Диссертация (1150101), страница 22
Текст из файла (страница 22)
ЗНАЧЕНИЯ СОЛЬВАТАЦИОННЫХ ИЗБЫТКОВ ВОБЛАСТИ ГОМОГЕННОСТИДЛЯ ТРОЙНЫХ ВОДНО-СОЛЕВЫХСИСТЕМ С ОБЩИМ ИОНОМБ.1. NaCl - CaCl2 –H2O.Б.1.1. Расчет по изоактивате растворителя.m – моляльность, моль/кг р-ля; ∆ – значения химического потенциала NaCl врастворах; x – мольная доля компонента раствора; 2 – давление насыщенногопара воды, мм.рт.ст.; 2 – активность воды; Γ()– сольватационный избытокчастиц i над j в окружении центральной частицы k.1)2)2 =15,0; 2 =0,6313+2∆, Γ+ (2+ )3,913,93,873,863,813,743,683,560,070,140,220,260,380,50,620,84-2-1,75-1,5-1,25-1-0,75-0,5-0,250,650,36-0,27-0,35-0,23-0,43-0,39-0,292++55,8627,8617,5914,8510,037,485,944,24+Γ2+ (+ )-36,23-10,034,675,232,313,192,341,242 =15,5; 2 =0,6524+2∆, Γ+ (2+ )3,763,713,693,663,613,543,473,320,050,10,170,220,360,50,670,96-2-1,75-1,5-1,25-1-0,75-0,5-0,250,630,44-0,07-0,11-0,03-0,27-0,23-0,162++75,237,121,7116,6410,037,085,183,46+Γ2+ (+ )-47,32-16,51,441,860,291,891,210,56- 147 -3)4)5)6)2 =16,0; 2 =0,6734+2∆, Γ+ (2+ )3,593,563,513,473,393,323,223,070,10,170,240,260,450,60,791,17-2-1,75-1,5-1,25-1-0,75-0,5-0,250,260,03-0,51-0,26-0,01-0,34-0,21-0,072++35,920,9414,6313,357,535,534,082,62+Γ2+ (+ )-9,2-0,677,443,510,091,880,860,172 =16,5; 2 =0,6944+2∆, Γ+ (2+ )3,473,393,373,343,223,173,072,820,070,120,190,260,450,610,861,38-2-1,75-1,5-1,25-1-0,75-0,5-0,250,250,17-0,080,010,0046-0,23-0,040,112++49,5728,2517,7412,857,165,23,572,04+Γ2+ (+ )-12,34-4,831,46-0,15-0,031,180,14-0,222 =17,0; 2 =0,7155+2∆, Γ+ (2+ )3,293,223,193,173,072,972,822,380,070,120,170,310,50,691,031,86-2-1,75-1,5-1,25-1-0,75-0,5-0,250,250,040,130,28-0,06-0,150,150,362++4726,8318,7610,236,144,32,741,28+Γ2+ (+ )-11,85-0,97-2,47-2,890,380,65-0,42-0,462 =17,5; 2 =0,7365+2∆, Γ+ (2+ )3,073,042,992,952,852,722,50,120,170,260,360,570,841,31-2-1,75-1,5-1,25-1-0,75-0,5-0,18-0,09-0,11-0,07-0,0028-0,020,232++25,5817,8811,58,1953,241,91+Γ2+ (+ )4,61,611,310,590,010,07-0,44- 148 -1,987)8)9)10)2,41-0,250,420,82-0,342 =18,0; 2 =0,7576+2∆, Γ+ (2+ )2,972,922,872,822,772,662,552,181,490,070,140,220,310,430,690,931,73,13-2,25-2-1,75-1,5-1,25-1-0,75-0,5-0,250,630,35-0,07-0,21-0,05-0,090,060,410,412++42,4320,8613,059,16,443,862,741,280,48+Γ2+ (+ )-26,74-7,220,861,90,330,34-0,15-0,52-0,22 =18,5; 2 =0,7786+2∆, Γ+ (2+ )2,772,722,672,622,572,432,181,680,620,070,120,190,360,480,761,222,274,42-2,25-2-1,75-1,5-1,25-1-0,75-0,5-0,250,260,170,30,11-0,120,080,270,480,512++39,5722,6714,057,285,353,21,790,740,14+Γ2+ (+ )-10,24-3,8-4,25-0,770,64-0,27-0,48-0,35-0,072 19,0; 2 =0,7997+2∆, Γ+ (2+ )2,552,52,482,382,332,131,730,990,070,170,260,410,550,91,73,23-2,25-2-1,75-1,5-1,25-1-0,75-0,51,10,560,04-0,12-0,080,310,480,482++36,4314,719,545,84,242,371,020,31+Γ2+ (+ )-39,98-8,22-0,360,70,34-0,73-0,49-0,152 =19,5; 2 =0, 8207+2∆, Γ+ (2+ )2,382,352,330,050,120,19-2,5-2,25-21,070,590,112++47,619,5812,26+Γ2+ (+ )-51,13-11,47-1,36- 149 -2,232,172,081,731,2611)12)13)14)0,310,480,691,292,27-1,75-1,5-1,25-1-0,750,09-0,040,140,370,327,194,523,011,340,56-0,620,2-0,43-0,49-0,182 =20,0; 2 =0,8418+2∆, Γ+ (2+ )2,182,132,082,031,881,681,290,640,120,190,260,410,621,031,843,08-2,5-2,25-2-1,75-1,5-1,25-1-0,750,07-0,1-0,090,010,060,270,250,152++18,1711,2184,953,031,630,70,21+Γ2+ (+ )-1,331,120,71-0,07-0,19-0,45-0,18-0,032 =20,5; a2 =0,8628+2∆, Γ+ (2+ )1,931,881,861,781,681,531,190,590,070,140,220,360,550,881,552,63-2,75-2,5-2,25-2-1,75-1,5-1,25-10,620,360,120,070,050,210,230,152++27,5713,438,454,943,051,740,770,22+Γ2+ (+ )-17,2-4,77-1-0,35-0,16-0,37-0,18-0,032 =21,0; 2 =0,8838+2∆, Γ+ (2+ )1,731,681,661,581,491,391,190,720,050,120,190,310,50,741,152,1-3-2,75-2,5-2,25-2-1,75-1,5-1,251,050,580,120,130,04-0,010,210,392++34,6148,745,12,981,881,030,34+Γ2+ (+ )-36,45-8,09-1,02-0,67-0,110,02-0,22-0,132 =21,5; 2 =0,9049+2∆, Γ+ (2+ )1,490,05-3,251,052++29,8+Γ2+ (+ )-31,3- 150 -1,441,411,391,291,160,970,5915)16)17)0,120,170,260,430,671,031,74-3-2,75-2,5-2,25-2-1,75-1,50,43-0,070,10,10,010,090,18128,295,3531,730,940,34-5,20,61-0,54-0,29-0,02-0,08-0,062 =22,0; 2 =0,9259+2∆, Γ+ (2+ )1,261,221,161,090,940,740,40,070,140,240,360,60,981,55-3,25-3-2,75-2,5-2,25-2-1,750,630,440,10,040,140,05-0,032++188,714,833,031,570,760,26+Γ2+ (+ )-11,35-3,86-0,47-0,14-0,22-0,040,012 =22,5; 2 =0,9470+2∆, Γ+ (2+ )0,940,890,840,740,640,370,070,170,260,410,61,05-3,5-3,25-3-2,75-2,5-2,251,10,540-0,050,040,22++13,435,243,231,81,070,35+Γ2+ (+ )-14,73-2,85-0,010,09-0,05-0,072 =23,0; 2 =0,9680+2∆, Γ+ (2+ )0,590,570,50,450,350,150,070,120,170,330,480,81-4-3,75-3,5-3,25-3-2,750,29-0,020,170,23-0,060,092++8,434,752,941,360,730,19+Γ2+ (+ )-2,460,12-0,49-0,320,04-0,02- 151 -Б.1.2.
