Дизайн и синтез металлоценов 4 группы - эффективных прекатализаторов гомо - и сополимеризации алкенов (1098265), страница 89
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Длины связей d [А] и величины углов ω [град] в соединении 1.67ZrCl21.67СвязьZr(1)-Cl(1)Zr(1)-Cl(2)Zr(1)-C(1)Zr(1)-C(1')Zr(1)-C(9)Zr(1)-C(9')Zr(1)-C(2)Zr(1)-C(2')Zr(1)-C(8)Zr(1)-C(8')Zr(1)-C(7)Zr(1)-C(7')C(1)-C(9)C(1)-C(2)C(1)-C(10)C(2)-C(3)C(2)-C(7)C(3)-C(4)C(4)-C(5)C(5)-C(6)C(6)-C(7)C(7)-C(8)C(8)-C(9)d [А]2.414(3)2.420(3)2.437(10)2.437(10)2.441(10)2.452(10)2.526(12)2.533(11)2.544(10)2.550(10)2.618(10)2.622(11)1.395(13)1.420(14)1.531(14)1.439(14)1.46(2)1.31(2)1.44(2)1.35(2)1.43(2)1.385(14)1.40(2)УголCl(1)-Zr(1)-Cl(2)C(9)-C(1)-C(2)C(9)-C(1)-C(10)C(2)-C(1)-C(10)C(1)-C(2)-C(3)C(1)-C(2)-C(7)C(3)-C(2)-C(7)C(4)-C(3)-C(2)C(3)-C(4)-C(5)C(6)-C(5)-C(4)C(5)-C(6)-C(7)C(8)-C(7)-C(6)C(8)-C(7)-C(2)C(6)-C(7)-C(2)C(7)-C(8)-C(9)C(1)-C(9)-C(8)C(2')-C(1')-C(9')C(2')-C(1')-C(10)C(9')-C(1')-C(10)C(1')-C(2')-C(3')C(1')-C(2')-C(7')C(3')-C(2')-C(7')C(4')-C(3')-C(2')ω [град]99.48(11)106.4(10)124.6(9)126.6(9)137.3(11)107.4(9)115.3(10)122.2(12)121.3(12)121.4(11)118.3(12)130.9(13)107.5(11)121.5(11)107.8(11)110.8(10)107.0(10)129.8(9)120.6(10)135.8(11)108.7(9)115.4(10)120.5(12)412приложениеC(1')-C(2')C(1')-C(9')C(1')-C(10)C(2')-C(3')C(2')-C(7')C(3')-C(4')C(4')-C(5')C(5')-C(6')C(6')-C(7')C(7')-C(8')C(8')-C(9')C(10)-C(11)C(10)-C(15)C(11)-C(12)C(12)-C(13)C(13)-C(14)C(14)-C(15)1.410(14)1.421(14)1.564(14)1.42(2)1.46(2)1.34(2)1.46(2)1.32(2)1.41(2)1.420(14)1.41(2)1.535(14)1.544(14)1.54(2)1.51(2)1.501(14)1.54(2)C(3')-C(4')-C(5')C(6')-C(5')-C(4')C(5')-C(6')-C(7')C(6')-C(7')-C(8')C(6')-C(7')-C(2')C(8')-C(7')-C(2')C(9')-C(8')-C(7')C(8')-C(9')-C(1')C(11)-C(10)-C(1)C(11)-C(10)-C(15)C(1)-C(10)-C(15)C(11)-C(10)-C(1')C(1)-C(10)-C(1')C(15)-C(10)-C(1')C(10)-C(11)-C(12)C(13)-C(12)-C(11)C(14)-C(13)-C(12)C(13)-C(14)-C(15)C(14)-C(15)-C(10)123.1(12)118.1(12)121.0(12)132.1(11)121.6(10)106.2(10)108.5(10)109.5(10)110.7(8)106.8(9)115.8(9)112.4(8)99.8(8)111.5(8)111.4(9)112.3(9)112.0(10)110.4(9)110.2(9)Таблица П8.
