Н.Я. Турова - Неорганическая химия в таблицах (1109028), страница 59
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ÒÎ. 109),[Sb2F11] (Õ. ÒÎ. 81), ÍÓËÔÕ.,ÉÇÎÕÑ-ÊÇÎ., ÍÂÕËÑÐ ë´-ÑÃÓÂÊÐÞÌ (c-ÕÓËÅ. ÃËÒËÓ.,sp3 d),Xe ì F 1.83 (àÍÄ.), 1.91 (ÂÍÔ.),.. FXeF 80, 82, 162 5)[XeOF3]+X ë, X=SbF6 (Õ. ÒÎ. 104),Sb2F11 (Õ. ÒÎ. 61), ÍÓËÔÕ., ÃÙ.,ÍÂÕËÑÐ ë ÆËÔ×ÇÐÑËÆ 6)XeO(OTeF5)4Xe(OTeF5)6, ÍÓËÔÕ., ÍÓÂÔÐ. 18)F2 [(t, p); (NiF2)]Xetÿ! Xe + O2 + M2On,ÂÐËÑÐ ë ÑÍÕ., Xe ì O 1.86HMO[XeOF5]+[Sb2F11]ÿ5XeF4, ÍÓËÔÕ., ÃÙ., Õ.
ÒÎ. 135 11), ÄÑÊÅ.,DH = ÿ251, Ó. Ä HF (ÐÇ ÆËÔ.), ÔËÎßÐ.ÑÍËÔÎ.: + Pt ÿ! PtF4 + PtF6;+ NH3 ÿ! N2 + . . . ; + Ag ÿ! Ag2+;ÏÑÎ. ë ÍÄÂÆÓÂÕ .(c-ÑÍÕ.,sp3 d 2 ), Xe ì F 1.95.15)PF(ÿX(ÿXe(TeO2F4)2 19)Xe(OTeF5)4, ÍÓËÔÕ., ÉÇÎÕ., Õ. ÒÎ. 72 Ô ÓÂÊÎ.;Ä ÔÕÓ. ë ÍÄÂÆÓÂÕÞ [XeO4], Xe ì O 2.03 18)nOKMeO+X4Na3HXeO6 H2OM4/n[XeO6], ÒÇÓÍÔÇÐÂÕÞ, M = Li ;, Na( n H2O;, n = 6; 8), K ë Cs, Ó. Ä ¯2°,Ba; (ÃÙ.), Ag; (ÚÇÓÐ.), Zn;, Pb;,3+La; (ÉÇÎÕ.), Th;, UO2+2 , Au( 40 H2O;), (ÑÓÂÐÉ.);XeOF4, É., ÃÙ., d 3:17, Õ. ÒÎ.
ÿ41, ÓÂÊÎ. >300, DH = ÿ25,ÎÇÕÖÚ >XeF6, ÏÑÎ. ë ÕÇÕÓÂÅ. ÒËÓÂÏËÆÂ Ô ° Ä ÄÇÓÛËÐÇ,Xe ì F(àÍÄ.) 1.90, Xe=O(ÂÍÔ.) 1.70; C7.8, ÅÓÂ×ËÕËÆCs[(XeOF4)3F] 6))O2eÿOH2Cs[XeO2F3]H2O;N2O5O3 +MOHF3Cs[XeOF3], ÍÓËÔÕ.,ÉÇÎÕ. 15)[XeO2F]+X ë, X = ¿F6, ÃÇÎ. ÕÄ. Ä-ÄÂXeO2(OTeF5)2, ÅÓ. [:XeO4] ë ÆËÔ×ÇÐÑËÆ, Xe ì O 1.73 Ë 2.02 6)2 );XeO3F2, Õ. ÒÎ. ÿ54POXeO2F2, ÍÓËÔÕ., ÃÙ., Õ. ÒÎ. 31, ÏÑÎ. ë c-ÕÓËÅ. ÃËÒËÓ. (ÆËÔ×ÇÐÑËÆ), Xe ì O 1.89 (ÂÍÔ.), Xe ì F 1.71 (àÍÄ.), FXeF 105, OXeF 92; DH = +235; >25 ÿ! XeO2 + O2 (ÏÇÆÎ.) 15)H (ÿXe ÿOXM[XeO3¤], M = K ë Cs, ¤ = F ë Br, ÍÓËÔÕ.,ÃÙ., ÖÔÕ. F>Cl>Br, ÂÐËÑÐ ë [XeO3F2/2],Xe ì F 1.75 ë 1.79, Xe ì O 2.36, 2.482XeOF2, ÍÓËÔÕ., ÔÄ.-ÉÇÎÕ., Õ.
