Дизайн и синтез металлоценов 4 группы - эффективных прекатализаторов гомо - и сополимеризации алкенов (1098265), страница 90
Текст из файла (страница 90)
Величины длин связей (d, Å) и валентных углов (ω) в молекулеSiZrCl23.502.22.СвязьZr(1)-Cl(11)Zr(1)-Cl(12)Zr(1)-C(11)Zr(1)-C(31)Zr(1)-C(32)Zr(1)-C(12)Zr(1)-C(22)Zr(1)-C(33)Zr(1)-C(42)Zr(1)-C(13)Zr(1)-C(14)Zr(1)-C(34)Zr(2)-Cl(21)Zr(2)-Cl(22)Zr(2)-C(51)Zr(2)-C(71)Zr(2)-C(72)Zr(2)-C(52)Zr(2)-C(62)Zr(2)-C(73)Zr(2)-C(82)Zr(2)-C(53)Zr(2)-C(54)Zr(2)-C(74)Si(1)-C(30)Si(1)-C(50)Si(1)-C(11)Si(1)-C(31)Si(2)-C(70)Si(2)-C(90)Si(2)-C(51)Si(2)-C(71)C(11)-C(12)C(11)-C(22)C(12)-C(13)C(12)-C(29)C(13)-C(14)C(13)-H(13)C(14)-C(15)C(14)-C(22)C(15)-C(16)d [А]2.4205(7)2.4213(7)2.448(3)2.475(2)2.506(2)2.509(2)2.525(3)2.562(2)2.563(2)2.600(2)2.632(2)2.633(2)2.4199(7)2.4287(7)2.449(3)2.483(2)2.497(2)2.516(3)2.516(2)2.551(2)2.563(2)2.590(2)2.617(2)2.630(2)1.861(3)1.867(3)1.878(2)1.881(3)1.856(3)1.865(3)1.872(3)1.886(3)1.443(4)1.460(3)1.398(3)1.511(3)1.416(3)0.95001.436(3)1.447(3)1.368(4)УголCl(11)-Zr(1)-Cl(12)Cl(11)-Zr(1)-C(11)Cl(12)-Zr(1)-C(11)Cl(11)-Zr(1)-C(31)Cl(12)-Zr(1)-C(31)C(11)-Zr(1)-C(31)Cl(11)-Zr(1)-C(32)Cl(12)-Zr(1)-C(32)C(11)-Zr(1)-C(32)C(31)-Zr(1)-C(32)Cl(11)-Zr(1)-C(12)Cl(12)-Zr(1)-C(12)C(11)-Zr(1)-C(12)C(31)-Zr(1)-C(12)C(32)-Zr(1)-C(12)Cl(11)-Zr(1)-C(22)Cl(12)-Zr(1)-C(22)C(11)-Zr(1)-C(22)C(31)-Zr(1)-C(22)C(32)-Zr(1)-C(22)C(12)-Zr(1)-C(22)Cl(11)-Zr(1)-C(33)Cl(12)-Zr(1)-C(33)C(11)-Zr(1)-C(33)C(31)-Zr(1)-C(33)C(32)-Zr(1)-C(33)C(12)-Zr(1)-C(33)C(22)-Zr(1)-C(33)Cl(11)-Zr(1)-C(42)Cl(12)-Zr(1)-C(42)C(11)-Zr(1)-C(42)C(31)-Zr(1)-C(42)C(32)-Zr(1)-C(42)C(12)-Zr(1)-C(42)C(22)-Zr(1)-C(42)C(33)-Zr(1)-C(42)Cl(11)-Zr(1)-C(13)Cl(12)-Zr(1)-C(13)C(11)-Zr(1)-C(13)C(31)-Zr(1)-C(13)C(32)-Zr(1)-C(13)ω [град]100.06(2)121.49(6)122.26(6)122.57(6)121.52(6)69.03(8)132.49(6)88.25(6)90.44(8)33.71(8)88.01(6)132.80(6)33.81(8)90.06(8)119.75(8)131.65(6)88.57(6)34.10(8)90.12(8)94.91(8)54.52(8)103.58(6)79.24(6)121.22(8)54.88(8)31.92(8)144.04(8)124.74(8)89.43(6)132.30(6)89.37(8)33.48(8)53.89(8)93.81(8)119.06(8)53.17(8)78.65(6)104.23(6)54.67(8)120.71(8)144.51(8)422приложениеC(15)-C(23)C(16)-C(20)C(16)-C(17)