Автореферат (1150068), страница 3
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ɋɪɟɞɢ ɧɟɦɟɬɨɤɫɢɥɢɪɨɜɚɧɧɵɯ ɩɨɥɢɦɟɪɨɜɧɚɢɦɟɧɶɲɟɣ ɫɤɨɪɨɫɬɶɸ ɞɟɝɪɚɞɚɰɢɢ ɨɛɥɚɞɚɟɬ ɩɥɟɧɤɚ ɤɨɦɩɥɟɤɫɚpoly[Ni(Saltmen)], ɫɨɞɟɪɠɚɳɚɹ ɱɟɬɵɪɟ ɦɟɬɢɥɶɧɵɯ ɡɚɦɟɫɬɢɬɟɥɹɦɢ ɜɞɢɚɦɢɧɨɜɨɦɦɨɫɬɭȼɜɟɞɟɧɢɟɜɦɨɫɬɢɤɨɜɭɸɱɚɫɬɶɥɢɝɚɧɞɚɦɟɬɢɥɶɧɵɯɡɚɦɟɫɬɢɬɟɥɟɣ ɩɪɢɜɨɞɢɬ ɬɚɤɠɟ ɤ ɡɚɦɟɞɥɟɧɢɸ ɞɟɝɪɚɞɚɰɢɢɦɟɬɨɤɫɢɥɢɪɨɜɚɧɧɨɝɨ ɤɨɦɩɥɟɤɫɚ SRO\>1LCH3OSaltmen)] ɩɨ ɫɪɚɜɧɟɧɢɸɫ ɤɨɦɩɥɟɤɫɨɦ poly[Ni(CH3OSalen)]. Ɇɨɠɧɨ ɩɪɟɞɩɨɥɨɠɢɬɶ ɱɬɨɩɚɞɟɧɢɟ ɫɤɨɪɨɫɬɢ ɞɟɝɪɚɞɚɰɢɢ ɩɥɟɧɨɤ ɫɚɥɟɧɨɜɵɯ ɤɨɦɩɥɟɤɫɨɜ ɧɢɤɟɥɹɨɩɪɟɞɟɥɹɟɬɫɹ ɫɬɟɪɢɱɟɫɤɢɦɢ ɮɚɤɬɨɪɚɦɢ ɦɟɬɢɥɶɧɵɯ ɡɚɦɟɫɬɢɬɟɥɟɣ,ɩɪɟɩɹɬɫɬɜɭɸɳɢɯ ɤɨɨɪɞɢɧɚɰɢɢ ɦɨɥɟɤɭɥ ɜɨɞɵ ɤ ɚɤɫɢɚɥɶɧɨɦɭɩɨɥɨɠɟɧɢɸɚɬɨɦɨɜɧɢɤɟɥɹ.ɉɨɞɪɚɡɞɟɥ ɩɨɫɜɹɳɟɧɢɡɭɱɟɧɢɸɨɛɪɚɬɢɦɨɫɬɢɞɟɝɪɚɞɚɰɢɢɩɨɥɢɦɟɪɧɵɯɤɨɦɩɥɟɤɫɨɜɛɟɡɜɨɞɵɣɰɢɤɥɫɇ Ɉpoly[Ni(Salen)].ȼɞɚɧɧɨɦ1.5ɩɨɫɥɟɫɭɲɤɢ ɋɫɥɭɱɚɟ ɱɬɨɛɵ ɞɨɫɬɚɬɨɱɧɨ1.0ɩɨɫɥɟɫɭɲɤɢ ɋɩɨɫɥɟɫɭɲɤɢ ɋɛɵɫɬɪɨɞɨɛɢɬɶɫɹɩɨɥɧɨɣɩɨɬɟɪɢ0.5ɷɥɟɤɬɪɨɚɤɬɢɜɧɨɫɬɢ ɩɨɥɢɦɟɪɧɵɯ0.0ɩɥɟɧɨɤɫɚɥɟɧɨɜɵɯɤɨɦɩɥɟɤɫɨɜɜ-0.5ɷɥɟɤɬɪɨɥɢɬɛɵɥɨɞɨɛɚɜɥɟɧɨ 10%-1.0ɜɨɞɵ Ɋɢɫ.