Расчет по изопотенциалам NaCl.m – моляльность, моль/кг р-ля; ∆ – значения химического потенциала NaCl врастворах; x – мольная доля компонента раствора; 1 – вода; 1 – активность воды;Γ()– сольватационный избыток частиц i над j в окружении центральной частицыk.1)2)3)∆, = -3,25211Γ1(2+ )Γ1(2+ ) + Γ1(2+ )2+11Γ2+ (1)1,491,260,890,450,050,070,170,330,90490,92590,9470,968-0,53-0,42-0,26-0,214,399,239,745,40,030,020,020,010,020,010,010,0021+−∆, = -3,0211Γ1(2+ )Γ1(2+ ) + Γ1(2+ )2+11Γ2+ (1)1,731,441,220,840,350,050,120,140,260,480,88380,90490,92590,9470,968-0,49-0,52-0,44-0,26-0,1915,748,134,315,773,450,030,030,020,020,010,010,020,010,010,0019+−∆, = -2,75211Γ1(2+ )Γ1(2+ ) + Γ1(2+ )2+11Γ2+ (1)1,931,681,411,160,740,370,070,120,170,240,411,050,86280,88380,90490,92590,9470,968-0,56-0,53-0,53-0,43-0,72-1,139,126,894,625,2112,9520,070,030,030,030,020,010,010,020,020,020,010,010,01+−- 152 -4)5)6)∆, = -2,5211Γ1(2+ )Γ1(2+ ) + Γ1(2+ )2+11Γ2+ (1)2,382,181,881,661,391,090,640,050,120,140,190,260,360,60,82070,84180,86280,88380,90490,92590,947-0,71-0,57-0,53-0,57-0,51-0,42-0,3516,138,512,714,33,884,55,310,040,040,030,030,030,020,010,030,020,020,020,020,010,003+−∆, = -2,25211Γ1(2+ )Γ1(2+ ) + Γ1(2+ )2+11Γ2+ (1)2,972,772,552,352,131,861,581,290,940,370,070,070,070,120,190,220,310,430,61,050,75760,77860,79970,82070,84180,86280,88380,90490,92590,947-0,66-0,64-0,65-0,68-0,59-0,53-0,56-0,52-0,44-0,39-0,92-1,034,118,584,42,974,653,964,675,790,050,050,050,040,040,030,030,020,020,010,030,030,030,030,020,020,020,010,010,0039+−∆, = -2,0211Γ1(2+ )Γ1(2+ ) + Γ1(2+ )2+11Γ2+ (1)3,913,763,593,473,293,072,922,722,52,332,081,781,491,160,070,050,10,070,070,120,140,120,170,190,260,360,50,670,63130,65240,67340,69440,71550,73650,75760,77860,79970,82070,84180,86280,88380,9049-0,78-0,79-0,8-0,76-0,71-0,74-0,71-0,65-0,69-0,66-0,58-0,57-0,57-0,54-5,522,52,15-3,413,985,36-0,820,853,342,974,684,694,13,970,070,070,060,060,060,060,050,050,050,040,040,030,030,020,050,060,050,050,040,040,040,030,030,030,020,020,020,01+−- 153 -0,747)8)0,980,9259-0,544,50,010,01∆, = -1,75211Γ1(2+ )Γ1(2+ ) + Γ1(2+ )2+11Γ2+ (1)3,93,713,563,393,223,042,872,672,482,232,031,681,390,970,40,140,10,170,120,120,170,220,190,260,310,410,550,741,031,550,63130,65240,67340,69440,71550,73650,75760,77860,79970,82070,84180,86280,88380,90490,9259-0,71-0,78-0,78-0,72-0,75-0,77-0,7-0,69-0,68-0,68-0,62-0,58-0,6-0,52-0,51-5,651,190,88-3,432,424,680,140,683,543,274,114,034,14,094,290,070,070,060,060,060,050,050,050,040,040,040,030,030,020,010,050,050,050,040,050,040,030,030,030,030,020,020,020,010,01+−∆, = -1,5211Γ1(2+ )Γ1(2+ ) + Γ1(2+ )2+11Γ2+ (1)3,873,693,513,373,192,992,822,622,382,171,881,531,190,590,220,170,240,190,170,260,310,360,410,480,620,881,151,740,63130,65240,67340,69440,71550,73650,75760,77860,79970,82070,84180,86280,88380,9049-0,71-0,76-0,78-0,72-0,74-0,78-0,75-0,68-0,67-0,67-0,64-0,66-0,62-0,57-4,440,290,35-3,412,114,612,21,611,642,764,424,454,395,190,070,070,060,060,060,050,050,050,040,040,030,030,020,010,050,050,050,040,040,040,040,030,030,030,020,020,010,01+−- 154 -∆, = -1,259)211Γ1(2+ )Γ1(2+ ) + Γ1(2+ )2+11Γ2+ (1)3,863,663,473,343,172,952,772,572,332,081,681,190,720,260,220,260,260,310,360,430,480,550,691,031,552,10,63130,65240,67340,69440,71550,73650,75760,77860,79970,82070,84180,86280,8838-0,69-0,73-0,79-0,8-0,75-0,74-0,75-0,69-0,69-0,69-0,7-0,76-0,79-3,1-0,480,871,012,132,181,861,332,374,776,295,344,350,070,070,060,060,060,050,050,050,040,040,030,020,010,050,050,050,050,040,040,040,030,030,030,020,020,0110)+−∆, = -1,0211Γ1(2+ )Γ1(2+ ) + Γ1(2+ )2+11Γ2+ (1)3,813,613,393,223,072,852,662,432,131,731,290,590,380,360,450,450,50,570,690,760,91,291,842,630,63130,65240,67340,69440,71550,73650,75760,77860,79970,82070,84180,8628-0,71-0,74-0,76-0,79-0,77-0,77-0,75-0,66-0,69-0,8-0,76-0,66-1,350,821,230,391,432,181,831,393,765,665,144,570,070,070,060,060,060,050,050,040,040,030,020,010,050,050,050,050,050,040,040,030,030,020,020,0111)+−∆, = -0,75211Γ1(2+ )Γ1(2+ ) + Γ1(2+ )2+11Γ2+ (1)3,743,543,323,172,970,50,50,60,610,690,63130,65240,67340,69440,7155-0,73-0,76-0,79-0,78-0,77-0,510,931,090,652,10,070,060,060,060,050,050,050,050,050,04+−- 155 -2,722,552,181,731,260,6412)0,840,931,221,72,273,080,73650,75760,77860,79970,82070,8418-0,79-0,76-0,74-0,81-0,84-0,851,982,554,414,644,314,310,050,050,040,030,020,01∆μ,NaCl = -0,5+−211Γ1(2+ )Γ1(2+ ) + Γ1(2+ )3,683,473,223,072,822,52,181,680,990,620,670,790,861,031,311,72,273,230,63130,65240,67340,69440,71550,73650,75760,77860,7997-0,76-0,76-0,8-0,82-0,79-0,85-0,85-0,86-0,910,71,361,521,712,913,74,074,695,2313)0,040,040,030,020,020,012+10,070,060,060,060,050,050,040,030,021Γ2+ (1)0,050,050,050,050,040,040,030,030,02∆μ,NaCl = -0,25211Γ1(2+ )Γ1(2+ ) + Γ1(2+ )2+11Γ2+ (1)3,563,323,072,822,381,981,490,620,840,961,171,381,862,413,134,420,63130,65240,67340,69440,71550,73650,75760,7786-0,78-0,81-0,84-0,83-0,88-0,97-0,98-0,981,542,12,433,194,033,884,424,930,060,060,060,050,040,040,030,010,050,050,050,040,040,040,030,01+−- 156 -Б.2.
