.A., Vyazovkin S., Grant D.J.W.Model-free treatment of the dehydration kinetics of nedocromil sodium trihydrate // J. Pharm.Sci. 2003. V. 92.
№. 7. P. 1367–1376. 1138. ПРИЛОЖЕНИЕ Таблица 9.1 Элементный состав Na-КАН по результатам РСМА (в ат%) NaAlSiTi13.668.708.7913.2111.4711.5611.938.688.4713.469.829.9313.589.088.7411.0510.1010.2113.588.698.3913.318.618.4812.4010.1310.6814.059.529.4013.959.299.2812.9710.7310.9712.319.9510.0712.709.059.3913.3110.3510.5813.0210.5311.2413.478.398.4413.808.218.4213.668.538.2213.928.778.5811.9011.3712.7914.299.348.9513.648.818.4514.049.509.4212.8111.9310.4913.1810.2110.2913.789.228.9914.319.359.590.0813.838.728.500.08CaFeMg0.250.110.050.160.050.090.070.85K114Продолжение таблицы 9.1 NaAlSiTi14.159.929.830.0713.849.519.5314.1210.5410.3613.9411.0011.2613.3910.6711.1013.989.9910.3613.8610.4910.3913.959.699.9413.929.749.6514.018.708.0913.7910.0110.7614.128.758.9113.179.769.5913.3610.1511.3013.669.859.7414.298.488.9012.759.739.7514.649.939.5812.1211.9613.1314.239.9110.3013.999.7211.3613.1010.6210.5113.959.319.7113.8210.8211.6713.3811.1111.6613.789.579.3114.408.858.6412.5211.0311.9413.589.0110.1613.5310.3711.0711.9311.8213.5213.719.429.580.14CaFeMgK115Продолжение таблицы 9.1 NaAlSiTiCaFe11.878.428.5713.678.878.6614.419.088.7014.279.9210.5014.279.899.9714.009.169.0714.429.399.7914.049.179.2914.558.858.5414.1411.0512.0213.218.208.5411.178.739.0613.037.607.6512.9912.1714.4812.908.878.9913.199.669.790.2711.749.219.630.0712.887.297.1111.779.2710.0812.887.647.3912.548.628.6811.899.9110.6613.829.3410.5913.8410.7411.8714.079.7610.0312.798.258.350.0411.697.127.500.190.33MgK2.850.140.330.09116Таблица 9.2 Зависимость удельной теплоемкости (в Дж·г−1·К−1) от температуры (в К)для образца Na-КАН (m = 0.32353 г), рассчитанная по данным АКTС pTС pTС pTС p“Гелиевая14.720.009930.770.062352.230.167774.910.3021область”15.070.010631.490.065652.940.174675.920.3037T С p6.390.000715.420.011032.210.068553.650.179076.930.30296.650.001115.770.011232.930.072954.370.183277.940.30946.910.001416.120.011533.650.076255.080.192578.940.31617.170.000916.470.012534.360.079955.800.191479.950.32087.430.001116.820.013035.080.082456.510.194480.430.32367.680.001417.170.014135.800.084157.230.199681.480.33277.920.001817.520.013836.510.088757.940.202582.520.33728.170.001917.870.014637.220.093558.660.2044“Азотная об-8.410.002518.210.015537.930.101559.370.2120ласть”, серия 18.650.002418.560.016538.650.099960.080.215379.030.31468.880.003218.910.017439.370.104960.800.214880.430.32369.140.003519.250.017840.080.109261.510.220281.480.33279.370.003919.600.018740.800.111262.220.228782.520.33729.600.003919.940.020341.510.114662.930.229883.570.33989.840.004920.620.022242.220.118163.650.233284.620.341110.070.004721.360.024242.940.122564.360.237985.660.347110.370.005522.100.026543.650.126965.070.242186.700.352310.740.006422.830.028844.360.130165.780.247787.740.357011.110.006623.560.030945.080.134466.490.249788.790.361711.480.007024.290.033945.790.139167.200.255889.830.365511.850.008025.010.037646.510.142267.910.257390.870.371812.210.007725.740.038447.220.145268.620.262191.910.376812.580.007926.460.042347.940.149169.330.264892.950.379412.940.008427.180.044448.650.153770.040.268693.990.384013.300.008127.900.047949.370.158170.890.272895.020.394613.650.008728.620.051750.080.160971.900.280296.060.392814.000.009529.330.055550.800.164272.900.282797.100.401214.360.009730.050.058051.510.166073.910.292698.140.4081117Продолжение таблицы 9.2С pTС pTС pTС pTС p99.180.4133131.150.5390162.720.6476193.770.7418224.080.8387100.210.4147132.180.5400163.730.6492194.760.7451225.000.8301101.250.4177133.200.5439164.740.6507195.760.7474225.960.8369102.290.4237134.220.5524165.750.6498196.750.7555226.920.8417103.320.4297135.250.5521166.760.6551197.740.7584227.880.8426104.360.4296136.270.5565167.770.6609198.730.7567228.840.8461105.400.4347137.290.5614168.780.6618199.720.7631229.800.8500106.430.4428138.320.5640169.780.6707200.710.7662230.750.8482107.470.4434139.340.5670170.790.6731201.690.7716231.710.8509108.500.4491140.360.5706171.790.6774202.680.7667232.660.8535109.540.4537141.380.5790172.800.6795203.660.7692233.610.8556110.570.4585142.400.5805173.810.6836204.640.7787234.560.8621111.600.4647143.420.5815174.810.6875205.620.7835235.510.8634112.640.4697144.440.5877175.820.6871206.610.7794236.460.8606113.670.4691145.460.5916176.820.6906207.590.7860237.410.8644114.700.4730146.480.5930177.810.6923208.570.7869238.350.8655115.730.4780147.500.5938178.820.6958209.520.7876239.300.8713116.760.4846148.520.5985179.820.6983210.490.7945240.190.8736117.790.4845149.530.6027180.820.7047211.470.7956241.130.8732118.820.4901150.550.6051181.820.7074212.450.8013242.070.8763119.850.4951151.570.6075182.820.7072213.420.8030243.010.8771120.880.4941152.580.6148183.820.7126214.400.8063243.950.8888121.910.4984153.600.6148184.820.7122215.370.8046244.880.8905122.940.5092154.620.6186185.820.7156216.340.8123245.810.8900123.970.5120155.630.6252186.820.7181217.310.8099246.750.8893125.000.5145156.650.6296187.820.7265218.280.8139247.670.8907126.020.5196157.660.6296188.810.7291219.250.8212248.600.8970127.050.5239158.680.6318189.810.7301220.220.8224249.530.9003128.080.5239159.690.6329190.810.7280221.190.8209250.450.9030129.100.5300160.700.6383191.800.7304222.150.8266251.380.8962130.130.5292161.700.6449192.800.7385223.110.8300252.310.8943T 118Продолжение таблицы 9.2TС pС pTС pTС pTС p253.230.904492.050.3780113.760.4748135.290.5535156.630.6290254.150.906293.090.3819114.790.4756136.310.5575157.640.6305255.000.903994.120.3892115.820.4779137.330.5574158.650.6320255.910.906195.160.3912116.850.4837138.350.5612159.660.6371256.830.917096.200.3958117.870.4874139.370.5679160.670.6395257.740.916697.240.3991118.900.4908140.390.5717161.670.6475258.650.913898.270.4049119.930.4968141.410.5726162.680.6532“Азотная об-99.310.4069120.960.4997142.430.5766163.690.6501ласть”, серия 2100.340.4139121.980.5037143.440.5820164.700.6566T79.190.3157101.380.4195123.010.5082144.460.5826165.710.658980.590.3277102.410.4255124.040.5133145.470.5858166.720.665881.630.3300103.450.4282125.060.5157146.490.5898167.730.668682.680.3366104.480.4286126.090.5182147.500.5944168.730.666483.720.3404105.510.4360127.110.5221148.520.5984169.740.674084.760.3436106.540.4419128.140.5265149.530.6020170.750.674485.810.3496107.580.4465129.160.5278150.550.6105171.750.679486.850.3572108.610.4490130.180.5321151.560.6093172.760.680987.890.3652109.640.4558131.200.5357152.580.6132173.760.682788.930.3664110.670.4612132.220.5431153.590.6156174.760.682389.970.3690111.700.4641133.240.5467154.600.618991.010.3768112.730.4669134.270.5544155.620.6227Таблица 9.3 Результаты высокотемпературной калориметрии растворения в расплаве дляобразца Na-КАН (в Дж·г−1)H 973 H 298.15 sol H 973 H973 H 298.15 sol H 9731295.361307.221321.521326.181361.701295.451314.771316.981259.101331.72119Таблица 9.4 Элементный состав образца Ca-КАН по результатам РСМА (в ат%)ONaAlSiKCaCr65.5814.329.1710.380.5566.1514.488.939.970.4763.249.3611.5312.3566.0413.439.2810.650.6065.5313.779.2910.790.6265.8114.059.1710.450.5265.6013.689.4410.780.5163.1411.5111.0612.7265.3114.239.2610.690.5156.1613.188.3810.570.581.599.5465.3511.988.5710.920.600.352.2464.3813.689.7411.5468.9714.327.648.740.3465.7214.248.9610.410.6865.9012.879.2811.230.7265.2813.109.8011.090.7262.5713.4210.5512.021.443.311.110.14Fe0.210.460.52Таблица 9.5 Зависимость удельной теплоемкости (в Дж·г−1·К−1) от температуры (в К)для