C(17)-C(18)C(17)-H(17A)C(17)-H(17B)C(18)-C(19)C(18)-H(18A)C(18)-H(18B)C(19)-C(20)C(19)-H(19A)C(19)-H(19B)C(20)-C(21)C(21)-C(22)C(21)-H(21)C(23)-C(24)C(23)-C(28)C(24)-C(25)C(24)-H(24)C(25)-C(26)C(25)-H(25)C(26)-C(27)C(26)-H(26)C(27)-C(28)C(27)-H(27)C(28)-H(28)C(29)-H(29A)C(29)-H(29B)C(29)-H(29C)C(30)-H(30A)C(30)-H(30B)C(30)-H(30C)C(31)-C(32)C(31)-C(42)C(32)-C(33)C(32)-C(49)C(33)-C(34)C(33)-H(33)C(34)-C(35)C(34)-C(42)C(35)-C(36)C(35)-C(43)C(36)-C(40)C(36)-C(37)C(37)-C(38B)C(37)-C(38A)C(37)-H(37C)C(37)-H(37D)C(37)-H(37A)C(37)-H(37B)C(38A)-C(39)C(38A)-H(38A)C(38A)-H(38B)C(38B)-C(39)C(38B)-H(38C)C(38B)-H(38D)C(39)-C(40)1.490(3)1.437(4)1.513(3)1.541(4)0.99000.99001.538(4)0.99000.99001.508(4)0.99000.99001.357(4)1.419(3)0.95001.385(4)1.392(3)1.387(4)0.95001.379(4)0.95001.375(4)0.95001.388(4)0.95000.95000.98000.98000.98000.98000.98000.98001.444(3)1.453(3)1.395(4)1.510(3)1.418(3)0.95001.425(3)1.443(3)1.362(4)1.493(4)1.433(4)1.509(4)1.456(8)1.539(7)0.99000.99000.95980.96011.495(7)0.99000.99001.552(9)0.99000.99001.515(4)C(12)-Zr(1)-C(13)C(22)-Zr(1)-C(13)C(33)-Zr(1)-C(13)C(42)-Zr(1)-C(13)Cl(11)-Zr(1)-C(14)Cl(12)-Zr(1)-C(14)C(11)-Zr(1)-C(14)C(31)-Zr(1)-C(14)C(32)-Zr(1)-C(14)C(12)-Zr(1)-C(14)C(22)-Zr(1)-C(14)C(33)-Zr(1)-C(14)C(42)-Zr(1)-C(14)C(13)-Zr(1)-C(14)Cl(11)-Zr(1)-C(34)Cl(12)-Zr(1)-C(34)C(11)-Zr(1)-C(34)C(31)-Zr(1)-C(34)C(32)-Zr(1)-C(34)C(12)-Zr(1)-C(34)C(22)-Zr(1)-C(34)C(33)-Zr(1)-C(34)C(42)-Zr(1)-C(34)C(13)-Zr(1)-C(34)C(14)-Zr(1)-C(34)Cl(21)-Zr(2)-Cl(22)Cl(21)-Zr(2)-C(51)Cl(22)-Zr(2)-C(51)Cl(21)-Zr(2)-C(71)Cl(22)-Zr(2)-C(71)C(51)-Zr(2)-C(71)Cl(21)-Zr(2)-C(72)Cl(22)-Zr(2)-C(72)C(51)-Zr(2)-C(72)C(71)-Zr(2)-C(72)Cl(21)-Zr(2)-C(52)Cl(22)-Zr(2)-C(52)C(51)-Zr(2)-C(52)C(71)-Zr(2)-C(52)C(72)-Zr(2)-C(52)Cl(21)-Zr(2)-C(62)Cl(22)-Zr(2)-C(62)C(51)-Zr(2)-C(62)C(71)-Zr(2)-C(62)C(72)-Zr(2)-C(62)C(52)-Zr(2)-C(62)Cl(21)-Zr(2)-C(73)Cl(22)-Zr(2)-C(73)C(51)-Zr(2)-C(73)C(71)-Zr(2)-C(73)C(72)-Zr(2)-C(73)C(52)-Zr(2)-C(73)C(62)-Zr(2)-C(73)Cl(21)-Zr(2)-C(82)Cl(22)-Zr(2)-C(82)C(51)-Zr(2)-C(82)C(71)-Zr(2)-C(82)31.70(7)53.25(8)175.59(8)123.46(8)102.09(6)79.80(6)55.28(8)121.47(8)125.41(8)53.13(8)32.52(7)149.21(8)143.80(8)31.41(7)79.66(6)103