Диссертация (1145462), страница 26
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B. 2006. V. 116. P. 23-28.174. Esbensen K., Kirsanov D., Legin A., Rudnitskaya A., Mortensen J., Pedersen J.,Vognsen L., Makarychev-Mikhailov S., Vlasov Y. Fermentation monitoring usingmultisensor systems: Feasibility study of the electronic tongue // Anal. Bioanal. Chem.2004. V 378 (2). P. 391-395.175. Peris M., Escuder-Gilabert L. On-line monitoring of food fermentation processesusing electronic noses and electronic tongues: A review // Anal.
Chim. Acta. 2013. V.804. P. 29-36.176. Hu N., Ha D., Wu C., Zhou J., Kirsanov D., Legin A., Wang P. A LAPS array withlow cross-talk for non-invasive measurement of cellular metabolism // Sens. Actuat. A.2012. V. 187. P. 50-56.172ПРИЛОЖЕНИЕ 1.Таблица 1. Параметры искусственных нейронных сетей, использованные вэксперименте по увеличению селективности определения лантанидов в смесях.СмесьИНС по стационарнымИНС по динамическимданнымданнымSm-EuSm-GdEu-GdSm-EuSm-GdТип сетис обратным распространением ошибокАлгоритм обученияРегуляризация по БайесуСкорость обученияα=0.01Число нейронов вовходном слоеЧисло скрытых слоевЧисло нейронов вскрытом слоеПередаточная функция вскрытом слоеЧисло нейронов ввыходном слоеПередаточная функция ввыходном слоеОбщее СКО в обучающемнабореОбщее СКО в тестовомнабореEu-Gd888808080111111544745logsiglogsiglogsiglogsigtansiglogsig222222purelintansigpurelinpurelinpurelinpurelin2.7·10-52.8·10-52.1·10-52.5·10-52.9·10-52.7·10-54.2·10-55.6·10-55.1·10-52.9·10-53.3·10-54.5·10-5173Таблица 2.Исходные данные от мультисенсорной системы (величиныпотенциалов сенсоров), использованные для прогнозирования значений ХПК спомощью ПЛС-регрессии.Образецs1s2s3s4s5s6s7s8s9s10s11s12s13ХПКw1181,9123,5132,3154,8146,0-26,9155,1110,2178,1130,4133,098,9165,662,0w2189,5172,9122,0155,8142,19,6157,1121,3187,1140,0139,5106,6170,965,3w3185,4164,3133,4154,7147,6-15,9165,5137,9200,2151,3146,4103,4172,991,4w4203,6181,7140,8172,2153,147,2177,8157,0219,3170,0164,6124,0193,7104,5w5163,890,1121,7135,0131,7-50,4154,5113,6185,5124,1123,180,2154,791,4w6180,6161,3113,7143,8132,74,5156,0129,0195,3138,8136,4103,3165,6101,2w7203,6199,1162,2167,6171,2-10,7149,695,6148,5126,3123,087,4156,959,1w8222,9227,1188,0187,5197,46,9183,7128,5172,2149,2149,1111,1179,236,1w9217,7216,6181,4185,8188,41,3185,3130,0178,8150,6148,9119,2180,029,5w10194,9193,6150,4162,4160,5-7,7159,6107,7154,9127,2121,990,4152,946,0w11244,4239,3209,4218,3203,721,9195,9145,3177,0179,4167,7136,3192,226,1w12217,1212,8180,4187,1182,716