Длины связей d [А] и величины углов ω [град] в соединении 1.81.NZrCl21.81СвязьZr(1)-Cl(2)Zr(1)-Cl(1)Zr(1)-C(6)Zr(1)-C(1)Zr(1)-C(10)Zr(1)-C(5)Zr(1)-C(2)Zr(1)-C(7)Zr(1)-C(9)Zr(1)-C(4)Zr(1)-C(3)Zr(1)-C(8)N(1)-C(14)N(1)-C(13)N(1)-C(16)C(1)-C(5)C(1)-C(2)C(1)-C(11)C(2)-C(3)d [А]2.431(2)2.432(2)2.447(3)2.451(3)2.455(3)2.460(3)2.465(3)2.470(3)2.545(3)2.547(3)2.549(4)2.550(3)1.449(4)1.459(4)1.461(4)1.413(4)1.415(4)1.529(3)1.407(4)УголCl(2)-Zr(1)-Cl(1)C(14)-N(1)-C(13)C(14)-N(1)-C(16)C(13)-N(1)-C(16)C(5)-C(1)-C(2)C(5)-C(1)-C(11)C (2)-C(1)-C(11)C(3)-C(2)-C(1)C(4)-C(3)-C(2)C(3)-C(4)-C(5)C (1)-C(5)-C(4)C(10)-C(6)-C(7)C(10)-C(6)-C(11)C(7)-C(6)-C(11)C(6)-C(7)-C(8)C(9)-C(8)-C(7)C(8)-C(9)-C(10)C(9)-C(10)-C(6)C(12)-C(11)-C(6)ω [град]100.63(7)111.1(2)111.4(3)110.6(3)106.7(2)125.5(2)124.3(3)108.7(3)108.1(3)108.4(3)108.0(3)106.4(2)125.3(2)125.0(2)108.3(3)108.1(2)108.5(3)108.6(2)113.2(2)413приложениеC(3)-C(4)C(4)-C(5)C(6)-C(10)C(6)-C(7)C(6)-C(11)C(7)-C(8)C(8)-C(9)C(9)-C(10)C(11)-C(12)C(11)-C(15)C(12)-C(13)C(14)-C(15)1.382(6)1.420(4)1.416(4)1.421(3)1.525(3)1.421(4)1.382(5)1.412(4)1.524(4)1.535(3)1.519(4)1.519(4)C(12)-C(11)-C(1)C(6)-C(11)-C(1)C(12)-C(11)-C(15)C(6)-C (11)-C(15)C(1)-C(11)-C(15)C(13)-C(12)-C(11)N(1)-C(13)-C(12)N(1)-C(14)-C(15)C(14)-C(15)-C(11)112.0(2)99.7(2)107.2(2)112.2(2)112.5(2)111.9(2)111.2(2)111.2(2)110.5(2)Таблица П9.
Длины связей d [А] и величины углов ω [град] в соединении 1.86.СвязьSn-C(18)Sn-C(20)Sn-C(16)Sn-C(3')Zr-Cl(2)Zr-Cl(1)Zr-C(3)Zr-N(1)Zr-Cl(3)Zr-C(2)Zr-C(1)Zr-C(4)Zr-C(9)N(1)-C(15)N(1)-C(12)N(1)-C(13)C(1)-C(2)C(1)-C(9)C(1)-C(10)C(2)-C(3)C(3)-C(4)C(4)-C(5)C(4)-C(9)C(5)-C(6)d [А]2.25(3)2.19(2)2.13(3)2.196(10)2.416(3)2.419(3)2.431(10)2.438(8)2.449(3)2.461(8)2.493(8)2.553(9)2.556(9)1.488(12)1.488(13)1.521(12)1.424(12)1.474(13)1.482(13)1.411(14)1.42(2)1.36(2)1.406(13)1.34(2)УголC(18)Sn-C(20)C(18)Sn-C(16)C(20)Sn-C(16)C(18)Sn-C(3')C(20)Sn-C(3')C(16)Sn-C(3')Cl(2)-Zr-Cl(1)Cl(2)-Zr-N(1)Cl(1)-Zr-N(1)Cl(2)-Zr-Cl(3)Cl(1)-Zr-Cl(3)N(1)-Zr-Cl(3)C(15)-N(1)-C(12)C(15)-N(1)-C(13)C(12)-N(1)-C(13)C(15)-N(1)-ZrC(12)-N(1)-ZrC(13)-N(1)-ZrC(2)-C(1)-C(9)C(2)-C(1)-C(10)C(9)-C(1)-C(10)C(3)-C(2)-C(1)C(2)-C(3)-C(4)C(5)-C(4)-C(9)ω [град]117.8(8)113.2(10)106.0(9)101.4(7)105.6(5)112.8(8)128.53(11)83.4(2)79.3(2)86.90(13)86.24(11)151.7(2)105.9(8)107.0(7)106.5(7)107.5(6)117.4(6)111.9(6)104.6(8)124.4(8)130.6(8)108.8(9)110.2(9)122.8(11)414приложениеC(6)-C(7)C(7)-C(8)C(8)-C(9)C(1')-C(2')C(1')-C(9')C(1')-C(10)C(2')-C(3')C(3')-C(4')C(4')-C(5')C(4')-C(9')C(5')-C(6')C(6')-C(7')C(7')-C(8')C(8')-C(9')C(10)-C(14)C(10)-C(11)C(11)-C(12)C(13)-C(14)C(16)-C(17)C(18)-C(19)C(20)-C(21)1.37(2)1.32(2)1.422(14)1.360(12)1.476(13)1.520(12)1.474(13)1.465(13)1.384(13)1.409(13)1.38(2)1.40(2)1.359(14)1.410(14)1.557(13)1.556(13)1.555(13)1.510(13)1.08(4)1.27(4)1.55(2)C(5)-C(4)-C(3)C(9)-C(4)-C(3)C(6)-C(5)-C(4)C(5)-C(6)-C(7)C(8)-C(7)-C(6)C(7)-C(8)-C(9)C(4)-C(9)-C(8)C(4)-C(9)-C(1)C(8)-C(9)-C(1)C(2')-C(1')-C(9')C(2')-C(1')-C(10)C(9')-C(1')-C(10)C(1')-C(2')-C(3')C(2')-C(3')-C(4')C(2')-C(3')-SnC(4')-C(3')-SnC(5')-C(4')-C(9')C(5')-C(4')-C(3')C(9')-C(4')-C(3')C(6')-C(5')-C(4')C(5')-C(6')-C(7')C(8')-C(7')-C(6')C(7')-C(8')-C(9')C(8')-C(9')-C(4')C(8')-C(9')-C(1')C(4')-C(9')-C(1')C(1)-C(10)-C(1')C(1)-C(10)-C(14)C(1')-C(10)-C(14)C(1)-C(10)-C(11)C(1')-C(10)-C(11)C(14)-C(10)-C(11)C(12)-C(11)-C(10)N(1)-C(12)-C(11)N(1)-C(13)-C(14)C(13)-C(14)-C(10)C(17)-C(16)-SnC(19)-C(18)-SnC(21)-C(20)-Sn131.6(10)105.6(9)117.9(12)121.4(13)122.4(13)119.1(12)116.3(10)110.6(8)133.1(10)108.1(8)125.5(8)126.4(8)111.0(8)103.7(8)106.5(6)106.3(7)120.0(9)130.4(9)109.5(8)120.2(10)119.5(10)121.3(10)119.7(10)119.1(9)133.8(9)107.1(8)109.2(7)113.0(8)108.8(7)108.6(7)111.1(8)106.2(7)110.9(8)112.9(8)113.1(8)112.5(7)109(3)115(2)112.9(12)415приложениеТаблица П10.
Длины связей d [А] и величины углов ω [град]в соединении 1.89.ZrCl21.89СвязьZr(1)-Cl(1)Zr(1)-Cl(2)Zr(1)-C(1)Zr(1)-C(6)Zr(1)-C(5)Zr(1)-C(10)Zr(1)-C(7)Zr(1)-C(2)Zr(1)-C(4)Zr(1)-C(8)Zr(1)-C(3)Zr(1)-C(9)C(1)-C(2)C(1)-C(5)C(1)-C(11)C(2)-C(3)C(3)-C(4)C(4)-C(5)C(6)-C(7)C(6)-C(10)C(6)-C(11)C(7)-C(8)C(8)-C(9)C(9)-C(10)C(11)-C(23)C(11)-C(12)C(12)-C(13)C(12)-C(17)C(13)-C(14)C(14)-C(15)C(15)-C(16)C(16)-C(17)C(17)-C(18)C(18)-C(19)C(18)-C(23)C(19)-C(20)C(20)-C(21)C(21)-C(22)C(22)-C(23)d [А]2,432(2)2,422(2)2,448(6)2,456(5)2,458(6)2,459(5)2,463(6)2,467(6)2,540(6)2,546(6)2,550(6)2,551(6)1,408(8)1,416(8)1,543(7)1,405(8)1,391(9)1,405(8)1,408(8)1,413(8)1,533(8)1,421(9)1,384(9)1,418(9)1,526(8)1,544(8)1,374(8)1,404(8)1,388(8)1,376(10)1,375(11)1,388(9)1,444(9)1,390(9)1,405(9)1,365(12)1,381(11)1,395(9)1,389(9)УголCl(2)-Zr(1)-Cl(1)C(2)-C(1)-C(5)C(2)-C(1)-C(11)C(5)-C(1)-C(11)C(3)-C(2)-C(1)C(4)-C(3)-C(2)C