.57(6)120.69(8)54.90(8)53.04(8)123.60(8)144.42(8)31.64(7)32.21(8)147.18(8)175.95(8)98.02(3)122.70(6)122.70(6)124.23(6)121.58(6)68.64(8)132.39(6)88.60(6)90.51(9)33.50(8)89.15(6)134.13(6)33.68(8)88.93(8)119.00(9)130.92(6)89.27(6)33.97(8)90.25(8)96.05(8)54.43(8)102.54(6)79.93(6)121.39(8)54.97(8)32.25(8)142.53(8)126.49(8)90.96(6)133.07(6)88.29(8)33.44(8)423приложениеC(39)-H(39C)C(39)-H(39D)C(39)-H(39A)C(39)-H(39B)C(40)-C(41)C(41)-C(42)C(41)-H(41)C(43)-C(48)C(43)-C(44)C(44)-C(45)C(44)-H(44)C(45)-C(46)C(45)-H(45)C(46)-C(47)C(46)-H(46)C(47)-C(48)C(47)-H(47)C(48)-H(48)C(49)-H(49A)C(49)-H(49B)C(49)-H(49C)C(50)-H(50A)C(50)-H(50B)C(50)-H(50C)C(51)-C(52)C(51)-C(62)C(52)-C(53)C(52)-C(69)C(53)-C(54)C(53)-H(53)C(54)-C(55)C(54)-C(62)C(55)-C(56)C(55)-C(63)C(56)-C(60)C(56)-C(57)C(57)-C(58)C(57)-H(57A)C(57)-H(57B)C(58)-C(59)C(58)-H(58A)C(58)-H(58B)C(59)-C(60)C(59)-H(59A)C(59)-H(59B)C(60)-C(61)C(61)-C(62)C(61)-H(61)C(63)-C(68)C(63)-C(64)C(64)-C(65)C(64)-H(64)C(65)-C(66)C(65)-H(65)C(66)-C(67)C(66)-H(66)C(67)-C(68)0.99000.99000.96020.96001.365(4)1.433(3)0.95001.377(4)1.393(4)1.381(4)0.95001.382(5)0.95001.377(4)0.95001.392(4)0.95000.95000.98000.98000.98000.98000.98000.98001.440(4)1.452(3)1.399(3)1.507(3)1.415(3)0.95001.432(3)1.443(3)1.374(4)1.488(3)1.442(4)1.516(3)1.537(4)0.99000.99001.526(4)0.99000.99001.509(4)0.99000.99001.347(3)1.419(3)0.95001.390(4)1.397(4)1.385(4)0.95001.374(4)0.95001.381(4)0.95001.387(4)C(72)-Zr(2)-C(82)C(52)-Zr(2)-C(82)C(62)-Zr(2)-C(82)C(73)-Zr(2)-C(82)Cl(21)-Zr(2)-C(53)Cl(22)-Zr(2)-C(53)C(51)-Zr(2)-C(53)C(71)-Zr(2)-C(53)C(72)-Zr(2)-C(53)C(52)-Zr(2)-C(53)C(62)-Zr(2)-C(53)C(73)-Zr(2)-C(53)C(82)-Zr(2)-C(53)Cl(21)-Zr(2)-C(54)Cl(22)-Zr(2)-C(54)C(51)-Zr(2)-C(54)C(71)-Zr(2)-C(54)C(72)-Zr(2)-C(54)C(52)-Zr(2)-C(54)C(62)-Zr(2)-C(54)C(73)-Zr(2)-C(54)C(82)-Zr(2)-C(54)C(53)-Zr(2)-C(54)Cl(21)-Zr(2)-C(74)Cl(22)-Zr(2)-C(74)C(51)-Zr(2)-C(74)C(71)-Zr(2)-C(74)C(72)-Zr(2)-C(74)C(52)-Zr(2)-C(74)C(62)-Zr(2)-C(74)C(73)-Zr(2)-C(74)C(82)-Zr(2)-C(74)C(53)-Zr(2)-C(74)C(54)-Zr(2)-C(74)C(30)-Si(1)-C(50)C(30)-Si(1)-C(11)C(50)-Si(1)-C(11)C(30)-Si(1)-C(31)C(50)-Si(1)-C(31)C(11)-Si(1)-C(31)C(70)-Si(2)-C(90)C(70)-Si(2)-C(51)C(90)-Si(2)-C(