M. Hargittai, I. Hargittai - Symmetry through the Eyes of a Chemist (793765), страница 48
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Bersuker, J. Mol. Struct. 44–52.Chapter 7Chemical ReactionsBy some fortuitous concourse of atoms.Marcus Tullius Cicero [1]The chemical reaction is the “most chemical” event. The first application of symmetry considerations to chemical reactions can beattributed to Wigner and Witmer [2]. The Wigner–Witmer rulesare concerned with the conservation of spin and orbital angularmomentum in the reaction of diatomic molecules. Although symmetryis not explicitly mentioned, it is present implicitly in the principle ofconservation of orbital angular momentum. It was Emmy Noether(1882–1935), a German mathematician, who established that therewas a one-to-one correspondence between symmetry and the differentconservation laws [3, 4].The real breakthrough in recognizing the role that symmetry playsin determining the course of chemical reactions has occurred onlyrecently, mainly through the activities of Woodward and Hoffmann[5, 6], Fukui [7, 8], Bader [9, 10], Pearson [11], Halevi [12, 13],and others.
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