Отзыв официального оппонента 1 (Каталитическая деоксигенация жирных кислот, получаемых из масел и жиров, в высшие олефины)
Описание файла
Файл "Отзыв официального оппонента 1" внутри архива находится в следующих папках: Каталитическая деоксигенация жирных кислот, получаемых из масел и жиров, в высшие олефины, Документы. PDF-файл из архива "Каталитическая деоксигенация жирных кислот, получаемых из масел и жиров, в высшие олефины", который расположен в категории "". Всё это находится в предмете "химия" из Аспирантура и докторантура, которые можно найти в файловом архиве РТУ МИРЭА. Не смотря на прямую связь этого архива с РТУ МИРЭА, его также можно найти и в других разделах. Архив можно найти в разделе "остальное", в предмете "диссертации и авторефераты" в общих файлах, а ещё этот архив представляет собой кандидатскую диссертацию, поэтому ещё представлен в разделе всех диссертаций на соискание учёной степени кандидата химических наук.
Просмотр PDF-файла онлайн
Текст из PDF
OT3bIBoqnUJ.HaJIbHOrO onnoneara na .n.HCCepTaUHOHHyIO pafioryKysnenoaa Ilerpa Cepreeaaxa"KaTaJlHTHqeCKaB AeOKCHreHaUHB iKHpHhIX KHCJlOT, nOJlyqaeMbIX H3 MaCeJl H iKHpOB, BBbICmHe OJlef}»HHhI", npencrasnenayro na COHCKaHHe yqeHOH crenena xaananara XHMHqeCKHXnayx rro cneuaansaocra 02.00.04 - <pH3HqeCKIDl XHMHjI.AKTYaJlbHoCTb TeMhI.Ilpencraanaenas .n:HccepTaUHoHHIDl paoora nocaameaa npofinesrerrepepafiorxa B0306HOBnjleMOrOH sropasaoro csrpsa C nouomsro KaTanHTHqeCKOH peaKUHH .n.eOKCHreHaUHH )I<:HpHhIX KHcnOT.O.n.HaKO aBTopa HHTepecyeT He «TP~HUHOHHoe» HarrpaBneHHe rrpOTeKaHHjI .n:aHHoH peaKUHH,npasonamee K 06pa30BaHHIO 6HOTOrrnHB, a uanpanneaae, npnsoztautee K nonysemno TaKHXueHHhIX nponyxros, KaKssrcmae one<pHHhI.
n03TOMY paccxarpaeaexaa pafiora, HeCOMHeHHO,jlBMeTCjI axryansaoit.,l(HccepTaUHjI ssmonueaa B COOTBeTCTBHH C rpe60BaHHjlMH BAK P<I>. Crpyxrypa H 06'heMzracceprauaa OTBeqaIOTrpefioaaaaax,rrpe.n:'hjlBnjleMhIM K KBanH<pHKaUHOHHhIM pa60TaM . Pa60TaH3nO)KeHa aa 140 crpanauax MarnHHorrHCHoro TeKCTa H conepxorr 23 Ta6nHUhI, 24 pacynxa, aTaK)Ke 6H6nHorpa<pHIO, axmoaaromyro 185 HaHMeHOBaHHjI.AHMH3 cOAepiKaHHB AHccepTaUHoHHoHpafio'rsr.B nareparypnoa 0630pe zraccepranaa nonpofiao paccaorpeasr 06mHe 3aKOHOMepHOCTH, a TaK)Kexarannsaropsr, KHHeTHKa H MexaHH3M peaKUHH .n.eOKCHreHaUHHOCHOBHhle rrYTH nporexanaa,)KHpHhIXKHcnOT.conepxauiaeBOrnensnoxasecrsepaccxorpeasraKTHBHororereporeanueKOMrrOHeHTaxaranasaropsrpaamrnnsre.n:eOKCHreHauHHcoenaaeaasnnreparypnov 0630pe TaK)Ke H3nO)KeHa cOBpeMeHHM HH<popMaUHjI 06 ofinacrsxHHKeM.BnpaxeaenaxHcnocofiax nonysenaa asrcurax onerpaaoe.B 3KcrrepHMeHTaJIbHOH qaCTH onacaasr semecrsa H ofiopynoaanne, acnonsaosaansre B patiore, aTaK)Ke MeTo.n:HKarrpHrOTOBneHHjIKaTanH3aTopOBH <pH3HKO-XHMHqeCKHeMeTo.n:hI .n.M HXaccnenoaaaaa.
