Анализ, классификация и прогноз свойств гумусовых кислот (1098260), страница 23
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=eZ\ZHIJ?>?E?GB?FHE?DMEYJGHF:KKH<H=HKHKL:<:=MFMKH<UODBKEHL>ey hij_^_e_gby FF khklZ\Z ]mfmkh\uo dbkehl [ue \u[jZg f_lh^wdkdexabhgghc ojhfZlh]jZnbb iha\heyxsbc ihemqblv bgnhjfZpbx g_lhevdhhkj_^gboFFghbhiheghcdjb\hcFFJ]mfmkh\uodbkehlGZjy^mk g_khfg_ggufb ^hklhbgkl\Zfb f_lh^Z ih^jh[gh h[km`^_ggufb \ h[ahj_ebl_jZlmju_]hijbf_g_gb_dZgZebamex[uoihebwe_dljheblh\b]mfmkh\uodbkehl \ qZklghklb khijy`_gh k hiZkghklvx ihy\e_gby Zjl_nZdlh\ – lZdgZau\Z_fuog_wdkdexabhgguownn_dlh\Ihwlhfmhkh[h_\gbfZgb_\gZr_cjZ[hl_ [ueh h[jZs_gh gZ hij_^_e_gb_ Z^_d\Zlguo mkeh\bc ZgZebaZ]mfmkh\uo dbkehl \dexqZy \u[hj h[jZapZ kjZ\g_gby ^ey jZkq_lZ FFJDjhf_lh]h[ueZihklZ\e_gZaZ^ZqZih\ukblv\uoh^qbke_gghcbgnhjfZpbbh oZjZdl_j_ FFJ ]mfmkh\uo dbkehl aZ kq_l ^_lZevghc bgl_jij_lZpbbwdkdexabhgguoojhfZlh]jZffbdjb\hcFFJ5.1 <u[hjhilbfZevguomkeh\bcZgZebaZHij_^_e_gb_ fhe_dmeyjgh-fZkkh\h]h khklZ\Z ij_iZjZlh\ ]mfmkh\uodbkehl ijh\h^beb k bkihevah\Zgb_f ojhfZlh]jZnbq_kdhc kbkl_fujZajZ[hlZgghc gZ dZn_^j_ \h^ghc obfbb \ L_ogbq_kdhf Mgb\_jkbl_l_DZjekjmw [Frimmel et al., 1992] Kbkl_fZ \dexqZeZ \ k_[y Z\lhkZfie_jbg`_dlhj fe aZiheg_ggmx ]_e_f klZevgmx dhehgdm ff × 25 kf ^\Zihke_^h\Zl_evgh kh_^bg_gguo ^_l_dlhjZ – ki_dljhnhlhf_ljbq_kdbc bijhlhqguc ^_l_dlhj jZkl\hj_ggh]h hj]Zgbq_kdh]h m]e_jh^Z *UDHQW]HO=_jfZgby kgZ[`_gguo bgl_jn_ckZfb ^ey j_]bkljZpbb ZgZeblbq_kdh]hkb]gZeZ b mijZ\eyxsbc dhfivxl_j <k_ ZgZebau [ueb \uiheg_gu gZdZn_^j_ \h^ghc obfbb Mgb\_jkbl_lZ DZjekjmw Z\lhjhf ^bkk_jlZpbbH[jZ[hldm j_amevlZlh\ ijh\h^beb gZ i_jkhgZevghf dhfivxl_j_ k ihfhsvxhjb]bgZevgh]h ijh]jZffgh]h h[_ki_q_gby ³Geltreat” jZajZ[hlZggh]h:< Dm^jy\p_\uf[Kudryavtsev et al., 2000].>ey mkljZg_gby wnn_dlh\ we_dljhklZlbq_kdh]h \aZbfh^_ckl\byihebZgbhgh\]mfmkh\uodbkehlkfZl_jbZehfdhehgdb–]b^jhnbevguf]_e_fToyopearl-HW, – \k_ hij_^_e_gby \uihegyebkv \ 0.028 M nhknZlghf [mn_j_ijbjG kh]eZkgh[Perminova et al., 1998]Dhgp_gljZpby]mfmkh\uodbkehl\h njZdpbhgbjm_fuo ijh[Zo g_ ij_\urZeZ f] hj]Zgbq_kdh]h m]e_jh^Z(CeIjh[m]mfmkh\uodbkehlij_^\Zjbl_evghmjZ\gh\_rb\Zebkih^\b`ghcnZahc H[t_f ZgZebabjm_fhc ijh[u – 2 fe Kdhjhklv wexbjh\Zgby –1 fefbg>ey \u[hjZ ]_ey k hilbfZevguf ^bZiZahghf njZdpbhgbjh\Zgby jy^ij_iZjZlh\ ]mfmkh\uo dbkehl [ue ijhZgZebabjh\Zg gZ dhehgdZo174aZiheg_gguo ]_eyfb k jZaebqguf jZaf_jhf ihj – Toyopearl 40 HW(S),50 HW(S)b 55 HW(S).
