73092-1 (647354), страница 3
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Результаты оценок коэффициента диффузии раствора LiCl
| C mol/l | Dтеор (30) | Dтеор (35) | Dтеор (38) | Dтеор (40) | Dлит [10] | Dлит [11] |
| 0,0000 | 1,3226 | 1,1808 | 1,1808 | 1,3226 | 1,1802 | |
| 0,0010 | 1,2865 | 1,1570 | 1,1386 | 1,2733 | 1,1621 | |
| 0,0030 | 1,2710 | 1,1429 | 1,1208 | 1,2521 | 1,1500 | |
| 0,0050 | 1,2573 | 1,1346 | 1,1075 | 1,2362 | 1,1431 | |
| 0,0100 | 1,2354 | 1,1222 | 1,0886 | 1,2134 | 1,1336 | |
| 0,0500 | 1,1489 | 1,1025 | 1,0422 | 1,1545 | 1,1146 | |
| 0,1000 | 1,1022 | 1,1124 | 1,0402 | 1,1468 | 1,1059 | |
| 0,2000 | 1,1475 | 1,0973 | ||||
| 0,3000 | 1,1838 | 1,0886 | ||||
| 0,4500 | 1,2352 | 1,0886 | ||||
| 0,5000 | 0,9452 | 1,2516 | 1,0978 | 1,1861 | 1,0973 | |
| 0,6000 | 0,9198 | 1,2839 | 1,1071 | 1,1920 | 1,1016 | |
| 0,7000 | 1,3161 | 1,1059 | ||||
| 1,0000 | 0,8423 | 1,4187 | 1,1454 | 1,2183 | 1,1232 | |
| 2,0000 | 0,6978 | 1,9135 | 1,2362 | 1,2849 | 1,1750 | |
| 3,0000 | 0,5749 | 2,6936 | 1,2834 | 1,3095 | 1,2355 | |
| 3,5000 | 0,5174 | 3,1728 | 1,2687 | 1,2839 | 1,2649 | |
| 5,1000 | 0,3668 | 4,8993 | 1,0982 | 1,0851 | ||
| 7,7500 | 0,1929 | 7,1468 | 0,5907 | 0,5639 | ||
| 10,4200 | 0,0821 | 6,2716 | 0,1978 | 0,1831 | ||
| 14,0823 | 0,0000 | -4,8622 | 0,0000 | 0,0000 |
Таблица 6
Результаты оценок вязкости раствора LiCl
| C mol/l | теор (29) | теор (41) | теор (41а) | теор (42) | лит [10] | лит [12] | эксп |
| 0,0000 | 0,9433 | 1,0619 | 0,9481 | 1,0177 | 0,8937 | 0,9125 | |
| 0,0010 | 0,9697 | 1,1013 | 0,9848 | 1,0191 | 0,8586 | ||
| 0,0050 | 0,9923 | 1,1322 | 1,0143 | 1,0211 | 0,9228 | ||
| 0,0100 | 1,0098 | 1,1518 | 1,0334 | 1,0227 | 0,9024 | ||
| 0,0500 | 1,0859 | 1,2031 | 1,0861 | 1,0308 | |||
| 0,1000 | 1,1319 | 1,2055 | 1,0933 | 1,0380 | 0,9613 | ||
| 0,1250 | 1,0412 | 0,9044 | 0,9663 | ||||
| 0,2500 | 1,0552 | 0,9221 | 0,9928 | ||||
| 0,5000 | 1,3199 | 1,1422 | 1,0571 | 1,0790 | 0,9534 | 1,0156 | 1,0337 |
| 0,6000 | 1,3563 | 1,1326 | 1,0519 | 1,0877 | |||
| 1,0000 | 1,4811 | 1,0947 | 1,0292 | 1,1204 | 1,0212 | 1,0628 | 1,0986 |
| 1,2300 | 1,5612 | 1,0844 | 1,0256 | 1,1381 | |||
| 2,0000 | 1,7879 | 1,0143 | 0,9759 | 1,1942 | 1,2208 | ||
| 2,5140 | 1,9657 | 0,9835 | 0,9557 | 1,2301 | 1,1504 | ||
| 3,0000 | 2,1701 | 0,9770 | 0,9575 | 1,2632 | |||
| 3,5000 | 2,4112 | 0,9883 | 0,9766 | 1,2969 | |||
| 5,1000 | 3,4014 | 1,1418 | 1,1556 | 1,4030 | |||
| 7,7500 | 6,4663 | 2,1229 | 2,2235 | 1,5781 | |||
| 10,4200 | 15,1968 | 6,3379 | 6,8471 | 1,7584 | |||
| 14,0823 | 2,0172 |
Таблица 7
Результаты оценок электропроводностей, функции от среднемолярного коэффициента активности, степени диссоциации, параметр экранирования и функции распределения для раствора NaCl
