Отзыв оппонента 2 (Основы технологии получения хлористого метила каталитическим окислительным хлорированием метана под давлением)
Описание файла
Файл "Отзыв оппонента 2" внутри архива находится в следующих папках: Основы технологии получения хлористого метила каталитическим окислительным хлорированием метана под давлением, Документы. PDF-файл из архива "Основы технологии получения хлористого метила каталитическим окислительным хлорированием метана под давлением", который расположен в категории "". Всё это находится в предмете "технические науки" из Аспирантура и докторантура, которые можно найти в файловом архиве РТУ МИРЭА. Не смотря на прямую связь этого архива с РТУ МИРЭА, его также можно найти и в других разделах. Архив можно найти в разделе "остальное", в предмете "диссертации и авторефераты" в общих файлах, а ещё этот архив представляет собой кандидатскую диссертацию, поэтому ещё представлен в разделе всех диссертаций на соискание учёной степени кандидата технических наук.
Просмотр PDF-файла онлайн
Текст из PDF
OT3bIB04lHU;HaJlbHOrOCepreeensrKaTaJlHTHqeCKHMnpeACTaBJleHHYIOonnonenra«OCHOBbIHa COHCKaHHeAKryaJlbHOCTbyxeaoä05.17.04 -TeMbIrrOCBSI~eHa paJpa60TKenonyseaaaTeXHOJlOrHHAHccepTaU;HH.OCHOB TeXHonorMMxnopaponaaaeaMeTaHaTeXHHqeCKHXpacnonararomeäOrpOMHbIMM sanacasraBew;eCTB.)J;aHHaSl ,lJJ1ccepTalJ,M9HHaSl paöorarrpoM3BoAcTBaxnopMcToronpapozraoronepeopaerrrauaarasa,BHa ero XßMMlJecKYIO nepepaöorxyBMexaHM3Ma peaxuaanpO.IJ:YKTOB.l103TOMYMO.IJ:enb, YlJMTblBalO~YIOKOMrrOHeHTaMM xaranasaropa,rrpO.IJ:YKTa npasoznrrnpenno.raranocsCBSl3aHaB nepnyropaspaöorarr,conpaacemreocymecrsnarouraxaKryMbHOH 3a.IJ:alJeH.oxacmrrem.aoroKMHeTMlJeCKMX.IJ:aHHbIXrrosaomrn asropyMaprnpYTOB,oxepezrs C nepecvorpovxnopaposanasMeTaHa.
AHMM3CO.IJ:ep)J<aTenbHYIOKMHeTMlJeCKYIOxaranaaapyexux)J;OKaJaHO TaK)J(e, lJTO KpaJnMlJHbIMM06paJOBaHßIOHe B3aßMO.IJ:eHCTBßeMeTaHa C MoneKynSlpHbIMpanee,onedmasr,CMHTe3a,B TOM lJMCne, B aasmae<PYHKIJ,MOHMß3aIJ,MIOMeTaHa, SlBMeTCSI,öesycnosao,HCCJleAOBaHHHPOCCMM,KOTOPbIH ncnonssyercaC03.IJ:aHMeHOBbIX ß YCOBeprneHCTBOBaHMecy~eCTByIO~MX rcxaononrä,oömerrpansroroCTaAMeHxosnrnexcarrepcrrercmse nepeära OT sxcnopra csrpsa K sxcnopryHOBH3HaMeTßnaSlBnSleTCSInepsoäTorrnMBHO-3HepreTßlJeCKOrOuemrsre rrpO.IJ:YKTbIOCHOBHoro opramrsecxoroHayxaasHaYK noB KOTOPOM rrOCTOSlHHOB03paCTaIOT. YlJßTbIBaSIcrpyxrypuOCHOBHOMKaK saeproaocnrens,nOA AaBJleHHeM»,OpraHHqeCKHXMeTaHa.