(3)-C(4)-C(5)C(4)-C(5)-C(1)C(7)-C(6)-C(10)C(7)-C(6)-C(11)C(10)-C(6)-C(11)C(6)-C(7)-C(8)C(9)-C(8)-C(7)C(8)-C(9)-C(10)C(6)-C(10)-C(9)C(23)-C(11)-C(6)C(23)-C(11)-C(1)C(6)-C(11)-C(1)C(23)-C(11)-C(12)C(6)-C(11)-C(12)C(1)-C(11)-C(12)C(13)-C(12)-C(17)C(13)-C(12)-C(11)C(17)-C(12)-C(11)C(12)-C(13)-C(14)C(15)-C(14)-C(13)C(16)-C(15)-C(14)C(15)-C(16)-C(17)C(16)-C(17)-C(12)C(16)-C(17)-C(18)C(12)-C(17)-C(18)C(19)-C(18)-C(23)C(19)-C(18)-C(17)C(23)-C(18)-C(17)C(20)-C(19)-C(18)C(19)-C(20)-C(21)C(20)-C(21)-C(22)C(23)-C(22)-C(21)C(22)-C(23)-C(18)C(22)-C(23)-C(11)C(18)-C(23)-C(11)ω [град]100,92(8)106,8(5)124,6(5)125,3(5)108,6(6)108,1(5)108,2(5)108,3(6)106,6(5)124,8(5)125,1(5)108,7(6)108,1(6)108,0(6)108,7(5)114,2(4)114,9(5)99,2(4)101.8(4)113,2(4)114,2(4)119,7(6)130,8(5)109,4(5)120.0(6)120.0(7)121,1(7)119,2(7)120,0(7)130,7(6)109,3(5)120,6(7)129,6(7)109,7(5)119,5(8)120,4(7)121,3(7)118,7(7)119,4(6)130,9(6)109,7(5)416приложениеТаблица П11.
Величиныдлин связей (d, Å) ивалентных углов (ω) вмолекуле 2.22.PhN2.22СвязьN(1)-C(5)N(1)-C(1)N(1)-C(4)C(1)-C(2)C(2)-C(3)C(3)-C(4)C(5)-C(6)C(5)-C(15)C(6)-C(7)C(6)-C(14)C(7)-C(8)C(7)-C(12)C(8)-C(9)C(9)-C(10)C(10)-C(11)C(11)-C(12)C(12)-C(13)C(13)-C(14)C(15)-C(16)C(16)-C(21)C(16)-C(17)C(17)-C(18)C(18)-C(19)C(19)-C(20)C(20)-C(21)d [А]1.336(6)1.457(8)1.463(7)1.524(10)1.527(11)1.509(9)1.367(7)1.506(7)1.466(7)1.458(7)1.376(8)1.442(8)1.385(8)1.408(11)1.352(10)1.385(9)1.421(9)1.350(8)1.521(8)1.350(8)1.408(8)1.379(12)1.366(10)1.379(11)1.396(10)УголC(5)-N(1)-C(1)C(5)-N(1)-C(4)C(1)-N(1)-C(4)N(1)-C(1)-C(2)C(3)-C(2)-C(1)C(2)-C(3)-C(4)N(1)-C(4)-C(3)N(1)-C(5)-C(6)N(1)-C(5)-C(15)C(6)-C(5)-C(15)C(5)-C(6)-C(7)C(5)-C(6)-C(14)C(7)-C(6)-C(14)C(8)-C(7)-C(6)C(8)-C(7)-C(12)C(6)-C(7)-C(12)C(7)-C(8)-C(9)C(10)-C(9)-C(8)C(11)-C(10)-C(9)C(10)-C(11)-C(12)C(13)-C(12)-C(11)C(13)-C(12)-C(7)C(11)-C(12)-C(7)C(14)-C(13)-C(12)C(13)-C(14)-C(6)C(5)-C(15)-C(16)C(21)-C(16)-C(17)C(21)-C(16)-C(15)C(17)-C(16)-C(15)C(18)-C(17)-C(16)C(19)-C(18)-C(17)C(18)-C(19)-C(20)C(19)-C(20)-C(21)C(16)-C(21)-C(20)ω [град]123.4(5)126.7(5)108.7(6)104.3(7)102.5(7)101.7(6)107.1(7)126.6(5)114.1(5)119.3(5)127.6(5)126.5(5)105.9(5)135.4(5)118.1(5)106.3(5)120.0(7)120.5(8)121.2(8)118.8(8)130.5(8)108.0(5)121.3(7)110.0(6)109.6(6)115.2(6)120.2(7)124.3(7)115.5(8)117.8(9)122.2(10)119.5(9)119.1(11)121.1(9)417приложениеТаблица П12.
Величины длин связей (d, Å) и валентных углов (ω) в молекуле 3.39.SiZrCl23.39СвязьZr(1)-Cl(2)Zr(1)-Cl(1)Zr(1)-C(3)Zr(1)-C(33)Zr(1)-C(32)Zr(1)-C(4)Zr(1)-C(2)Zr(1)-C(34)Zr(1)-C(31)Zr(1)-C(1)Zr(1)-C(9)Zr(1)-C(42)Si(1)-C(24)Si(1)-C(3)Si(1)-C(23)Si(1)-C(33)C(1)-C(2)C(1)-C(9)C(1)-H(1)C(2)-C(3)C(2)-C(16)C(3)-C(4)C(4)-C(5)C(4)-C(9)C(5)-C(6)C(5)-H(5)C(6)-C(7)C(6)-H(6)C(7)-C(8)C(7)-H(7)C(8)-C(9)C(8)-C(10)C(10)-C(11)C(10)-C(15)C(11)-C(12)C(11)-H(11)C(12)-C(13)C(12)-H(12)d [А]2.4113(16)2.4159(16)2.457(5)2.471(5)2.499(5)2.521(5)2.523(5)2.531(5)2.578(5)2.608(5)2.626(5)2.636(5)1.848(6)1.858(5)1.862(6)1.875(6)1.405(7)1.422(7)0.95001.437(7)1.516(7)1.469(7)1.417(7)1.428(7)1.362(7)0.95001.413(7)0.95001.345(7)0.95001.440(7)1.484(7)1.380(7)1.401(7)1.385(7)0.95001.399(7)0.9500УголCl(2)-Zr(1)-Cl(1)Cl(2)-Zr(1)-C(3)Cl(1)-Zr(1)-C(3)Cl(2)-Zr(1)-C(33)Cl(1)-Zr(1)-C(33)C(3)-Zr(1)-C(33)Cl(2)-Zr(1)-C(32)Cl(1)-Zr(1)-C(32)C(3)-Zr(1)-C(32)C(33)-Zr(1)-C(32)Cl(2)-Zr(1)-C(4)Cl(1)-Zr(1)-C(4)C(3)-Zr(1)-C(4)C(33)-Zr(1)-C(4)C(32)-Zr(1)-C(4)Cl(2)-Zr(1)-C(2)Cl(1)-Zr(1)-C(2)C(3)-Zr(1)-C(2)C(33)-Zr(1)-C(2)C(32)-Zr(1)-C(2)C(4)-Zr(1)-C(2)Cl(2)-Zr(1)-C(34)Cl(1)-Zr(1)-C(34)C(3)-Zr(1)-C(34)C(33)-Zr(1)-C(34)C(32)-Zr(1)-C(34)C(4)-Zr(1)-C(34)C(2)-Zr(1)-C(34)Cl(2)-Zr(1)-C(31)Cl(1)-Zr(1)-C(31)C(3)-Zr(1)-C(31)C(33)-Zr(1)-C(31)C(32)-Zr(1)-C(31)C(4)-Zr(1)-C(31)C(2)-Zr(1)-C(31)C(34)-Zr(1)-C(31)Cl(2)-Zr(1)-C(1)Cl(1)-Zr(1)-C(1)ω [град]96.86(5)121.18(12)125.69(13)120.78(13)126.14(12)67.54(17)88.24(13)132.21(13)89.41(18)33.30(17)87.41(12)133.10(12)34.30(15)88.87(17)94.47(17)132.82(12)92.31(12)33.50(17)88.48(17)118.23(17)54.53(16)133.89(13)92.33(12)87.43(16)33.85(16)54.06(17)117.64(16)91.54(16)80.54(12)101.74(12)120.26(17)54.88(17)32.26(16)124.94(16)142.16(16)53.36(16)104.91(11)80.55(12)418приложениеC(13)-C(14)C(13)-C(19)C(14)-C(15)C(14)-H(14)C(15)-H(15)C(16)-C(17)C(16)-C(18)C(16)-H(16A)C(17)-H(17A)C(17)-H(17B)C(17)-H(17C)C(18)-H(18A)C(18)-H(18B)C(18)-H(18C)C(19)-C(20)C(19)-C(21)C(19)-C(22)C(20)-H(20A)C(20)-H(20B)C(20)-H(20C)C(21)-H(21A)C(21)-H(21B)C(21)-H(21C)C(22)-H(22A)C(22)-H(22B)C(22)-H(22C)C(23)-H(23A)C(23)-H(23B)C(23)-H(23C)C(24)-H(24A)C(24)-H(24B)C(24)-H(24C)C(31)-C(32)C(31)-C(42)C(31)-H(31)C(32)-C(33)C(32)-C(53)C(33)-C(34)C(34)-C(35)C(34)-C(42)C(35)-C(36)C(35)-H(35)C(36)-C(40)C(36)-C(37)C(37)-C(38)C(37)-H(37A)C(37)-H(37B)C(38)-C(39)C(38)-