Реакции радиационно-индуцированных избыточных электронов с молекулами карбонильных соединений в низкотемпературных матрицах, страница 24

Продемонстрировано, чтоучет локального окружения в расчетах в рамках микросольватационной моделипозволяет удовлетворительно описывать параметры стабилизированных анионрадикалов, получающихся из таких молекул.4. Обнаружено, что при реакциях избыточных электронов с молекулами«мостиковых» амидоэфиров структуры (CH3)2NC(O)(CH2)nC(O)OCH3 (n = 1 – 3) всобственныхматрицахснаблюдаетсястабилизациясильнымидвухмежмолекулярнымитипованион-радикаловвзаимодействиямислокализациейнеспаренного электрона на сложноэфирной и амидной группах, соответственно.163Список литературы1. Excess electrons in dielectric media / Jay-Gerin J.-P., Ferradini C. Boca Raton:CRC Press, 1991.

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