Анализ, классификация и прогноз свойств гумусовых кислот (1098260), страница 24

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G = . G − . G]^_ ∆Kd – g_wdkdexabhgguc wnn_dl(5.2). G– b^_Zevguc Kd,H[S.G–wdki_jbf_glZevghhij_^_ey_fucKd∆Kd fh`gh e_]dh jZkkqblZlv ^ey ZgZeblh\ k ba\_klghc fhe_dmeyjghcfZkkhc gZoh^y . G ih dZeb[jh\hqguf aZ\bkbfhklyf I> LZd gZijbf_j ^eybkke_^h\Zgguo ihebf_jh\ I> IKK IF: b I: bf_xsbo FF >ZH[Skhhl\_lkl\mxsb_ . G khklZ\eyxlbLh]^Z∆Kd^eywlbo`_\_s_kl\ khklZ\ey_l b \hajZklZy ih f_j_ \hajZklZgbym^_evgh]h aZjy^Z ihebf_jh\ Ke_^h\Zl_evgh \_ebqbgZ ∆Kd y\ey_lkynmgdpb_c kljmdlmju ZgZeblZ dhlhjZy hij_^_ey_l _]h \aZbfh^_ckl\by kfZljbp_c ]_ey Ijb wlhf _keb wnn_dl k\_jowdkdexabb ijb\h^bl diheh`bl_evguf agZq_gbyf ∆Kd lh wnn_dl ki_pbnbq_kdhc Z^khj[pbb [m^_lijb\h^blvd_]hhljbpZl_evgufagZq_gbyfIjbgbfZy \h \gbfZgb_ qlh \ hlebqb_ hl bkihevah\Zgguo fh^_evguoihebf_jh\ kljmdlmjgh-]jmiih\hc khklZ\ ]mfmkh\uo dbkehl \dexqZ_l \ k_[ydZd bhgh]_ggu_ nmgdpbhgZevgu_ ]jmiiu ]b^jhnbevgu_ m]e_\h^gu_njZ]f_glulZdb]b^jhnh[gu_ZjhfZlbq_kdb_bZedbevgu_njZ]f_glulhboih\_^_gb_\\u[jZgghcojhfZlh]jZnbq_kdhckbkl_f_ljm^ghk\_klbddZdhfmeb[h h^ghfm ba bkke_^h\Zgguo h[jZaph\ kjZ\g_gby >ey \u[hjZ gZb[he__Z^_d\Zlghc fh^_eb g_h[oh^bfh [ueh mklZgh\blv dhebq_kl\_ggmx\aZbfhk\yav f_`^m \_ebqbghc g_wdkdexabhggh]h wnn_dlZ b kljmdlmjhcZgZebabjm_fh]h \_s_kl\Z K wlhc p_evx \ l_o `_ wdki_jbf_glZevguomkeh\byo [ue ijhZgZebabjh\Zg p_euc jy^ gbadhfhe_dmeyjguo ZgZeh]h\kljmdlmjguo njZ]f_glh\ ]mfmkh\uo dbkehl kihkh[guo dZd dwe_dljhklZlbq_kdbf lZd b khj[pbhgguf \aZbfh^_ckl\byf k ]_e_fIh^jh[gh_ hibkZgb_ ijh\_^_gguo wdki_jbf_glh\ ijb\_^_gh \ gZr_c jZ[hl_[Perminova, 1999] Z hkgh\gu_ ihemq_ggu_ j_amevlZlu h[km`^Zxlky \ke_^mxs_fjZa^_e_.5.2 H[hkgh\Zgb_\u[hjZh[jZapZkjZ\g_gby^eyhij_^_e_gbyfhe_dmeyjguofZkk]mfmkh\uodbkehl>ey mklZgh\e_gby \aZbfhk\yab f_`^m kljmdlmjhc ZgZeblZ bg_wdkdexabhggufwnn_dlhfhij_^_ey_fuf_]h\aZbfh^_ckl\b_fkfZljbp_c]_ey[ueZkhklZ\e_gZ\u[hjdZbah[rbjgh]hjy^Zhj]Zgbq_kdbokh_^bg_gbcfh^_ebjmxsbo hkgh\gu_ kljmdlmjgu_ njZ]f_glu ]mfmkh\uo dbkehl < boqbkeh \hreb dZj[hgh\u_ ZjhfZlbq_kdb_ b ZebnZlbq_kdb_ dbkehlu kibjlum]e_\h^ubZfbghdbkehluIjbeh`_gb_<k_mdZaZggu_kh_^bg_gby[ueb179ijhZgZebabjh\Zgu \ l_o `_ mkeh\byo qlh b ij_iZjZlu ]mfmkh\uo dbkehl]_ev – Toyopearl HW50S wex_gl – 0.028 F nhknZlguc [mn_j k p_evxH[Shij_^_e_gby khhl\_lkl\mxsbo .