ÒÎ. 90, ÄÊÓ.,..Ä ÔÕÓ. ë ÙÇÒË ÍÄÂÆÓÂÕÑÄ;OFÿ15 ÿ! XeF2 + XeO2F2..(ÑÃÇÔÙÄÇÚËÄÂÇÕÔâ) 15)FOF..FO..XeF2 (ÿXe)K4XeO6 2 XeO3;,ÍÓËÔÕ., ÉÇÎÕ., ÄÊÓ.;+ Mn2+ ÿ!HMnO4H+KOH (ÿXe)OFMO¬ÔÇÐÂÕÞ, MHXeO4, M = Na ë Cs, ÍÓËÔÕ., ÃÙ.M2XeO4, ÔËÎßÐ. ÑÍËÔÎ.Ba3XeO6;, ÓÂÊÎ. 250H2O + MgO(ÿMgF2;)Xe¿F5[H4XeO6], K1 = 10 , K2 = 10ÿ6, K3 = 10ÿ11;ÿ+ Mn2+ ÿ! HMnO4; + IOÿ3 ÿ! IO4 ;+ CoII ÿ! CoIIIÿO2 (ÏÅÐÑÄ.)H2XeO4 > H++ HXeO4ë, Ó-ÓÞ ÖÔÕ., ÑÚ. ÔËÎßÐ. ÑÍËÔÎ.,+ Fe2+ ÿ! Fe3+ (pH = 7); + Hg ÿ! Hg2+2Xe(OH)4, ÍÓËÔÕ., ÃÙ., Õ. ÒÎ.
90,Õ. Í. 115, ÄÊÓ.XeO4, Å., ÔÄ.-ÉÇÎÕ., ÄÑÊÅ. ÿ196, Õ. ÒÎ. ÿ36, ÄÊÓ.,DH = +640, ÏÑÎ. ë ÕÇÕÓÂàÆÓ, Xe ì O 1.74 17)<0 (ÿXe ÿO2)H2SO4 (ÿ5 )XeO3, ËÅÎÞ, ÃÙ., ÄÊÓ. (ÍÂÍ ÕÓÑÕËÎ), Ó. Ä ¯2° 2 ®,DH = +402, ÏÑÎ. ë c-ÕÇÕÓÂàÆÓ [:XeO3] (sp3 ),20)Xe ì O 1.76, OXeO 103 (ÔÓ. IOÿ3)O3 ;&6:; OH[H2XeO6]2 ëXeF2+Hÿ&10:; OHÿ[HXeO6]3 ë&12ÃÙ. ÑÍÕ. ÂÐËÑÐÞ,ÔËÎßÐÇÌÛ. ÑÍËÔÎ.(ÒÓË pH<7)111£¡¦¯´¯½¦ ³°³´°Á¯ªÁ (´ª±½ ¤ª¢²ª¥ª©¡¸ªª) ª ¬°°²¥ª¯¡¸ª°¯¯½¦ ®¯°¤°¤²¡¯¯ª¬ª ¸¦¯´²¡¾¯°¤° ¡´°®¡(E ë ÎÑÍÂÎËÊÑÄÂÐÐÂâ ÒÂÓ àÎ.)´ËÒ¹ËÔÎÑ £ÂÎÇÐÕÐÑÇàÎ.ÔÑÔÕÑâÐËÇ, ÏÑÎÇÍÖÎÞ ¬. ¹.ÒÂÓÄÂÎÇÐÕÐÞÌ ËÎË ËÑÐÂÖÅÑÎ22sp, 1807s5f, 180p 2, 90AX2AX2222±ÓÑÔÕÓÂÐÔÕÄÇÐÐÂâÍÑÐ×ËÅÖÓÂÙËâÎËÐÇÌÐÂâ(ÅÂÐÕÇÎß)ÖÅÎÑÄÂâ±ÓËÏÇÓÞ¹ËÔÎÑ £ÂÎÇÐÕÐÑÇ´ËÒàÎ.ÔÑÔÕÑâÐËÇ, ÏÑÎÇÍÖÎÞ ¬. ¹.ÒÂÓÄÂÎÇÐÕÐÞÌ ËÎË ËÑÐÂÖÅÑÎBe¤2, ¤ = F ë I (Å.), CO2, N2O, [NO2]+d 10: ZnCl2 (Å.), HgCl2, [Ag(NH3)2]+,d 0: [UO2]2+, [NpO2]2+, [PuO2]2+AX333sp2, 120d 2s, 120p 3, 90sp3,109 280AX2EAX3AX43234ÒÎÑÔÍËÌ ÕÓ-ÍÖÅÎÑÄÂâ(c-ÕÓ-Í)ÕÓËÅ.
ÒËÓÂÏËÆÂÕÇÕÓÂàÆÓK[BeF3] (Å.), B¤3, [BO3]3ÿ, B2Cl4, [CO3]2ÿ, C2H4,[NO3]ÿ, SO3 (Å.), [O (HgCl)3]+;d 10: [HgI3]ÿd 6: [FeO3]4ÿd 0: Sc¤3 (Å.)sp d,120 (àÍÄ.),90 (ÂÍÔ.)55ÕÓËÅ. ÃËÒËÓ.AlH3 2NR3, [SnCl5]ÿ, PF5 (Å.), SOF4, [IO5]3ÿ,ClO2F3AX55ÕÇÕÓÂÅ. ÒËÓÂÏËÆÂ[InCl5]2ÿAX4E4ÆËÔ×ÇÐÑËÆ(c-ÕÓËÅ. ÃËÒËÓ.)[PBr4]ÿ, [SbF4]ÿ, SF4, TeCl4, [¤O2F2]ÿ, [¤F4]+,¤OF3, XeO2F2 (2F-ÂÍÔ), XeO3FAX3E23´-ÑÃÓÂÊÐÂâ(c-ÕÓËÅ. ÃËÒËÓ.)ClF3, BrF3, [XeF3]+, XeOF2AX2E32ÎËÐÇÌÐÂâ(c-ÕÓËÅ.
