73092-1 (647354), страница 4
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Результаты оценок вязкости раствора NaCl
| C mol/l | теор (29) | теор (41) | теор (41а) | теор (42) | лит [10] | лит [12] | эксп |
| 0,0000 | 0,9507 | 0,9985 | 0,9555 | 1,0320 | 0,8937 | 0,9545 | |
| 0,0010 | 0,9715 | 1,0264 | 0,9850 | 1,0307 | 0,9544 | 0,882 | |
| 0,0030 | 0,9859 | 1,0445 | 1,0045 | 1,0299 | |||
| 0,0050 | 0,9965 | 1,0569 | 1,0178 | 1,0293 | |||
| 0,0100 | 1,0142 | 1,0766 | 1,0393 | 1,0284 | 0,896 | ||
| 0,0500 | 1,0824 | 1,1348 | 1,1062 | 1,0254 | |||
| 0,0700 | 1,0966 | 1,1405 | 1,1149 | 1,0248 | |||
| 0,1000 | 1,1262 | 1,1561 | 1,1340 | 1,0242 | 0,9020 | 0,9583 | 0,9467 |
| 0,1250 | 1,0239 | 0,9053 | 0,9598 | ||||
| 0,2000 | 1,1819 | 1,1655 | 1,1522 | 1,0237 | 0,9653 | ||
| 0,2200 | 1,0238 | ||||||
| 0,2500 | 1,0240 | 0,9154 | 0,9636 | ||||
| 0,5000 | 1,2841 | 1,1494 | 1,1496 | 1,0271 | 0,9361 | 0,9717 | 1,0031 |
| 0,8860 | 1,0345 | 0,9815 | 0,9831 | ||||
| 1,0000 | 1,4018 | 1,1120 | 1,1208 | 1,0370 | 1,063 | ||
| 1,5000 | 1,5053 | 1,0791 | 1,0904 | 1,0486 | 1,0276 | 0,9984 | |
| 1,8300 | 1,0568 | 1,0760 | 1,0051 | ||||
| 2,0000 | 1,6091 | 1,0512 | 1,0622 | 1,0610 | 1,0773 | 1,0091 | 1,12 |
| 3,0000 | 1,8334 | 1,0122 | 1,0191 | 1,0870 | |||
| 4,0000 | 2,1006 | 1,0077 | 1,0081 | 1,1138 | |||
| 5,0000 | 2,4306 | 1,0477 | 1,0400 | 1,1411 | |||
| 5,5203 | 1,1555 |
Таблица 10
Результаты оценок электропроводностей, функции от среднемолярного коэффициента активности, степени диссоциации, параметр экранирования и функции распределения для раствора KCl
| C mol/l | лит [13, 10] | (36) | (37) | | | | f |
| 0,0000 | 149,89 | 149,8840 | 149,7958 | 0,0000 | 1,0000 | 1,0000 | 1,0000 |
| 0,0010 | 145,90 | 146,0854 | 146,2624 | -0,0164 | 0,9734 | 1,0092 | 0,9939 |
| 0,0030 | 144,92 | 145,2336 | 145,6019 | -0,0271 | 0,9668 | 1,0160 | 0,9895 |
| 0,0050 | 143,61 | 144,0036 | 144,5005 | -0,0338 | 0,9581 | 1,0207 | 0,9865 |
| 0,0100 | 140,80 | 141,3354 | 142,0616 | -0,0450 | 0,9394 | 1,0292 | 0,9809 |
| 0,0500 | 134,41 | 135,3996 | 137,0724 | -0,0779 | 0,8967 | 1,0653 | 0,9579 |
| 0,1000 | 130,01 | 131,2067 | 133,5506 | -0,0915 | 0,8674 | 1,0924 | 0,9409 |
| 0,5000 | 117,25 | 118,4013 | 123,3921 | -0,0968 | 0,7822 | 1,2066 | 0,8727 |
| 0,7000 | 113,60 | 114,4728 | 120,2643 | -0,0880 | 0,7579 | 1,2445 | 0,8512 |
| 1,0000 | 111,07 | 111,4574 | 118,3158 | -0,0693 | 0,7410 | 1,2922 | 0,8249 |
| 1,5000 | 107,20 | 106,6835 | 114,9154 | -0,0253 | 0,7152 | 1,3579 | 0,7900 |
| 2,0000 | 104,12 | 102,6718 | 112,0035 | 0,0311 | 0,6946 | 1,4132 | 0,7617 |
| 2,2220 | 102,70 | 100,8436 | 110,5826 | 0,0584 | 0,6852 | 1,4356 | 0,7505 |
| 3,0000 | 100,70 | 97,3787 | 108,5911 | 0,1519 | 0,6718 | 1,5061 | 0,7164 |
| 3,5000 | 0,1979 | 1,5466 | 0,6976 | ||||
| 3,9000 | 0,2187 | 1,5770 | 0,6837 | ||||
| 5,0000 | 0,1568 | 1,6534 | 0,6502 | ||||
| 6,0000 | -0,1237 | 1,7157 | 0,6240 | ||||
| 7,0000 | -0,7022 | 1,7731 | 0,6009 |
Таблица 11
Результаты оценок коэффициента диффузии раствора KCl
| C mol/l | Dтеор (30) | Dтеор (35) | Dтеор (38) | Dтеор (40) | Dлит [10] |
| 0,0000 | 1,7234 | 1,7223 | 1,7223 | 1,7234 | 1,7220 |
| 0,0010 | 1,6775 | 1,6941 | 1,6650 | 1,6608 | 1,6969 |
| 0,0030 | 1,6662 | 1,6757 | 1,6476 | 1,6398 | 1,6805 |
| 0,0050 | 1,6512 | 1,6641 | 1,6297 | 1,6196 | 1,6710 |
| 0,0100 | 1,6189 | 1,6449 | 1,5948 | 1,5806 | 1,6563 |
| 0,0500 | 1,5454 | 1,5881 | 1,5304 | 1,5006 | 1,6105 |
| 0,1000 | 1,4948 | 1,5648 | 1,5025 | 1,4626 | 1,5932 |
| 0,2000 | 1,5498 | 1,5880 | |||
| 0,3000 | 1,5477 | 1,5880 | |||
| 0,5000 | 1,3481 | 1,5556 | 1,5025 | 1,4277 | 1,5984 |
| 0,7000 | 1,3062 | 1,5708 | 1,5161 | 1,4321 | 1,6122 |
| 1,0000 | 1,2771 | 1,6030 | 1,5645 | 1,4687 | 1,6347 |
| 1,1800 | 1,6273 | 1,6502 | |||
| 1,5000 | 1,2326 | 1,6788 | 1,6424 | 1,5321 | 1,6788 |
| 2,0000 | 1,1972 | 1,7759 | 1,7273 | 1,6058 | 1,7280 |
| 3,0000 | 1,1578 | 1,9840 | 1,9206 | 1,7810 | 1,8248 |
| 3,5000 | 2,0632 | 1,8662 | |||
| 3,9000 | 2,0990 | 1,8973 | |||
| 5,0000 | 1,9923 | ||||
| 6,0000 | 1,5092 | ||||
| 7,0000 | 0,5129 |
Таблица 12
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