Диссертация (1150357), страница 3
Текст из файла (страница 3)
,.CNaCl = 0.0010.0Ққ),1/:ημm(m = 1 ± 0.2).0.ҚNaCl/,қ.η (t=5.3.Қθ. ,3).9.0 (.3.Қθ. ),m(t)CNaCl = 0.00Қ0.0Қ./,m= Қ (.3.Қθ. ,Ққ).0.Қ/NaClt= 5m = 2.3.: t1t2,(T) – t1 = 0.1T.Қ0.1t2 = 1T,,(mt,)t1 = 0.1T.t2 = TNaCl,.,t1 = 0.1Tёt2 = 1T,(.. 3.3.(a = 0.қ33.0–9.0NaClt1 = 0.1TҚ.t2 = 1T).3.Қ7 (),ζ.0 –),963.3(a = 0.23t1 =0.1Tt2 =1T,.3.0λ.0 –/3n0 = 1.1×107СNaCl,),/3/,n0 = 3.6×1011.аm't=0.1T*m't=1T0.0010.010.10.0011.51.92.31.12.82.32.51.10.011.01.30.11.91.90.0011.01.05.8-6.20.010.10.0011.01.51.01.12.31.1≤0.Қ9.00.010.11.01.51.12.1≤0.Қ3.04.0С/,≤0.00Қ~0.1*m,..зя= .
.m’(lgCNaCl)′=.зя3.0 (3.Қ7 ,Қ),,/ .).(≤0.00Қζ.0–λ.0(m’(lgCNaCl))CNaCl = 0.0Қ/ ,,.λ.0ё(0.Қ–0.қ/ )[84,114,135,209].t = 1Tμ3.0m’(lgCNaCl),NaCl (3.17 ,97Қ).,,-ζ.0–λ.0t = 1T.,m’(lgCNaCl)CNaCl = 0.Қt1 =0.1T,/,,(. 3.17 (,2 – 4)).3.5pH 3.0pH 4.0pHλ.0m't=0.1T3.02.52.01.51.00.5321-lgCNaCl3.53.0ζ.0m't=1T3.0λ.02.52.01.51.00.532-lgCNaCl1.3.Қ7(a = 0.23)NaCl3.0-9.0, t1 = 0.1T ( )t2 = 1T ( ).,,(.
3.Қη–3.Қ7. 3.3),mt,NaCl, . ...983.0,,,λ.0ζ.0..яIII.2.2.2ч( = 0.βγчч)Л( = 0.қ3)NaCl (0.00Қ, 0.0Қ.3.Қκ, -0.Қ/ )Қ.(. II.3.3.).3.0CNaCl = 0.001/(V2 < 10 kT),Қ).0.Қ kT (0.0Қ0.Қ/.3.Қκ.NaCl,(( = 0.қ3.3.Қκ. ,қ)σКCХ3.4.(W1) ())((W2) (. II.3.3.).Қ.W1 W23.0CNaCl = 0.00ҚW2 – қθ.3,/3).1.2,W1. .,.99W = 1.2,,.( = 0.23λ.0NaClμ 0.00Қ/)0.0Қ/,10(.3.Қκ.Қ,қ).0,2/(1) CNaCl=0.0010,1V/kT(2) CNaCl=0.01/(3) CNaCl=0.1/10,02040602h,113V/kTV/kT-0,11212002040600-0,2204060h,3-1/(1) CNaCl=0.001(2) CNaCl=0.01(3) CNaCl=0.1-1/3/80h,/(1) CNaCl=0.001(2) CNaCl=0.01/(3) CNaCl=0.1/-2-2.3.Қκ( = 0.23( ),λ.0 ( )NaCl ()3.0 ( ),/ ): 0.001 (1), 0.01 (2), 0.1 (3).W1(.
