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е.Т, КCa1-хCoxF2Sr1-х-yMnхCoyF2х = 0.01х = 0.03х = 0; y = 0.005х = 0.01; y = 0х = 0.01; y = 0.0015013.52.7830.415.812.26013.03.1328.114.411.67012.63.4226.113.311.18012.13.6724.012.410.79011.73.8821.911.710.310011.44.0520.111.29.9011011.14.1918.610.79.5612010.84.3017.410.39.2513010.54.3816.39.928.9514010.24.4515.39.588.6815010.04.4914.49.288.421609.744.5113.59.018.181709.504.5012.88.757.941809.284.4812.28.487.721909.064.4411.68.227.502008.864.4011.17.977.282108.664.3510.67.687.082208.474.3010.27.466.872308.254.259.807.186.692408.054.199.456.926.502507.844.139.076.676.312607.654.078.736.476.142707.464.028.376.265.982807.303.978.036.055.802907.143.937.755.875.653007.03.97.55.75.48471Таблица 1.32.Сглаженные значения теплопроводности монокристалловбинарного гетеровалентного твердого раствора Са1-xYbxF2+xТеплопроводность k, Вт/(м К), при содержании Yb x, ф.е.T, Кx = 0.000150x = 0.0005x = 0.001x = 0.005x = 0.007x = 0.016248.530.68.58.06.260534429.89.59.06.870464028.610.49.67.280403626.910.910.17.590353225.211.210.57.810031.52923.611.410.78.111028.52622.011.310.68.412025.324.220.711.110.58.713023.922.219.410.910.38.814021.820.718.210.610.18.915020.219.117.210.49.99.0516018.417.916.210.29.78.9517016.716.715.39.959.58.8518016.715.614.59.689.28.719015.314.713.89.458.98.520014.014.013.29.188.68.3521013.113.312.68.928.48.1522012.512.712.18.608.18.023012.012.311.68.357.97.824011.511.811.18.157.77.625010.911.310.67.947.537.526010.410.810.37.727.357.427010.110.49.97.557.207.22809.710.19.57.377.017.12909.49.79.27.196.856.93008.49.48.87.06.76.7472Продолжение таблицы 1.32T, КТеплопроводность k, Вт/(м К), при содержании Yb x, ф.е.x = 0.015x = 0.02x = 0.025x = 0.03x = 0.05504.473.452.912.531.31605.104.083.443.061.60705.734.573.863.501.83806.245.034.243.842.04906.575.384.534.132.261006.875.624.824.412.431107.105.835.034.612.581207.205.965.164.752.691307.226.055.274.862.811407.226.105.374.932.931507.206.125.454.983.031607.176.125.505.003.101707.126.095.525.013.151807.076.035.535.013.191907.025.975.535.013.212006.975.925.545.013.222106.955.875.545.013.232206.925.825.545.003.242306.895.775.544.993.242406.865.725.534.973.242506.825.665.524.943.242606.765.635.524.903.242706.695.635.524.863.242806.635.635.524.833.242906.575.635.524.803.223006.55.635.534.763.19350––––3.04400––––2.82450––––2.66500––––2.51550––––2.37600––––2.23673––––2.08473Продолжение таблицы 1.32Теплопроводность k, Вт/(м К), при содержании Yb x, ф.е.T, Кx = 0.09x = 0.12x = 0.15x = 0.20x = 0.25500.900.680.580.480.40601.050.800.710.580.49701.200.920.810.680.56801.351.040.910.780.63901.501.141.000.870.721001.651.231.080.930.801101.761.311.191.000.851201.871.411.281.060.901301.971.491.381.120.951402.041.581.441.161.011502.101.651.491.211.051602.171.711.551.261.081702.221.781.621.311.121802.281.841.671.351.161902.331.901.711.381.192002.371.931.751.421.222102.411.981.781.461.262202.442.031.811.501.312302.472.091.831.531.352402.502.151.871.571.392502.532.201.891.611.432602.552.261.921.641.482702.572.311.961.681.532802.592.371.981.731.582902.612.432.011.771.623002.622.482.041.821.67474Таблица 1.33.Сглаженные значения теплопроводности монокристалловбинарного гетеровалентного твердого раствора Sr1-xYbxF2+xТеплопроводность k, Вт/(м К), при содержании Yb x, ф.