51)C(70)-Si(2)-C(71)C(90)-Si(2)-C(71)C(51)-Si(2)-C(71)C(12)-C(11)-C(22)C(12)-C(11)-Si(1)C(22)-C(11)-Si(1)C(12)-C(11)-Zr(1)C(22)-C(11)-Zr(1)Si(1)-C(11)-Zr(1)C(13)-C(12)-C(11)C(13)-C(12)-C(29)C(11)-C(12)-C(29)C(13)-C(12)-Zr(1)C(11)-C(12)-Zr(1)53.81(8)91.70(8)118.46(8)53.19(8)78.18(6)105.73(6)54.62(8)119.81(8)144.84(9)31.75(7)53.31(8)174.20(8)121.19(8)100.70(6)80.97(6)55.24(8)121.44(8)126.87(8)53.23(8)32.57(7)151.65(8)142.30(8)31.54(8)79.59(6)104.69(6)119.77(8)54.95(8)53.33(8)121.14(8)144.94(8)31.81(8)32.15(8)144.34(8)174.27(8)105.94(14)112.62(12)113.08(12)115.31(13)114.19(12)95.82(11)105.45(14)113.29(12)112.41(13)114.91(13)115.44(13)95.50(11)105.2(2)126.38(19)125.05(19)75.42(14)75.82(15)98.07(10)109.7(2)122.7(2)127.6(2)77.75(15)70.77(14)424приложениеC(67)-H(67)C(68)-H(68)C(69)-H(69A)C(69)-H(69B)C(69)-H(69C)C(70)-H(70A)C(70)-H(70B)C(70)-H(70C)C(71)-C(72)C(71)-C(82)C(72)-C(73)C(72)-C(89)C(73)-C(74)C(73)-H(73)C(74)-C(75)C(74)-C(82)C(75)-C(76)C(75)-C(83)C(76)-C(80)C(76)-C(77)C(77)-C(78)C(77)-H(77A)C(77)-H(77B)C(78)-C(79)C(78)-H(78A)C(78)-H(78B)C(79)-C(80)C(79)-H(79A)C(79)-H(79B)C(80)-C(81)C(81)-C(82)C(81)-H(81)C(83)-C(84)C(83)-C(88)C(84)-C(85)C(84)-H(84)C(85)-C(86)C(85)-H(85)C(86)-C(87)C(86)-H(86)C(87)-C(88)C(87)-H(87)C(88)-H(88)C(89)-H(89A)C(89)-H(89B)C(89)-H(89C)C(90)-H(90A)C(90)-H(90B)C(90)-H(90C)УголC(24)-C(23)-C(28)C(24)-C(23)-C(15)C(28)-C(23)-C(15)C(23)-C(24)-C(25)C(23)-C(24)-H(24)0.95000.95000.98000.98000.98000.98000.98000.98001.436(4)1.454(4)1.403(4)1.519(4)1.422(3)0.95001.429(4)1.439(3)1.376(4)1.492(4)1.428(4)1.511(4)1.534(4)0.99000.99001.520(4)0.99000.99001.511(4)0.99000.99001.362(4)1.427(3)0.95001.384(4)1.394(4)1.391(4)0.95001.365(5)0.95001.382(5)0.95001.377(4)0.95000.95000.98000.98000.98000.98000.98000.9800ω [град]118.0(2)121.9(2)120.1(2)121.1(3)119.5C(29)-C(12)-Zr(1)C(12)-C(13)-C(14)C(12)-C(13)-Zr(1)C(14)-C(13)-Zr(1)C(12)-C(13)-H(13)C(14)-C(13)-H(13)Zr(1)-C(13)-H(13)C(13)-C(14)-C(15)C(13)-C(14)-C(22)C(15)-C(14)-C(22)C(13)-C(14)-Zr(1)C(15)-C(14)-Zr(1)C(22)-C(14)-Zr(1)C(16)-C(15)-C(14)C(16)-C(15)-C(23)C(14)-C(15)-C(23)C(15)-C(16)-C(20)C(15)-C(16)-C(17)C(20)-C(16)-C(17)C(16)-C(17)-C(18)C(16)-C(17)-H(17