| C mol/l | лит [13, 10] | (36) | (37) | | | | f |
| 0,0000 | 126,45 | 126,4452 | 126,4559 | 0,0000 | 1,0000 | 1,0000 | 1,0000 |
| 0,0010 | 123,74 | 123,8839 | 124,1052 | -0,0160 | 0,9786 | 1,0100 | 0,9930 |
| 0,0030 | 121,93 | 122,1710 | 122,5421 | -0,0264 | 0,9643 | 1,0173 | 0,9879 |
| 0,0050 | 120,64 | 120,9423 | 121,4142 | -0,0329 | 0,9541 | 1,0223 | 0,9844 |
| 0,0100 | 118,53 | 118,9344 | 119,5879 | -0,0435 | 0,9374 | 1,0316 | 0,9780 |
| 0,0500 | 111,06 | 111,7609 | 113,1362 | -0,0731 | 0,8783 | 1,0706 | 0,9515 |
| 0,0700 | 109,62 | 110,3868 | 111,9977 | -0,0784 | 0,8669 | 1,0836 | 0,9428 |
| 0,1000 | 106,74 | 107,5453 | 109,4273 | -0,0825 | 0,8441 | 1,0999 | 0,9320 |
| 0,2000 | 101,71 | 102,5226 | 105,0841 | -0,0829 | 0,8043 | 1,1412 | 0,9053 |
| 0,5000 | 93,62 | 94,0614 | 97,8557 | -0,0551 | 0,7404 | 1,2233 | 0,8544 |
| 1,0000 | 85,76 | 85,3416 | 90,3338 | 0,0092 | 0,6782 | 1,3158 | 0,8005 |
| 1,5000 | 79,86 | 78,5873 | 84,3315 | 0,0894 | 0,6316 | 1,3868 | 0,7614 |
| 2,0000 | 74,71 | 72,6592 | 78,8992 | 0,1885 | 0,5908 | 1,4467 | 0,7300 |
| 3,0000 | 65,57 | 62,2472 | 68,9945 | 0,4430 | 0,5185 | 1,5470 | 0,6801 |
| 4,0000 | 57,23 | 53,0225 | 59,8362 | 0,7554 | 0,4526 | 1,6317 | 0,6408 |
| 5,0000 | 49,46 | 44,7258 | 51,3076 | 1,0944 | 0,3911 | 1,7062 | 0,6080 |
| 5,5203 | 1,2691 | 1,7421 | 0,5928 |
Таблица 8
Результаты оценок коэффициента диффузии раствора NaCl
| C mol/l | Dтеор (30) | Dтеор (35) | Dтеор (38) | Dтеор (40) | Dлит [10] | Dлит [11] |
| 0,0000 | 1,4539 | 1,3912 | 1,3912 | 1,4539 | 1,3910 | |
| 0,0010 | 1,4227 | 1,3690 | 1,3535 | 1,4103 | 1,3694 | 1,3738 |
| 0,0030 | 1,4019 | 1,3546 | 1,3300 | 1,3830 | 1,3565 | 1,3565 |
| 0,0050 | 1,3871 | 1,3455 | 1,3144 | 1,3649 | 1,3478 | 1,3478 |
| 0,0100 | 1,3628 | 1,3307 | 1,2904 | 1,3367 | 1,3349 | 1,3392 |
| 0,0500 | 1,2769 | 1,2895 | 1,2242 | 1,2559 | 1,3020 | 1,3046 |
| 0,0700 | 1,2604 | 1,2821 | 1,2181 | 1,2460 | 1,3046 | 1,3046 |
| 0,1000 | 1,2273 | 1,2764 | 1,2017 | 1,2250 | 1,2813 | |
| 0,2000 | 1,1694 | 1,2760 | 1,1920 | 1,2057 | ||
| 0,2200 | 1,2775 | 1,2787 | ||||
| 0,5000 | 1,0764 | 1,3146 | 1,2086 | 1,2085 | ||
| 0,5700 | 1,3259 | 1,2701 | 1,2701 | |||
| 1,0000 | 0,9861 | 1,4040 | 1,2493 | 1,2395 | 1,2822 | 1,2787 |
| 1,5000 | 0,9182 | 1,5157 | 1,2874 | 1,2741 | ||
| 2,0000 | 0,8590 | 1,6536 | 1,3216 | 1,3078 | 1,3098 | |
| 3,0000 | 0,7539 | 2,0075 | 1,3724 | 1,3631 | 1,3522 | |
| 4,0000 | 0,6580 | 2,4422 | 1,3787 | 1,3781 | 1,3772 | |
| 5,0000 | 0,5687 | 2,9138 | 1,3259 | 1,3358 | 1,3738 | |
| 5,5203 | 3,1569 |
Таблица 9
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