H(38A)C(38)-H(38B)C(39)-C(40)C(39)-H(39A)C(39)-H(39B)C(40)-C(41)C(41)-C(42)C(41)-C(43)C(43)-C(44)1.377(8)1.520(7)1.388(7)0.95000.95001.501(7)1.525(8)1.00000.98000.98000.98000.98000.98000.98001.514(8)1.530(9)1.533(8)0.98000.98000.98000.98000.98000.98000.98000.98000.98000.98000.98000.98000.98000.98000.98001.413(7)1.419(7)0.95001.424(7)1.514(7)1.457(7)1.428(7)1.437(7)1.344(7)0.95001.421(7)1.511(7)1.516(8)0.99000.99001.520(8)0.99000.99001.493(7)0.99000.99001.374(7)1.423(7)1.473(7)1.376(7)C(3)-Zr(1)-C(1)C(33)-Zr(1)-C(1)C(32)-Zr(1)-C(1)C(4)-Zr(1)-C(1)C(2)-Zr(1)-C(1)C(34)-Zr(1)-C(1)C(31)-Zr(1)-C(1)Cl(2)-Zr(1)-C(9)Cl(1)-Zr(1)-C(9)C(3)-Zr(1)-C(9)C(33)-Zr(1)-C(9)C(32)-Zr(1)-C(9)C(4)-Zr(1)-C(9)C(2)-Zr(1)-C(9)C(34)-Zr(1)-C(9)C(31)-Zr(1)-C(9)C(1)-Zr(1)-C(9)Cl(2)-Zr(1)-C(42)Cl(1)-Zr(1)-C(42)C(3)-Zr(1)-C(42)C(33)-Zr(1)-C(42)C(32)-Zr(1)-C(42)C(4)-Zr(1)-C(42)C(2)-Zr(1)-C(42)C(34)-Zr(1)-C(42)C(31)-Zr(1)-C(42)C(1)-Zr(1)-C(42)C(9)-Zr(1)-C(42)C(24)-Si(1)-C(3)C(24)-Si(1)-C(23)C(3)-Si(1)-C(23)C(24)-Si(1)-C(33)C(3)-Si(1)-C(33)C(23)-Si(1)-C(33)C(2)-C(1)-C(9)C(2)-C(1)-Zr(1)C(9)-C(1)-Zr(1)C(2)-C(1)-H(1)C(9)-C(1)-H(1)Zr(1)-C(1)-H(1)C(1)-C(2)-C(3)C(1)-C(2)-C(16)C(3)-C(2)-C(16)C(1)-C(2)-Zr(1)C(3)-C(2)-Zr(1)C(16)-C(2)-Zr(1)C(2)-C(3)-C(4)C(2)-C(3)-Si(1)C(4)-C(3)-Si(1)C(2)-C(3)-Zr(1)C(4)-C(3)-Zr(1)Si(1)-C(3)-Zr(1)C(5)-C(4)-C(9)C(5)-C(4)-C(3)C(9)-C(4)-C(3)C(5)-C(4)-Zr(1)C(9)-C(4)-Zr(1)54.67(17)119.20(17)143.66(17)53.53(16)31.73(15)121.17(16)173.89(15)80.08(11)102.56(12)54.79(16)119.60(17)125.05(17)32.14(15)52.77(15)141.23(16)150.44(16)31.53(15)105.70(11)80.07(11)118.78(16)54.92(16)53.10(16)143.42(16)121.47(16)32.22(15)31.56(15)145.35(15)173.44(15)113.7(2)103.7(3)115.8(3)115.1(3)94.4(2)114.7(3)108.2(4)70.8(3)74.9(3)125.9125.9120.1110.1(4)122.4(5)126.5(4)77.5(3)70.7(3)127.7(3)105.3(4)127.2(4)124.6(4)75.8(3)75.2(3)99.5(2)119.4(4)132.6(5)108.0(4)119.3(4)78.0(3)419приложениеC(43)-C(48)C(44)-C(45)C(44)-H(44)C(45)-C(46)C(45)-H(45)C(46)-C(47)C(46)-C(49)C(47)-C(48)C(47)-H(47)C(48)-H(48)C(49)-C(52)C(49)-C(51)C(49)-C(50)C(50)-H(50A)C(50)-H(50B)C(50)-H(50C)C(51)-H(51A)C(51)-H(51B)C(51)-H(51C)C(52)-H(52A)C(52)-H(52B)C(52)-H(52C)C(53)-H(53A)C(53)-H(53B)C(53)-H(53C)УголC(11)-C(12)-C(13)C(11)-C(12)-H(12)C(13)-C(12)-H(12)C(14)-C(13)-C(12)C(14)-C(13)-C(19)C(12)-C(13)-C(19)C(13)-C(14)-C(15)C(13)-C(14)-H(14)C(15)-C(14)-H(14)C(14)-C(15)-