е.T, Кx = 0.001x = 0.005x = 0.01x = 0.02x = 0.055012227.711.26.902.88608323.310.846.892.95706320.810.536.883.02805119.010.246.873.10904217.79.986.853.1810035.516.69.656.803.2611031.215.59.426.733.3212027.614.79.186.663.3713025.013.78.936.593.4214022.612.98.716.503.4515021.012.38.506.383.4616019.611.78.296.253.4617018.011.28.026.103.4618016.610.67.795.963.4519015.110.27.575.853.4420013.69.87.345.733.4221012.69.57.135.603.4022012.19.26.915.473.3523011.78.946.695.333.3324011.28.656.505.233.3125010.78.426.335.153.3026010.38.216.185.063.302709.98.006.064.983.302809.557.765.934.933.302909.37.585.814.883.293009.07.425.684.863.29475Таблица 1.34.Сглаженные значения теплопроводности монокристалловбинарного гетеровалентного твердого раствора Ba1-xYbxF2+xТеплопроводность k, Вт/(м К), при содержании Yb x, ф.е.T, Кx = 0.005x = 0.01x = 0.03x = 0.06504915.44.972.55604012.84.662.517033.311.54.462.458028.510.54.262.399024.79.74.102.3310021.59.03.962.2911019.28.43.842.2412017.37.93.722.2013015.87.43.602.1714014.47.03.502.1415013.26.653.422.1216012.16.363.362.1017011.26.143.302.0818010.65.923.252.0619010.25.703.202.052009.85.493.152.042109.45.293.102.032209.15.133.052.022308.74.982.992.012408.44.862.952.012508.14.732.922.002607.84.602.911.992707.54.462.901.992807.24.332.891.982906.954.212.881.983006.734.142.881.97476Таблица 1.35.Сглаженные значения теплопроводности монокристалловбинарного гетеровалентного твердого раствора Ca1-xYxF2+xТеплопроводность k, Вт/(м К), при содержании Y x, ф.е.Т, Кх = 0.005х = 0.01х = 0.05х = 0.10 (ИК РАН)5017.211.762.00.916017.911.352.31.097018.211.052.651.258018.310.752.951.409018.110.383.221.5410017.510.223.301.6511016.610.03.401.7612015.89.793.481.8613015.19.703.551.9514014.49.603.622.0415013.79.423.702.1116013.29.253.752.1717012.79.053.802.2318012.28.903.812.2819011.78.833.832.3220011.38.603.842.3621011.08.503.852.4022010.68.333.852.4423010.38.123.852.472409.957.933.882.502509.637.853.902.542609.337.803.912.582709.057.603.932.632808.807.503.962.672908.577.453.982.713008.37.314.02.77477Продолжение таблицы 1.35Теплопроводность k, Вт/(м К), при содержании Y x, ф.е.Т, Кх = 0.12 (ИК РАН)х = 0.15х = 0.20х = 0.73500.780.6850.5600.55600.980.8080.6900.65701.150.9200.8020.75801.291.030.9070.84901.411.141.010.921001.541.251.101.001101.631.341.181.071201.711.421.251.141301.791.491.311.201401.861.551.371.251501.921.611.411.291601.981.661.451.341702.021.711.481.381802.071.751.511.411902.111.791.541.442002.151.831.561.472102.181.861.591.502202.221.901.621.532302.251.941.651.552402.281.981.671.572502.322.021.691.592602.362.051.711.612702.42.081.731.622802.452.101.751.632902.52.131.771.633002.552.151.791.63478Таблица 1.36.Сглаженные значения теплопроводности монокристалловбинарного гетеровалентного твердого раствора Ca1-xLaxF2+xТеплопроводность k, Вт/(м К), при содержании La x, ф.е.Т, Кх = 0.01х = 0.16х = 0.255015.92.211.956015.22.061.817014.62.001.738014.01.971.689013.51.951.6510013.01.931.6411012.71.921.6412012.21.921.6413011.81.921.6514011.41.931.6615011.01.941.6716010.61.961.6817010.41.971.6918010.11.981.711909.892.001.732009.652.011.762109.402.031.792209.162.051.812308.922.061.822408.682.071.832508.442.081.842608.222.081.852708.012.081.872807.812.101.902907.612.131.943007.422.172.00479Таблица 1.37.