3.4).W2100CNaCl = 0.Қ/қ,,,,,(/.3.Қκ. ,қV(h)CNaCl = 0.1,(Vmax < 10 kT).Қ(λ.03).,W1. 3.4.).,,, . .–.-3.ζ.( = 0.қ3σКCХ)3.0 – λ.0,.pHCNaCl,/Vmа ,kThmax,-V2,kThmin,0.0010.110.30.040.00145.51.60.0134.40.0010.01аааау яW1W233.01.226.30.01102.2>1010170.8-1.10.124.6>101012.2-388.41.00.01128.9>1010261.9-100.50.60.128.2>101015.1-0.001589.91.00.01128.2>1010254.9-0.01246.50.40.131.1>101017.6-0.10.21.31.63.71.11.2*0.013.00.14.00.15.86.20.19.0*Vm = 0.1 kT.101,,NaCl,-.( = 0.қ3.).3.19.λ.NaCl2.0-V21.51.00.50.0321-lgCNaCl.3.Қλλ.0 ( = 0.23NaCl).,.kTCNaCl = 0.00Қ/V2 = - 1.6 kTCNaCl = 0.Қ/ .λ.0.3.қ0t1 = 0.1T,t2 = 1T ,.1022.5m't=0.1Tm'm't=T2.01.51.00.50.00.11.6-V2.3.қ0(a = 0.23λ.0t1 = 0.1T)t2 = 1T.,,0.Қ kT.,t1t2.,.III.2.3.(a = 0.55)III.2.3.1 Эяч(a = 0.55))( = 0.55..n0 = 3.2×1063.0.3.қҚ( ).NaCl= 0.001/3.NaCl= 0.001, 0.0Қ0.Қ//(Қ),103.,NaCl1/n = 7.3×10-6(.3.қҚ.
,қ31/n = 7.5×10-6λ.03.қҚ (1/n*10 ,).332641/(1) CNaCl=0.0012(2) CNaCl=0.01/(3) CNaCl=0.1/0508736(2) CNaCl=0.01/(3) CNaCl=0.1/150200250t,3008/(1) CNaCl=0.0011/n*10 ,10071/n*10 ,/36/(1) CNaCl=0.001(2) CNaCl=0.01/(3) CNaCl=0.1/24332141220050100150200250300 t,050100150200250300 t,.3.21( = 0.553.0 ( ),(( )2), 0.1 ()λ.0 ( )3),)NaCl: 0.001, 0.01, 0.18633).( = 0.55/η/ (n0 = 3.2×106NaCl: 0.001 (/3)1), 0.01104λ.0NaClη:μ(m = 1 ± 0.2).m: t1t2,0.1(T) – t1 = 0.1T0.3t2 = 0.3T.(III.2.2.1),(mt,).NaCl,t1 = 0.1Tёt2 = 0.3T,(.),. 3.5.3.η.,(a = 0.55n0 = 3.2×106/3.СNaCl,3.04.05.8-6.29.0/m't=0.1Tm't=0.3T0.0010.011.01.71.02.30.11.72.20.0011.01.00.010.10.0011.01.01.01.41.01.00.010.10.0011.01.01.01.01.01.10.011.01.00.11.11.31/n(t) (С,а/С <0.
01С <0.1С >0.1С <0.1. 3.21),NaCl,),105.3.ққt1 = 0.1T3.0,t2 = 0.3T,/ .< 0.01NaCl 0.0Қ,/.,t2 = 0.3Tm’(lgCNaCl),t1 =0.1T,,,(.3.ққ.1).ζ.0λ.0 (қ, ζ)m’(lgCNaCl)()CNaCl = 0.0Қ/ ,.NaClҚ(3) .,(,. 3.қҚ, 3.ққ. 3.η),mt,()NaCl,. ...( = 0.ηη),..ζ.03.0,,λ.0 -1063.0ζ.02.5m't=0.1Tλ.02.01.51.00.5321-lgCNaCl2.5m't=0.3T3.0ζ.02.0λ.01.51.00.5321-lgCNaCl.3.қ2(a = 0.55σКCХ)3.0-λ.0t1 = 0.1T ( )t2 = 0.3T ( ).107яIII.β.γ.βч( = 0.ηηчч)Л( = 0.55)NaCl (0.00Қ, 0.0Қ0.Қ/ ).3.23, - .(.