A)C(18)-C(17)-H(17A)C(16)-C(17)-H(17B)C(18)-C(17)-H(17B)H(17A)-C(17)-H(17B)C(19)-C(18)-C(17)C(19)-C(18)-H(18A)C(17)-C(18)-H(18A)C(19)-C(18)-H(18B)C(17)-C(18)-H(18B)H(18A)-C(18)-H(18B)C(20)-C(19)-C(18)C(20)-C(19)-H(19A)C(18)-C(19)-H(19A)C(20)-C(19)-H(19B)C(18)-C(19)-H(19B)H(19A)-C(19)-H(19B)C(21)-C(20)-C(16)C(21)-C(20)-C(19)C(16)-C(20)-C(19)C(20)-C(21)-C(22)C(20)-C(21)-H(21)C(22)-C(21)-H(21)C(21)-C(22)-C(14)C(21)-C(22)-C(11)C(14)-C(22)-C(11)C(21)-C(22)-Zr(1)C(14)-C(22)-Zr(1)C(11)-C(22)-Zr(1)УголC(55)-C(54)-C(62)C(53)-C(54)-Zr(2)C(55)-C(54)-Zr(2)C(62)-C(54)-Zr(2)C(56)-C(55)-C(54)119.09(16)109.7(2)70.56(14)75.51(14)125.1125.1120.4132.0(2)106.7(2)121.3(2)73.09(14)122.92(17)69.67(14)116.9(2)122.7(2)120.5(2)121.7(2)128.9(2)109.4(2)103.0(2)111.2111.2111.2111.2109.1103.7(2)111.0111.0111.0111.0109.0103.1(2)111.1111.1111.1111.1109.1122.5(2)128.8(2)108.7(2)118.5(2)120.7120.7119.1(2)132.2(2)108.7(2)119.04(18)77.81(14)70.09(14)ω [град]121.9(2)73.18(14)123.36(18)69.87(14)116.4(2)425приложениеC(25)-C(24)-H(24)C(26)-C(25)-C(24)C(26)-C(25)-H(25)C(24)-C(25)-H(25)C(27)-C(26)-C(25)C(27)-C(26)-H(26)C(25)-C(26)-H(26)C(26)-C(27)-C(28)C(26)-C(27)-H(27)C(28)-C(27)-H(27)C(27)-C(28)-C(23)C(27)-C(28)-H(28)C(23)-C(28)-H(28)C(12)-C(29)-H(29A)C(12)-C(29)-H(29B)H(29A)-C(29)-H(29B)C(12)-C(29)-H(29C)H(29A)-C(29)-H(29C)H(29B)-C(29)-H(29C)Si(1)-C(30)-H(30A)Si(1)-C(30)-H(30B)H(30A)-C(30)-H(30B)Si(1)-C(30)-H(30C)H(30A)-C(30)-H(30C)H(30B)-C(30)-H(30C)C(32)-C(31)-C(42)C(32)-C(31)-Si(1)C(42)-C(31)-Si(1)C(32)-C(31)-Zr(1)C(42)-C(31)-Zr(1)Si(1)-C(31)-Zr(1)C(33)-C(32)-C(31)C(33)-C(32)-C(49)C(31)-C(32)-C(49)C(33)-C(32)-Zr(1)C(31)-C(32)-Zr(1)C(49)-C(32)-Zr(1)C(32)-C(33)-C(34)C(32)-C(33)-Zr(1)C(34)-C(33)-Zr(1)C(32)-C(33)-H(33)C(34)-C(33)-H(33)Zr(1)-C(33)-H(33)C(33)-C(34)-C(35)C(33)-C(34)-C(42)C(35)-C(34)-C(42)C(33)-C(34)-Zr(1)C(35)-C(34)-Zr(1)C(42)-C(34)-Zr(1)C(36)-C(35)-C(34)C(36)-C(35)-C(43)C(34)-C(35)-C(43)C(35)-C(36)-C(40)C(35)-C(36)-C(37)C(40)-C(36)-C(37)C(38B)-C(37)-C(36)C(36)-C(37)-C(38A)119.5120.3(3)119.8119.8119.3(3)120.4120.4120.5(3)119.7119.7120.8(3)119.6119.6109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5104.9(2)126.09(19)125.08(18)