,4156,9106,3157,9140,1137,8104,7170,632,7w13205,7190,4152,6179,7166,7-9,3142,593,8154,1125,3129,299,0159,835,9w14221,2213,2169,7191,1179,117,0160,5113,8168,2143,5141,9109,2174,219,6w15200,5218,9193,2184,5180,3-10,4161,8114,4160,7144,4147,187,0174,342,5w16201,1222,3196,6183,2182,5-8,6163,3115,5161,1144,4147,789,7175,339,4w17165,4164,4129,0156,2140,3-5,0146,6109,1175,6137,4129,2124,9158,888,2w18157,0109,8147,2146,9143,1-43,5153,7102,0165,0124,7125,684,7157,694,7w19211,0197,5160,6171,2174,0-10,4178,8132,0179,4140,2133,388,2168,326,3w20227,8219,1181,0189,3188,614,3159,7113,2156,7144,7143,6109,2175,519,7w21194,4193,7158,0164,5156,627,7175,2164,5185,6157,2151,4109,7182,262,4w22215,8201,1181,9186,8175,0-3,6205,2220,0207,0191,4179,8139,7198,559,1w23175,7127,2164,4162,9157,5-38,0149,193,4161,0127,2130,087,0162,745,7w24185,3171,1161,9169,8162,1-25,4159,0110,2171,4134,4136,7101,4169,249,0w25188,9189,4175,7166,1166,6-25,9163,0113,9169,2142,0143,3105,7177,152,3w26191,1148,6180,6159,8169,2-33,5165,0119,1163,8137,8138,195,9171,145,7w27177,3104,1143,0155,6140,6-22,3163,4118,7175,7136,4136,494,8169,452,3w28182,2119,1145,3145,7151,8-38,3155,7112,0172,8131,1129,990,9162,765,3w29226,0220,6197,6188,8195,73,9181,0124,8165,8153,2154,4107,1174,426,1w30205,1159,9180,5177,3181,9-36,2162,099,8141,3128,9129,793,3161,826,1w31207,0158,3178,0180,9182,2-29,5152,891,9145,1131,9133,1107,2165,326,1w32208,0161,1177,1181,2182,6-36,5151,089,9144,2129,2133,1101,9165,426,1w33223,3216,7180,7183,0189,519,8184,3125,3170,6150,5148,9106,7176,319,6174w34226,9216,0187,6195,8194,11,8174,6119,3174,5153,6155,8108,4184,419,6w35232,6238,0206,0198,0210,01,2181,6121,3160,1154,9156,7121,0187,219,6w36240,7244,0198,1206,6210,541,1178,6136,7165,9166,7162,2125,1191,319,6w37183,9163,7138,9155,1146,2-20,1160,1149,5225,9141,1144,0101,4173,784,9w38169,7131,3125,8147,4131,6-26,6154,5137,1212,9128,3130,096,9162,978,4w39203,2203,0199,1173,9190,2-22,3164,499,1148,7132,6132,295,8164,819,6w40201,0224,0166,0164,0181,1-9,0162,1115,2144,2128,2117,283,5151,122,9w41204,0178,0141,8172,3148,441,3175,1171,2244,8169,6166,8135,1195,681,6w42166,0143,4107,5133,2117,6-15,8149,3126,4199,0117,2121,079,0147,394,7w43166,496,5127,2133,2133,2-39,0154,6132,4207,9127,4127,495,6159,998,0w44158,787,3123,4135,1124,3-37,9149,1126,1204,3122,9124,186,4156,894,7w45165,5145,6109,3127,8121,1-14,6143,0127,6204,4120,5118,492,5145,398,0w46194,9174,7136,4161,9151,35,0174,4155,4230,4149,6150,0128,3179,794,7w47206,6174,2146,0172,7153,0-5,5176,8177,5245,6183,5175,4141,7192,8117,6175Таблица 3.