Сглаженные значения теплопроводности монокристалловбинарного гетеровалентного твердого раствора Ca1-xCexF2+xТеплопроводность k, Вт/(м К), при содержании Ce x, ф.е.Т, Кх = 0.01 выдерж.х = 0.01х = 0.05х = 0.105015.010.834.152.796014.710.834.132.717014.410.744.122.678013.910.564.112.659013.410.384.102.6410012.910.24.112.6411012.49.974.122.6512012.09.714.122.6613011.79.484.122.6714011.39.244.132.6815010.98.974.132.7016010.68.754.142.7217010.28.544.142.741809.918.364.152.761909.608.184.162.792009.308.014.172.812109.027.824.182.832208.757.654.192.852308.527.504.202.882408.327.354.202.902508.117.184.212.922607.927.044.222.952707.756.924.232.982807.616.804.253.022907.486.684.273.053007.346.574.283.08480Продолжение таблицы 1.37Теплопроводность k, Вт/(м К), при содержании Ce x, ф.е.Т, Кх = 0.15х = 0.16х = 0.19х = 0.20502.252.111.901.80602.202.001.811.74702.161.931.761.72802.141.901.741.71902.141.891.731.711002.151.891.731.711102.161.901.741.721202.171.911.751.731302.181.921.761.741402.191.931.771.751502.201.941.781.761602.211.951.801.771702.221.961.811.791802.241.9741.831.811902.261.9881.851.832002.282.0031.871.852102.302.0191.891.872202.332.0351.901.892302.362.0551.921.922402.392.0801.931.952502.422.1081.951.982602.462.1351.982.012702.502.1632.012.052802.552.1902.052.092902.602.2152.102.133002.642.2432.152.18481Таблица 1.38.Сглаженные значения теплопроводности монокристалловбинарного гетеровалентного твердого раствора Ca1-xPrxF2+xТеплопроводность k, Вт/(м К), при содержании Pr x, ф.е.Т, Кх = 0.01х = 0.03х = 0.105013.26.043.436012.45.943.387011.85.863.368011.45.803.359011.05.753.3410010.65.693.3511010.35.623.3812010.05.573.411309.715.513.431409.425.453.441509.145.403.451608.905.363.461708.695.323.461808.505.283.461908.315.233.462008.115.193.452107.945.143.442207.765.103.432307.585.063.422407.425.023.412507.284.973.42607.154.923.42707.034.883.42806.904.853.42906.804.823.43006.74.83.4482Таблица 1.39.Сглаженные значения теплопроводности монокристалловбинарного гетеровалентного твердого раствора Ca1-xErxF2+xТ, КТеплопроводность k, Вт/(м К), при содержании Er x, ф.е.х = 0.01х = 0.05х = 0.075х = 0.1050605.506.461.131.390.710.840.580.71707.291.620.980.82807.821.811.120.93908.152.011.251.041008.362.161.371.131108.532.301.501.221208.612.421.601.291308.612.511.691.361408.582.591.771.421508.582.651.841.491608.382.711.891.561708.252.761.941.621808.102.811.981.661907.962.842.011.702007.802.872.041.732107.662.902.071.762207.512.932.091.782307.362.952.121.812407.202.972.141.842507.052.982.161.862606.892.992.181.892706.763.002.191.912806.633.002.211.932906.513.002.221.953006.413.002.231.97350–2.952.282.02400–2.902.282.06450–2.842.242.08500–2.752.202.10550–2.652.162.12600–2.552.122.14650–2.542.122.16673–2.542.122.17483Таблица 1.40.Сглаженные значения теплопроводности монокристалловбинарного гетеровалентного твердого раствора Ca1-xTmxF2+xТ, КТеплопроводность k, Вт/(м К), при содержании Tm x, ф.е.