ÃËÒËÓ.)[ICl2]ÿ, [¤3]ÿ, XeF2AX55ÕÓËÅ. ÃËÒËÓ.d 8: [Mn(CO)5]ÿ, Fe(CO)5, [Co(CO)3(PR3)2]+,[Pt(SnCl3)5]3ÿ, [CuCl5]3ÿ (3d 9 ÿ! 3d 84d 1)d 7: Mn(CO)4(NO) (Å.), [NiBr3(PEt3)2]Sn¤2 (Å.), [NO2]ÿ, N2F2, O3, SO2 (Å.), ClO2+dsp 3,120 (àÍÄ.),90 (ÂÍÔ.)PH3, AsF3 (Å.)[Be(H2O)4]2+, [OBe4] Ä ÏÑÎ. Be4O(OAc)6; [BF4]ÿ,[AlCl4]ÿ, CH4, [SiO4]4ÿ, NOF3, [SO4]2ÿ, [ClO4]ÿd 10: Ni(CO)4, [Cu(CN)4]3ÿ, [Zn(CN)4]2ÿ, [GaH4]ÿ,GeCl4, [AsO4]3ÿ, [SeO4]2ÿ, [BrO4]ÿ, XeO4d 9: Co(CO)3(NO), Cs2[CuCl4]d 8: [Fe(CO)2(NO)2], [Co(CO)4]ÿ, [NiCl4]2ÿd 7: [Mn(CO)(NO)3], [CoCl4]2ÿd 6: [FeCl4]2ÿ; d 5: [MnCl4]2ÿ; d 3: [FeO4]3ÿsp3, 103AX3E3ÕÓËÅ. ÒËÓÂÏËÆÂ(c-ÕÇÕÓÂàÆÓ)NH3, NF3, N2F4, [AsO3]3ÿ, [H3O]+, SOCl2,[SO3]2ÿ, [Sen], [SeO3]2ÿ, [IO3]ÿ, [BrO3]ÿ, XeO3sp3, 103AX2E22ÖÅÎÑÄÂâ(c-ÕÇÕÓÂàÆÓ)H2O, OF2, [Sn], SCl2, Te¤2, [ClF2]+, [ClO2]ÿ, XeO2"#ÕÇÕÓÂÅ.
ÒËÓÂÏËÆÂ(ÙÇÐÕÓÂÎßÐÞÌÂÕ. ÐÂÆ ÙÇÐÕÓÑÏÍÄÂÆÓÂÕÂ)d 6: [RuCl2(PR3)3]d 4: [Et4N]2[MnCl5]d 2sp2, 90AX55d 3spAX55ÕÓËÅ. ÃËÒËÓ.d 0: NbCl5, V¤5d 4s, 90AX55ÕÇÕÓÂÅ. ÒËÓÂÏËÆÂd 2: VCl3(SMe2)2, [Mo(CN)5]ÿ, [ReO¤4]ÿAX66ÑÍÕ.[Mg(H2O)6]2+, [AlF6]3ÿ, [SiF6]2ÿ, [Pb(OH)6]2ÿ,[PCl6]ÿ, SF6, [IO6]5ÿ, [IF6]+, [IO2F4]ÿd 10: AgCl, [Cd(OH)6]4ÿ, [InF6]3ÿ, [SnCl6]2ÿ,[Sb(OH)6]ÿ, TeF6, IOF5, [XeO6]4ÿd 9: K2[CuCl4] (ËÔÍÂÉ. ÑÍÕ.); d 8: [AuBr6]3ÿd 7: [FeI(NO)+(H2O)5]2+, [Co(NH3)6]2+ÄÞÔÑÍÑd 6: [Fe(H2O)6]2+, [CoF6]3ÿÔÒËÐÑÄÞÇ d 5: [Mn(H2O)6]2+, [Fe(H2O)6]3+d 4: [Cr(H2O)6]2+, [Mn(C2O4)3]3ÿ46112d 3s, 109 280AX44ÕÇÕÓÂàÆÓd 2: Cr(OC4H9-t)4, [MnO4]3ÿ, [FeO4]2ÿd 1: VCl4, [CrO4]3ÿ, [MnO4]2ÿ, [RuO4]ÿd 0: TiCl4, [VO4]3ÿ, [CrO4]2ÿ, [MnO4]ÿ, OsO4dsp2, 90AX44ÍÄÂÆÓÂÕd 8: [Co(CN)4]3ÿ, [Ni(CN)4]2ÿ, [PtCl4]2ÿ, CuO,[Au(OH)4]ÿ±ÓËÏÇÓÞAX5H2S, H2Se, [TlCl2]ÿ3±ÓÑÔÕÓÂÐÔÕÄÇÐÐÂâÍÑÐ×ËÅÖÓÂÙËâ{sp3d 2, 90AX5E5ÕÇÕÓÂÅ.