nO.n:p06HO onacansr MeTO.n:HKH npoaenenas KaTanHTHqeCKHX OrrhITOB, aaanasarrpo.n.yKTOB peaKUHH, rrnaHHpOBaHHjI KHHeTHqecKHx 3KcrrepHMeHToB H KBaHTOBO-XHMHqeCKOrOMo.n.enHpOBaHHjI.OCHoBHhlepesynsrarupa60ThI H3nO)KeHhI BTnase 3nacceprauaa.IlpoaeneaoaccnenoaanaeBnHjlHHjI npaponsr MeTanna, npexypcopa H HOCHTeM aa aKTHBHOCTh H ceneKTHBHOCTh peaKUHH.n.eOKCHreHaUHH creapauosoti KHcnOThI no ssrcurax onedmaoa. ABTOpOM yCTaHOBneHO, qTOnaafonee aKTHBHhIMH H ceneKTHBHhlMH KaTanH3aTOpaMH YKa3aHHOH peaKUHH B paccaarpaeaevsrxycnosaax jlBMIOTCjI aaxens-cynupannsre xaranasaropsr, nonyseaasreKOMrrOHeHTa na OKCH.n.
anIOMHHHjI HnH canaxarens.aaaeceaaexaKTHBHoroCnenyerynasnroeOTMeTHTbBbIIIOJIHeHHOeKBaHTOBO-XHMHqeCKOerrOJIyqeHHbIXaBTopOM.neOKCHreHaU:HHyCTaHOBHTb,MO.neJIHpOBaHHe,3KcrrepHMeHTaJIbHbIXCTeapHHOBOH:KHCJIOTbInepsasasnr-rropacsernsrxCOqeTaHHe B paoore 3KCrrepHMeHTaJIbHbIX H.naHHbIXaaHaTaK)KenocrpoeaaeKHHemqeCKOH:HHKeJIb-CYJIb<lm.nHOMOCHOBHbIMaaOCHOBaHHHMo.neJIHnponeccaKaTaJIH3aTOpeaanpaaneaaexMeTO.nOB.rr03BOJIHJIO~BJUleTC~peaKU:HH.neKap60HHJIHpOBaHHe.K HaH60Jlee Ba~HhlM peaym-raraja nacceprauaoaaoayCTaHOBJIeHa 3aBHCHMOCTbrrOJIyqeHHbIXaKTHBHOCTHcynsdiaraH3OTBpeMeHHHpa60Tbi MO~HO OTHeCTHCeJIeKTHBHOCTHBOCCTaHOBJIeHH~HHKeJIeBbIXrerrraneuenosu:eJIeBbIXranpaposaaae,anaMOHOMeTaJIJIHqeCKOrO.norrOJIHHTeJIbHOMYTOpMO)KeHHIOFnu).(ceJIeKTHBHOCTb rro)l;ocToBepHOCTbMeTO.nbIMeTo.nHK,pe3YJlbTaTOB.~BJI~eTC~HeKaTaJIH3aTOpaOJIHrOMepH3aU:HH,npasonarcepe6pOMynysmaarrOKa3aTeJIHKnpoueccaB 6HMeTaJIJIHqeCKHX KaTaJIH3aTOpax aa rrOBepXHOCTH HOCHTeJUIBpafioreKaTaJIH3aTOpOBXANES H EXAFS.
BHCrrOJIb30BaHbICOBpeMeHHbIeP<I>A,aIT3M,3KcrrepHMeHTaJIbHOH: qaCTH.nJI~ Ha.ne)KHOH: H.neHTH<pHKaU:HHHCrrOJIb3yeMbIxKHHeTHqeCKHXKaTaJIH3aTOpaxnonsa THrra aKTHBHbIX u:eHTpOB C pa3HbIMH <pyHKU:HHMH.xapaxrepasanaaKaTaJIH3aTOpOBCTeapHHOBOH: KHCJIOTbIOJIHrOMepH3aU:H~.rrpOMOTHpOBaHHe<pOPMHP)'lOTC~cepsr B CHCTeMe Ni-S.npouecca .neOKCHreHaU:HHHHKeJIb-CYJIh<PH.nHbIXKaTaJIH3aTOpOB,npexypcopa, Hatimortaesras3aBHCHMOCTb CB~3bIBaeTC~ aBTOpOM C BeJIHqHHOH: aTOMHOH: .nOJIHOCHOBHOH: KOHKypHp)'lOm;eH: peaxuaeiicnenyromee:3KcrrepHMeHTOBHKBaHTOBO-XHMHqeCKOrOTaK)Ke<pH3HKO-XHMHqeCKHe.nIDI6HMeTaJIJIHqeCKHXnpaseneso nozrpofinoe onacaaaenpozryxrospeaKU:HH,nposenenasMo.neJIHpOBaHH~.