7 ɱɬɨ ɩɪɢɜɨɞɢɬ ɤ-1.5ɩɨɥɧɨɣ ɞɟɝɪɚɞɚɰɢɢ ɩɥɟɧɤɢ-0.20.00.20.40.60.8ȿȼɩɨɫɥɟ ɰɢɤɥɢɪɨɜɚɧɢɹ ɜ ɬɟɱɟɧɢɢ ɰɢɤɥɨɜ ɉɪɢ ɧɚɝɪɟɜɟ ɜɵɲɟ0Ɋɢɫ7 - ȼɥɢɹɧɢɟɞɨɛɚɜɤɢɜɨɞɵɜ 100 ɋ ɱɚɫɬɶ ɤɨɨɪɞɢɧɢɪɨɜɚɧɧɨɣɪɚɫɬɜɨɪ ɮɨɧɨɜɨɝɨ ɷɥɟɤɬɪɨɥɢɬɚ ɩɪɢ ɜɨɞɵ ɢɫɩɚɪɹɟɬɫɹ ɢ ɩɥɟɧɤɚɰɢɤɥɢɪɨɜɚɧɢɢ ɜ ɬɟɱɟɧɢɟ ɰɢɤɥɨɜ ɢ ɱɚɫɬɢɱɧɨ ɜɨɫɫɬɚɧɚɜɥɢɜɚɟɬ ɫɜɨɸɋɬɟɩɟɧɶɜɥɢɹɧɢɟɬɟɦɩɟɪɚɬɭɪɵɧɚɪɟɝɟɧɟɪɚɰɢɸ ɷɥɟɤɬɪɨɚɤɬɢɜɧɨɫɬɶɷɥɟɤɬɪɨɚɤɬɢɜɧɨɫɬɢɩɨɥɢɦɟɪɧɵɯ ɷɬɨɝɨɜɨɫɫɬɚɧɨɜɥɟɧɢɹɡɚɜɢɫɢɬ ɨɬɩɥɟɧɨɤSRO\>1L6DOHQ@.ɞɥɢɬɟɥɶɧɨɫɬɢ ɤɨɧɬɚɤɬɚ ɫ ɜɨɞɨɣɢ ɬɟɦɩɟɪɚɬɭɪɵ ɫɭɲɤɢ (Ɋɢɫ 7),ɨɞɧɚɤɨɜɨɛɳɟɦɫɥɭɱɚɟɫɬɟɩɟɧɶɨɛɪɚɬɢɦɨɫɬɢɞɟɝɪɚɞɚɰɢɢɩɨɥɢɦɟɪɧɨɣɩɥɟɧɤɢSRO\>1L6DOHQ@ɦɚɥɚɢɩɪɚɤɬɢɱɟɫɤɨɝɨɡɧɚɱɟɧɢɹɧɟɢɦɟɟɬȼ ɉɨɞɪɚɡɞɟɥɟ ɢɫɫɥɟɞɨɜɚɧɚ ɞɟɝɪɚɞɚɰɢɹ ɩɥɟɧɨɤ ɩɨɥɢɦɟɪɧɵɯɤɨɦɩɥɟɤɫɨɜ ɧɢɤɟɥɹ ɫ ɨɫɧɨɜɚɧɢɹɦɢ ɒɢɮɮɚ ɜ ɩɪɢɫɭɬɫɬɜɢɢ ɯɥɨɪɢɞ ɢɛɪɨɦɢɞ-ɢɨɧɨɜ Ɉɩɪɟɞɟɥɟɧɨ ɱɬɨ ɩɪɢ ɞɨɛɚɜɥɟɧɢɢ ɜ Ɏɗ ɝɚɥɨɝɟɧɢɞɢɨɧɨɜ ɩɪɨɢɫɯɨɞɢɬ ɩɨɫɬɟɩɟɧɧɚɹ ɩɨɬɟɪɹ ɷɥɟɤɬɪɨɚɤɬɢɜɧɨɫɬɢ ɢɡɭɱɚɟɦɵɯɩɨɥɢɦɟɪɧɵɯ ɤɨɦɩɥɟɤɫɨɜ ɫɤɨɪɨɫɬɶ ɤɨɬɨɪɨɣ ɨɩɪɟɞɟɥɹɟɬɫɹ ɫɬɪɭɤɬɭɪɨɣɥɢɝɚɧɞɚ ȼ ɫɥɭɱɚɟ ɰɢɤɥɢɪɨɜɚɧɢɹ ɩɨɥɢɦɟɪɧɨɝɨ ɤɨɦɩɥɟɤɫɚpoly[Ni(Salen)] (Ɋɢɫ 8ɚ ɩɪɢ ɞɨɛɚɜɥɟɧɢɢ ɯɥɨɪɢɞ-ɢɨɧɨɜ ɧɚ ɩɟɪɜɨɦ200,ɦȺ013ɰɢɤɥɟɩɪɨɢɫɯɨɞɢɬɧɟɨɛɪɚɬɢɦɵɣɩɪɢɪɨɫɬɦɚɫɫɵɩɨɥɢɦɟɪɧɨɣɩɥɟɧɤɢɢɧɟɨɛɪɚɬɢɦɨɟ ɭɜɟɥɢɱɟɧɢɟ ɡɚɪɹɞɚ ɟɺ ɨɤɢɫɥɟɧɢɹ ɧɚ ɇɚɩɨɫɥɟɞɭɸɳɢɯ ɰɢɤɥɚɯ ɩɪɨɢɫɯɨɞɢɬ ɛɵɫɬɪɚɹ ɩɨɬɟɪɹ ɷɥɟɤɬɪɨɚɤɬɢɜɧɨɫɬɢɷɬɨɣɩɨɥɢɦɟɪɧɨɣɩɥɟɧɤɢɢɤɞɟɫɹɬɨɦɭɰɢɤɥɭɨɧɚɬɟɪɹɟɬɡɚɪɹɞɚɨɤɢɫɥɟɧɢɹ Ɉɞɧɚɤɨ ɩɨɬɟɪɢ ɦɚɫɫɵ ɩɥɟɧɤɢ poly[Ni(Salen@ ɧɟɩɪɨɢɫɯɨɞɢɬ Ɋɢɫ 8ɛ ɧɚɩɪɨɬɢɜ ɩɨɫɥɟ ɭɜɟɥɢɱɟɧɢɹ ɦɚɫɫɵ ɧɚ ɩɟɪɜɵɯɰɢɤɥɚɯɩɪɨɢɫɯɨɞɢɬɟɺɫɬɚɛɢɥɢɡɚɰɢɹɚ1.21.03.5ɰ-30ɋ2H5)4NCl3.0'm, PɝFɦ2ɰ-30ɋ2H5)4NCl0.8,ɦ$ɛ4.0ɰɎɗɰ-30ɋ2H5)4NCl-3ɰ 0ɋ2H5)4NCl0.60.40.20.02.52.01.51.00.5-0.2-0.20.00.20.40.00.0000.60.0050.0100.0150.0200.0250.030TɄɥɫɦ2ȿȼɊɢɫ 8 - Ɋɟɡɭɥɶɬɚɬɵ ɗɄȽɆ ɩɨɥɢɦɟɪɧɨɝɨ ɤɨɦɩɥɟɤɫɚ poly[Ni(Salen@ ɜɩɪɢɫɭɬɫɬɜɢɢ ɯɥɨɪɢɞ-ɢɨɧɨɜ ɚ ɢɡɦɟɧɟɧɢɟ ɷɥɟɤɬɪɨɚɤɬɢɜɧɨɫɬɢ ɧɚ ɩɟɪɜɨɦɩɹɬɨɦ ɢ ɞɟɫɹɬɨɦ ɰɢɤɥɚɯ ɫ ɞɨɛɚɜɥɟɧɢɟɦ -3 M ɋ2H5)4NCl ɛ ɡɚɜɢɫɢɦɨɫɬɶɢɡɦɟɧɟɧɢɹɦɚɫɫɵɨɬɡɚɪɹɞɚɜɯɨɞɟɰɢɤɥɢɪɨɜɚɧɢɹɩɨɬɟɧɰɢɚɥɚȼ ɫɥɭɱɚɟ ɪɟɝɢɫɬɪɚɰɢɢ ɜɨɥɶɬɚɦɩɟɪɧɵɯ ɤɪɢɜɵɯ ɦɟɬɨɤɫɢɥɢɪɨɜɚɧɧɨɝɨɩɨɥɢɦɟɪɧɨɝɨ ɤɨɦɩɥɟɤɫɚ SRO\>1LCH3O6DOHQ@ ɜ ɩɪɢɫɭɬɫɬɜɢɢ ɯɥɨɪɢɞɢɨɧɨɜɧɚɩɟɪɜɨɦɰɢɤɥɟɡɚɪɹɞ ɨɤɢɫɥɟɧɢɹɬɚɤɠɟɭɜɟɥɢɱɢɜɚɟɬɫɹɧɚ(Ɋɢɫ9ɚɧɨɡɧɚɱɢɬɟɥɶɧɨɝɨɧɟɨɛɪɚɬɢɦɨɝɨɩɪɢɪɨɫɬɚɦɚɫɫɵɩɨɥɢɦɟɪɧɨɣɩɥɟɧɤɢ ɤɨɦɩɥɟɤɫɚ ɧɟ ɩɪɨɢɫɯɨɞɢɬ Ɋɢɫ 9ɛ ɇɚɩɪɨɬɢɜ ɩɪɢɞɚɥɶɧɟɣɲɟɦ ɰɢɤɥɢɪɨɜɚɧɢɢ ɜ ɯɥɨɪɢɞ-ɫɨɞɟɪɠɚɳɟɦ ɷɥɟɤɬɪɨɥɢɬɟɩɪɨɢɫɯɨɞɢɬ ɪɟɡɤɨɟ ɫɧɢɠɟɧɢɟ ɦɚɫɫɵ ɦɨɞɢɮɢɰɢɪɨɜɚɧɧɨɝɨ ɷɥɟɤɬɪɨɞɚɬɚɤɢɦ ɨɛɪɚɡɨɦ ɱɬɨ ɤ ɩɹɬɨɦɭ ɰɢɤɥɭ ɪɟɝɢɫɬɪɚɰɢɢ ɜɨɥɶɬɚɦɩɟɪɨɝɪɚɦɦɩɪɨɢɫɯɨɞɢɬ ɩɪɚɤɬɢɱɟɫɤɢ ɩɨɥɧɚɹ ɞɟɫɬɪɭɤɰɢɹ ɩɨɥɢɦɟɪɧɨɣ ɩɥɟɧɤɢ ɱɬɨɩɨɞɬɜɟɪɠɞɚɟɬɫɹ ɜɢɡɭɚɥɶɧɵɦ ɨɫɦɨɬɪɨɦ ɷɥɟɤɬɪɨɞɚ ɉɪɢ ɷɬɨɦ ɩɥɟɧɤɚɩɨɥɢɦɟɪɧɨɝɨ ɤɨɦɩɥɟɤɫɚ SRO\>1LCH3O6DOHQ@ ɛɵɫɬɪɨ ɬɟɪɹɟɬ ɫɜɨɸɷɥɟɤɬɪɨɚɤɬɢɜɧɨɫɬɶ ɡɚɪɹɞ ɟɺ ɨɤɢɫɥɟɧɢɹ ɤ ɞɟɫɹɬɨɦɭ ɰɢɤɥɭ ɫɨɫɬɚɜɥɹɟɬɦɟɧɟɟɨɬɡɚɪɹɞɚɨɤɢɫɥɟɧɢɹɩɟɪɜɨɝɨɰɢɤɥɚɫɞɨɛɚɜɥɟɧɢɟɦɯɥɨɪɢɞɢɨɧɨɜ(Ɋɢɫ9ɚ.14ɚ,ɦ$0.4ɛɰɎɗɰ-30ɋ2H5)4NCl1.0ɰ-30ɋ2H5)4NCl0.5ɰ-30ɋ2H5)4NCl'm, PɝFɦ20.60.20.0-0.20.0-0.5-1.0-1.5-2.0-2.5-0.20.00.20.40.60.0000.0050.0100.01524ɄɥɫɦȿȼɊɢɫ9 - ɊɟɡɭɥɶɬɚɬɵɗɄȽɆɩɨɥɢɦɟɪɧɨɝɨɤɨɦɩɥɟɤɫɚpoly[NiɋH3OSalen@ɜɩɪɢɫɭɬɫɬɜɢɢɯɥɨɪɢɞ-ɢɨɧɨɜɚɢɡɦɟɧɟɧɢɟɷɥɟɤɬɪɨɚɤɬɢɜɧɨɫɬɢɧɚɩɟɪɜɨɦɩɹɬɨɦɢɞɟɫɹɬɨɦɰɢɤɥɚɯɫɞɨɛɚɜɥɟɧɢɟɦ-3 M ɋ2H5)4NClɛɡɚɜɢɫɢɦɨɫɬɶɢɡɦɟɧɟɧɢɹɦɚɫɫɵɨɬɡɚɪɹɞɚɜɯɨɞɟɰɢɤɥɢɪɨɜɚɧɢɹɩɨɬɟɧɰɢɚɥɚȼ ɉɨɞɪɚɡɞɟɥɟ 4 ɞɥɹ ɭɬɨɱɧɟɧɢɹ ɫɯɟɦɵ ɞɟɝɪɚɞɚɰɢɢ ɩɨɥɢɦɟɪɧɵɯɤɨɦɩɥɟɤɫɨɜ ɧɢɤɟɥɹ ɜ ɩɪɢɫɭɬɫɬɜɢɢ ɨɫɧɨɜɚɧɢɣ Ʌɶɸɢɫɚ ɩɪɨɞɭɤɬɵɞɟɫɬɪɭɤɰɢɢ ɩɨɥɢɦɟɪɧɵɯ ɤɨɦɩɥɟɤɫɨɜ ɢɡɭɱɟɧɵ ɦɟɬɨɞɨɦ ɆȺɅȾɂ ɇɚɨɫɧɨɜɟ ɷɬɢɯ ɪɟɡɭɥɶɬɚɬɨɜ ɩɪɟɞɥɨɠɟɧ ɦɟɯɚɧɢɡɦ ɞɟɝɪɚɞɚɰɢɢ ɩɥɟɧɨɤɩɨɥɢɦɟɪɧɵɯɤɨɦɩɥɟɤɫɨɜɧɢɤɟɥɹɫɨɫɧɨɜɚɧɢɹɦɢɒɢɮɮɚɜɩɪɢɫɭɬɫɬɜɢɢɨɫɧɨɜɚɧɢɣ Ʌɶɸɢɫɚ Ɋɚɫɫɦɨɬɪɢɦ ɷɬɢ ɦɟɯɚɧɢɡɦɵ ɧɚ ɩɪɢɦɟɪɟɞɟɝɪɚɞɚɰɢɢ ɩɥɟɧɨɤ ɫɚɥɟɧɨɜɵɯ ɤɨɦɩɥɟɤɫɨɜ ɜ ɩɪɢɫɭɬɫɬɜɢɢ ɯɥɨɪɢɞɢɨɧɨɜ Ⱦɟɝɪɚɞɚɰɢɹ ɧɟɦɟɬɨɤɫɢɥɢɪɨɜɚɧɧɵɯ ɩɨɥɢɦɟɪɧɵɯ ɤɨɦɩɥɟɤɫɨɜɧɚɩɪɢɦɟɪSRO\>1L6DlHQ@ɩɪɨɬɟɤɚɟɬ ɜɞɜɚɷɬɚɩɚ (Ɋɢɫ10)ɇɚɩɟɪɜɨɦɷɬɚɩɟɩɪɨɢɫɯɨɞɢɬɨɤɢɫɥɟɧɢɟNi+2 ɞɨNi+3 ɢɤɨɨɪɞɢɧɚɰɢɹɯɥɨɪɢɞ-ɢɨɧɨɜɤɚɤɫɢɚɥɶɧɨɦɭɩɨɥɨɠɟɧɢɸɚɬɨɦɚ ɧɢɤɟɥɹȼɩɟɪɜɭɸɨɱɟɪɟɞɶɷɬɨɦɨɠɟɬɩɪɢɜɟɫɬɢ ɤ ɪɚɡɞɜɢɝɚɧɢɸ ɫɥɨɺɜ ɩɨɥɢɦɟɪɚ ɢ ɩɨɬɟɪɟ ɩɪɨɜɨɞɢɦɨɫɬɢ ɩɨɟɝɨ ɜɟɪɬɢɤɚɥɶɧɵɦ ɫɬɟɤɚɦ Ⱦɚɥɟɟ ɯɥɨɪɢɞ-ɢɨɧ ɦɨɠɟɬ ɨɤɢɫɥɹɬɶɫɹ ɧɚɧɢɤɟɥɟ ɫ ɨɛɪɚɡɨɜɚɧɢɟɦ ɪɚɞɢɤɚɥɚ ɯɥɨɪɚ ɤɨɬɨɪɵɣ ɫɩɨɫɨɛɟɧ ɚɬɚɤɨɜɚɬɶɨɪɝɚɧɢɱɟɫɤɭɸɱɚɫɬɶɥɢɝɚɧɞɚ15Ɋɢɫ 10 – Ɇɟɯɚɧɢɡɦ ɞɟɝɪɚɞɚɰɢɢ ɩɥɟɧɨɤ ɧɟɦɟɬɨɤɫɢɥɢɪɨɜɚɧɧɵɯ ɤɨɦɩɥɟɤɫɨɜɧɢɤɟɥɹɫɨɫɧɨɜɚɧɢɹɦɢɒɢɮɮɚȼ ɫɥɭɱɚɟ ɦɟɬɨɤɫɢɥɢɪɨɜɚɧɧɵɯ ɩɨɥɢɦɟɪɧɵɯ ɤɨɦɩɥɟɤɫɨɜ ɜɱɚɫɬɧɨɫɬɢ ɤɨɦɩɥɟɤɫɚ SRO\>1LɋH3OSalHQ@ ɩɨɬɟɪɹ ɷɥɟɤɬɪɨɚɤɬɢɜɧɨɫɬɢɩɪɢ ɞɨɛɚɜɥɟɧɢɢ ɯɥɨɪɢɞ-ɢɨɧɨɜ ɜ ɪɚɫɬɜɨɪ Ɏɗ ɜɟɪɨɹɬɧɨ ɩɪɨɬɟɤɚɟɬɩɪɟɢɦɭɳɟɫɬɜɟɧɧɨ ɩɨ ɢɧɨɦɭ ɦɟɯɚɧɢɡɦɭ Ɋɢɫ 1).