Исходные данные от мультисенсорной системы (величиныпотенциалов сенсоров), полученные при анализе ферментационных растворовE. coli.ОбразецC1C2C3C5C7C8C10C11A1A3A5A8A12Sol1-2170,0175,9112,7202,9112,435,2244,97,645,630,1-10,5-23,834,3-303,92-299,5160,7110,1202,594,7-28,5240,8-284,348,143,4-108,3-27,141,9-278,83-2103,9-29,996,8193,971,833,1252,0-287,832,028,3-100,3-51,433,1-271,54-2118,19,885,3183,5-43,5-83,1238,4-310,36,3-17,5-17,9-78,530,6-316,85-2104,853,780,7183,970,331,0233,0-287,323,6-37,0-21,4-83,914,4-343,46-2243,0107,690,4192,192,069,3230,5496,933,9-23,2-12,0-87,521,2-354,37-2242,9109,488,8187,238,815,2223,7431,021,3-45,7-8,3-90,517,2-353,48-2214,7120,973,4174,6-39,5-140,2215,5373,219,1-88,18,9-130,211,5-358,19-2235,4113,568,7194,2-20,8-7,0206,4359,414,4-39,1-4,1-109,936,0-360,810-2181,9106,659,8183,4-69,3-93,8198,5336,6-36,7-72,8-11,0-154,115,7-376,211-2188,579,561,8176,0-167,1-193,9188,7256,1-48,9-86,4-12,9-148,427,7-377,71-8113,5-130,930,4-137,4-38,9-37,9-39,7-149,045,9-17,0-203,94,4-284,7-221,72-893,3-22,221,0-165,8-238,9-65,8-59,5-462,336,1-42,6-101,8-52,7-284,4-258,03-8122,2-89,0-123,9-54,8-202,4-100,0-131,2-272,519,9-70,2-248,7-74,7-284,5-266,84-8-61,2-127,4-159,3-163,6-246,9-174,7-111,4-389,430,2-70,3-359,2-71,7-274,4-266,55-8-127,0-89,7-57,3-114,2-153,6-63,8-84,8-442,017,4-62,6-200,0-86,9-267,4-264,46-8-38,7-136,0-88,5-142,9-167,5-183,4-83,7-295,426,4-42,4-274,3-100,6-272,8-257,97-8-114,9-149,9-140,8-163,3-167,4-136,9-187,9-298,231,1-30,4-298,6-130,5-285,1-266,88-8-115,0-108,1-178,5-142,2-187,0-186,5-195,5-359,94,2-64,3-256,5-171,1-298,0-273,49-8-82,0-90,1-35,5-92,6-179,6-126,5-104,6-319,96,1-77,9-295,5-155,9-302,3-289,110-8-106,4-160,9-138,8-165,4-174,7-211,0-178,9-278,08,7-71,1-263,8-135,3-278,0-307,7176Таблица 4.
Исходные данные от мультисенсорной системы (величиныпотенциалов сенсоров), полученные при анализе томатов. Кодировка образцов: C– Санстрим, D – Аморосо, E – Триша, F – Клотиль.ОбразецsA2sA3sA4sA7sA8sA11sA13sC4sC9sC10sC11sA5sA12sC7spHC244,0235,4181,6120,4265,3333,9329,5288,7174,6234,2101,7319,5334,4231,515,5C250,0243,8187,6121,9273,4331,3330,6280,7169,7224,795,2316,6333,0228,525,3C254,4250,7195,6124,0278,7327,0332,8281,9168,5221,194,6310,9328,6232,613,3C252,3250,5189,0131,1275,5322,3331,3280,3168,0221,193,3307,0324,6231,39,3C252,0236,6187,2122,6274,3327,0320,3280,2169,0232,4100,5314,2327,6229,7-1,3C254,3246,5206,4118,8282,9317,4321,5284,2169,3229,2101,5308,7321,7233,0-24,0C255,2250,0202,9120,4283,7316,1322,4281,9167,4226,4100,2307,1320,6229,0-20,6C252,0249,4194,5112,4272,4312,4324,1280,0174,1233,3100,7299,7317,1234,616,2C257,6258,6202,3127,3279,3318,9328,1273,6164,8222,790,9302,9322,6229,814,0C254,6256,3196,6114,0276,8308,7327,2282,3175,4232,899,6295,5312,3238,213,9D232,4221,9174,1122,0253,6332,0319,2301,9184,9247,3116,8313,9333,1237,832,8D238,4226,3177,6124,2257,8332,9320,3301,0183,1243,6111,6312,0334,1239,421,1D243,3236,4176,9119,4265