образца Ca-КАН (m = 0.823188 г), рассчитанная по данным АКТС pТС pТС pТС p“Гелиевая8.690.002010.220.002813.120.005616.110.0104область”8.840.001810.500.003113.420.006016.410.0111Т С p7.340.00088.990.002410.790.003213.710.006516.720.01167.520.00069.150.002211.080.003414.010.006917.030.01247.690.00109.290.002111.370.003914.300.007317.330.01317.860.00149.440.002211.650.004114.600.007817.640.01378.030.00149.590.002311.950.004214.900.008217.950.01468.190.00169.730.002512.250.004415.200.008818.250.01538.360.00189.870.002612.540.004915.500.009418.560.01628.510.001810.010.002712.830.005315.800.009818.870.0171120Продолжение таблицы 9.5 TС pTС pTС pTС pTС p19.180.017941.490.116171.280.271293.070.3667126.990.498719.490.018742.280.120572.480.276493.870.3700128.230.502919.800.019643.070.124673.690.282094.670.3737129.460.507320.110.020643.860.128774.890.287395.470.3767130.700.511420.680.022144.650.133076.100.292696.280.3804131.940.515321.420.024545.450.137477.300.298097.080.3838133.180.519722.160.026946.240.141578.510.303597.880.3872134.420.524022.910.029347.040.145679.720.308898.690.3909135.660.527623.660.032047.830.149980.930.314199.490.3940136.900.532024.410.034948.630.154282.140.3192100.290.3972138.150.535725.160.038149.430.158083.350.3248101.300.4025139.390.540225.920.041250.220.1621“Азотная об-102.510.4071140.640.543926.680.044151.020.1665ласть”103.720.4119141.880.547827.440.047351.820.171078.480.3026104.940.4166143.130.551428.210.050552.620.175679.440.3071106.150.4218144.380.555928.980.053953.420.180780.240.3104107.370.4266145.660.560829.750.057454.210.185681.040.3140108.590.4313146.910.563630.520.061255.010.190881.840.3172109.810.4359148.160.567531.290.064955.810.195682.640.3210111.020.4406149.420.571032.070.068656.610.200383.440.3246112.240.4456150.670.575532.850.072662.230.227784.240.3279113.470.4500151.930.579333.640.076463.030.233085.050.3316114.690.4546153.180.582734.420.080163.830.237385.850.3351115.910.4590154.440.586435.200.084164.630.240786.650.3384117.140.4637155.700.589935.980.087965.440.244387.450.3419118.360.4677156.960.593236.760.091666.240.248188.250.3454119.590.4725158.220.597137.550.095567.050.252089.050.3491120.820.4770159.490.601238.330.099767.850.255789.850.3527122.050.4813160.750.604939.120.103668.660.259890.660.3563123.280.4856162.020.608339.910.107569.460.263191.460.3596124.510.4902163.280.611940.700.111770.270.266892.260.3629125.760.4949164.550.6154121Продолжение таблицы 9.5 ТС pТС pТС pТС pТС p165.850.6193192.890.6891223.280.7582253.710.8224286.240.8831167.130.6225194.190.6924224.600.7606255.020.8244287.530.8855168.400.6260195.490.6957225.920.7634256.340.8270288.810.8874169.670.6297196.800.6990227.240.7663257.650.8289290.090.8887170.950.6333198.110.7020228.630.7696260.260.8350292.640.8940172.220.6368199.420.7054229.950.7721261.570.8373293.910.8968173.500.6400200.730.7070232.590.7799262.880.8404295.180.8993174.780.6436202.050.7103233.910.7826264.180.8428296.450.9014176.060.6466203.370.7128235.230.7857265.490.8448297.720.9035177.340.6499204.690.7159236.540.7885266.790.8478298.990.9055178.620.6525206.020.7193237.860.7907268.090.8495301.730.9106179.910.6560207.410.7223239.180.7929269.400.8518303.380.9131181.190.6597210.060.7279240.500.7961273.340.8597305.040.9167182.480.6631211.380.7319241.810.8008274.630.8618306.700.9188183.770.6666212.710.7344243.130.8048275.930.8641308.370.9209185.060.6699214.030.7375244.450.8065277.220.8665313.400.9287186.400.6737215.350.7403247.070.8104278.520.8694315.100.9311187.700.6766216.670.7433248.390.8126279.810.8721316.790.9336188.990.6800218.000.7455249.770.8148281.100.8747320.230.9364190.290.6824219.320.7482251.080.8169283.670.8783321.940.9404191.590.6859221.960.7550252.400.8193284.960.8805323.670.9429.