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GZbemqr__ dhjj_eypbhggh_khhlghr_gb_ h[tykgyxs__ \ZjbZpbb \_ebqbgu g_wdkdexabhggh]hwnn_dlZijb\_^_ghgb`_∆Kd = 0.21 – 1.24HArOH/O – 0.18C/O + 0.35HCOOH/O –– 0.47(N+S)/C + 0.07C/H(5.3)=jZnbd khhl\_lkl\mxsbc j_]j_kkbhgghc aZ\bkbfhklb ihdZaZg gZjbk 5.4.∆ .GH[SU ∆ .GFDOFJbk 5.4. Dhjj_eypbhggZy \aZbfhk\yav jZkkqblZgguo ih mjZ\g_gbx(5.3) ∆Kdcalc b wdki_jbf_glZevgh gZc^_gguo ∆Kdexp ^eygZ[hjZbg^b\b^mZevguohj]Zgbq_kdbokh_^bg_gbckibkhd\Ijbeh`_gbbIhemq_ggh_ dhjj_eypbhggh_ khhlghr_gb_ bf__l e_]dh ljZdlm_fucnbabq_kdbckfukedexq_\ufnZdlhjhfhij_^_eyxsbfojhfZlh]jZnbq_kdh_ih\_^_gb_ hj]Zgbq_kdh]h ZgZeblZ \ \u[jZgghc kbkl_f_ y\ey_lkyhlghkbl_evgh_ kh^_j`Zgb_ dbkehjh^Z b _]h jZkij_^_e_gb_ f_`^mbhgh]_ggufbnmgdpbhgZevgufb]jmiiZfb–dZj[hdkbevgufbbn_ghevgufb]b^jhdkbeZfbIjZdlbq_kdbc\uoh^ihemq_ggh]hkhhlghr_gbykhklhbl\lhfqlh agZy mdZaZggu_ iZjZf_lju fh`gh ij_^kdZaZlv \_ebqbgm181g_wdkdexabhggh]h wnn_dlZ ^ey hj]Zgbq_kdh]h ZgZeblZ \\_klbkhhl\_lkl\mxsmx ihijZ\dm \ wdki_jbf_glZevguc Kd b jZkkqblZlv FF ihg_bhgh]_gguf h[jZapZf kjZ\g_gby gZijbf_j I> beb IW= H^gZdh \ kbemlh]h qlh ^ey \u\h^Z mdZaZggh]h khhlghr_gby [ueb bkihevah\Zgu lhevdhgbadhfhe_dmeyjgu_ kh_^bg_gby g_h[oh^bfh [ueh ijh\_jblv _]hijbf_gbfhklv ^ey \ukhdhfhe_dmeyjguo kh_^bg_gbc h[eZ^Zxsboihebwe_dljheblgufbwnn_dlZfbK wlhc p_evx \ khhl\_lkl\bb k hibkZgghc ijhp_^mjhc [ueZ ijh\_^_gZdhjj_dlbjh\dZ ^Zgguo ^ey fh^_evguo ihebwe_dljheblh\ k ba\_klghc FF –I:IF:bIKK<_ebqbgZ∆KdjZkkqblZggh]hkihfhsvxkhhlghr_gbykhklZ\beZb^eyI:IF:bIKKkhhl\_lkl\_gghBkihevamyjZkkqblZggmx \_ebqbgm hij_^_eyeb .

G b gZoh^beb FF ih dZeb[jh\hqghcaZ\bkbfhklb^eyI>Ihemq_ggu_j_amevlZluihdZaZgugZjbk 5.5.FF>Z FF>ZI:wdki_jbf_glZevgZyjZkq_lgZy[_adhjj_dpbbIF:wdki_jbf_glZevgZyjZkq_lgZy[_adhjj_dpbb.G.GFF>ZIKKwdki_jbf_glZevgZyjZkq_lgZy[_adhjj_dpbb.GJbk 5.5. DZeb[jh\hqgu_aZ\bkbfhklb^eyfh^_evguoihebwe_dljheblh\ gZc^_ggu_ wdki_jbf_glZevgh bjZkkqblZggu_kihfhsvxkhhlghr_gbyDZd \b^gh ba ij_^klZ\e_gguo aZ\bkbfhkl_c hij_^_e_gb_ FFH[Sihebwe_dljheblh\ih\_ebqbg_ . G kbkihevah\Zgb_fI>\dZq_kl\_h[jZapZ182kjZ\g_gby ijb\h^bl d kms_kl\_gghfm aZ\ur_gbx j_amevlZlh\ djb\Zy ³[_aH[Sdhjj_dpbb´ Lh]^Z dZd dhjj_dpby . G gZ jZkkqblu\Z_fmx \_ebqbgmg_wdkdexabhggh]h wnn_dlZ – ∆Kd iha\hey_l ]hjZa^h [he__ Z^_d\Zlghhij_^_eylvFFihebwe_dljheblh\djb\Zy³jZkq_lgZy´gZjbk Hkh[_gghohjhrbo j_amevlZlh\ m^Z_lky ^h[blvky ^ey ihebwe_dljheblh\ k gbadbfm^_evguf aZjy^hf IKK lh]^Z dZd ZiijhdkbfZpby ^ey I: kms_kl\_gghom`_ Ih-\b^bfhfm wlh k\yaZgh k mkbe_gb_f ihebwe_dljheblguo wnn_dlh\ihf_j_\hajZklZgbym^_evgh]haZjy^ZfZdjhfhe_dmeIjbgbfZy\h\gbfZgb_qlh m^_evguc aZjy^ ]mfmkh\uo dbkehl g_ ij_\hkoh^bl lZdh\hc ^ey IKK lhkhhlghr_gb_fh`ghijbf_gylv^eyhp_gdbbo∆Kd.>eyjZkq_lZg_wdkdexabhggh]hwnn_dlZ]mfmkh\uodbkehlbkihevah\Zebkj_^gb_ih\k_c\u[hjd_baij_iZjZlh\\_ebqbguZlhfguokhhlghr_gbcO/K, H/C b (N+S)/C ijb\_^_ggu_ \ Ijbeh`_gbb 3.2.

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