Термодинамические свойства кристаллических фаз, образующихся при получении глинозема методом Байера, страница 19

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№. 7. P. 1367–1376. 1138. ПРИЛОЖЕНИЕ Таблица 9.1 Элементный состав Na-КАН по результатам РСМА (в ат%) NaAlSiTi13.668.708.7913.2111.4711.5611.938.688.4713.469.829.9313.589.088.7411.0510.1010.2113.588.698.3913.318.618.4812.4010.1310.6814.059.529.4013.959.299.2812.9710.7310.9712.319.9510.0712.709.059.3913.3110.3510.5813.0210.5311.2413.478.398.4413.808.218.4213.668.538.2213.928.778.5811.9011.3712.7914.299.348.9513.648.818.4514.049.509.4212.8111.9310.4913.1810.2110.2913.789.228.9914.319.359.590.0813.838.728.500.08CaFeMg0.250.110.050.160.050.090.070.85K114Продолжение таблицы 9.1 NaAlSiTi14.159.929.830.0713.849.519.5314.1210.5410.3613.9411.0011.2613.3910.6711.1013.989.9910.3613.8610.4910.3913.959.699.9413.929.749.6514.018.708.0913.7910.0110.7614.128.758.9113.179.769.5913.3610.1511.3013.669.859.7414.298.488.9012.759.739.7514.649.939.5812.1211.9613.1314.239.9110.3013.999.7211.3613.1010.6210.5113.959.319.7113.8210.8211.6713.3811.1111.6613.789.579.3114.408.858.6412.5211.0311.9413.589.0110.1613.5310.3711.0711.9311.8213.5213.719.429.580.14CaFeMgK115Продолжение таблицы 9.1 NaAlSiTiCaFe11.878.428.5713.678.878.6614.419.088.7014.279.9210.5014.279.899.9714.009.169.0714.429.399.7914.049.179.2914.558.858.5414.1411.0512.0213.218.208.5411.178.739.0613.037.607.6512.9912.1714.4812.908.878.9913.199.669.790.2711.749.219.630.0712.887.297.1111.779.2710.0812.887.647.3912.548.628.6811.899.9110.6613.829.3410.5913.8410.7411.8714.079.7610.0312.798.258.350.0411.697.127.500.190.33MgK2.850.140.330.09116Таблица 9.2 Зависимость удельной теплоемкости (в Дж·г−1·К−1) от температуры (в К)для образца Na-КАН (m = 0.32353 г), рассчитанная по данным АКTС pTС pTС pTС p“Гелиевая14.720.009930.770.062352.230.167774.910.3021область”15.070.010631.490.065652.940.174675.920.3037T С p6.390.000715.420.011032.210.068553.650.179076.930.30296.650.001115.770.011232.930.072954.370.183277.940.30946.910.001416.120.011533.650.076255.080.192578.940.31617.170.000916.470.012534.360.079955.800.191479.950.32087.430.001116.820.013035.080.082456.510.194480.430.32367.680.001417.170.014135.800.084157.230.199681.480.33277.920.001817.520.013836.510.088757.940.202582.520.33728.170.001917.870.014637.220.093558.660.2044“Азотная об-8.410.002518.210.015537.930.101559.370.2120ласть”, серия 18.650.002418.560.016538.650.099960.080.215379.030.31468.880.003218.910.017439.370.104960.800.214880.430.32369.140.003519.250.017840.080.109261.510.220281.480.33279.370.003919.600.018740.800.111262.220.228782.520.33729.600.003919.940.020341.510.114662.930.229883.570.33989.840.004920.620.022242.220.118163.650.233284.620.341110.070.004721.360.024242.940.122564.360.237985.660.347110.370.005522.100.026543.650.126965.070.242186.700.352310.740.006422.830.028844.360.130165.780.247787.740.357011.110.006623.560.030945.080.134466.490.249788.790.361711.480.007024.290.033945.790.139167.200.255889.830.365511.850.008025.010.037646.510.142267.910.257390.870.371812.210.007725.740.038447.220.145268.620.262191.910.376812.580.007926.460.042347.940.149169.330.264892.950.379412.940.008427.180.044448.650.153770.040.268693.990.384013.300.008127.900.047949.370.158170.890.272895.020.394613.650.008728.620.051750.080.160971.900.280296.060.392814.000.009529.330.055550.800.164272.900.282797.100.401214.360.009730.050.058051.510.166073.910.292698.140.4081117Продолжение таблицы 9.2С pTС pTС pTС pTС