C(10)C(14)-C(15)-H(15)C(10)-C(15)-H(15)C(17)-C(16)-C(2)C(17)-C(16)-C(18)C(2)-C(16)-C(18)C(17)-C(16)-H(16A)C(2)-C(16)-H(16A)C(18)-C(16)-H(16A)C(16)-C(17)-H(17A)C(16)-C(17)-H(17B)H(17A)-C(17)-H(17B)C(16)-C(17)-H(17C)H(17A)-C(17)-H(17C)H(17B)-C(17)-H(17C)C(16)-C(18)-H(18A)C(16)-C(18)-H(18B)H(18A)-C(18)-H(18B)C(16)-C(18)-H(18C)H(18A)-C(18)-H(18C)H(18B)-C(18)-H(18C)1.387(7)1.383(8)0.95001.391(7)0.95001.375(7)1.521(8)1.388(8)0.95000.95001.516(8)1.528(7)1.528(8)0.98000.98000.98000.98000.98000.98000.98000.98000.98000.98000.98000.9800ω [град]120.9(5)119.5119.5117.0(5)120.7(5)122.3(5)122.7(5)118.7118.7119.9(5)120.0120.0115.6(4)111.4(5)107.2(4)107.5107.5107.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5C(3)-C(4)-Zr(1)C(6)-C(5)-C(4)C(6)-C(5)-H(5)C(4)-C(5)-H(5)C(5)-C(6)-C(7)C(5)-C(6)-H(6)C(7)-C(6)-H(6)C(8)-C(7)-C(6)C(8)-C(7)-H(7)C(6)-C(7)-H(7)C(7)-C(8)-C(9)C(7)-C(8)-C(10)C(9)-C(8)-C(10)C(1)-C(9)-C(4)C(1)-C(9)-C(8)C(4)-C(9)-C(8)C(1)-C(9)-Zr(1)C(4)-C(9)-Zr(1)C(8)-C(9)-Zr(1)C(11)-C(10)-C(15)C(11)-C(10)-C(8)C(15)-C(10)-C(8)C(10)-C(11)-C(12)C(10)-C(11)-H(11)C(12)-C(11)-H(11)УголC(35)-C(34)-Zr(1)C(42)-C(34)-Zr(1)C(33)-C(34)-Zr(1)C(36)-C(35)-C(34)C(36)-C(35)-H(35)C(34)-C(35)-H(35)C(35)-C(36)-C(40)C(35)-C(36)-C(37)C(40)-C(36)-C(37)C(36)-C(37)-C(38)C(36)-C(37)-H(37A)C(38)-C(37)-H(37A)C(36)-C(37)-H(37B)C(38)-C(37)-H(37B)H(37A)-C(37)-H(37B)C(37)-C(38)-C(39)C(37)-C(38)-H(38A)C(39)-C(38)-H(38A)C(37)-C(38)-H(38B)C(39)-C(38)-H(38B)H(38A)-C(38)-H(38B)C(40)-C(39)-C(38)C(40)-C(39)-H(39A)C(38)-C(39)-H(39A)C(40)-C(39)-H(39B)C(38)-C(39)-H(39B)H(39A)-C(39)-H(39B)C(41)-C(40)-C(36)C(41)-C(40)-C(39)C(36)-C(40)-C(39)70.5(3)118.8(5)120.6120.6121.3(5)119.3119.3122.7(5)118.7118.7117.4(5)122.6(4)119.8(4)108.4(4)131.3(5)120.2(5)73.6(3)69.9(3)125.0(3)117.7(5)122.2(5)120.1(5)121.8(5)119.1119.1ω [град]118.3(3)77.9(3)70.8(3)118.6(5)120.7120.7122.8(5)128.4(5)108.8(5)103.7(5)111.0111.0111.0111.0109.0105.8(4)110.6110.6110.6110.6108.7103.7(5)111.0111.0111.0111.0109.0122.0(5)127.8(5)110.1(5)420приложениеC(20)-C(19)-C(13)C(20)-C(19)-C(21)C(13)-C(19)-C(21)C(20)-C(19)-C(22)C(13)-C(19)-C(22)C(21)-C(19)-C(22)C(19)-C(20)-H(20A)C(19)-C(20)-H(20B)H(20A)-C(20)-H(20B)C(19)-C(20)-H(20C)H(20A)-C(20)-H(20C)H(20B)-C(20)-H(20C)C(19)-C(21)-H(21A)C(19)-C(21)-H(21B)H(21A)-C(21)-H(21B)C(19)-C(21)-H(21C)H(21A)-C(21)-H(21C)H(21B)-C(21)-H(21C)C(19)-C