)J;aHHbIH npouecc3TMneHa, norpeöaocrnCHJlHHOH HPHHbIXJlOpHCTOro MeTHJlaCTeneHH KaHAHAaTaTeXHOJlOrHHoco6eHHOCTMrr03BonMT BnonyxeaaaOKHCJlHTeJlbHbIM XJlOpHpOBaHHeMCneU;HaJlbHOCTHoxacmrrensnsrapaöoryHa AHccepTaU;HOHHYIOa B3aßMO.IJ:eHCTBßeMeTaHa C conaaaueneaoroxnOPOM, KaKxaramrsaropa,TaKMM06PaJOM .IJ:OKaJaHaKaTMMTßlJeCKaSlaKTßBHOCTbOCHOBHbIXero KOMrrOHeHTOB.IIpaKTHqeCKaH3HalJeHßHueuuocrspa60TbIOCHOBHbIX napauerpoarexneparypanpouecca,3aKnlOlJaeTCSIB ycranonneaanpeaxnanOXM(cooraomenaeBpeMSI KOHTaKTa, COCTaB xaranasaropa),.IJ:OcTßraeTcSIBbICOKaSICeneKTßBHOCTbrro IJ,eneBoMYxnOPßCTOMY MeTßny.Ouemca•cOAepJKaHHH H CTPYKryPbIAHccepTaU;HHonTßMMbHbIXnpnpearenron,KOTOPbIX•Crpyxrypacrpanauaxzracceprauaa5IBJI5IeTC5Ixnaccasecxoä.,lJ;ßCCepTaU;ß5Iß3JIO)l(eHa Ha 196MalIIßHorrßCHoro TeKCTa ß COCTOßTas BBe.n;eHß5I,rnrreparypnororrOCTaHOBKli aana-m,conepxanas,excnepaaearam.aoäqaCTßBbIBO.n;OB,npanoxeaaaß cnacxaßxersrpexnacreämrreparypsr,oösopa,OCHOBHoromonoxaromero161HaßMeHOBaHße.BoBBe.n;eHßß zranopaapaöoranaocra,axryansaocrapa60TbIC<POPMYJIßpoBaHbInens ß OCHOBHbleaanaxaHOBß3Ha, reoperaxecxassaunrry,oöocaoaaaaeanpoöarnorß npaxrasecxaspa60TbI, a raioseßcreneaaeeßCCJIe.n;OBaHß5I,nayxaas3HaqßMOCTb, rrOJIO)l(eHß5I, B,bIHOCßMble Hanonpoöaoonacanacrpyxrypazmccepranaonrroäpa6oThI.nepsoäBcymecrnyromaxraroxe,[JIaBe(OE30PJU1TEPATYPhI)Ha ceroznonnnaä.n;eHbcnocoöosnanoaaropyxaaeraxaOKliCJIßTeJIbHOrO XJIOpßpOBaHß5I MeTaHa.
IlpoaeztenasräC<POPMYJIßpOBaTbOCHOBHYIOuem, pa60TbI ([JIaBaaanasn, xoropsre neoöxonavopennrrs.n;JI5Irrposenenaspeaxnan2), a TaK)l(e onpenenarsee .n;OCTß)I(eHß5I.OXM, oöpaöorxa'raroxe, MeTo.n;ßKß ßCCJIe.n;OBaHß5Ixnaeraxanposeztenaaxpovarorparpasecsoroxaramrsarope,.n;JI5Ionpeneneaaapeaxnaa.aaanasa,coapeaeansrxMeTo.n;ßK nonyaeanasxcnepaaearansnsrx.n;aHHbIX,a,lJ;eTaJIbHOe onacaaneorrpenenennaKOJIßQeCTBaxnopoaonopozraßCCJIe.n;OBaHß5Ixaranasaropoaß MexaHß3MaHaJIß3 rr03BOJIßJITpeTb5I rnana (MeTo.n;ßQeCKa5I QaCTb) BKJIIOQaer ormcaaaexarannsaropa,ormcamre,rrOJIYQeHß5IHß31IIßX OJIe<pßHOB, a.n;eTaJIbHO paCCMO'IpeHbI TeXHOJIOrß5I, xaramrsaropsr,npoueccanonpoönoecoztepacaaasMeTo.n;ßKliMe.n;ß Bß xnopa, a TaK)l(e npasreaeaae<pß3ßKO-xßMßQeCKliX MeTo.n;OB,TaKßXTaK P<l>A ß 3JIeK'IpoHHa5I MßKpOCKOrrß5I,He OCTaBJI5IIOTCOMHeHßll B .n;OCTOBepHOCTßrrOJIYQeHHbIXpe3YJIbTaTOB.OCHOBHble pe3YJIbTaTbI pa60ThI ß3JIO)l(eHbI B rJIaBaX 4-7 znrccepramra.coseranaenpasreneaaeoxcnepaverrram.asrxcoapeueansrxzmccepranaoanoäßpaCQeTHbIX MeTo.n;OB, aTaK)l(e onpaanaaaoe<pß3ßKo-XßMßQeCKliX MeTo.n;OBaaanasapa60TbI npezrnozorrsYnaxnoerr03BOJIßJIO asropyC6aJIaHcßpoBaHHYlO rro XJIOpy npamnmaansayroTeXHOJIOrßlleCKYlOcxesry rrpOMbIlIIJIeHHOllYCTaHOBKlinpouecca OXM.IIo.LJ:TBep~eHueHaY"lJHbIXnyönaxannsx.U3.LJ:aHUSlX.ony6JIUKOBaUuSIOCHoBHoeOCHOBHbIX.