ÒËÓÂÏËÆÂ(ÙÇÐÕÓÂÎßÐÞÌ ÂÕ.Ä ÙÇÐÕÓÇ ËÎË ÒÑÆÙÇÐÕÓÑÏ ÍÄÂÆÓÂÕÂ)(c-ÑÍÕ.)[SbF5]2ÿ, [SF5]ÿ, ¤F5, [¤OF4]ÿ, [XeF5] +AX4E24ÍÄÂÆÓÂÕ(c-ÑÍÕ.)[ICl4]ÿ, XeF4¹ËÔÎÑ £ÂÎÇÐÕÐÑÇ´ËÒàÎ.ÔÑÔÕÑâÐËÇ, ÏÑÎÇÍÖÎÞ ¬. ¹.ÒÂÓÄÂÎÇÐÕÐÞÌ ËÎË ËÑÐÂÖÅÑαÓÑÔÕÓÂÐÔÕÄÇÐÐÂâÍÑÐ×ËÅÖÓÂÙËâ±ÓËÏÇÓÞÐËÊÍÑÔÒËÐÑÄÞÇ6d 2sp3, 90d 4sp (?)AX6AX5EAX7667ÑÍÕ.ÕÓËÅ. ÒÓËÊÏÂÒÇÐÕÂÅ. ÃËÒËÓ.{d 7: [Os(NH3)6]+, [NiF6]3ÿd 6: ³r(CO)6, [Mn(CN)6]5ÿ, [Fe(CN)6]4ÿ,[Co(NH3)6]3+, [NiF6]2ÿ5d : [Mn(CN)6]4ÿ, [Fe(CN)6]3ÿ,[PtF6]ÿ4d : [TiDipy3], [Mo(CN)6]4ÿ,[Mn(CN)6]3ÿ, [OsCl6]2ÿ, [IrF6]ÿ, PtF6d 3: [V(H2O)6]2 +, [Cr(NH3)6]3+,[MnCl6]2ÿ, [OsF6]ÿ, IrF6d 2: [V(H2O)6]3 +, [CrF6]2ÿ,[ReOCl5]2ÿ, [OsN¤5]2ÿ, RuF61d : [Ti(H2O)6]3+, [VF6]2ÿ,[MoF6]ÿ, ReF6, OsOF50d : [Sc(OH)6]3 ë, [Ti¤6]2ÿ, [VF6]ÿ, MoF6,[ReO3Cl3]2ÿ, [OsO4(OH)2]2ÿ¹ËÔÎÑ £ÂÎÇÐÕÐÑÇ´ËÒàÎ.ÔÑÔÕÑâÐËÇ, ÏÑÎÇÍÖÎÞ ¬.
¹.ÒÂÓÄÂÎÇÐÕÐÞÌ ËÎË ËÑÐÂÖÅÑÎ8sp3d 4,d 4sp37AX6EIF7AX5E2d 5sp, d 4sp2,d 3sp3AX7ËÔÍÂÉ. ÑÍÕ.(c-ÒÇÐÕÂÅ. ÃËÒËÓ.ËÎË c-ÑÆÐÑÛÂÒÑÚÐÞÌ ÑÍÕ.)[IF6]ÿ, XeF6 (Å.), [XeOF5]ÿ5ÒÎÑÔÍËÌ 5-ÖÅÑÎßÐËÍ(c-ÒÇÐÕÂÅ. ÃËÒËÓ.)[XeF5]ÿ7ÒÇÐÕÂÅ. ÃËÒËÓ.d 0:d 1:d 2:d 3:d 4:677ÑÆÐÑÛÂÒÑÚÐÞÌÑÍÕ.ÑÆÐÑÛÂÒÑÚÐÂâÕÓËÅ. ÒÓËÊÏÂ8±ÓËÏÇÓÞÂÐÕËÒÓËÊÏÂ(ÕÑÏÔÑÐÑÄÔÍËÌ ÍÖÃ)( ÒÑÄÑÓÑÕ 45 ëÂÐÕËÒÓËÊÏ¡ÓØËÏÇÆÂ)[XeF8]2ÿ, [Ba(H2O)8]2+,Zr[IO3]4, [TaF8]3ÿ, [W(CN)8]2ÿ, [Mo(CN)8]4ÿ,[ReF8]2ÿ, [Eu(H2O)6Cl2]+ÍÖÃThO2, UO2, (NH3)4[U(C2O4)4]ÆÑÆÇÍÂàÆÓTi(NO3)4 (NO3 ë ÃËÆÇÐÕÂÕÐÞ), [ZrF8]4ÿ,[CrV(O2)4]3ÿ, [Mo(CN)8]2ÿ, [Co(NO3)4]2ÿ,[Fe(NO3)4]ÿ, [Re(CN)8]3ÿÅÇÍÔÂÅ.