NaCl - CdCl2 –H2O.Б.2.1. Расчет по изоактивате растворителя.m – моляльность, моль/кг р-ля; ∆ – значения химического потенциала NaCl врастворах; x – мольная доля компонента раствора; 2 – давление насыщенногопара воды, мм.рт.ст.; 2 – активность воды; Γ()– сольватационный избытокчастиц i над j в окружении центральной частицы k.1)2)3)2 =19,00; 2 =0,7997+2∆, Γ+ ( )26,676,576,431,31,491,73-2,375-2,25-2,1250,250,310,372+5,134,413,72+Γ+2 ( )-1,28-1,37-1,382 =19,25; 2 =0,8102+2∆, Γ+ ( )26,626,56,436,346,246,085,912,981,731,040,520,780,951,111,351,491,731,924,434,864,914,95-2,75-2,625-2,5-2,375-2,25-2,125-2-1-0,75-0,625-0,50,830,640,620,350,140,16-0,05-0,29-0,68-0,84-0,862+8,496,845,794,74,193,513,080,670,360,210,11+Γ+2 ( )-7,05-4,38-3,59-1,65-0,59-0,560,150,190,240,180,092 =19,50; 2 =0,8207+2∆, Γ+ ( )26,656,576,396,346,296,26,085,960,170,310,690,780,881,021,161,33-4-3,5-3-2,875-2,75-2,625-2,5-2,3750,420,640,510,130,250,280,230,312+39,1221,199,268,137,156,085,244,48+Γ+2 ( )-16,43-13,56-4,72-1,06-1,79-1,7-1,21-1,39- 157 -5,825,685,495,35,043,413,262,892,511,991,350,714)5)1,541,781,972,22,443,63,824,054,244,434,624,67-2,25-2,125-2-1,875-1,75-1,375-1,25-1,125-1-0,875-0,75-0,6250,330,13-0,03-0,020,07-0,14-0,47-0,51-0,57-0,56-0,69-0,823,783,192,792,412,070,950,850,710,590,450,290,15-1,25-0,410,080,05-0,140,130,40,360,340,250,20,122 =19,75; 2 =0,8312+2∆, Γ+ ( )26,396,316,16,015,985,875,775,65,495,345,114,94,644,263,783,312,932,512,061,420,8500,170,310,640,760,8511,161,351,491,731,972,22,442,773,153,533,723,964,14,294,384,46-4-3,5-3-2,875-2,75-2,625-2,5-2,375-2,25-2,125-2-1,875-1,75-1,625-1,5-1,375-1,25-1,125-1-0,875-0,75-0,6250,420,560,650,320,270,440,390,160,140,280,1-0,020,050,170,11-0,23-0,46-0,53-0,59-0,64-0,74-0,732+37,5920,359,537,917,045,874,974,153,683,092,592,231,91,541,20,940,790,630,50,330,190+Γ+2 ( )-15,79-11,4-6,19-2,53-1,9-2,58-1,94-0,66-0,52-0,87-0,260,04-0,1-0,26-0,130,220,360,330,30,210,1402 =20,0; 2 =0,8418+2∆, Γ+ ( )26,055,965,725,685,585,490,170,310,640,730,881-4-3,5-3-2,875-2,75-2,6250,420,560,460,480,460,282+35,5919,238,947,786,345,49+Γ+2 ( )-14,95-10,77-4,11-3,73-2,92-1,54- 158 -5,375,255,114,924,734,494,213,883,452,892,512,081,580,950,286)7)1,161,351,491,731,972,22,442,773,13,443,633,863,964,14,19-2,5-2,375-2,25-2,125-2-1,875-1,75-1,625-1,5-1,375-1,25-1,125-1-0,875-0,750,390,160,140,280,1-0,020,050,090,0005-0,26-0,46-0,57-0,67-0,67-0,724,633,893,432,842,42,041,731,41,110,840,690,540,40,230,07-1,81-0,62-0,48-0,8-0,240,04-0,09-0,1300,220,320,310,270,150,052 =20,25; 2 =0,8523+2∆, Γ+ ( )25,725,615,395,35,25,114,974,824,664,474,2343,713,412,932,412,011,561,040,380,170,260,640,730,8511,161,331,491,731,972,162,422,683,033,323,533,673,843,96-4-3,5-3-2,875-2,75-2,625-2,5-2,375-2,25-2,125-2-1,875-1,75-1,625-1,5-1,375-1,25-1,125-1-0,8750,00340,560,670,330,460,440,320,160,210,280,02-0,05-0,010,03-0,01-0,28-0,51-0,58-0,6-0,652+33,6521,588,427,266,125,114,283,623,132,582,151,851,531,270,970,730,570,430,270,1+Γ+2 ( )-0,11-12,08-5,64-2,4-2,82-2,25-1,37-0,58-0,66-0,72-0,040,090,02-0,040,010,20,290,250,160,072 =20,50; 2 =0,8628+2∆, Γ+ ( )25,395,254,994,874,80,170,310,590,730,83-4-3,5-3-2,875-2,750,420,460,750,590,642+31,7116,948,466,675,78+Γ+2 ( )-13,32-7,79-6,35-3,94-3,7- 159 -4,684,544,44,264,043,833,553,312,932,461,961,470,990,478)9)1,041,161,351,491,751,942,182,422,683,013,253,443,533,67-2,625-2,5-2,375-2,25-2,125-2-1,875-1,75-1,625-1,5-1,375-1,25-1,125-10,550,210,160,20,210,010,01-0,050,01-0,1-0,36-0,58-0,65-0,64,53,913,262,862,311,971,631,371,090,820,60,430,280,13-2,48-0,82-0,52-0,57-0,49-0,02-0,020,07-0,010,080,220,250,180,082 =20,75; 2 =0,8733+2∆, Γ+ ( )25,044,924,594,544,454,284,163,973,783,573,313,072,742,461,891,470,990,520,170,310,590,730,830,971,161,31,491,681,922,162,422,632,923,133,293,39-4-3,5-3-2,875-2,75-2,625-2,5-2,375-2,25-2,125-2-1,875-1,75-1,625-1,5-1,375-1,25-1,1250,420,470,750,590,330,560,360,160,190,170,160,06-0,09-0,12-0,18-0,42-0,59-0,682+29,6515,877,786,225,364,413,593,052,542,131,721,421,130,940,650,470,30,15+Γ+2 ( )-12,45-7,46-5,84-3,67-1,77-2,47-1,29-0,49-0,48-0,36-0,28-0,090,10,110,120,20,180,12 =21,00; 2 =0,8838+2∆, Γ+ ( )24,644,524,264,164,043,883,743,570,120,310,640,730,830,971,211,35-4-3,5-3-2,875-2,75-2,625-2,5-2,3751,240,970,470,220,330,750,53-0,032+38,6714,586,665,74,8743,092,64+Γ+2 ( )-47,95-14,14-3,13-1,25-1,61-3-1,640,08- 160 -3,413,172,892,552,221,81,230,80,3810)11)1,491,731,922,162,392,582,822,993,15-2,25-2,125-2-1,875-1,75-1,625-1,5-1,375-1,250,150,170,030,02-0,17-0,21-0,29-0,46-0,492,291,831,511,180,930,70,440,270,12-0,34-0,31-0,05-0,020,160,150,130,120,062 =21,25; 2 =0,8944+2∆, Γ+ ( )24,34,163,883,743,643,53,313,152,982,72,462,11,71,30,830,380,170,310,640,710,830,971,161,331,491,731,942,162,392,582,773,15-4-3,5-3-2,875-2,75-2,625-2,5-2,375-2,25-2,125-2-1,875-1,75-1,625-1,5-1,3750,420,560,340,220,460,560,470,160,220,220,03-0,02-0,16-0,29-0,070,172+25,2913,426,065,274,393,612,852,3721,561,270,970,710,50,30,12+Γ+2 ( )-10,62-7,52-2,06-1,16-2,02-2,02-1,34-0,38-0,44-0,34-0,040,020,110,150,02-0,022 =21,50; 2 =0,9049+2∆, Γ+ ( )23,933,783,453,363,223,072,892,72,512,251,961,561,140,750,330,170,310,620,730,851,021,161,351,491,711,922,132,352,492,63-4-3,5-3-2,875-2,75-2,625-2,5-2,375-2,25-2,125-2-1,875-1,75-1,625-1,50,420,520,580,480,560,450,30,160,10,180,03-0,05-0,25-0,45-0,462+23,1212,195,564,63,793,012,4921,681,321,020,730,490,30,13+Γ+2 ( )-9,71-6,34-3,22-2,21-2,12-1,35-0,75-0,32-0,17-0,24-0,030,040,120,140,06- 161 -12)13)14)2 =21,75; 2 =0,9154+2∆, Γ+ ( )23,523,363,032,892,742,582,392,22,011,731,370,950,590,240,170,310,640,730,881,021,191,331,491,711,872,112,252,35-4-3,5-3-2,875-2,75-2,625-2,5-2,375-2,25-2,125-2-1,875-1,75-1,6250,420,560,470,490,560,410,240,050,170,07-0,01-0,12-0,47-0,562+20,7110,844,733,963,112,532,011,651,351,010,730,450,260,1+Γ+2 ( )-8,7-6,07-2,22-1,94-1,74-1,04-0,48-0,08-0,23-0,070,010,050,120,062 =22,00; 2 =0,9259+2∆, Γ+ ( )23,072,912,552,412,272,131,891,751,471,140,80,430,140,170,310,640,730,881,021,161,351,491,661,872,012,13-4-3,5-3-2,875-2,75-2,625-2,5-2,375-2,25-2,125-2-1,875-1,750,420,560,470,490,560,290,310,17-0,020,07-0,09-0,37-0,442+18,069,393,983,32,582,091,631,30,990,690,430,210,07+Γ+2 ( )-7,59-5,26-1,87-1,62-1,44-0,61-0,51-0,220,02-0,050,040,080,032 =22,25; 2 =0,9364+2∆, Γ+ ( )22,652,462,081,941,81,611,41,180,90,170,310,640,780,881,021,161,31,49-4-3,5-3-2,875-2,75-2,625-2,5-2,375-2,250,420,560,780,490,260,30,140,170,092+15,597,943,252,492,051,581,210,910,6+Γ+2 ( )-6,55-4,45-2,54-1,22-0,53-0,47-0,17-0,15-0,05- 162 -0,590,241,641,82-2,125-2-0,05-0,020,360,130,0202 =22,5; 2 =0,947015)+2∆, Γ+ ( )22,221,991,581,421,251,090,850,610,330,050,170,360,690,780,91,021,191,351,491,59-4-3,5-3-2,875-2,75-2,625-2,5-2,375-2,25-2,1250,770,650,340,250,260,310,310,06-0,22-0,372+13,065,532,291,821,391,070,710,450,220,03+Γ+2 ( )-10,06-3,59-0,78-0,46-0,36-0,33-0,22-0,030,050,012 =22,75; 2 =0,957516)+2∆, Γ+ ( )21,731,491,040,90,710,470,240,050,170,380,690,830,921,071,191,28-4-3,5-3-2,875-2,75-2,625-2,5-2,3750,90,650,570,350,20,21-0,15-0,312+10,183,921,511,080,770,440,20,04+Γ+2 ( )-9,16-2,55-0,86-0,38-0,15-0,090,030,012 =23,00; 2 =0,968017)+2∆, Γ+ ( )21,180,990,470,280,090,170,380,710,830,92-4-3,5-3-2,875-2,750,90,680,470,22-0,0218)2 =23,25; 2 =0,97852 ∆, 0,710,470,210,45-4-3,52+6,942,610,660,340,1+Γ+2 ( )-6,25-1,77-0,31-0,070,002- 163 -2 =23,50; 2 =0,989119)2 ∆, 0,240,07-4Б.2.2.
![](https://s.studizba.com/z.php?f=/templates/si/i/noavatar.png&w=100&h=100&t=1"){kind=avatar}