х = 0.01х = 0.02х = 0.04х = 0.0650608.08.92.733.201.381.780.961.18709.53.592.111.348010.03.932.391.509010.24.232.561.6410010.44.472.711.7611010.44.672.831.8812010.44.812.961.9813010.34.923.052.0914010.15.003.132.171509.905.073.202.231609.685.123.262.281709.455.153.302.331809.235.183.332.361908.985.193.342.392008.755.203.352.422108.535.203.352.452208.315.193.352.482308.125.183.352.522407.925.173.352.542507.735.153.352.562607.555.133.342.572707.375.113.342.572807.205.083.332.572907.065.053.322.573006.95.013.302.57350–4.813.202.54400–4.553.082.48450–4.242.932.41500–3.902.782.34550–3.582.622.24600–3.342.502.17650–3.142.372.11673–3.052.312.09484Таблица 1.41.Сглаженные значения теплопроводности монокристаллов бинарного гетеровалентного твердого раствора Sr1-xLaxF2+xТеплопроводность k, Вт/(м К), при содержании La x, ф.е.Т, Кх = 0.01х = 0.02х = 0.045040.925.312.16031.920.110.57025.917.19.58021.815.18.79018.913.78.010017.012.57.511015.511.77.112014.211.06.813013.210.56.614012.510.06.315011.99.516.116011.39.145.917010.98.775.718010.58.445.519010.18.165.42009.77.855.32109.37.615.22209.07.455.12308.77.265.02408.457.094.912508.206.964.842607.956.804.782707.756.654.702807.586.544.622907.406.434.563007.286.314.5485Таблица 1.42.Сглаженные значения теплопроводности монокристалловгетеровалентных твердых растворов Ba1-xRxF2+x (R = La, Nd, Gd)Теплопроводность k, Вт/(м К), при содержании R x, ф.е.Т, КBa1-xLaxF2+хх = 0.25х = 0.30500.9040.83600.89870Ba1-xNdxF2+xх = 0.01Ba1-xGdxF2+xх = 0.02х = 0.40х = 0.01х = 0.1022.99.930.77033.32.440.8419.79.260.78227.52.360.8950.8417.28.670.79422.52.29800.8960.8515.18.080.80318.92.22900.8970.8613.57.500.81116.52.161000.8980.8712.27.010.81814.42.101100.9020.8711.16.580.82412.92.051200.9060.8810.36.150.83111.82.001300.9120.889.675.820.83610.81.961400.9190.899.125.550.84310.11.921500.9270.898.595.320.8499.511.881600.9360.908.165.100.8559.001.851700.9450.907.744.900.8618.501.821800.9540.917.364.740.8678.031.791900.9650.917.044.590.8737.641.772000.9760.916.724.440.8797.331.752100.9870.926.484.310.8847.001.742200.9970.926.254.180.8906.701.732301.010.926.054.050.8956.461.722401.020.935.853.920.9006.251.712501.030.935.683.820.9056.051.702601.040.935.523.710.9105.851.692701.050.935.373.620.9145.661.682801.060.935.223.550.9195.461.672901.070.945.083.480.9235.291.663001.080.944.953.410.9265.131.65486Таблица 1.43.Сглаженные значения теплопроводности монокристалловбинарного гетеровалентного твердого раствора Ba1-xHoxF2+xТеплопроводность k, Вт/(м К), при содержании Ho x, ф.е.Т, Кх = 0.01х = 0.02х = 0.05х = 0.15509.87.24.061.84608.76.73.891.76707.866.33.751.70807.275.93.631.65906.765.53.511.611006.305.23.391.581105.964.93.291.551205.654.73.211.521305.384.513.141.501405.204.343.081.491505.044.223.021.491604.904.102.971.501704.774.002.921.511804.663.922.891.531904.573.852.871.552004.483.802.861.582104.413.762.8541.612204.363.722.8531.652304.313.682.8551.702404.253.642.8611.752504.193.612.8691.792604.143.582.8761.842704.103.562.8831.902804.063.542.8911.952904.023.522.8982.003003.983.52.9042.04487Таблица 1.44.Сглаженные значения теплопроводности монокристалловбинарного гетеровалентного твердого раствора Ba1-xCexF2+xТеплопроводность k, Вт/(м К), при содержании Ce x, ф.е.