pe3YJIbTaTOBconepacaaneITo MaTepUaJIaM zmcceprauaapa60Torryönaxosanoorpazceno.LJ:UCCepTaIIuu BB5 naysnsrxasropcxaxpa60TBBe,lJ;YInHX penensapyeauxnaysnsrx)l(ypmUIax,MHHHCTepCTBa oöpasosaaaaH HaYKH P<l>, a 'raroxe rrony-renaaroperpepara 'raxsce rrOJlHOCTblOcoorsercrayerBKJUOqeHHbIX BconepzcaamonepenensBAK1 rrareirr P<l>. Conepzcanae,lJ;HCCepTanHH.Ilo ,lJ;HCCepTanHOHHoHpaöore HMeIOTC}IcJle,lJ;YIOInHe3aMeqaHHH:1.IlposeztenaepeaKQHH OXMnocraaoaxysanasnmrreparypsr,B KOTOPOM3TOMY sorrpocynparrOBbIlIIeHHOM ,lJ;aBJlemm BbIHeceHO BH B Ha3BaHHe ,lJ;HCCepTanHoHHOHpa6OTbI,KaKHe npeavymecraaH rronpaxrnvecrorKaKOH npaxaaeonnaxoHe yneneaoBHHMaHH}I, He }lCHO,O)l(H,lJ;aIOTC}IOT TaKOH, oprannsanaanponecca.
PeaKnH}I HCCJle,lJ;OBaHarrpn 'rpex BeJlHqHHaX ,lJ;aBJIeHH}I:1,arvocrpepaouHaH60JIee rrO,lJ;p06HOHMeHHO npnKOTOPbIH OInYTHMO YJIyqlIIaeTC}I npaKaTaJIH3aTopa. IlposonanacsTaKOHopranasauaaH3 oösopa6 H 9 aTM., rrprrrev,,lJ;aBJleHHH.E,lJ;HHCTBeHHbIHnapauerp,rrOBbIlIIeHHH ,lJ;aBJIeHH}I-rrpOH3BO,lJ;HTeJIbHOCTbouenxa 3KOHOMHqeCKOH neJleC006pa3HOCTHJlH asroponnpouecca? BbIlIIe 9 aTM. 3KcrrepHMeHTOB He 6bIJIO. Ilosexy?BTaKOM cnysae spxn JI~ MO)l(HOHa3bIBaTb 3TO ,lJ;aBJIeHHeOrrTHMaJIbHbIM.2.qeM onpenenancsXOT}I 6bI npenaaprrrensno.oraesaer4.2.6BbI60p HOCHTeJI}I?EbIJIH JIH acnsrraasrTpe6oBaHHIO HaJIßqH}{ He6oJIblIIOH y,lJ;eJIbHOHnosepxnocra60JIblIIOe qHCJIO OKCH,lJ;HbIXHOCHTeJIeH,nanpnaep,aJIlOMOCHJIHKaT YKa3aHnonpaayxeaaernpyroroeroztpyrae HOCHTeJIHcpasneaaeKaKOrrTHMaJIbHbIHOKCH,lJ;THTaHa.