ÃËÒËÓ.[UO2(H2O)6]2+ÕÇÕÓÂÅ. ÑÆÐÑÛÂÒÑÚÐÂâÒÓËÊÏÂLi3ThI7ÕÓÇØÛÂÒÑÚÐÂâÕÓËÅ. ÒÓËÊÏÂPbCl2, Ba¤2, EuCl2, [Nd(H2O)9]3+, [Sc(H2O9]3+,[Th(SO4)4]4ÿ, K2[PaF7], UCl3, [ReH9]2ÿ,Tl(NO3)3 3 H2Od 2: MoS2, WS29sp3d 3,sp3d 2f (?)AX8±ÓÑÔÕÓÂÐÔÕÄÇÐÐÂâÍÑÐ×ËÅÖÓÂÙËâsp3d 5(NH4)3[ZrF7], OsF7OsF7[V(CN)7]4ÿ[Mo(CN)7]4ÿ[Re(CN)7]4ÿ10AX99AX8E8ÍÄÂÆÓÂÕÐÂâ ÂÐÕËÒÓËÊÏÂ[XeF8]2ÿ[Th (ÕÓÑÒÑÎÑÐÂÕ)5]ÿ10ÍÄÂÆÓÂÕÐÂâÒÓËÊÏÂ Ô 2ÙÇÐÕÓËÓÑÄÂÐÐÞÏËÅÓÂÐâÏËÒÇÐÕÂÅ. ÃËÒËÓ.[UO2(C2O4)2]2ÿAX1011AX1111ÕÓËÅ. ÒÓËÊÏ ÔÙÇÐÕÓËÓÑÄÂÐÐÞÏËÑÔÐÑÄÂÐËâÏË ËÓÇÃÓÂÏËLnF3, UF3, Th(NO3)4 5 H2O12AX1212ËÍÑÔÂàÆÓLa2(SO4)3 9 H2O, [Ce(NO3)6]3ÿ, [Th(NO3)6]2ÿ,[UO2(C2O4)3]4ÿd 0: [NbOF6]3ÿd 0: [NbF7]2ÿ, [TaF7]2ÿ, LnO(OH), YO(OH)(ÍÖÃÑÑÍÕÂàÆÓ Ë ÇÅÑ ÅÇÍÔÂÅ.ÂÐÂÎÑÅ ÄÔÕÓÇÚÂáÕÔâ Ä ËÑÐÐÞØÍÓËÔÕ.)113£¡¨¯¦«ºª¦ ´ª±½ ¬²ª³´¡ª¹¦³¬ª· ³´²µ¬´µ²¶ÑÓÏÖδËÒ ÓÇÛÇÕÍˬ.
¹. Ë ÏÐÑÅÑÅÓÂÐÐËÍÙÇÐÕÓÂÎßÐÑÅÑ ÂÕÑϬ. ¹. Ë ÏÐÑÅÑÅÓÂÐÐËÍÎËÅÂÐƳÕÓÂÐËÙ¶ÑÓÏÖÎÂ6, ÑÍÕ.2, ÅÂÐÕÇÎß15ÓÑÏÃ.8, ËÔÍÂÉ. ÄÑÔßÏËÄÇÓÛËÐÐËÍ{ 2, ÖÅÑÎ34UCl3ÅÇÍÔÂÅ.9, ÕÓÇØÛÂÒÑÚÐÂâ ÕÓËÅ. ÒÓËÊÏÂ3, ÕÓËÅ. ÒËÓÂÏËÆÂ32LaF3ÅÇÍÔÂÅ.3(ÕÓ-Í)+6(ÒÓËÊÏÂ)+2(ÂÍÔ.) = 11{ 3, ÕÓ-Í77YF3ÓÑÏÃ.9=8+1UCl4ÕÇÕÓÂÅ.4 (ËÔÍÂÉ. ÕÇÕÓÂàÆÓ) +ì86FeCl3ÓÑÏÃÑàÆÓËÚÇÔÍÂâ 6, ÑÍÕ.a-FeÍÖÃ. ÑÃÝÇÏÐÑ-8, ÍÖÃì90ReO3ÍÖÃ.PuBr3ÅÇÍÔÂÅ. ÒÎ. ÖÒÂÍ.ì12, ÅÇÍÔÂÅ.