Т, Кх = 0.0003х = 0.0006х = 0.0009х = 0.00125096856766606761527051468040.590х = 0.0015х = 0.01х = 0.506918.60.55515417.30.5942414316.20.6336.73433.535.215.20.6732.730.628.528.329.514.20.7110027.626.024.624.325.913.30.7511024.022.621.521.522.612.40.7812021.220.118.718.919.811.60.8013018.818.116.917.017.510.80.8214016.616.415.315.415.610.10.8415015.115.013.914.014.49.540.8516013.713.712.912.913.39.020.8617012.612.712.011.912.28.550.8718011.811.8411.211.111.48.130.8819011.111.1510.410.410.77.740.88520010.410.509.819.7410.07.390.8882109.739.939.329.309.507.070.8932209.219.408.868.909.046.780.8982308.708.898.448.458.586.520.9052408.308.438.068.088.176.320.9112507.918.037.707.707.856.110.9182607.577.717.387.387.585.890.9232707.257.407.147.147.285.690.9302806.987.076.886.886.955.500.9352906.706.806.596.596.615.320.9403006.456.546.36.36.35.170.944488Таблица 1.45.Сглаженные значения теплопроводности монокристалловбинарных гетеровалентных твердых растворов Сa0.99R0.01F2.01 (R = РЗЭ)Теплопроводность k, Вт/(м К)Т, КR = LaR = CeR = PrR = NdR = SmR = GdR = Tb5015.915.013.217.713.119.18.806015.214.712.416.312.717.59.407014.614.411.815.212.416.49.708014.013.911.414.312.015.510.09013.513.411.013.611.614.810.110013.012.910.613.011.314.210.211012.712.410.312.411.113.810.112012.212.010.011.910.913.310.013011.811.79.7111.510.612.79.8414011.411.39.4211.210.312.39.6815011.010.99.1410.810.011.99.4816010.610.68.9010.59.6011.49.2317010.410.28.6910.19.3011.08.9218010.19.918.509.809.1010.58.7010.28.471909.899.608.319.508.902009.659.308.119.158.709.808.242109.409.027.948.868.509.488.022209.168.757.768.588.309.177.802308.928.527.588.288.008.867.622408.688.327.428.047.808.607.482508.448.117.287.847.708.367.352608.227.927.157.657.608.177.252708.017.757.037.477.407.967.132807.817.616.907.297.207.757.002907.617.486.807.157.007.536.903007.427.346.707.006.907.356.80489Продолжение таблицы 1.45Теплопроводность k, Вт/(м К)Т, КR = DyR = HoR = Er506.006.005.50607.207.40708.1080R = YbR = Lu8.006.207.006.468.907.207.708.407.299.507.808.508.709.107.8210.08.409.10909.309.608.1510.28.709.501009.709.908.3610.48.809.801109.9010.08.5310.48.909.8010.08.6110.49.059.809.908.6110.38.959.7010.18.859.6012010.013010.0R = Tm1409.929.808.581509.759.608.589.908.709.501609.599.408.389.688.509.301709.409.208.259.458.359.131809.208.958.109.238.158.941908.968.707.968.988.008.742008.748.507.808.757.808.522108.528.307.668.537.608.332208.308.127.518.317.508.152308.107.977.368.127.408.002407.837.857.207.927.207.852507.647.737.057.737.107.712607.507.606.897.556.907.582707.387.456.767.376.707.432807.257.306.637.206.607.302907.137.196.517.066.407.203007.007.066.416.906.307.10490Таблица 1.46.Сглаженные значения теплопроводности монокристалловбинарных гетеровалентных твердых растворов Sr0.99R0.01F2.01 (R = РЗЭ)Теплопроводность k, Вт/(м К)Т, КR=YR = LaR = CeR = PrR = SmR = GdR = Tb5012.737.417.021.111.7822.28.436012.229.515.718.911.6320.89.177011.724.414.917.211.4519.39.418011.320.914.115.611.2617.99.469010.918.413.414.311.0416.69.4110010.616.612.813.410.7515.49.2311010.315.212.112.610.4814.39.041209.9014.111.511.910.1513.48.831309.5913.111.011.39.8712.58.611409.3012.210.510.79.5811.88.401508.9911.510.110.29.3011.28.221608.6811.09.729.789.0010.78.051708.4010.59.359.368.7210.27.871808.1410.19.018.968.459.847.671907.889.708.708.618.199.447.482007.649.318.448.317.909.047.302107.438.928.198.047.648.667.132207.208.587.937.787.398.366.952306.998.277.697.517.148.086.782406.818.007.507.286.917.786.622506.647.737.317.086.737.546.452606.487.527.086.866.557.336.302706.347.356.876.656.407.156.152806.217.206.696.486.276.986.002906.077.046.536.326.166.835.863005.956.96.376.166.056.715.74491Продолжение