74.32(13)76.58(13)97.08(10)109.8(2)122.3(2)127.9(2)76.27(14)71.97(13)120.43(16)109.5(2)71.81(14)76.94(14)125.2125.2117.8131.4(2)106.6(2)122.0(2)71.42(13)122.24(16)71.20(13)117.0(2)121.9(2)121.1(2)122.0(2)128.7(3)109.2(2)104.8(4)103.2(3)C(56)-C(55)-C(63)C(54)-C(55)-C(63)C(55)-C(56)-C(60)C(55)-C(56)-C(57)C(60)-C(56)-C(57)C(56)-C(57)-C(58)C(56)-C(57)-H(57A)C(58)-C(57)-H(57A)C(56)-C(57)-H(57B)C(58)-C(57)-H(57B)H(57A)-C(57)-H(57B)C(59)-C(58)-C(57)C(59)-C(58)-H(58A)C(57)-C(58)-H(58A)C(59)-C(58)-H(58B)C(57)-C(58)-H(58B)H(58A)-C(58)-H(58B)C(60)-C(59)-C(58)C(60)-C(59)-H(59A)C(58)-C(59)-H(59A)C(60)-C(59)-H(59B)C(58)-C(59)-H(59B)H(59A)-C(59)-H(59B)C(61)-C(60)-C(56)C(61)-C(60)-C(59)C(56)-C(60)-C(59)C(60)-C(61)-C(62)C(60)-C(61)-H(61)C(62)-C(61)-H(61)C(61)-C(62)-C(54)C(61)-C(62)-C(51)C(54)-C(62)-C(51)C(61)-C(62)-Zr(2)C(54)-C(62)-Zr(2)C(51)-C(62)-Zr(2)C(68)-C(63)-C(64)C(68)-C(63)-C(55)C(64)-C(63)-C(55)C(65)-C(64)-C(63)C(65)-C(64)-H(64)C(63)-C(64)-H(64)C(66)-C(65)-C(64)C(66)-C(65)-H(65)C(64)-C(65)-H(65)C(65)-C(66)-C(67)C(65)-C(66)-H(66)C(67)-C(66)-H(66)C(66)-C(67)-C(68)C(66)-C(67)-H(67)C(68)-C(67)-H(67)C(67)-C(68)-C(63)C(67)-C(68)-H(68)C(63)-C(68)-H(68)C(52)-C(69)-H(69A)C(52)-C(69)-H(69B)H(69A)-C(69)-H(69B)C(52)-C(69)-H(69C)123.2(2)120.3(2)121.8(2)128.9(2)109.3(2)102.8(2)111.2111.2111.2111.2109.1104.5(2)110.9110.9110.9110.9108.9103.3(2)111.1111.1111.1111.1109.1122.0(2)129.6(2)108.4(2)119.2(2)120.4120.4118.7(2)132.5(2)108.8(2)120.44(17)77.57(14)70.48(14)118.1(2)120.0(2)121.9(2)120.5(3)119.8119.8120.9(3)119.6119.6119.4(3)120.3120.3120.3(3)119.9119.9121.0(3)119.5119.5109.5109.5109.5109.5426приложениеC(38B)-C(37)-H(37C)C(36)-C(37)-H(37C)C(38A)-C(37)-H(37C)C(38B)-C(37)-H(37D)C(36)-C(37)-H(37D)C(38A)-C(37)-H(37D)H(37C)-C(37)-H(37D)C(36)-C(37)-H(37A)C(38A)-C(37)-H(37A)C(36)-C(37)-H(37B)C(38A)-C(37)-H(37B)H(37A)-C(37)-H(37B)C(39)-C(38A)-C(37)C(39)-C(38A)-H(38A)C(37)-C(38A)-H(38A)C(39)-C(38A)-H(38B)C(37)-C(38A)-H(38B)H(38A)-C(38A)-H(38B)C(37)-C(38B)-C(39)C(37)-C(38B)-H(38C)C(39)-C(38B)-H(38C)C(37)-C(38B)-H(38D)C(39)-C(38B)-H(38D)H(38C)-C(38B)-H(38D)C(38A)-C(39)-C(40)C(40)-C(39)-C(38B)C(40)-C(39)-H(39C)C(38B)-C(39)-H(39C)C(40)-C(39)