II.3.3.).3.0CNaCl = 0.0010.0Қ/,10 kT (NaCl.3.қ3. ,ҚқV(h)қ).,(Vmax < 10 kT).( = 0.55)σКCХ3.6.(W1)(W2) (3.0CNaCl = 0.00ҚW1 > 1010,/W2 – қλ.3,CNaCl = 0.0Қ/.қκ0,W1. .W2 – 3.2,,.W13.0Қ(W20.Қ/ NaCl. 3.6.).,,t1 = 0.1T–.t2 = 0.3T. II.3.3.)., . .,,.10810pHV/kT/(1) CNaCl=0.001(2) CNaCl=0.01/(3) CNaCl=0.1/521020406080h,2pH6pH923V/kT-511331212V/kT020406008020h,60/(1) CNaCl=0.001-140(2) CNaCl=0.01/(3) CNaCl=0.1/-280/(1) CNaCl=0.001-1h,(2) CNaCl=0.01/(3) CNaCl=0.1/-2.3.23( = 0.553.0 ( ),( ),0.1 (3). (n0 = 3.2×1069.0 ( ))NaCl (/3/ ): 0.001 (1), 0.01 (2),)( = 0.55λ.0NaClμ 0.00Қ/0.0Қ)/109,10 kT (W1.3.23.,Ққ).(W2.
3.6),.3.6.( = 0.ηησКCХ)3.0 – λ.0,,.pH3.04.05.86.29.0CNaCl, MVmа ,kThmax,-V2,kThmin,0.00141.62.30.030.018.32.40.11.70.001W1W263.1>101029.30.416.82803.21.24.03.71.31.0287.50.90.01112.0>101084.80.0180.31.10.224.5>10105.40.131.80.62.74.9>10101.00.001644.91.00.01126.8>1010106.10.01596.80.30.131.3>10107.690.1345.10.31.87.1>10101.20.001686.91.00.01127.5>1010106.90.01596.80.30.131.3>10107.70.1345.10.31.87.1>10101.2аааау я---,CNaCl = 0.Қ/Қ.κ kT (. 3.қ3.,3;.3.θ).λ.0110–W1 > 1010,Қ.қ,W2.,,NaCl-,-..3.қζ3.0 – 9.0.NaCl7-V23.06ζ.054λ.03210321-lgCNaCl.3.24( = 0.ηη)NaCl,V2 (lgCNaCl).V2/V2 = (-1.8) – (- 4.0) kTμ V2 = (-1.8) kTλ.0CNaCl = 0.001kTCNaCl = 0.Қ, V2 = (-2.7) kT/ (.3.θ).ζ.0, V2 = - 4.0 kT1113.0.m't=0.3T (lgC) (( = 0.ηη)σКCХ(W2)λ.0.3.қ3)3.0 –.3.қ5.2.5.3.қη3.0lgW2ζ.02.0W2λ.01.5( = 0.ηη)σКCХ1.03.0 – 9.0.0.50.0321-lgCNaCl,/ ,CNaCl = 0.0Қ0,(Қ.0)/CNaCl = 0.1.,.,,(lgW = Қ3.0λ.0,(C,lgW2(lgC)),,.
3.η).W2NaCl,..3.қ6m't=0.3T3.0 - 9.0.112,mt(V2),3.0-9.0,3.0/ )NaCl (CNaCl > 0.00Қ(..3.қθ),.,,,,,.,,W1,.Vmax = 8.3 kT,ζ.0λ.0 (. 3.қθ)ҚV2,V2 ~ 0.2 kT,.V2..3.қ62.5m't=0.3T2.0( = 0.ηη)1.53.01.0ζ.03.0 - λ.00.5λ.0,t2 = 0.3T.0.001234V2,kT 5,,.113III.2.4.(a = 1.02)III.β.ζ.1 Эяч(a = 1.0β))( = 1.02../n0 = 2.0×1063.(a = Қ.0қ3.0NaCl= 0.001 – 0.Қ)/.3.қ7.32071/n*10 ,31521015/(1) CNaCl=0.001(2) CNaCl=0.01/(3) CNaCl=0.1/050100150200250( = 1.02)300 t,.3.қ73.0NaClμ 0.00Қ (/ ; (n0 = 2.0×1063.0/3Қ), 0.0Қ (қ), 0.Қ ()CNaCl = 0.00Қ0.0Қ/,Қ/n = 9.4×10-6 (3)Қ)Қ/n = 12.0×10-6η3(қ).n0 = 2.0×106NaCl0.Қ//3.114Қ/n20.6×10-6 (,ηҚ/n3).( = 1.02λ.071/n*10 ,.3.қκ (NaCl2015)./(1) CNaCl=0.0013)(2) CNaCl=0.01/(3) CNaCl=0.1/103215050100150200250t,3002071/n*10 ,3/(1) CNaCl=0.00115(2) CNaCl=0.01/(3) CNaCl=0.1/103251050100150200250300 t,.3.қκ( = Қ.0қ( )(λ.0 ( )3)σКCХμ 0.00Қ (/ (n0 = 2.0×106.)/λ.03Қ), 0.0Қ (қ), 0.Қ).NaClμημ(m = 1 ± 0.2).mμ t1t2,0.Қ(T) – t1 = 0.1T0.қt2 = 0.2T.115(mt,),t1 = 0.1TσКCХt2 = 0.2T.t1 = 0.1T,ёt2 = 0.2T,(.),.
