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As in (4.2), ψ (x) is the ground state wave function that satisfies
(T+V(x))ψ(x)=Eψ(x), | (4.79) |
which can also be written in the same form as (1.14)
| (4.80) |
with
| (4.81) |
Here, unlike (1.32), V (x) can now also be asymmetric. Taking the difference between ψ (x) times (4.75) and χ (x) times (4.80), we derive
| (4.82) |
Introduce
ψ(x)=χ(x)f(x), | (4.83) |
in which f (x) satisfies
| (4.84) |
On account of Figs. (4.82) and (4.83), the same equation can also be written as
| (4.85) |
Eq. (4.80) will again be solved iteratively by introducing
ψn(x)=χ(x)fn(x) | (4.86) |
with ψn and its associated energy determined by
| (4.87) |
and
| (4.88) |
In terms of fn (x), we have
| (4.89) |
On account of (4.88), we also have
| (4.90) |
and
| (4.91) |
For definiteness, let us assume that
Ea>Eb | (4.92) |
in Figs. (4.69a) and (4.69b); therefore and
, in accordance with (4.76a). Start with, for n = 0,
f0(x)=1, | (4.93) |
we can derive {En} and {fn (x)}, with
| (4.94) |
by using the boundary conditions, either
| (4.95) |
or
| (4.96) |
It is straightforward to generalize the Hierarchy theorem to the present case. As in Section 3, in Case (A), the validity of the Hierarchy theorem imposes no condition on the magnitude of . But in Case (B) we assume
to be not too large so that (4.91) and the boundary condition fn (−∞) = 1 is consistent with
fn(x)>0 | (4.95) |
for all finite x. From the Hierarchy theorem, we find in Case (A)
E1>E2>E3> | (4.96) |
and
1 | (4.97) |
while in Case (B)
E1>E3>E5> | (4.98) |
E2<E4<E6< | (4.99) |
1 | (4.100) |
and
1 | (4.101) |
A soluble model of an asymmetric square-well potential is given in Appendix A to illustrate these properties.
5. The N-dimensional problem
The N-dimensional case will be discussed in this section. We begin with the electrostatic analog introduced in Section 1. Suppose that the (n − 1)th iterative solution fn − 1 (q) is already known. The nth order charge density σn (q) is
| (5.1) |
in accordance with Figs. (1.23) and (1.24). Likewise, from Figs. (1.26) and (1.29) the dielectric constant κ of the medium is related to the trial function (q) by
κ(q)= | (5.2) |
and the nth order energy shift is determined by
| (5.3) |
In the following we assume the range of w (q) to be finite, with
w(∞)=0 | (5.4) |
and
0 | (5.5) |
Introduce
| (5.6) |
where δ (w (q) − W) is Dirac’s δ-function, W is a constant parameter and the integrations in Figs. (5.3) and (5.6) are over all q-space. Similarly, for any function F (q), we define
| (5.7) |
In the N-dimensional case, the generalization of [F], introduced by (3.15), is
| (5.8) |
In terms of Fav (W), (5.8) can also be written as
| (5.9) |
Thus from Figs. (5.1) and (5.3) we have
| (5.10) |
the n-dimensional extension of (3.14).
Following Figs. (1.27) and (1.28), the nth order electric field is and the displacement field is
| (5.11) |
The corresponding Maxwell equation is
| (5.12) |
Eqs. Figs. (5.11) and (5.12) determine fn except for an additive constant, which can be chosen by requiring
| (5.13) |
Therefore,
fn(q) | (5.14) |
As in the one-dimensional case discussed in Section 3, (5.10) gives the same condition of fine energy tuning at each order of iteration. It is this condition that leads to convergent iterative solutions derived in Section 3. We now conjecture that
| (5.15) |
and
| (5.16) |
also hold in higher dimensions. Although we are not able to establish this conjecture, in the following we present the proofs of the N-dimensional generalizations of some of the lemmas proved in Section 3.
Lemma 1
For any pair fm(q) and fl(q) if at all W within the range (5.5),
| (5.17) |
and
| (5.18) |
Proof
For any function , define
| (5.19) |
Thus for any function F (q), we have
[F(q)]= | (5.20) |
therefore,
| (5.21) |
and
| (5.22) |
By setting the subscript n in (5.10) to be m + 1, we obtain
| (5.23) |
Also by definition (5.19),
| (5.24) |
The difference of Figs. (5.23) and (5.24) gives
| (5.25) |
From (5.10) and setting the subscript n to be l + 1, we have
| (5.26) |
Regard and
as two constant parameters. Multiply (5.25) by
, (5.26) by
and take their difference. The result is
| (5.27) |
analogous to (4.43).
(i) If , then for
| (5.28) |
Thus, the function inside the bracket
in (5.21) is positive, being the product of two negative factors,
and
. Also, when
, these two factors both reverse their signs. Consequently (5.17) holds.
(ii) If , we see that for
, (5.28) reverses its sign, and therefore the function inside the bracket
in (5.27) is now negative. The same negative sign can be readily established for
. Consequently, (5.18) holds and Lemma 1 is established.
Lemma 2
Identical to Lemma 2 of Section 3.
In order to establish the N-dimensional generalization of Lemma 3 of Section 3, we define
| (5.29) |
Because of (5.3), Qn (W) is also given by
| (5.30) |
We may picture that the entire q-space is divided into two regions
| (5.31) |
and
| (5.32) |
with Qn (W) the total charge in I, which is also the negative of the total charge in II. By using Figs. (5.1) and (5.7), we see that
| (5.33) |
Lemma 3
For any pair fm (q) and fl (q) if at all W within the range (5.5)
| (5.34) |