B paszrene(peKOMeH,lJ;OBaHHbIH), qTOC ,lJ;pyrHMH HOCHTeJI}lMH, HJIH C aJIlOMOCHJIHKaTaMHCOCTaBa.3.B pasnenerOTOBHJIHnpomrrxoä3.1. 3KcrrepHMeHTaJIbHOH qaCTH YKa3aHO, qTO KaTaJIH3aTOpB H36bITKe pacTBOpHTeJI}I C rrOCJIe,IJ;yIOIneHCYIIIKOH npa11O-130C.,[(aJIee npn HCCJIe,lJ;OBaHHHKaTaJIH3aTOpa 6bIJIO YCTaHOBJIeHOqTO COJIH nepaeaovepaopacnpenenensrrroerorrosepxnocraHpacrsopsrrrJIOXO npoaaxarorBnopsr.Ilpencraanaercs60JIee neJIeC006pa3HbIM B ,lJ;aHHOMcnysae HCrrOJIb30BaTbnpornnxyrroBJIaroeMKocTH (B03MO)l(HO HeO,lJ;HOKpaTHYIO)C rrOCJIe,IJ;yIOIneH,lJ;JIHTeJlbHOHCYIIIKOH rrpnKOMHaTHOHreaneparype.4.IlpencraanaercsKaTaJIH3aTOpe CsaxynopxeHMaJIOBep0}lTHbIM, qTO YBeJIHqeHHe coztepzcanas6 ,lJ;O8% npasenerMe,lJ;HBK TOTaJIbHOMYCHH)I(eHHIO rrOBepXHOCTHH rrOJIHOHrrop, HO 3TO JIerKO nponeprrrsH3MepeHHeM BeJIHqHHbI rrOBepXHOCTHrro E3Toöi.eaa rrop ,lJ;JI}I6 H 8% KaTaJIH3aTOpaCOOTBeTCTBeHHO,TeM öonee, qTO Heo6xo,lJ;HMbIHHHCTPYMeHTapHHHMeeTC}I (pasnen4.2.4 cTP.
99).5.HnrepecnoeKaTaJIH3aTOpeno6-8%06b5lCHeHHH (pasnen6.crenensxornaHe H3MeH5IeTC5I, K CO)l(aJIeHHIO, OCTaJIOCb 6e3pens«CKOPOCTbIO 06pa30BaHIDI»anerrrpe)l,CTaBJI5IeTC5I He BrrOJIHe0 CbeMe HJIH rrpOH3BO)l,HTeJIbHOCTH KaTaJIH3aTOpa (PHC.98, pHC. 43, CTp. 100, qaCTO B rexcre).7.HescernarrOH51THO, B qeM(Hanpavep,YCJIOBIDIX?CTaUICTHKa,TO8.Ta6JIHU;bInoseayaKIJ;eHTrrOBbIllIeHHOM)l,aBJIeHHH,(conepacanaeMe)l,H,BJIIDIHIDI(Ta6JIHu;a 4.8, crp.B9.He» (crp.H4.8,B rrapaxonsrrsr61-63).npnO)l,HHaKOBbIXECJIHaapsapyensrxHe )l,JI5I scex)l,eJIaeTC5I HaBrrOJIHe 51CHO,BpeM5IKOHTaKTa,)l,aBJIeHIDI 'raioxesronpocronapaxerpos)l,JI5InpoueccanposenenaenoseayorrTHMH3aU;HIOresmeparypa)erorrpOBO)l,51T rrpnB351JIH KaTaJIH3aTOpHeOXMnparrapaxrerpos1aTM.?OrrTHMaJIbHOrOIIpHCOCTaBa99).ueynaxaueTeKCTe )l,HCCepTaU;HH BcrpeqaIOTC5I«rrOKa3aTeJIH KaTaJIH3aTopa»«nosenenae4.7.OHa npasenenaIIoCKOJIbKYH3yqeHHHOTJIHqHe onsrrosaxcnepaaenros?)l,aHHOH cepanTOM...yaoca5.1, CTp.