p99.180.4133131.150.5390162.720.6476193.770.7418224.080.8387100.210.4147132.180.5400163.730.6492194.760.7451225.000.8301101.250.4177133.200.5439164.740.6507195.760.7474225.960.8369102.290.4237134.220.5524165.750.6498196.750.7555226.920.8417103.320.4297135.250.5521166.760.6551197.740.7584227.880.8426104.360.4296136.270.5565167.770.6609198.730.7567228.840.8461105.400.4347137.290.5614168.780.6618199.720.7631229.800.8500106.430.4428138.320.5640169.780.6707200.710.7662230.750.8482107.470.4434139.340.5670170.790.6731201.690.7716231.710.8509108.500.4491140.360.5706171.790.6774202.680.7667232.660.8535109.540.4537141.380.5790172.800.6795203.660.7692233.610.8556110.570.4585142.400.5805173.810.6836204.640.7787234.560.8621111.600.4647143.420.5815174.810.6875205.620.7835235.510.8634112.640.4697144.440.5877175.820.6871206.610.7794236.460.8606113.670.4691145.460.5916176.820.6906207.590.7860237.410.8644114.700.4730146.480.5930177.810.6923208.570.7869238.350.8655115.730.4780147.500.5938178.820.6958209.520.7876239.300.8713116.760.4846148.520.5985179.820.6983210.490.7945240.190.8736117.790.4845149.530.6027180.820.7047211.470.7956241.130.8732118.820.4901150.550.6051181.820.7074212.450.8013242.070.8763119.850.4951151.570.6075182.820.7072213.420.8030243.010.8771120.880.4941152.580.6148183.820.7126214.400.8063243.950.8888121.910.4984153.600.6148184.820.7122215.370.8046244.880.8905122.940.5092154.620.6186185.820.7156216.340.8123245.810.8900123.970.5120155.630.6252186.820.7181217.310.8099246.750.8893125.000.5145156.650.6296187.820.7265218.280.8139247.670.8907126.020.5196157.660.6296188.810.7291219.250.8212248.600.8970127.050.5239158.680.6318189.810.7301220.220.8224249.530.9003128.080.5239159.690.6329190.810.7280221.190.8209250.450.9030129.100.5300160.700.6383191.800.7304222.150.8266251.380.8962130.130.5292161.700.6449192.800.7385223.110.8300252.310.8943T 118Продолжение таблицы 9.2TС pС pTС pTС pTС p253.230.904492.050.3780113.760.4748135.290.5535156.630.6290254.150.906293.090.3819114.790.4756136.310.5575157.640.6305255.000.903994.120.3892115.820.4779137.330.5574158.650.6320255.910.906195.160.3912116.850.4837138.350.5612159.660.6371256.830.917096.200.3958117.870.4874139.370.5679160.670.6395257.740.916697.240.3991118.900.4908140.390.5717161.670.6475258.650.913898.270.4049119.930.4968141.410.5726162.680.6532“Азотная об-99.310.4069120.960.4997142.430.5766163.690.6501ласть”, серия 2100.340.4139121.980.5037143.440.5820164.700.6566T79.190.3157101.380.4195123.010.5082144.460.5826165.710.658980.590.3277102.410.4255124.040.5133145.470.5858166.720.665881.630.3300103.450.4282125.060.5157146.490.5898167.730.668682.680.3366104.480.4286126.090.5182147.500.5944168.730.666483.720.3404105.510.4360127.110.5221148.520.5984169.740.674084.760.3436106.540.4419128.140.5265149.530.6020170.750.674485.810.3496107.580.4465129.160.5278150.550.6105171.750.679486.850.3572108.610.4490130.180.5321151.560.6093172.760.680987.890.3652109.640.4558131.200.5357152.580.6132173.760.682788.930.3664110.670.4612132.220.5431153.590.6156174.760.682389.970.3690111.700.4641133.240.5467154.600.618991.010.3768112.730.4669134.270.5544155.620.6227Таблица 9.3 Результаты высокотемпературной калориметрии растворения в расплаве дляобразца Na-КАН (в Дж·г−1)H 973 H 298.15   sol H 973 H973 H 298.15   sol H 9731295.361307.221321.521326.181361.701295.451314.771316.981259.101331.72119Таблица 9.4 Элементный состав образца Ca-КАН по результатам РСМА (в ат%)ONaAlSiKCaCr65.5814.329.1710.380.5566.1514.488.939.970.4763.249.3611.5312.3566.0413.439.2810.650.6065.5313.779.2910.790.6265.8114.059.1710.450.5265.6013.689.4410.780.5163.1411.5111.0612.7265.3114.239.2610.690.5156.1613.188.3810.570.581.599.5465.3511.988.5710.920.600.352.2464.3813.689.7411.5468.9714.327.648.740.3465.7214.248.9610.410.6865.9012.879.2811.230.7265.2813.109.8011.090.7262.5713.4210.5512.021.443.311.110.14Fe0.210.460.52Таблица 9.5 Зависимость удельной теплоемкости (в Дж·г−1·К−1) от температуры (в