,5323,0320,1294,3179,5234,0104,9302,5326,9239,813,8D245,0236,3176,0119,9266,5320,7318,6295,7178,8233,3104,2298,7323,0241,011,7D241,6223,9179,5122,6261,6322,3310,6296,4178,2243,6111,0307,9326,7238,8-3,6D242,7224,8172,8118,1260,8319,0309,9297,9180,2245,3112,6303,4321,8240,7-14,4D236,9226,9199,9122,0253,6319,1309,5295,1181,6244,3110,4297,6323,2235,920,6D243,4233,3188,6118,1261,0311,9311,3293,9183,4245,6111,0295,3318,3241,411,6D248,0246,7189,7121,3268,2308,4316,1285,1174,0232,1100,0288,4312,4238,6-5,1D247,7246,5186,3121,4267,8317,2314,9284,8174,5231,9100,2284,8312,8238,87,1E254,5244,7191,5131,0276,8341,5332,1268,7159,4218,188,1328,2343,2219,218,6E255,2251,4194,1125,1279,0331,6332,2272,5162,6217,990,1319,5332,0226,721,6E248,5233,0193,8133,0270,7339,3322,1273,9165,1232,4100,7329,1338,3221,621,2E259,8249,0201,3133,0283,7331,5323,2271,4157,9219,592,1319,0333,4222,7-4,3E264,3255,8215,7135,9292,9330,9323,0266,3153,9213,789,1316,8332,3221,7-11,4E262,8255,9212,8132,7291,3327,0323,8267,5156,0215,591,3315,9329,9221,1-7,9E259,1253,9203,7134,2276,6331,5325,7262,6155,9217,484,7315,3333,3217,614,2E257,3257,5204,0124,2277,6321,3326,7263,7160,4219,589,2307,4326,7224,310,7E261,4261,8206,6133,4282,8325,1328,0261,7155,8213,782,2307,1327,3223,910,6E261,7263,0206,3128,3283,2321,2330,7265,9160,8218,986,8307,2324,4228,115,1F250,7247,2187,6130,4274,8331,9326,4274,2164,4218,993,3315,1331,9229,817,7F243,5228,8196,9130,7262,7341,1316,8283,4173,5240,8114,2326,2342,2224,031,9177F247,3231,9184,7124,1267,8329,8313,2281,3169,7234,3103,6313,2332,0232,1-12,6F247,8235,9190,9124,2270,3324,6311,3280,7167,3229,2100,6308,3328,9229,5-29,4F252,7241,5196,0134,1275,2329,0314,9279,4164,5226,098,2314,6332,8227,0-2,6F254,0242,4190,3130,2275,1324,4315,1280,7164,4225,898,2310,5328,5228,9-13,7F247,3240,1195,5125,7263,5324,1314,5275,1168,3230,897,1306,9325,9228,511,6F251,0243,3195,5127,8268,4324,4316,1273,6166,7228,595,6307,4327,3227,111,6F252,4252,0200,3125,2272,9319,0319,9272,6166,0224,794,1302,1324,5229,77,6F254,7254,2200,6129,2275,3318,6319,3272,1163,4221,490,3298,6319,0229,84,0178Таблица 5.
Исходные данные от мультисенсорной системы (величины потенциалов сенсоров), полученные при анализеобразцов пива. Кодировка образцов: В1 – образцы класса “geuze”, B2 – образцы одинарной ферментации, UKN –неизвестные образцы.Образцыs1s2s3s4s5s6s7s8s9s10s11s12s13s14s15s16s17s18s19s20s21s22s23s24s25s26s27s28B1120,8205,3239,9308,8289,8375,4262,1386,4355,6179,0327,347,3280,1117,7268,885,3137,259,5295,5273,9217,8254,1104,4217,417,217,4111,7-319,8B1121,3197,9234,6303,9281,5377,3250,0410,6356,9164,8325,552,3280,5120,1269,082,4138,758,3293,6273,9218,2258,5166,7212,113,914,3111,0-320,9B1117,3197,7242,7301,1279,5368,6253,6406,6351,8180,8323,459,2277,8121,1280,171,5137,448,9288,7271,5211,3259,6172,0192,68,411,698,8-328,4B1116,3195,5236,1300,8282,0369,4253,9395,7354,8186,9322,064,9277,3120,9289,972,3136,754,0290,4272,5210,0261,4171,4193