-H(39D)C(38B)-C(39)-H(39D)H(39C)-C(39)-H(39D)C(38A)-C(39)-H(39A)C(40)-C(39)-H(39A)C(38A)-C(39)-H(39B)C(40)-C(39)-H(39B)H(39A)-C(39)-H(39B)C(41)-C(40)-C(36)C(41)-C(40)-C(39)C(36)-C(40)-C(39)C(40)-C(41)-C(42)C(40)-C(41)-H(41)C(42)-C(41)-H(41)C(41)-C(42)-C(34)C(41)-C(42)-C(31)C(34)-C(42)-C(31)C(41)-C(42)-Zr(1)C(34)-C(42)-Zr(1)C(31)-C(42)-Zr(1)C(48)-C(43)-C(44)C(48)-C(43)-C(35)C(44)-C(43)-C(35)C(45)-C(44)-C(43)C(45)-C(44)-H(44)C(43)-C(44)-H(44)C(44)-C(45)-C(46)C(44)-C(45)-H(45)C(46)-C(45)-H(45)110.8110.880.6110.8110.8137.6108.9111.2110.8110.9111.5109.1105.7(4)110.6110.6110.6110.6108.7107.1(5)110.3110.3110.3110.3108.6104.3(3)102.2(4)111.3111.3111.3111.3109.2110.4110.8111.4110.9109.0122.2(2)129.0(3)108.8(2)118.3(2)120.9120.9118.5(2)132.4(2)109.1(2)120.89(16)76.59(13)69.94(13)118.0(3)122.2(2)119.8(2)121.4(3)119.3119.3119.7(3)120.2120.2H(69A)-C(69)-H(69C)H(69B)-C(69)-H(69C)Si(2)-C(70)-H(70A)Si(2)-C(70)-H(70B)H(70A)-C(70)-H(70B)Si(2)-C(70)-H(70C)H(70A)-C(70)-H(70C)H(70B)-C(70)-H(70C)C(72)-C(71)-C(82)C(72)-C(71)-Si(2)C(82)-C(71)-Si(2)C(72)-C(71)-Zr(2)C(82)-C(71)-Zr(2)Si(2)-C(71)-Zr(2)C(73)-C(72)-C(71)C(73)-C(72)-C(89)C(71)-C(72)-C(89)C(73)-C(72)-Zr(2)C(71)-C(72)-Zr(2)C(89)-C(72)-Zr(2)C(72)-C(73)-C(74)C(72)-C(73)-Zr(2)C(74)-C(73)-Zr(2)C(72)-C(73)-H(73)C(74)-C(73)-H(73)Zr(2)-C(73)-H(73)C(73)-C(74)-C(75)C(73)-C(74)-C(82)C(75)-C(74)-C(82)C(73)-C(74)-Zr(2)C(75)-C(74)-Zr(2)C(82)-C(74)-Zr(2)C(76)-C(75)-C(74)C(76)-C(75)-C(83)C(74)-C(75)-C(83)C(75)-C(76)-C(80)C(75)-C(76)-C(77)C(80)-C(76)-C(77)C(76)-C(77)-C(78)C(76)-C(77)-H(77A)C(78)-C(77)-H(77A)C(76)-C(77)-H(77B)C(78)-C(77)-H(77B)H(77A)-C(77)-H(77B)C(79)-C(78)-C(77)C(79)-C(78)-H(78A)C(77)-C(78)-H(78A)C(79)-C(78)-H(78B)C(77)-C(78)-H(78B)H(78A)-C(78)-H(78B)C(80)-C(79)-C(78)C(80)-C(79)-H(79A)C(78)-C(79)-H(79A)C(80)-C(79)-H(79B)C(78)-C(79)-H(79B)H(79A)-C(79)-H(79B)C(81)-C(80)-C(76)109.5109.5109.5109.5109.5109.5109.5109.5104.9(2)126.6(2)124.24(19)73.78(14)76.30(13)97.14(10)109.9(2)122.3(2)127.8(2)75.99(14)72.72(14)119.77(17)109.3(2)71.76(15)77.15(14)125.4125.4117.6131.4(2)106.3(2)122.3(2)71.04(14)120.76(16)71.37(14)116.3(2)122.8(2)120.8(2)121.9(2)129.2(2)108.9(2)102.5(2)111.3111.