ÂÐÂÎÑÅ78³ÑÇÆËÐÇÐËâÕËÒ ¡·3ÍÖÃÑÑÍÕÂàÆÓÂC (ÂÎÏÂÊ)ÍÖÃ.4(= 8 ë 4), ÕÇÕÓÂàÆÓì54C (ÅÓÂ×ËÕ)ÅÇÍÔÂÅ.3, ÕÓ-Íì54P ë ÃÇÎ.ÍÖÃ.3 (= 8 ë5), ÕÓËÅ. ÒËÓÂÏËÆÂ, PPP 60ì40P ë ÚÇÓÐ.ÓÑÏÃ.3, ÕÓËÅ. ÒËÓÂÏËÆÂì40S8ÓÑÏÃ.2 (= 8 ë 6), SSS 108ì18I2ÓÑÏÃ.1 (= 8 ë 7)ì6³ÑÇÆËÐÇÐËâ(ÒÓÂÄËÎÑ ÀÏ-²ÑÊÇÓË)NaClÍÖÃ.6, ÑÍÕ.6, ÑÍÕ.85CsClÍÖÃ.8, ÍÖÃ8, ÍÖÃ85ZnS (Ô×ÂÎÇÓËÕ)ÍÖÃ.4, ÕÇÕÓÂàÆÓ4, ÕÇÕÓÂàÆÓ81ZnS (ÄáÓÕÙËÕ)ÅÇÍÔÂÅ.4, ÕÇÕÓÂàÆÓ4, ÕÇÕÓÂàÆÓ81³ÑÇÆËÐÇÐËâ= ZnOÕËÒ ¡·NiAsÅÇÍÔÂÅ.6, ÑÍÕ.6, ÑÍÕ.94BNÅÇÍÔÂÅ.3, ÕÓ-Í3, ÕÓ-Í69PbOÕÇÕÓÂÅ.4, ÕÇÕÓÂÅ. ÒËÓÂÏËÆÂ4, ÕÇÕÓÂàÆÓ61PtSÕÇÕÓÂÅ.4, ÍÄÂÆÓÂÕ4, ÕÇÕÓÂàÆÓ108CaC2ÕÇÕÓÂÅ.10 Ë 2, ÕÇÕÓÂÅ. ÒËÓÂÏËÆÞ,5, ÕÇÕÓÂÅ. ÒËÓÂÏËÆÂZrF4ÏÑÐÑÍÎ.1144, ÕÇÕÓÂàÆÓì772, ÖÅÑÎ328, ÂÐÕËÒÓËÊÏÂ2, ÖÅÑÎ65³ÑÇÆËÐÇÐËâa-Al2O3 (ÍÑÓÖÐÆ) ÓÑÏÃÑàÆÓËÚÇÔÍÂâ 6, ËÔÍÂÉ.
ÑÍÕ.4, ËÔÍÂÉ. ÕÇÕÓÂàÆÓ70ÕËÒ ¡2O3Mn2O3ÍÖÃ.6 (6 ÄÇÓÛËÐ ÍÖÃÂ)4, ÕÇÕÓÂàÆÓ12La2O3ÅÇÍÔÂÅ.7, ÑÆÐÑÛÂÒÑÚÐÞÌ ÑÍÕ.4 (= 3 + 1)77MgAl2O4ÍÖÃ.Mg ë 4, ÕÇÕÓÂàÆÓ4, ÕÇÕÓÂàÆÓ (= 3Al+1Mg)7065(ÛÒËÐÇÎß)´ÓÑÌÐÞÇAl ë 6, ÑÍÕ.CaTiO3ÓÑÏÃ. (ÒÔÇÄÆÑÍÖ-Ca ë 12, ÍÖÃÑÑÍÕÂàÆÓ2 Ti + 4 Ca (ÕÇÕÓÂÅ.(ÒÇÓÑÄÔÍËÕ)ÃËÚÇÔÍÂâ)(ÍÖà ËÊ 4 ÅÓ. [TiO3])ÃËÒËÓ.)Ti ë 6, ÑÍÕ.ÔÑÇÆËÐÇÐËâK2PtCl679ÍÖÃ. (ÕËÒ.K ë 12, ÍÖÃÑÑÍÕÂàÆÓÂÐÕË- CaF2)(ÕÇÕÓÂàÆÓ ËÊ 4 ÅÓ. [PtCl6])ÔÃÎËÉÇÐÐÞÇ ÑÔÐÑÄÂÐËâÏË2Pt+4K (ÕÇÕÓÂÅ. ÃËÒËÓ.)1092 Ni95Pt ë 6, ÑÍÕ.FeS2 (ÒËÓËÕ)ÍÖÃ.6, ÑÍÕ.4, ÕÇÕÓÂàÆÓ90CaF2 (×ÎáÑÓËÕ)ÍÖÃ.8, ÍÖÃ4, ÕÇÕÓÂàÆÓ79PbCl2ÓÑÏÃ.9, ÕÓÇØÛÂÒÑÚÐÂâ ÕÓËÅ. ÒÓËÊϳÑÇÆËÐÇÐËâ3, ÕÓËÅ.