,19,714,6110,5-319,0B1112,3211,6238,1307,3294,1373,3251,9384,1352,8181,6335,930,8278,8115,4263,480,3130,361,9294,3273,0212,4253,0102,0228,112,112,895,7-333,9B1111,7206,6229,5302,4283,3375,8247,9398,6351,0169,9335,144,9279,1119,7266,378,7133,361,8294,4273,2214,3255,8140,7227,613,312,5117,1-323,7B1107,6205,1232,3300,0281,1365,5246,8399,7343,7182,2331,962,6276,2119,9272,969,5132,946,6288,1271,6207,8258,7156,8199,26,610,9111,9-336,6B1107,3197,0229,3297,1279,9366,8245,1405,9352,1186,3332,263,7274,3119,9286,963,2130,059,1290,8271,4206,1262,1176,9198,64,711,991,2-323,6B293,7208,7194,9278,9274,5346,6213,5368,2301,0177,7334,543,8273,0130,4271,889,5148,481,5295,6283,3232,8259,097,7194,215,716,6106,6-348,2B293,5197,2192,8273,9265,1349,7205,8376,0310,4163,6334,649,8276,6132,0271,188,1147,579,3296,4282,8232,8260,3120,8194,113,014,3102,7-345,2B289,4190,1200,1279,6255,5337,2212,1381,6300,1154,7330,160,9269,2130,7272,972,2152,068,5290,3278,9231,3262,3131,9166,14,48,0102,3-350,7B288,0191,6195,1277,5257,1333,4212,2372,3299,6164,4329,561,1271,0130,7283,074,3146,760,4290,9281,8225,8261,5139,5167,86,09,8102,9-344,5B289,6207,5198,5282,0268,2350,4221,2380,0306,8141,6327,537,2269,7138,9281,570,1153,389,9293,3282,8239,1264,7140,5171,98,011,2101,1-350,5B288,8182,5197,2274,9260,9348,1213,6387,4309,1144,9327,144,9264,5138,4280,564,4151,593,9293,0281,0236,3264,0165,5166,04,93,789,4-353,2B289,6186,8195,2275,3258,6344,3210,7388,1306,7129,3325,940,4263,6133,3264,256,2147,988,3288,4279,5231,6265,1166,0167,34,44,4102,5-348,6B287,7169,2193,1288,2257,4337,6209,9374,4296,1121,5321,944,6255,7133,0264,152,5144,575,4286,8277,1227,0263,4141,9170,54,92,0102,0-363,7B291,1168,4189,9282,9260,3339,0211,0350,4290,2128,7326,441,8256,6133,3246,849,6145,257,1287,3276,6223,2263,9108,5163,84,41,997,9-384,0B287,9171,9190,7287,3260,8334,6211,4345,7287,6141,1320,947,9251,2129,0258,350,1138,361,1286,1275,6221,4261,1100,6165,73,20,987,1-385,7B273,0217,3187,1282,2262,9334,0206,7347,3293,9161,8333,139,5260,6119,3259,675,9134,167,0282,6279,1222,8247,388,2195,71,79,778,0-361,0B272,2197,3182,4269,6256,0333,6197,9360,1299,1151,2336,346,1261,3117,0255,574,1126,863,3282,5277,4211,9248,595,1192,7-2,43,966,2-362,5B269,5199,5185,5267,9246,0318,9200,6354,7290,9155,1331,855,1254,7116,5256,463,5129,450,8275,2273,6209,9249,0107,7172,5-7,1-2,170,1-370,5B267,8177,9180,4257,7243,2323,3194,4375,8300,4149,4331,860,7258,2117,0277,653,3125,659,5279,2274,5206,2254,9148,2171,5-10,23,060,0-366,6B268,6212,2189,4272,7260,0332,6208,4361,8295,0137,6328,132,0252,6118,9268,660,2132,169,9277,9276,8218,7251,8121,1173,0-5,42,876,7-369,9B267,4182,0183,9263,8253,7331,5203,0374,4300,2138,6328,046,3251,3120,1266,652,5127,679,9278,2276,1215,6251,2153,7172,5-8,6-6,666,5-367,9B267,0190,3185,7261,7248,8324,9197,9380,0297,2137,1326,832,2248,5115,3253,743,5125,270,2273,4271,8210,8253,6158,8172,3-10,4-8,472,1-371,9B266,4162,0180,8270,3245,5324,2195,3361,9290,