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lh]^Z dZdnjZdpbhgbjh\Zgb_ =ND lhjnZ b =D ihq\ hkms_kl\ey_lky ihqlb gZ \_jog_fij_^_e_ _]h ^bZiZahgZ njZdpbhgbjh\Zgby Kd ≈ 0.2) Ihwlhfm g_h[oh^bfhijbagZlv qlh ^ey ih\ur_gby ^hklh\_jghklb hij_^_e_gby fhe_dmeyjghfZkkh\uooZjZdl_jbklbdlZdboij_iZjZlh\[he__ij_^ihqlbl_evgufy\ey_lkybkihevah\Zgb_]_eyk[hevrbfjZaf_jhfihj– 55 HW(S).+:6+:6+:6Kb]gZehlg_^.GJbk 5.1.
Djb\u_ wexbjh\Zgby ij_iZjZlZ AHF-RMX2 ihemq_ggu_gZ dhehgdZo aZiheg_gguo ]_e_f Toyopearl k jZaebqgufjZaf_jhfihj>ey bkdexq_gby aZ\bkbfhklb oZjZdl_jbklbd djb\uo wexbjh\Zgby hl]_hf_ljbq_kdbo iZjZf_ljh\ \u[jZgghc ojhfZlh]jZnbq_kdhc kbkl_fuh[t_fu m^_j`b\Zgby dhg\_jlbjh\Zeb \ dhwnnbpb_glu ^hklmighklb Kd),bkihevamy^eywlhcp_ebba\_klgh_khhlghr_gb_.G =95 − 99W − 9(5.1)]^_VR –h[t_fm^_j`b\ZgbyZgZeblZV0 –h[t_fwdkdexabbdhehgdbVt–h[sbch[t_fdhehgdb175>ey bkihevah\Zgghc ojhfZlh]jZnbq_kdhc kbkl_fu V0 b Vt khklZ\eyeb b fe khhl\_lkl\_ggh Wlb \_ebqbgu khhl\_lkl\mxl h[t_fm \uoh^Z³]hem[h]h´^_dkljZgZfhe_dmeyjgZyfZkkZfeg>Zbf_lZgheZ>Z>ey ijh\_jdb \hkijhba\h^bfhklb djb\uo wexbjh\Zgby \ dhhj^bgZlZo“ Kd” – ³hldebd ^_l_dlhjZ´ ihemq_gguo \ jZaebqguo ojhfZlh]jZnbq_kdbokbkl_fZo [ueh ijh\_^_gh njZdpbhgbjh\Zgb_ g_kdhevdbo ij_iZjZlh\ gZdhehgd_ k ^jm]bfb ]_hf_ljbq_kdbfb iZjZf_ljZfb ff × 40 kf ghaZiheg_gghc l_f `_ ]_e_f – Toyopearl HW50S.
DZd \b^gh ba khihklZ\e_gbykdhg\_jlbjh\Zgguo \ rdZem Kd ojhfZlh]jZff jbk 5.2) ^ey ij_iZjZlh\gZ[ex^Z_lky ohjhrZy \hkijhba\h^bfhklv djb\uo wexbjh\Zgby ihemq_gguo\ jZaebqguo ojhfZlh]jZnbq_kdbo kbkl_fZo Djhf_ lh]h [ebahklvijb\_^_gguogZlhf`_jbkmgd_djb\uowexbjh\Zgbyihemq_gguo\l_q_gb_]h^Z gZ h^ghc b lhc `_ kbkl_f_ iha\hey_l k^_eZlv \u\h^ h ohjhr_c\hkijhba\h^bfhklbj_amevlZlh\^Zggh]hf_lh^Z<k\yabkl_fqlhwdkdexabhggZyojhfZlh]jZnbyij_^klZ\ey_lkh[hcg_Z[khexlgucZhlghkbl_evgucf_lh^hij_^_e_gbyfhe_dmeyjguofZkkFFlh \_kvfZ \Z`guf b g_h[oh^bfuf wlZihf ZgZebaZ y\ey_lky dZeb[jh\dZojhfZlh]jZnbq_kdhcdhehgdbKeh`ghklbhkms_kl\e_gbywlhcijhp_^mju^eyhij_^_e_gby fhe_dmeyjgh-fZkkh\h]h jZkij_^_e_gby ]mfmkh\uo dbkehlk\yaZggu_ k hlkmlkl\b_f Z^_d\Zlguo h[jZaph\ kjZ\g_gby ih^jh[ghh[km`^Zxlky \ khhl\_lkl\mxs_c im[ebdZpbb Z\lhjZ [Perminova et al., 1998].>ey ^_fhgkljZpbb ijh[e_fu gZ jbk ijb\_^_gu dZeb[jh\hqgu_ djb\u_ihemq_ggu_ ^ey h^ghc b lhc `_ ojhfZlh]jZnbq_kdhc kbkl_fu k ihfhsvxq_luj_o gZ[hjh\ ihebf_jguo ]hfheh]h\ k jZaguf kh^_j`Zgb_f bhgh]_gguo]jmii gZ _^bgbpm fZkku < dZq_kl\_ h[jZaph\ kjZ\g_gby bkihevah\Zebiheb^_dkljZgu I>kFFbD>ZihebZdjbeZlugZljby I: – b D>Z ihebf_lZdjbeZlu gZljbyIF: – b .>Z ihebklbjhekmevnhgZlu gZljby IKK – b .>Z <k_ h[jZapu kjZ\g_gby [uebijbh[j_l_gu m nbjfu Polymer Standard Service (Mainz, Germany) Boiheb^bki_jkghklv g_ ij_\urZeZ .