ÒËÓÂÏËÆÂ+ 4 (ÏÑÔÕ.) = 8ÕËÒ ¡·4¬. ¹. = 8ÿå ÅÓ.³ÕÓÂÐËÙÂ9112, ÍÖÃÑÑÍÕÂàÆÓMg¬. ¹. Ë ÏÐÑÅÑÅÓÂÐÐËÍÎËÅÂÐÆÂ3, ÕÓËÅ. ÒËÓÂÏËÆÂÍÖÃ. ÒÎ. ÖÒÂÍ.ÄÇÜÇÔÕÄÂÕËÒ ¡·2¬. ¹. Ë ÏÐÑÅÑÅÓÂÐÐËÍÙÇÐÕÓÂÎßÐÑÅÑ ÂÕÑÏÂCuÙÇÐÕÓËÓÑÄÂÐÐÂâ±ÓÑÔÕÞÇ´ËÒ ÓÇÛÇÕÍËK2NiF4ÕÇÕÓÂÅ.Ni ë 6, ËÔÍÂÉ. ÑÍÕ.4, ÕÇÕÓÂàÆÓ{ 5, ÒÇÐÕÂÅ. ÒËÓÂÏËÆÂ62TiO2 (ÓÖÕËÎ)ÕÇÕÓÂÅ.6, ÑÍÕ.3, ÕÓ-Í65CdI2ÅÇÍÔÂÅ.6, ÑÍÕ.3, ÕÓËÅ. ÒËÓÂÏËÆÂ80CdCl2ÓÑÏÃÑàÆÓËÚÇÔÍÂâ 6, ÑÍÕ.3, ÕÓËÅ. ÒËÓÂÏËÆÂ80SiO2 (ÍÓËÔÕÑÃÂÎËÕ) ÍÖÃ.4, ÕÇÕÓÂàÆÓ2, ÅÂÐÕÇÎß59SiS2ÓÑÏÃ.4, ÕÇÕÓÂàÆÓ2, ÖÅÎÑÄÂâ, SiSSi 10059CO2ÍÖÃ.2, ÅÂÐÕÇÎß155Kë920 H2O, ÒÇÐÕÂÅÑÐÆÑÆÇÍÂàÆÓ¤ËÆÓÂÕÞ ÅÂÊÑÄ8 X 46 H2O, X = Cl2, H2S, ÍÖÃ.,N2O,CO2, CH4, Xe6 X 46 H2O, X = Br2, SO2,ÔÑÇÆËÐÇÐËâ ÄÍÎáÚÇÐËâ Ä ÔÕÓ.ÎßÆÂa = 12ì6¿¶¶¦¬´ª£¯½¦ ª°¯¯½¦ ²¡¥ªµ³½ (r)Ô ¬. ¹.
6, ÓÂÄÐÑÏ 1.40 A, ÐÂÒÓËÏÇÓ, Ä ÔÕÓÖÍÕÖÓÂØ ÑÍËÔÎÑÄ ®II°. ¿ÕË ÄÇÎËÚËÐÞ ËÔÒÑÎßÊÖáÕÔâ Ä ÍÓËÔÕÂÎÎÑØËÏËË ÒÓË ÔÓÂÄÐÇÐËË ÏÇÉÂÕÑÏÐÞØ ÓÂÔÔÕÑâÐËÌ, ÑÃÝÇÏÑÄàÎÇÏÇÐÕÂÓÐÞØ âÚÇÇÍ Ë Õ. Æ. £ ×ËÊËÍÇ ÕÄÇÓÆÑÅÑ ÕÇΠ(ÒÓË ÑÒËÔÂÐËË ÆË××ÖÊËË, ÒÎÑÕÐÇÌÛÇÌ ÛÂÓÑÄÑÌ ÖÒÂÍÑÄÍÇ ËÑÐÑÄ Ë Õ. Æ.) ÚÂÜÇ ÒÓËÏÇÐâáÕÔâ Õ. Ð. "ÍÓËÔÕÂÎÎËÚÇÔÍËÇ" ÓÂÆËÖÔÞ, ÊÐÂÚÇÐËâ ÍÑÕÑÓÞØ Ð 0.14 A ÒÓÇÄÞÛÂáÕ ÒÓËÄÇÆÇÐÐÞDZÓËÄÇÆÇÐÐÞÇ ÊÐÂÚÇÐËâ ÓÂÆËÖÔÑÄ ÃÂÊËÓÖáÕÔâ Рr O2ÿA ÏÇÐßÛÇ à××ÇÍÕËÄÐÞØ ËÑÐÐÞØ (Shannon R.D., Acta Crystallogr., 1976, A32, 751).Ä ÕÂÃÎ.; ËÔÍÎáÚÇÐËÇ ÔÑÔÕÂÄÎâáÕ ËÑÐÞ ¤ÿ, ¯+, N3ÿ, N5+, ¿2ÿ (¿ = O, S, Se, Te) Ë OHÿ, ÓÂÆËÖÔÞ ÍÑÕÑÓÞØ Ð 0.14 ËÑÐAc3+Ag1+¬.¹.6245678Ag2+ 46Ag3+ 46Al3+ 456Am2+ 789Am3+ 68Am4+ 68As3+ 6As5+ 46At7+ 6Au1+ 6Au3+ 46Au5+ 6B3+346Ba2+ 6789101112Be2+ 346Bi3+ 56rËÑЬ.¹.r1.120.671.001.091.151.221.280.790.940.670.750.390.480.531.211.261.310.971.090.850.950.580.330.460.621.370.680.850.570.010.110.271.351.381.421.471.521.571.610.160.270.450.961.03Bi3+Bi5+8686864346346678910124567812678910126810126686346661.170.760.960.830.931.960.590.310.250.390.080.150.161.001.061.121.181.231.340.780.870.951.031.101.311.011.071.141.191.251.340.870.971.071.140.950.820.921.810.120.080.270.970.85Bk3+Br1Br3+Br5+Br7+C4+Ca2+Cd2+Ce3+Ce4+3+CfCf4+Cl1Cl5+Cl7+3+CmCm4+ËÑЬ.¹.Cm4+ 8Co2+ 4568Co3+ 6Co4+ 46Cr2+ 6Cr3+ 6Cr4+ 46Cr5+ 468Cr6+ 46Cs1+ 689101112Cu1+ 246Cu2+ 456Cu3+ 6Dy2+ 678Dy3+ 6789Er3+ 6789Eu2+ 678r0.950.580.670.740.900.610.400.530.730.610.410.550.340.490.570.260.441.671.741.781.811.851.880.460.600.770.570.650.730.541.071.131.190.910.971.031.080.890.941.001.061.171.201.25ËÑÐ2+EuEu3+1-FFe2+Fe3+4+FeFe6+Fr1+Ga3+Gd3+Ge2+Ge4+H1+Hf4+Hg1+Hg2+Ho3+¬.¹.