0106,4322,340,9242,7117,1242,335,9123,841,0273,5270,4208,3255,0128,0174,4-9,7-10,562,6-387,0B270,8172,5178,9273,7249,6321,1198,3338,7281,7112,5326,333,8239,6115,3235,736,3123,948,0272,5269,4205,8253,894,3168,5-9,0-11,168,8-395,3B266,7144,0174,1259,2248,6319,8196,1333,5281,4132,3324,250,6243,2121,9248,831,2116,043,6274,0271,4198,6254,885,4168,0-12,3-9,060,8-394,7UKN1108,5221,2242,9309,8294,6381,1263,4401,8353,0165,2328,941,9272,2128,0276,965,4134,778,5291,6274,3218,7260,7163,2198,67,112,697,5-324,3UKN2107,0209,2240,7306,4290,4376,2254,1403,7350,0169,3328,046,8268,7122,9272,761,0128,474,1289,0272,7213,7257,5165,8198,45,77,4103,7-323,7UKN3106,9205,2238,3308,8287,6373,7253,9425,5353,2157,4326,235,5265,9127,9267,345,6127,367,5286,8270,1210,6261,6190,1206,07,02,395,5-329,8UKN4105,3194,8229,5308,1283,7366,2247,6397,7340,4146,5326,143,6263,7121,4252,442,5125,545,6283,7267,5207,1259,1156,9195,25,42,690,5-359,8UKN5109,4188,7225,3306,6288,1368,2243,2363,4330,5157,6327,748,0261,9121,5243,741,4124,240,4285,0267,7203,4261,1102,7196,95,13,882,4-376,0UKN6104,4189,5227,9309,1289,9371,6246,6356,5326,6177,1323,756,7257,4115,8253,144,3117,836,1280,7267,5194,2253,991,0197,68,46,698,8-369,1UKN771,4221,2222,2298,3287,9360,9241,9382,7330,4164,6334,842,1264,6118,9267,654,5120,268,6277,6276,1214,7252,4128,0185,6-2,95,478,4-355,0UKN869,3211,5224,4298,5287,4358,8241,4394,7337,5170,1339,132,6261,9117,1267,045,1113,565,3275,5270,0213,6251,1156,1185,3-4,3-2,260,3-358,6UKN970,3199,3216,0290,3278,4357,0227,2403,0334,4149,8333,835,3259,5117,6254,732,7116,460,7273,4270,3208,4254,2177,6187,9-5,2-3,779,5-359,8UKN1068,5188,4213,7293,5275,6347,2229,1381,9322,6140,1330,931,5255,8112,9244,228,7111,634,0270,3266,7203,8252,7142,4189,3-6,3-6,960,2-384,7UKN1172,4186,3212,3295,4278,5349,5231,0352,5312,3153,0332,043,6254,5115,6240,530,6114,333,6272,9268,4199,9253,696,9181,5-5,2-6,772,5-387,0UKN1268,5170,5210,0289,9277,8342,6223,8345,0310,2159,1330,247,7252,5117,8254,323,8108,238,8271,7266,8197,2253,986,8180,8-10,1-7,060,6-392,3UKN13118,0216,4243,4309,2292,7382,3265,9407,5356,7163,2320,646,4274,1128,3285,669,6138,774,3291,7274,7222,6261,2158,7192,313,215,1105,2-322,4UKN14115,4212,8247,3307,7292,1376,0268,1399,1351,7169,7318,951,7272,1122,6278,468,5136,581,8288,1272,8218,2258,2142,2190,212,112,6112,0-325,3UKN15116,3202,4238,5309,1286,0377,9257,3428,8355,3153,5318,643,6268,3128,0271,051,8134,272,3286,1270,8215,9263,8202,7195,211,46,6106,1-323,9UKN16115,0188,9233,7309,2284,3372,9253,7403,7346,0147,1318,248,2267,1126,6265,550,4132,449,1286,0268,6212,2262,8166,4194,410,89,0105,8-353,0UKN17118,3186,5232,5309,5290,4371,2252,4365,8334,8162,4321,253,1264,0123,0256,747,8130,437,6285,0267,6207,7261,3103,5187,911,48,299,0-373,5UKN18115,7176,6232,3303,6285,0363,6252,4361,6330,3164,9316,258,0261,7127,2257,942,4126,549,4284,4268,5205,0262,994,5181,17,07,987,7-376,3180.
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