3.7.mt=0,1T’(lgCNaCl)mt=0,2T(lgCNaCl),(3.қλ. ,3.0= 0.001/NaCl 0.Қ/NaClҚ).,.m’(lgCNaCl) (ζ.0–λ.0қ – ζ),.,,(≥ 0.1,(/ ).. 3.27–3.қλ. 3.7),3.0,. .( = 9.3 – ҚҚ.ζ).> Қλ,..3.0,,( = Қ.0қ.)1163.7,(a = Қ.0қn0=2.0×106/3.СNaCl,/0.0010.010.10.0010.010.10.0010.010.10.0010.010.13.04.05.8-6.29.0m't=0.1Tm't=0.2T1.22.52.51.21.11.11.11.11.11.01.01.11.23.23.71.21.11.11.11.11.21.01.01.1Са/,≤0.00Қ>0.1>0.1>0.14.5mt=0.2T3.53.0ζ.02.5λ.01.50.5321-lgCNaCl.3.қλ(a = 1.02)σКCХ3.0-λ.0t2 = 0.2T .),117яIII.β.ζ.βч( = 1.0βчч)Л( = Қ.0қ)σКCХ (0.00Қ, 0.0Қ0.Қ/ ).3.30. - .(. II.3.3).3.0CNaCl = 0.00Қ(.қ0.0Қ/.3.30. ,NaClҚ)V(h),CNaCl = 0.Қ/Vmax = 1.7 kT./,(( = Қ.0қ)3).σКCХ3.κ.(W1)(W2) (3.0CNaCl = 0.00Қ. II.3.3)./W2 – Ққ.7,W1 = 108,./CNaCl = 0.0Қ(W1.
3.κ).,,.Қ.ηW2–, . .Қ.6,1182/(1) CNaCl=0.001V/kT(2) CNaCl=0.01/(3) CNaCl=0.1/112020406080h,-1443312-2312221V/kT1V/kT02040600h,3-18020-16080h,3/(1) CNaCl=0.001-240(2) CNaCl=0.01/(3) CNaCl=0.1/-2-3-3-4/(1) CNaCl=0.001(2) CNaCl=0.01/(3) CNaCl=0.1/-4.3.30( = Қ.0қ( ),λ.0 ( )CNaCl = 0.Қ-NaCl (/)3.0 ( ),/ )μ 0.00Қ (Қ), 0.0Қ (қ), 0.Қ (3).119,.( = 1.02λ.0NaClμ 0.00Қ/)0.0Қ/,10 kT (.3.30.W1,Ққ).(W2.3.ζ).3.κ.( = Қ.0қσКCХ)3.0 – λ.0,,.pH3.0Vmа ,kThmax,-V2,kThmin,0.00122.53.70.080.011.73.90.001386.10.01CNaCl,W1W253.710812.70.912.81.51.61.30.02109.5>101044.563.31.40.521.6>10102.70.18.41.16.23.91731.00.001614.61.00.02120.8>101053.40.01477.30.80.328.7>10103.90.1284.90.53.86.3>10101.00.001934.71.00.02125.1>101056.70.01844.10.30.330.5>10104.30.1491.30.33.46.9>10101.0/аааау я-0.14.05.86.29.0---120,CNaCl = 0.Қλ.0/3.κ – 3.4 kT (.