Ⱦɨɧɨɪɧɵɟɡɚɦɟɫɬɢɬɟɥɢ ɜ ɚɥɶɞɟɝɢɞɧɵɯ ɮɪɚɝɦɟɧɬɚɯ ɥɢɝɚɧɞɚ ɭɜɟɥɢɱɢɜɚɸɬɷɥɟɤɬɪɨɧɧɭɸ ɩɥɨɬɧɨɫɬɶ ɜ ɫɨɩɪɹɠɟɧɧɨɣ ʌ-ɫɢɫɬɟɦɟ ɢ ɨɤɢɫɥɟɧɧɚɹɮɨɪɦɚɫɚɥɟɧɨɜɨɝɨɥɢɝɚɧɞɚɩɪɟɞɫɬɚɜɥɹɟɬɫɨɛɨɣɚɤɬɢɜɧɵɣɢɧɬɟɪɦɟɞɢɚɬɫɩɨɫɨɛɧɵɣ ɪɟɚɝɢɪɨɜɚɬɶ ɫ ɯɥɨɪɢɞ-ɚɧɢɨɧɨɦ ɢɥɢ ɯɥɨɪɢɞ-ɪɚɞɢɤɚɥɨɦɩɪɢɫɭɬɫɬɜɭɸɳɢɦɢɜɪɚɫɬɜɨɪɟ. ɉɪɢɷɬɨɦɜɡɚɢɦɨɞɟɣɫɬɜɢɢɮɢɤɫɢɪɭɟɬɫɹɯɢɧɨɢɞɧɚɹ ɫɬɪɭɤɬɭɪɚ ɥɢɝɚɧɞɚ ɜ ɪɟɡɭɥɶɬɚɬɟ ɱɟɝɨ ɨɫɥɚɛɥɹɟɬɫɹ ɫɜɹɡɶɧɢɤɟɥɶ-ɤɢɫɥɨɪɨɞ ɢ ɩɪɨɢɫɯɨɞɢɬ ɜɵɦɵɜɚɧɢɟ ɧɢɤɟɥɹ ɢɡ ɩɥɟɧɤɢȾɨɩɨɥɧɢɬɟɥɶɧɨ ɜɨɡɦɨɠɧɨ ɩɚɪɚɥɥɟɥɶɧɨɟ ɩɪɨɬɟɤɚɧɢɟ ɩɪɨɰɟɫɫɚɞɟɝɪɚɞɚɰɢɢɩɨɦɟɯɚɧɢɡɦɭɯɚɪɚɤɬɟɪɧɨɦɭɩɥɟɧɨɤɞɥɹɧɟɦɟɬɨɤɫɢɥɢɪɨɜɚɧɧɵɯɤɨɦɩɥɟɤɫɨɜɈɛɷɬɨɦɤɨɫɜɟɧɧɨɫɜɢɞɟɬɟɥɶɫɬɜɭɟɬɡɧɚɱɢɬɟɥɶɧɨɟ ɭɜɟɥɢɱɟɧɢɟ ɫɤɨɪɨɫɬɢ ɞɟɝɪɚɞɚɰɢɢ ɩɨɥɢɦɟɪɧɨɝɨɤɨɦɩɥɟɤɫɚ SRO\>1LɋH3OSalHQ@ ɩɨ ɫɪɚɜɧɟɧɢɸ ɫ ɤɨɦɩɥɟɤɫɨɦpoly[Ni(Salen)].16Ɋɢɫ 11 – Ɇɟɯɚɧɢɡɦ ɞɟɝɪɚɞɚɰɢɢ ɩɥɟɧɨɤ ɦɟɬɨɤɫɢɥɢɪɨɜɚɧɧɵɯ ɤɨɦɩɥɟɤɫɨɜɧɢɤɟɥɹɫɨɫɧɨɜɚɧɢɹɦɢɒɢɮɮɚɈɫɧɨɜɧɵɟɪɟɡɭɥɶɬɚɬɵɪɚɛɨɬɵɢɜɵɜɨɞɵ1.
ȼɯɨɞɟɪɚɛɨɬɵɦɟɬɨɞɨɦɩɨɬɟɧɰɢɨɫɬɚɬɢɱɟɫɤɨɣɷɥɟɤɬɪɨɩɨɥɢɦɟɪɢɡɚɰɢɢ ɛɵɥɢ ɫɢɧɬɟɡɢɪɨɜɚɧɵ ɲɟɫɬɶ ɬɢɩɨɜɩɨɥɢɦɟɪɧɵɯ ɩɥɟɧɨɤ ɤɨɦɩɥɟɤɫɨɜ ɧɢɤɟɥɹ ɫ ɨɫɧɨɜɚɧɢɹɦɢɒɢɮɮɚ ɨɬɥɢɱɢɹ ɦɟɠɞɭ ɤɨɬɨɪɵɦɢ ɨɩɪɟɞɟɥɹɸɬɫɹ ɤɚɤɫɬɪɭɤɬɭɪɨɣ ɥɢɝɚɧɞɚ ɬɚɤ ɢ ɫɬɪɭɤɬɭɪɨɣ ɞɢɚɦɢɧɨɜɨɝɨ ɦɨɫɬɚɈɩɪɟɞɟɥɟɧɨ ɱɬɨ ɦɨɪɮɨɥɨɝɢɹ ɢɡɭɱɚɟɦɵɯ ɩɨɥɢɦɟɪɧɵɯ ɩɥɟɧɨɤɡɚɜɢɫɢɬ ɜ ɨɫɧɨɜɧɨɦ ɨɬ ɫɬɪɭɤɬɭɪɵ ɞɢɚɦɢɧɨɜɨɝɨ ɦɨɫɬɚ ɚ ɢɯɩɥɨɬɧɨɫɬɶ ɨɩɪɟɞɟɥɹɟɬɫɹ ɤɚɤ ɫɬɪɭɤɬɭɪɨɣ ɩɨɫɥɟɞɧɟɝɨ ɬɚɤ ɢɡɚɦɟɫɬɢɬɟɥɹɦɢɜɮɟɧɢɥɶɧɵɯɤɨɥɶɰɚɯɥɢɝɚɧɞɚ2. ɍɫɬɚɧɨɜɥɟɧɨ ɱɬɨ ɜɨɥɶɬɚɦɩɟɪɧɵɟ ɨɬɤɥɢɤɢ ɷɥɟɤɬɪɨɞɨɜɦɨɞɢɮɢɰɢɪɨɜɚɧɧɵɯ ɩɨɥɢɦɟɪɧɵɦɢ ɤɨɦɩɥɟɤɫɚɦɢ ɧɢɤɟɥɹ ɫɨɫɧɨɜɚɧɢɹɦɢ ɒɢɮɮɚ, ɨɛɥɚɞɚɸɬ ɪɹɞɨɦ ɬɚɤɢɯ ɨɫɨɛɟɧɧɨɫɬɟɣ,ɤɚɤ ɧɚɥɢɱɢɟ ɩɥɟɱ ɩɟɪɟɝɢɛɨɜ ɥɢɛɨ ɞɜɭɯ ɩɚɪ ɩɢɤɨɜ ɧɚ ɐȼȺɤɪɢɜɵɯ ɧɟɦɟɬɨɤɫɢɥɢɪɨɜɚɧɧɵɯ ɢ ɦɟɬɨɤɫɢɥɢɪɨɜɚɧɧɵɯɤɨɦɩɥɟɤɫɨɜɫɨɨɬɜɟɬɫɬɜɟɧɧɨ3. Ɋɚɡɪɚɛɨɬɚɧɚ ɤɨɧɤɪɟɬɧɚɹ ɩɪɨɰɟɞɭɪɚ ɨɩɪɟɞɟɥɟɧɢɹ ɬɨɥɳɢɧɵɩɨɥɢɦɟɪɧɵɯ ɤɨɦɩɥɟɤɫɨɜ ɧɢɤɟɥɹ ɫ ɨɫɧɨɜɚɧɢɹɦɢ ɒɢɮɮɚ ɢɡɞɚɧɧɵɯɗɄȽɆ4.
ɉɪɢ ɨɩɪɟɞɟɥɟɧɢɢ ɦɟɬɨɞɨɦ ɫɩɟɤɬɪɨɫɤɨɩɢɢ ɢɦɩɟɞɚɧɫɚɩɚɪɚɦɟɬɪɨɜ ɩɟɪɟɧɨɫɚ ɡɚɪɹɞɚ ɜ ɢɡɭɱɚɟɦɵɯ ɩɨɥɢɦɟɪɧɵɯɤɨɦɩɥɟɤɫɚɯ ɨɛɧɚɪɭɠɟɧ ɫɦɟɲɚɧɧɵɣ ɬɢɩ ɱɚɫɬɨɬɧɨɣɡɚɜɢɫɢɦɨɫɬɢɯɚɪɚɤɬɟɪɢɡɭɸɳɢɣɫɹɨɞɧɨɜɪɟɦɟɧɧɵɦɩɪɢɫɭɬɫɬɜɢɟɦȼɚɪɛɭɪɝɫɤɨɣɢɩɫɟɜɞɨɺɦɤɨɫɬɧɨɣɫɨɫɬɚɜɥɹɸɳɢɯɇɚɢɛɨɥɟɟ ɜɟɪɨɹɬɧɨɣ ɩɪɢɱɢɧɨɣ ɜɨɡɧɢɤɧɨɜɟɧɢɹ ɬɚɤɨɣɫɦɟɲɚɧɧɨɣ ɡɚɜɢɫɢɦɨɫɬɢ ɹɜɥɹɟɬɫɹ ɩɪɢɫɭɬɫɬɜɢɟ ɜ ɩɥɟɧɤɟ ɩɨɦɟɧɶɲɟɣ ɦɟɪɟ ɞɜɭɯ ɨɤɢɫɥɟɧɧɵɯ ɮɨɪɦ ɤɨɦɩɥɟɤɫɨɜ17ɩɪɢɧɢɦɚɸɳɢɯ ɭɱɚɫɬɢɟ ɧɚɪɹɞɭ ɫ ɩɪɨɬɢɜɨɢɨɧɚɦɢ ɜ ɩɟɪɟɧɨɫɟɡɚɪɹɞɚɜɨɛɴɟɦɟɩɥɟɧɨɤ5.