(22)-H(22A)C(19)-C(22)-H(22B)H(22A)-C(22)-H(22B)C(19)-C(22)-H(22C)H(22A)-C(22)-H(22C)H(22B)-C(22)-H(22C)Si(1)-C(23)-H(23A)Si(1)-C(23)-H(23B)H(23A)-C(23)-H(23B)Si(1)-C(23)-H(23C)H(23A)-C(23)-H(23C)H(23B)-C(23)-H(23C)Si(1)-C(24)-H(24A)Si(1)-C(24)-H(24B)H(24A)-C(24)-H(24B)Si(1)-C(24)-H(24C)H(24A)-C(24)-H(24C)H(24B)-C(24)-H(24C)C(32)-C(31)-C(42)C(32)-C(31)-Zr(1)C(42)-C(31)-Zr(1)C(32)-C(31)-H(31)C(42)-C(31)-H(31)Zr(1)-C(31)-H(31)C(31)-C(32)-C(33)C(31)-C(32)-C(53)C(33)-C(32)-C(53)C(31)-C(32)-Zr(1)C(33)-C(32)-Zr(1)C(53)-C(32)-Zr(1)C(32)-C(33)-C(34)C(32)-C(33)-Si(1)C(34)-C(33)-Si(1)C(32)-C(33)-Zr(1)C(34)-C(33)-Zr(1)Si(1)-C(33)-Zr(1)C(35)-C(34)-C(42)C(35)-C(34)-C(33)C(42)-C(34)-C(33)113.7(5)107.1(5)109.1(5)107.9(5)109.7(5)109.4(5)109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5108.5(5)70.8(3)76.5(3)125.8125.8118.8110.4(4)121.6(5)127.9(5)77.0(3)72.3(3)120.5(3)105.0(5)127.2(4)124.1(4)74.4(3)75.3(3)98.5(2)118.0(5)132.8(5)109.2(5)C(40)-C(41)-C(42)C(40)-C(41)-C(43)C(42)-C(41)-C(43)C(31)-C(42)-C(41)C(31)-C(42)-C(34)C(41)-C(42)-C(34)C(31)-C(42)-Zr(1)C(41)-C(42)-Zr(1)C(34)-C(42)-Zr(1)C(44)-C(43)-C(48)C(44)-C(43)-C(41)C(48)-C(43)-C(41)C(43)-C(44)-C(45)C(43)-C(44)-H(44)C(45)-C(44)-H(44)C(44)-C(45)-C(46)C(44)-C(45)-H(45)C(46)-C(45)-H(45)C(47)-C(46)-C(45)C(47)-C(46)-C(49)C(45)-C(46)-C(49)C(46)-C(47)-C(48)C(46)-C(47)-H(47)C(48)-C(47)-H(47)C(43)-C(48)-C(47)C(43)-C(48)-H(48)C(47)-C(48)-H(48)C(52)-C(49)-C(46)C(52)-C(49)-C(51)C(46)-C(49)-C(51)C(52)-C(49)-C(50)C(46)-C(49)-C(50)C(51)-C(49)-C(50)C(49)-C(50)-H(50A)C(49)-C(50)-H(50B)H(50A)-C(50)-H(50B)C(49)-C(50)-H(50C)H(50A)-C(50)-H(50C)H(50B)-C(50)-H(50C)C(49)-C(51)-H(51A)C(49)-C(51)-H(51B)H(51A)-C(51)-H(51B)C(49)-C(51)-H(51C)H(51A)-C(51)-H(51C)H(51B)-C(51)-H(51C)C(49)-C(52)-H(52A)C(49)-C(52)-H(52B)H(52A)-C(52)-H(52B)C(49)-C(52)-H(52C)H(52A)-C(52)-H(52C)H(52B)-C(52)-H(52C)C(32)-C(53)-H(53A)C(32)-C(53)-H(53B)H(53A)-C(53)-H(53B)C(32)-C(53)-H(53C)H(53A)-C(53)-H(53C)H(53B)-C(53)-H(53C)115.9(5)122.8(5)121.3(5)130.5(5)106.9(4)122.6(5)72.0(3)124.2(3)69.9(3)116.8(5)122.0(5)121.2(5)122.0(5)119.0119.0121.7(5)119.2119.2116.0(5)121.4(5)122.6(5)122.6(5)118.7118.7120.9(5)119.6119.6112.3(5)107.2(5)110.9(5)109.3(5)108.8(5)108.3(5)109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5109.5421приложениеТаблица П13.
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