Фазовые равновесия в системах Pd-Cu-Sn и Pd-Au-Sn - экспериментальное исследование и термодинамический расчет (1105451), страница 28
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36.170VII. ПРИЛОЖЕНИЕТаблица П-1. Параметры моделей фаз системы Pd–Cu–Sn, подобранные в настоящейработеL: модель (Cu,Pd,Pd2Sn,Sn)= –14000,α: модель (Cu,Pd,Sn),,= –167300 + 100·T,,= –1027410 + 333·T,,= +800000β-CuPd/ γ-Cu3Sn: модель (Cu,Pd,Sn)0,25(Cu,Pd,Sn)0,25(Cu,Pd,Sn)0,25(Cu,Pd,Sn)0,25uPdSn = +4742,6vPdSn = +2425,4:= –180800 + 27·T:= –180800 + 27·T,:= –75440 + 117·T,:= –350000,:= –452800 + 133·Tξ-Cu10Sn3: модель (Cu,Pd)0,769(Sn)0,231:= 0,769·GHSERCU7 + 0,231·GHSERSN – 6382 – 2,048·T:= 0,769·GHSERPD + 0,231·GHSERSN – 38200 + 30·T,:= –65000 + 10*Tε-Cu3Sn: модель (Cu,Pd)0,75(Sn)0,25:= 0,75·GHSERCU + 0,25·GHSERSN – 8113 – 0,533·T:= 0,75·GHSERPD + 0,25·GHSERSN – 57730 + 30·T,7:= –33500Для меди и палладия за стандартное состояние принята их ГЦК-модификация (А1), для олова – ГЦТ-модификация (А5).171Pd3Sn: модель (Cu4,Pd3Sn)= 4·GHSERCU + 500= 3·GHSERPD + GHSERSN – 235906 + 38,5912·TPd2Sn: модель (Cu3,Pd2Sn)= 3·GHSERCU + 10000= 2·GHSERPD + GHSERSN – 192664,5 + 33,8517·Tγ-Pd2-xSn: модель (Cu,Pd)(Sn)(Cu,Pd,Va)::= GHSERCU + GHSERPD + GHSERSN – 100000::= GHSERCU + GHSERPD + GHSERSN – 90000,::= –30000,::= –10000::,= –117300 + 100·T::,= –10000τ1: модель (Cu5,Pd4Sn)= 5·GHSERCU + 6000= 4·GHSERPD + GHSERSN – 247850 + 38,5912·T,= –70000,= +270000τ2: модель (Cu,Pd)0,75(Sn)0,25:= 0,75·GHSERCU + 0,25·GHSERSN + 1500 – 2·T:= 0,75·GHSERPD + 0,25·GHSERSN – 58000 + 10·T,:= –26500,:= +9000172Таблица П-2.
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