К)для образца Ca-КАН (m = 0.823188 г), рассчитанная по данным АКТС pТС pТС pТС p“Гелиевая8.690.002010.220.002813.120.005616.110.0104область”8.840.001810.500.003113.420.006016.410.0111Т С p7.340.00088.990.002410.790.003213.710.006516.720.01167.520.00069.150.002211.080.003414.010.006917.030.01247.690.00109.290.002111.370.003914.300.007317.330.01317.860.00149.440.002211.650.004114.600.007817.640.01378.030.00149.590.002311.950.004214.900.008217.950.01468.190.00169.730.002512.250.004415.200.008818.250.01538.360.00189.870.002612.540.004915.500.009418.560.01628.510.001810.010.002712.830.005315.800.009818.870.0171120Продолжение таблицы 9.5 TС pTС pTС pTС pTС p19.180.017941.490.116171.280.271293.070.3667126.990.498719.490.018742.280.120572.480.276493.870.3700128.230.502919.800.019643.070.124673.690.282094.670.3737129.460.507320.110.020643.860.128774.890.287395.470.3767130.700.511420.680.022144.650.133076.100.292696.280.3804131.940.515321.420.024545.450.137477.300.298097.080.3838133.180.519722.160.026946.240.141578.510.303597.880.3872134.420.524022.910.029347.040.145679.720.308898.690.3909135.660.527623.660.032047.830.149980.930.314199.490.3940136.900.532024.410.034948.630.154282.140.3192100.290.3972138.150.535725.160.038149.430.158083.350.3248101.300.4025139.390.540225.920.041250.220.1621“Азотная об-102.510.4071140.640.543926.680.044151.020.1665ласть”103.720.4119141.880.547827.440.047351.820.171078.480.3026104.940.4166143.130.551428.210.050552.620.175679.440.3071106.150.4218144.380.555928.980.053953.420.180780.240.3104107.370.4266145.660.560829.750.057454.210.185681.040.3140108.590.4313146.910.563630.520.061255.010.190881.840.3172109.810.4359148.160.567531.290.064955.810.195682.640.3210111.020.4406149.420.571032.070.068656.610.200383.440.3246112.240.4456150.670.575532.850.072662.230.227784.240.3279113.470.4500151.930.579333.640.076463.030.233085.050.3316114.690.4546153.180.582734.420.080163.830.237385.850.3351115.910.4590154.440.586435.200.084164.630.240786.650.3384117.140.4637155.700.589935.980.087965.440.244387.450.3419118.360.4677156.960.593236.760.091666.240.248188.250.3454119.590.4725158.220.597137.550.095567.050.252089.050.3491120.820.4770159.490.601238.330.099767.850.255789.850.3527122.050.4813160.750.604939.120.103668.660.259890.660.3563123.280.4856162.020.608339.910.107569.460.263191.460.3596124.510.4902163.280.611940.700.111770.270.266892.260.3629125.760.4949164.550.6154121Продолжение таблицы 9.5 ТС pТС pТС pТС pТС p165.850.6193192.890.6891223.280.7582253.710.8224286.240.8831167.130.6225194.190.6924224.600.7606255.020.8244287.530.8855168.400.6260195.490.6957225.920.7634256.340.8270288.810.8874169.670.6297196.800.6990227.240.7663257.650.8289290.090.8887170.950.6333198.110.7020228.630.7696260.260.8350292.640.8940172.220.6368199.420.7054229.950.7721261.570.8373293.910.8968173.500.6400200.730.7070232.590.7799262.880.8404295.180.8993174.780.6436202.050.7103233.910.7826264.180.8428296.450.9014176.060.6466203.370.7128235.230.7857265.490.8448297.720.9035177.340.6499204.690.7159236.540.7885266.790.8478298.990.9055178.620.6525206.020.7193237.860.7907268.090.8495301.730.9106179.910.6560207.410.7223239.180.7929269.400.8518303.380.9131181.190.6597210.060.7279240.500.7961273.340.8597305.040.9167182.480.6631211.380.7319241.810.8008274.630.8618306.700.9188183.770.6666212.710.7344243.130.8048275.930.8641308.370.9209185.060.6699214.030.7375244.450.8065277.220.8665313.400.9287186.400.6737215.350.7403247.070.8104278.520.8694315.100.9311187.700.6766216.670.7433248.390.8126279.810.8721316.790.9336188.990.6800218.000.7455249.770.8148281.100.8747320.230.9364190.290.6824219.320.7482251.080.8169283.670.8783321.940.9404191.590.6859221.960.7550252.400.8193284.960.8805323.670.9429.