ɋɨɜɦɟɫɬɧɨɟɢɫɩɨɥɶɡɨɜɚɧɢɟɦɟɬɨɞɨɜɗɄȽɆɢɜɨɥɶɬɚɛɫɨɪɛɬɨɦɟɬɪɢɢ ɩɨɡɜɨɥɢɥɨ ɭɫɬɚɧɨɜɢɬɶ ɱɬɨ ɨɤɢɫɥɟɧɢɟɩɨɥɢɦɟɪɧɵɯ ɤɨɦɩɥɟɤɫɨɜ ɧɢɤɟɥɹ ɫ ɨɫɧɨɜɚɧɢɹɦɢ ɒɢɮɮɚɞɟɣɫɬɜɢɬɟɥɶɧɨ ɩɪɨɬɟɤɚɟɬ ɜ ɞɜɟ ɫɬɚɞɢɢ ɫ ɨɛɪɚɡɨɜɚɧɢɟɦ ɞɜɭɯɨɤɫɢɥɟɧɧɵɯ ɮɨɪɦ ɜɢɞɢɦɨ ɩɨ-ɪɚɡɧɨɦɭ ɜɡɚɢɦɨɞɟɣɫɬɜɭɸɳɢɯ ɫɪɚɫɬɜɨɪɢɬɟɥɟɦ ɍɫɬɚɧɨɜɥɟɧɧɨɟ ɧɚɥɢɱɢɟ ɞɜɭɯ ɨɤɢɫɥɟɧɧɵɯɮɨɪɦ ɜ ɩɥɟɧɤɚɯ ɩɪɢɜɟɥɨ ɤ ɪɚɡɜɢɬɢɸ ɫɨɨɬɜɟɬɫɬɜɭɸɳɢɯɬɟɨɪɟɬɢɱɟɫɤɢɯɩɪɟɞɫɬɚɜɥɟɧɢɣ6. Ɇɟɬɨɞɚɦɢ ɐȼȺ ɗɄȽɆ ɢ ɆȺɅȾɂ ɩɨɤɚɡɚɧɨ ɱɬɨ ɩɪɢɞɨɛɚɜɥɟɧɢɢɜɮɨɧɨɜɵɣɷɥɟɤɬɪɨɥɢɬɞɚɠɟɧɟɛɨɥɶɲɢɯɤɨɥɢɱɟɫɬɜɨɫɧɨɜɚɧɢɣ Ʌɶɸɢɫɚ ɜɨɞɵ ɢɥɢ ɝɚɥɨɝɟɧɢɞ-ɢɨɧɨɜ ɩɪɨɢɫɯɨɞɢɬɩɨɫɬɟɩɟɧɧɚɹɩɨɬɟɪɹɷɥɟɤɬɪɨɚɤɬɢɜɧɨɫɬɢɩɨɥɢɦɟɪɧɵɯɤɨɦɩɥɟɤɫɨɜ ɫɚɥɟɧɨɜɨɝɨ ɬɢɩɚ ɫɤɨɪɨɫɬɶ ɤɨɬɨɪɨɣ ɨɩɪɟɞɟɥɹɟɬɫɹɫɬɪɭɤɬɭɪɨɣ ɥɢɝɚɧɞɚ ɉɨɤɚɡɚɧɨ ɬɚɤɠɟ ɱɬɨ ɯɚɪɚɤɬɟɪ ɢɡɦɟɧɟɧɢɹɜɨɥɶɬɚɦɩɟɪɧɨɝɨɨɬɤɥɢɤɚɜɟɥɢɱɢɧɚɬɨɤɚɩɢɤɚɢɮɨɪɦɚɤɪɢɜɨɣɩɨɥɢɦɟɪɧɵɯ ɤɨɦɩɥɟɤɫɨɜ ɧɢɤɟɥɹ ɫ ɨɫɧɨɜɚɧɢɹɦɢ ɒɢɮɮɚ ɩɪɢɞɨɛɚɜɥɟɧɢɢ ɪɚɡɥɢɱɧɵɯ ɨɫɧɨɜɚɧɢɣ Ʌɶɸɢɫɚ ɝɚɥɨɝɟɧɢɞ-ɢɨɧɨɜɜɨɞɵɜɪɚɫɬɜɨɪɎɗ ɡɚɜɢɫɢɬ ɨɬ ɫɬɪɭɤɬɭɪɵ ɨɫɧɨɜɚɧɢɹ Ʌɶɸɢɫɚɗɬɨ ɫɜɢɞɟɬɟɥɶɫɬɜɭɟɬ ɨ ɜɨɡɦɨɠɧɨɫɬɢ ɩɪɚɤɬɢɱɟɫɤɨɝɨɢɫɩɨɥɶɡɨɜɚɧɢɹ ɩɨɥɢɦɟɪɧɵɯ ɩɥɟɧɨɤ ɤɨɦɩɥɟɤɫɨɜ ɫɚɥɟɧɨɜɨɝɨɬɢɩɚɜɤɚɱɟɫɬɜɟɫɟɧɫɨɪɨɜɧɚɪɚɡɥɢɱɧɵɟɨɫɧɨɜɚɧɢɹɅɶɸɢɫɚɈɫɧɨɜɧɨɟ ɫɨɞɟɪɠɚɧɢɟ ɞɢɫɫɟɪɬɚɰɢɢ ɨɩɭɛɥɢɤɨɜɚɧɨ ɜ ɫɥɟɞɭɸɳɢɯɪɚɛɨɬɚɯ:1.
Levin O. V. Charge transfer processes on electrodes modified bypolymer films of metal complexes with Schiff bases / O. V. Levin,M. P. Karushev, A. M. Timonov, E. V. Alekseeva, S. Zhang, V. V.Malev // Electrochimica Acta. - 2013. - V. 109. - P. 153-161.2. Sizov V. V. Redox transformations in electroactive polymer filmsderived from complexes of nickel with SalEn-type ligands:computational, EQCM, and spectroelectrochemical study / V. V.Sizov, M. V. Novozhilova, E. V. Alekseeva, M.
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