3.30.,3;W1 > 1010,.3.κ).W2 – Қ.0,.,,σКCХ,.-( = Қ.0қNaCl (-V2).3.3Қ).765ζ.04λ.03210321-lgCNaCl.3.3Қ( = Қ.0қNaCl,)ζ.0 – 9.0.V2(-lgCNaCl).V2V2 = (-3.4) – (- 6.2) kTCNaCl = 0.00ҚkTCNaCl = 0.Қ/(.3.κ)./121μ V2 = (-3.4) kTλ.0, V2 = - 3.8 kT, V2 = (-2.7) kT4.0..( = Қ.0қ)σКCХζ.0 – 9.0.3.3қ.0.0Қ/ ,(W2=Қ.0)0,CNaCl = 0.Қ/.2lgW21.5ζ.0λ.010.5032( = Қ.0қ)1 -lgCNaCl.3.3қσКCХζ.0 – 9.0.((.3.κ)ζ.0 – λ.0. 3.3Қ3.3қ)CNaCl = 0.0Қ/,.,,.,,,.,,122ζ.0λ.0CNaCl = 0.Қ/(Қ.0 – Қ.қ)Қ,V2 = 3.4 – 6.2 kT.,,,.ζ.0 – λ.0CNaCl = 0.Қ/ .III.2.5(а = 0.19)III.2.5.1. Эяч( = 0.19))( = 0.193.0 -λ.0..3.0NaCl= 0.001 – 0.Қη/.3.3ζ./n0 = 1.8×10113.μNaClημm(m = 1 ± 0.2).ζ.0,.3.33 ().NaClNaCl= 0.00Қ/(.η= 0.001 – 0.Қη/mҚNaClқ),= 0.0Қm = Қ.θ/m = Қ.κ (3.33).123m2/(1) CNaCl=0.001(2) CNaCl=0.01/(3) CNaCl=0.15/31210m5010015020025077/(1) CNaCl=0.00165(2) CNaCl=0.01/(3) CNaCl=0.15/300t,/(1) CNaCl=0.001m 65(2) CNaCl=0.01/(3) CNaCl=0.15/34433232221050100150200250111300 t,050100150200250300 t,7/(1) CNaCl=0.001m 65(2) CNaCl=0.01/(3) CNaCl=0.15/3243211050100150200300 t,250.3.33( = 0.19)3.0 – λ.0 ( - )σКCХμ 0.00Қ (Қ), 0.0Қ (n0 = 1.8×1011/3,қ), 0.Қη (λ.0μ n0 = 3.0×1063)/3/ ().3.0 –:124μNaClηm = ζ.ηm = ζ.қ,ζ.0(.3.33.,3).λ.0.3.33.
.,/n0 = 3.0·1063.NaCl= 0.00Қ/,30m = Қ.λ.NaCl 0.0Қ/m = 3.κ.0.Қη30,/ NaCl,μηm = 5.3.яIII.2.5.2ч( = 0.1λчч( = 0.ҚλЛ)NaCl (0.00Қ, 0.0Қ0.Қη/ ).3.34, - .3.λ.(W1)(W2) (. II.3.3).)1253.0 CNaCl = 0.00Қ/(V2 =0.02 kT) (.3.34. ,Қ).NaCl,CNaCl = 0.ҚηV2 <10 kT./-Vmax = 25.3 kT,V2 = 3.01.7 kT.CNaCl = 0.00ҚW1 > 1010,0.0Қ/W2 – ζκ.77.η,.CNaCl = 0.Қη/109,W1. .W2 – 1.2,,.,.( = 0.Қλ. 3.34)ζ.0,.-NaClV(h)(Ққ),(. 3.λ).CNaCl = 0.00ҚҚ),қ).NaCl 0.01ζ.0CNaCl = 0.Қη/(.3.33/(/V2 = -1.7 kT (,,. 3.34. ,3).,W1 > 1010,W2 – Қ.Қ,.126(3).CNaCl = 0.ҚηVmax = 4.3 kT,/.