TaKHM06pa30M,.nOCTOBepHOCTb pe3yJIbTaTOB, rrOJIyqeHHbIX aBTOpOM, He BbI3bIBaeT COMHeHHH:.;O:HccepTau:H~ Ky3HeU:OBaIT.C.~BJUleTC~ 3aKOHqeHHOH: HayqHo-KBaJIH<pHKaU:HOHHOH: pa60TOH:, BKOTOpOH: Ha OCHOBaHHH BWrrOJIHeHHbIX aaTopOM HCCJIe.nOBaHHH: rrpe.nJIO)KeH MexaHH3M peaKU:HH.neOKCHreHau:HH CTeapHHOBOH: KHCJIOTbI, rrporexarouteii C 06pa30BaHHeM BbIClIIHX OJIe<pHHOBHHKeJIb-CYJIb<PH.nHbIX KaTaJIH3aTOpax, qTOnay-moe.nOCTH)KeHHeB06JIaCTHrr03BOJI~eT KBaJIH<pHU:HpOBaThrereporeaaoroKaTaJIH3aCztaanyio60JIblIIHMnapaoory, KaKrrOTeHU:HaJIOMnpaxrasecxoro npaxeaeaaa.K pafiore1.HMelOTCH CJleL(yIOID,He 3aMeqaHHH:B 3KcrrepHMeHTaJIbHOH: qaCTH .nHcCepTaU:HoHHOH: pa60ThIosensonacana MeTo.nHKa nposeneaas peaKU:HH .neOKCHreHaU:HHH KHHeTHqeCKHXHO, K CO)KaJIeHHIO, oseas cxynoaanpaaep,onacana xeronaxaHCrrOJIb3yeMbIe B paficre HOCHTeJIHozraaxo 3TOT<paKTOpHey-rren npn06CTOneJIbHO Hnonpofiaoaxcnepanearoa,rrpHrOTOBJIeHH~ KaTaJIH3aTopoB.
TaK,ofinanaiorPa3JIHqHOH: BJIarOeMKOCTblO,BbI60pe MeTo.na rrpHrOTOBJIeHH~ KaTaJIH3aTOpOB.Hcnorrssyesroe asropoaCOOTHOIIIeHlIe «10 MJI pacrsopa na lOr HOClITemm B CJIy '-IaeClIJIlIKare~ 6y~eT npaKTlIqeCKlI nponllTKoH no BJIarOeMKOCTlI, a ~ aKTlIBlIpOBaHHOrOyrnx,ocofiennoeCJIlIeronOBepXHOCTbnOBbIIIIeHlISI r~po<t>IIJIbHOCTlI -He 6bIJIanpensaparensaoofipafiorana ~~rrpornrrxon B 1I36bITKe pacrsopnrena. TaKlIM 06pa30M,nOJIyqaeTCSI, qrO yCJIOBlISI npllrOTOBJIeHlISI KaTaJI1I3aTOpOB He BnOJIHe lI~eHTlIqHbI. 3TlIMacnonssyexsrx HOClITeJIeH MO:>KeT 06bSlCHSlTbCSI<t>aKTOM, a He TOJIbKO pa3JIlIqlleM B npaponenafimonaevoe na nOBepXHOCTlIAhO) 1ISi02pasna-moe pacnpenenenae qaCTlIU nopasxepy.2. ABTOplICnOJIb3yeTMeTO~HenpSIMoHcepsronpenenenas COCTOSlHlISI HIIKeJISI,MO~eJIlIpOBaHlISI· ~~KBaHTOBO-XlIMlIqeCKOrO1I cepe6pa BnonysenasrxKaTaJI1I3aTopax.
O~HaKonna sroro cymecrsyer npaxoii MeTO~ P<1>3C, KOTOpbIH n03BOJIlIJI 6bI TOqHO YCTaHOBlITbsapxztoasreCOCTOSlHlISIaKTlIBHbIXKOMnOHeHTOBnanOBepXHOCTlInOJIyqeHHbIXKaTaJI1I3aTopoB.3.OCTaeTcSIHenOHSlTHbIM,lICCJIe~OBaHlIe BJIlISlHlISInoseayaKTlIBHOCTb 1I CeJIeKTlIBHOCTb KaTaJIlI3aTOpoBHallMeHee aKTlIBHOro B ~aHHOHMO~eJIlI~~nocrpoensrpeaxunanpaponsr npexypcopa~eOKClIreHaUlIlIBbIllOJIHeHO na npaxepeMeTaJIJIa Cu, a TaK:>Ke,auxens-cynsdnrnaoronoxesryxopoureroKlIHeTlIqeCKlIeKaTaJI1I3aTOpa na OKClI~e aJIlOMlIH1IS1, B TOBpeMSI KaK HaHJIyqIIIlIe nOKa3aTeJIlI npouecca ~OCTlIfHYTbI na KaTaJI1I3aTOpeOrneseansienaHe~OCTaTKII