105).CJIOBOCOqeTaHHeKoppeKTHbIM,41, crp.Ha6JIIO)l,eHHe 0 TOM, qTO rrpn YBeJIHqeHHH CO)l,ep)l(aHIDI Me)l,H B(crp.46),IlpaseneaasreH orresarxn:«HOCHTeJIb KaTaJIHTHqeCKOH aKTHBHOCTH» (crp.48),COJIeH Ha rrOBepXHOCTH HOCHTeJI5l» (crp.100), Ha3BaHHe pasnenassrpaaceaas5.2 (crp.64,108), nonexy111),«oöpanrrsBHHMaHHe HaTOJIbKO HOCHTeJIeH?3aMeqaHIDI He CHH)l(aIOT u;eHHOCTHH 3HaqHMOCTH ztaccepranaonaoroHCCJIe)l,OBaHIDIH He BJIIDIIOT HaoöuteerrOJIO)l(HTeJIbHOe nnesarneaaeOT pa60TbI.3aKJIIOQeHHe~HccepTaU;HOHHa51XJIOpHCTOroMeTHJIapaöoraCHJIHHOHKaTaJIHTHqeCKHMH.C«OCHOBbIOKHCJIHTeJIbHbIM XJIOpHpOBaHHeM)l,aBJIeHHeM» rrpe)l,CTaBJI5IeT H3 ce651 3aBepllIeHHYIOHa aKryaJIbHYIOTeMY, HMeeT cymecrseaaoe3HaqeHHeOpraHHqeCKOrOpa3pa60TKHOCHOBTeXHOJIOrHH rrOJIyqeHIDI 3THJIeHa.aBTopOMnanpaanenanpaaepe6bITbHapeurenaeBa)l(HOH)l,JI5I rrpHMeHeHIDICnonsana-ra -K HCCJIe)l,OBaHHIO MexaHH3MarrO)l,TBep)l,HJIH CBOIO 3<p<peKTHBHOCTbC03)l,aHH5I a)l,eKBaTHOH CTerreHHOH KHHeTHqeCKOH MO)l,eJIHpeKOMeH.lI.OBaHLIMeTaHa)l,JI5I HaYKH H rrpOMbIIlIJIeHHOCTH)l,HCCepTaU;HH nonxoznrpeaKU;HH OKHCJIHTeJIbHOrO XJIOpHpOBaHH5I MeTaHaHarrOJIyqeHIDIHayqHO-KBaJIH<pHKaU;HOHHYIO paöoryOCHOBHoroPaspaöoraaasreCHHTe3a,TeXHOJIOrHHu;eJIbIOrrOBbIllIeHIDInpoueccaH MOryT3<p<peKTHBHOCTHcy~eCTBYIO~MXrronyxarsMC03,UaHIDI HOBbIXKaTaJIMTMqeCKHX np0l(eCCOB,n03BOJUlIO~MXueaasre np0'uYKTbI OCHOBHOrOOpraHMqeCKOrO CMHTe3a.Pa60TaCOOTBeTcTByeTOpraHWIeCKMXBe~eCTBXMMWIeCKMXOCHOBBMnacnoprypaanenaxHn.4MCCJIe,UoBaHMM n.2TeXHOJIOrMqeCKMX npMHUMnoBTeXHOJIOrHM, II03BOIDIIO~MX pemarsöesonacaocra.»CneUMaJIbHOCTM 05.17.04np06JIeMbI-TeXHOJIOrml«Pa3pa60TKaHaYKoeMKMXpecypcocöepexeaas<pM3MKO-XMMMqeCKMXM 3KOJIOrMqeCKOM«Co3,UaHMe HOBbIX KaTaJIMTMqeCKMX CMCTeM M TeXHOJIOrMMnpOM3BO,UCTBaOpraHHqeCKHX npO,UYKTOBHa MX OCHOBe».,n;MccepTaUMOHHIDI paöora«IloJIo)KeHIDI0 nopsnxesceaCOOTBeTcTByeTnpMCY)KJleHM5I yseasrxcreneaeä»I1paBHTeJIbCTBa POCCMMCKOM<I>e,UepaUMMNQ842 OT 24M3MeHeHM5IIlocTaHoBJIeHIDI"Tpe60BaHIDIM(nn.9-14,UeMCTBYIO~eroIlocTaHoBJIeHIDICeHT5I6p51 2013r.IlpaBMTeJIbcTBa POCCMMCKOM<I>e,UepaUMMOT 21r.