таблицы 1.46Теплопроводность k, Вт/(м К)Т, КR = DyR = Ho5010.310.36010.870R = ErR = TmR = YbR = Lu10.7612.3311.215.710.4210.3512.0610.8414.310.9310.3610.0511.7610.5313.48010.9710.279.7611.4910.2412.69010.9510.19.4911.179.9812.010010.89.849.2410.829.6511.411010.69.548.9810.469.4210.912010.39.288.7010.169.1810.413010.09.008.479.848.9310.01409.708.728.239.528.719.631509.398.488.019.288.509.281609.058.247.829.018.299.011708.707.987.618.748.028.721808.357.757.418.487.798.401907.987.557.228.257.578.132007.637.357.048.017.347.902107.327.176.877.797.137.672207.047.006.687.566.917.452306.796.836.507.346.697.242406.576.666.357.136.507.022506.376.516.226.966.336.812606.196.396.106.766.186.632706.036.285.996.606.066.472805.896.165.896.455.936.322905.796.075.806.315.816.183005.726.05.746.175.686.06492Таблица 1.47.Сглаженные значения теплопроводности монокристалловбинарных гетеровалентных твердых растворов Ba0.99R0.01F2.01 (R = РЗЭ)Теплопроводность k, Вт/(м К)Т, КR=YR = LaR = CeR = PrR = NdR = SmR = Gd5022.031.518.621.822.916.133.36018.824.917.318.219.714.927.57016.520.516.215.717.213.822.58014.417.215.213.815.112.818.99012.614.814.212.413.511.916.510011.313.413.311.212.211.114.411010.412.212.410.311.110.412.91209.7011.011.69.601309.0010.310.88.921408.509.6010.11508.059.001607.6017010.39.6511.89.679.1110.88.469.128.6110.19.548.028.598.169.518.509.027.648.167.759.007.248.098.557.337.747.398.501806.917.708.137.007.367.068.031906.607.397.746.727.046.787.642006.347.107.396.496.726.547.332106.096.837.076.276.486.307.002205.866.616.786.066.256.096.702305.676.366.525.876.055.906.462405.506.156.325.705.855.736.252505.335.986.115.525.685.586.052605.175.805.895.395.525.425.852705.025.635.695.235.375.275.662804.865.475.505.095.225.115.462904.725.325.324.955.084.985.293004.605.165.174.824.954.875.13493Продолжение таблицы 1.47Теплопроводность k, Вт/(м К)Т, КR = TbR = DyR = HoR = ErR = TmR = YbR = Lu5015.916.521.519.525.815.421.56014.614.918.616.721.312.818.17013.513.516.214.718.411.515.88012.612.414.413.116.210.513.99011.6511.313.111.714.39.7012.510010.8510.411.910.713.18.9511.511010.159.6411.09.8011.98.4110.71209.519.0410.19.1011.17.869.951308.948.559.448.5410.37.409.281408.458.058.868.109.637.058.611508.007.668.287.709.056.678.101607.597.317.847.348.546.367.671707.247.027.457.018.136.157.321806.946.747.056.677.765.937.031906.676.486.756.427.375.706.742006.416.266.506.187.085.486.482106.216.076.285.976.855.306.232206.035.886.095.796.605.156.032305.855.705.935.606.315.005.842405.705.545.775.436.054.865.662505.535.385.625.275.864.745.502605.405.215.475.115.704.605.342705.255.075.334.965.524.455.192805.104.945.184.825.374.325.062904.974.825.024.695.214.214.933004.844.74.894.575.054.144.80494Таблица 1.48.Зависимость теплопроводности монокристаллов твердых растворов Cа0.99R0.01F2.01от ионного радиуса и от массы легирующего РЗЭКристаллRi, Ангстрем Масса, а.е.м.

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