r9106789234646845686464566789646124678362468681.301.350.951.011.071.121.281.301.311.330.630.780.920.490.580.640.780.580.251.800.470.550.620.941.001.051.110.730.390.530.380.180.580.710.760.830.971.190.690.961.021.140.901.01ËÑЬ.¹. r3+HoI1I5+I7+In3+Ir3+Ir4+Ir5+K1+La3+Li1+Lu3+Mg2+Mn2+Mn3+9106364646866646789101267891012468689456845678561.071.122.200.440.950.420.530.620.800.920.680.620.571.371.381.461.511.551.591.641.031.101.161.221.271.360.590.760.920.860.981.030.570.660.720.890.660.750.830.900.960.580.580.64ËÑЬ.¹.Mn4+Mn4+Mn5+Mn6+Mn7+Mo3+Mo4+Mo5+Mo6+3-NN3+N5+Na1+Nb3+Nb4+Nb5+Nd2+Nd3+Ni2+Ni3+Ni4+No2+4644466646456746364567891266846788968912456666r0.390.530.330.250.250.460.690.650.460.610.410.500.590.731.460.160.100.130.991.001.021.121.181.241.390.720.680.790.480.640.690.741.291.350.981.111.161.270.550.630.690.560.481.1ËÑЬ.¹.Np2+ 6Np3+ 6Np4+ 68Np5+ 6Np6+ 6Np7+ 62O23468OH1- 2346Os4+ 6Os5+ 6Os6+ 56Os7+ 6Os8+ 46P3+4P5+56Pa3+ 6Pa4+ 68Pa5+ 689Pb2+ 46789101112Pb4+ 4568r1.101.010.870.980.750.720.711.351.361.381.401.421.321.341.351.370.630.570.490.540.520.390.440.170.290.381.040.901.010.780.910.950.981.191.231.291.351.401.451.490.650.730.770.94ËÑÐPd1+Pd2+Pd2+Pd3+Pd4+Pm3+Po4+Po6+Pr3+Pr4+Pt2+Pt4+Pt5+Pu3+Pu4+Pu5+Pu6+Ra2+Rb1+4+ReRe5+Re6+Re7+Rh3+Rh4+Rh5+Ru3+¬.¹.r24666689686689684666668668126789101112146664666660.590.640.860.760.610.971.091.140.941.080.670.991.131.180.850.960.600.800.620.571.000.860.960.740.711.481.701.521.561.611.631.661.691.721.830.630.580.550.380.530.660.600.550.68ËÑÐRu4+Ru5+Ru7+Ru8+S2S4+S6+Sb3+5+SbSc3+2-SeSe4+Se6+Si4+Sm2+Sm3+Sn4+Sr2+3+TaTa4+Ta5+¬.¹.r664466464566686646467896789124567867891012666780.620.560.380.361.840.370.120.290.760.800.760.600.740.871.980.500.280.420.260.401.221.271.320.961.021.081.131.240.550.620.690.750.811.181.211.261.311.361.440.720.680.640.690.74ËÑÐTb3+Tb3+Tb4+Tc4+Tc5+Tc7+Te2Te4+Te6+Th4+2+TiTi3+Ti4+Tl1+Tl3+Tm2+Tm3+3+UU4+¬.¹.r6789686646634646689101112664568681246867689667890.920.981.041.090.760.880.640.600.370.562.210.520.660.970.430.560.941.051.091.131.181.210.860.670.420.510.600.741.501.591.700.750.880.981.031.090.880.991.051.020.890.951.001.05ËÑÐU5+U6+V2+V3+V4+V5+W4+W5+W6+Xe8+Y3+Yb2+Yb3+Zn2+Zr4+¬.¹.r1267246786656845666456466789678678945684567891.170.760.840.450.520.730.810.860.790.640.530.580.720.350.460.540.660.620.420.510.600.400.480.900.961.021.071.021.081.140.870.920.981.040.600.680.740.900.590.660.720.780.840.89115.
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