He trocar npamurrraansnoroxapaxrepa3%Ni/Si0 2?1I He CHlI:>KaIOT B ueJIOMsnesarnemre OT zracceprauna. ABTOp BbIllOJIHlIJI 60JIbIIIOH 06beM pa60TbI 1I npOSlBlIJIce6S1 CJIO:>KlIBIIIlIMCSI lICCJIe~OBaTeJIeM, cnOC06HbIM CaMOCTOSITeJIbHO peurars naysraste 3a~aqll BTaKOH CJIO:>KHOH 06JIaCTlI XlIMlIlI, KaKBstaoztsrrereporenasra KaTaJI1I3.znrccepranaa ~OCTaTOqHO 060CHOBaHbI, lIJIJIlOcrpaTlIBHbIH MaTepllaJIynaxao~OnOJIHSleTo6cy~eHlIe nOJIyqeHHbIX pe3YJIbTaTOB.nesarnsrxTIo MaTepllaJIaM ztacceprauna ony6JIlIKOBaHo 9peueasapyensrx nay-msrx:>KYpHaJIaXorpaxaror OCHOBHoe conepxaaaeorpazcaer OCHOBHoe coztepxcaane 1I3HaqJ:IMOCTb1I3TIepeqHSIBAK.Ilytinaxanna~lICCepTaUlIlI 1I pe3YJIbTaTbIBbIBO~bI ~IICCepTaUlIlI ,3crarsa -B~OCTaTOqHO nOJIHOlICCJIe~OBaHlISI.Aaropediepara TaK:>Ke HOB1I3HY 1I npaKTlIqeCKYIOnpOBe~eHHoro IICCJIe~OBaHlISI..ll:lICCepTaUlIoHHaSI pafioraKysueuoaa Ilerpa Cepreeeaxa:>KUpHhlX KUCJIOT, nOJIY'IaeMhlX U3 MaCeJI U :>KUpOB, Bsanasax,pafior, B TOM qllCJIeypOBHIOcOOTBeTCTByeT«TIOJIO:>KeHIISI 0IIX peIIIeHlISI IIxparepnav,nopanxeaay-raoti"KaTaJIUTU'IeCKaH ,lJ;eOKCureHaU:UHasrcmaeOJIe4»uHhI" no nOCTaBJIeHHbIMHOB1I3He nOJIyqeHHbIX pe3yJIbTaTOB, nOJIHOCTblOnpe~bSIB~eMbIM BAK P<1> K KaH~lI~aTCKlIM ~IICCepTaUIISIM, (n.9-14npllCY:>K~eHIISIyseasrxTIpaBlITeJIbCTBa P<1> OT 24 ceHTSI6pSI 2013r.crenenea», yrnepsoienaoro nOCTaHOBJIeHlIeMNQ842).
Pa60Ta COOTBeTCTByeT CneUlIaJIbHOCTlI02.00.04 lPH3lflIeCKaJI XHMHSI Bpasnenax«CBSl3b peaKI.J;HOHHOHcnocofiaocra pearerrroaC HXcTPoeHHeM H YCJIOBHSlMH ocymeCTBJIeHHSI XHMHqeCKOH peaKI.J;HH» H «MaKpOKHHeTHKa, MeXaHH3MbICJIO:>KHbIXXHMlflIeCKHXnpOI.J;eCCOB,lPH3HKO-XHMHqeCKaJIKPHCTaJIJIH3aI.J;HSI», a ee aBTOp, Ky3HeUOBIlerp Cepreeann,pacrsopeaaerH.ll:P0.ll:HHaMHKa,3aCJIy:>KHBaeT npHcY:>K.ll:eHHSIHyneaoitCTeneHH xaananara XHMHqeCKHX HaYK no YKa3aHHOH CneI.J;HaJIbHOCTH.<1>.11.0. COCTaBHTeJISl:IlOqTOBbIH<1>HHalIIHHa EJIeHa )],MHTPHeBHaazrpec:1991991Mocxsa,fleHHHcKHHnpocnexr,47TeJI.+74991356389Aapec 3JIeKTPOHHoHno-rrsr:HaHMeHoBaHHe OpraHH3aI.J;HH:finesta@mail.ru<1>fEYH MHCTHTYT OpraHHqeCKOH XHMHHHM .H.)],. 3eJIHHCKOro POCCHHCKOHaKa.ll:eMHH aayx)],OJI:>KHOCTb:(MOX PAH)CTaplIIHH HayqHbIH COTPY.ll:HHKJlafioparopaaNQ 14 «Pa3pa60TKH HHCCJIe.ll:OBaHHSI nOJIHlPYHKI.J;HOHaJIbHbIXKaTaJIH3aTopOB», K.X.H.Ilonrmcs <1>HHalIIHHoH E.)],.YqeHbIH3aBepSlIOcexperaps MOX PAHKopuresen MpHHa KOHcTaHTHHoBHaPAH, K.X .H.28 anpena 2017r..