3111.3111.3109.2104.5(2)110.9110.9110.9110.9108.9102.5(2)111.3111.3111.3111.3109.2122.4(2)427приложениеC(47)-C(46)-C(45)C(47)-C(46)-H(46)C(45)-C(46)-H(46)C(46)-C(47)-C(48)C(46)-C(47)-H(47)C(48)-C(47)-H(47)C(43)-C(48)-C(47)C(43)-C(48)-H(48)C(47)-C(48)-H(48)C(32)-C(49)-H(49A)C(32)-C(49)-H(49B)H(49A)-C(49)-H(49B)C(32)-C(49)-H(49C)H(49A)-C(49)-H(49C)H(49B)-C(49)-H(49C)Si(1)-C(50)-H(50A)Si(1)-C(50)-H(50B)H(50A)-C(50)-H(50B)Si(1)-C(50)-H(50C)H(50A)-C(50)-H(50C)H(50B)-C(50)-H(50C)C(52)-C(51)-C(62)C(52)-C(51)-Si(2)C(62)-C(51)-Si(2)C(52)-C(51)-Zr(2)C(62)-C(51)-Zr(2)Si(2)-C(51)-Zr(2)C(53)-C(52)-C(51)C(53)-C(52)-C(69)C(51)-C(52)-C(69)C(53)-C(52)-Zr(2)C(51)-C(52)-Zr(2)C(69)-C(52)-Zr(2)C(52)-C(53)-C(54)C(52)-C(53)-Zr(2)C(54)-C(53)-Zr(2)C(52)-C(53)-H(53)C(54)-C(53)-H(53)Zr(2)-C(53)-H(53)C(53)-C(54)-C(55)C(53)-C(54)-C(62)119.9(3)120.0120.0119.9(3)120.1120.1121.2(3)119.4119.4109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5105.5(2)125.67(18)125.69(19)75.71(15)75.55(14)98.68(11)109.3(2)121.9(2)128.7(2)77.05(15)70.62(14)120.47(17)109.7(2)71.20(14)75.28(14)125.1125.1120.1131.5(2)106.6(2)C(81)-C(80)-C(79)C(76)-C(80)-C(79)C(80)-C(81)-C(82)C(80)-C(81)-H(81)C(82)-C(81)-H(81)C(81)-C(82)-C(74)C(81)-C(82)-C(71)C(74)-C(82)-C(71)C(81)-C(82)-Zr(2)C(74)-C(82)-Zr(2)C(71)-C(82)-Zr(2)C(84)-C(83)-C(88)C(84)-C(83)-C(75)C(88)-C(83)-C(75)C(83)-C(84)-C(85)C(83)-C(84)-H(84)C(85)-C(84)-H(84)C(86)-C(85)-C(84)C(86)-C(85)-H(85)C(84)-C(85)-H(85)C(85)-C(86)-C(87)C(85)-C(86)-H(86)C(87)-C(86)-H(86)C(88)-C(87)-C(86)C(88)-C(87)-H(87)C(86)-C(87)-H(87)C(87)-C(88)-C(83)C(87)-C(88)-H(88)C(83)-C(88)-H(88)C(72)-C(89)-H(89A)C(72)-C(89)-H(89B)H(89A)-C(89)-H(89B)C(72)-C(89)-H(89C)H(89A)-C(89)-H(89C)H(89B)-C(89)-H(89C)Si(2)-C(90)-H(90A)Si(2)-C(90)-H(90B)H(90A)-C(90)-H(90B)Si(2)-C(90)-H(90C)H(90A)-C(90)-H(90C)H(90B)-C(90)-H(90C)128.3(3)109.3(2)118.4(2)120.8120.8118.6(2)131.9(2)109.5(2)120.39(17)76.48(14)70.27(13)118.1(3)122.1(3)119.8(2)120.3(3)119.8119.8120.6(3)119.7119.7119.9(3)120.0120.0119.6(3)120.2120.2121.4(3)119.3119.3109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5428приложениеТаблица П14.
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