Диссертация (Теплопроводность твердотельных оптических материалов на основе неорганических оксидов и фторидов), страница 82

k(100 К)k(150 К)k(200 К)k(300 К)Са0.99La0.01F3.011.300138.9113.011.09.657.42Са0.99Ce0.01F3.011.283140.1212.910.99.307.34Са0.99Pr0.01F3.011.266140.9110.68.116.70Са0.99Nd0.01F3.011.249144.2413.010.89.157.00Са0.99Sm0.01F3.011.219150.4011.310.08.706.90Са0.99Gd0.01F3.011.193157.2514.211.99.807.35Са0.99Tb0.01F3.011.180158.9310.29.488.246.80Са0.99Dy0.01F3.011.167162.509.709.758.747.00Са0.99Ho0.01F3.011.150164.939.909.608.507.06Са0.99Er0.01F3.011.144167.268.368.587.806.41Са0.99Tm0.01F3.011.134168.939.908.756.90Са0.99Yb0.01F3.011.125173.048.808.707.806.30Са0.99Lu0.01F3.011.117174.979.809.508.527.1010.49.14Таблица 1.49.Зависимость теплопроводности монокристаллов твердых растворов Sr0.99R0.01F2.01от ионного радиуса и от массы легирующего РЗЭКристаллRi, Ангстрем Масса, а.е.м.Sr0.99Y0.01F3.011.159Sr0.99La0.01F3.011.300Sr0.99Ce0.01F3.0188.906k(50 К)k(100 К)k(200 К)k(300 К)10.310.67.645.95138.9137.416.69.316.901.283140.1217.012.88.446.37Sr0.99Pr0.01F3.011.266140.9121.113.48.316.16Sr0.99Sm0.01F3.011.219150.4011.810.87.906.05Sr0.99Gd0.01F3.011.193157.2522.215.49.046.71Sr0.99Tb0.01F3.011.180158.937.305.74Sr0.99Dy0.01F3.011.167162.5012.77.635.72Sr0.99Ho0.01F3.011.150164.9310.39.847.356.00Sr0.99Er0.01F3.011.144167.2610.89.247.045.74Sr0.99Tm0.01F3.011.134168.9312.310.88.016.17Sr0.99Yb0.01F3.011.125173.0411.29.657.345.68Sr0.99Lu0.01F3.011.117174.9715.77.906.068.439.2310.811.4495Таблица 1.50.Зависимость теплопроводности монокристаллов твердых растворов Ba0.99R0.01F2.01от ионного радиуса и от массы легирующего РЗЭКристаллRi, Ангстрем Масса, а.е.м.88.906k(100 К)k(150 К)k(200 К)k(300 К)22.011.36.344.60Ba0.99Y0.01F3.011.159Ba0.99La0.01F3.011.300138.9131.513.47.105.16Ba0.99Ce0.01F3.011.283140.1218.613.37.395.17Ba0.99Pr0.01F3.011.266140.9121.811.26.494.82Ba0.99Nd0.01F3.011.249144.2422.912.26.724.95Ba0.99Sm0.01F3.011.219150.4016.111.16.544.87Ba0.99Gd0.01F3.011.193157.2533.314.47.335.13Ba0.99Tb0.01F3.011.180158.9315.910.856.414.84Ba0.99Dy0.01F3.011.167162.5016.510.46.264.70Ba0.99Ho0.01F3.011.150164.9321.511.96.504.89Ba0.99Er0.01F3.011.144167.2619.510.76.184.57Ba0.99Tm0.01F3.011.134168.9325.813.17.085.05Ba0.99Yb0.01F3.011.125173.0415.45.484.14Ba0.99Lu0.01F3.011.117174.9721.56.484.808.9511.5496Таблица 1.51.Сглаженные значения теплопроводности монокристалловгетеровалентных твердых растворов Cd1-xRxF2+x (R = Nd, Ho, Er)Теплопроводность k, Вт/(м К)Т, КCd0.97Nd0.03F2.03Cd0.85Ho0.15F2.15Cd0.90Er0.10F2.105011.51.141.336010.11.201.40709.31.251.46808.71.301.53908.21.351.581007.71.411.631107.31.451.671206.91.481.721306.51.501.761406.21.521.791505.91.561.811605.61.591.821705.31.611.841805.11.621.851905.01.641.862004.81.661.872104.651.681.882204.521.701.882304.401.721.882404.311.731.882504.201.751.882604.131.761.882704.051.781.892804.001.811.902903.951.841.923003.881.861.33497Таблица 1.52.Сглаженные значения теплопроводности монокристалловтройных гетеровалентных твердых растворов Sr1-x-yLaxPryF2+x+yТеплопроводность k, Вт/(м К), при содержании La x, Pr y, ф.е.Т, Кх = 0.003y = 0.007х = 0.005y = 0.005х = 0.015y = 0.005х = 0.025y = 0.0055030.028.418.813.66025.623.616.211.87022.220.214.310.78019.617.912.89.959017.516.011.79.3410015.614.710.78.7511014.413.49.958.2612013.412.59.407.8713012.511.78.967.5314011.711.08.517.1715011.110.48.096.8916010.59.907.796.6517010.09.467.526.451809.559.057.256.261909.168.717.056.102008.848.356.875.942108.528.086.645.782208.197.806.435.642307.927.576.285.522407.667.366.155.402507.457.136.035.282607.256.955.915.182707.076.765.825.102806.906.595.725.032906.756.455.614.963006.626.345.54.9498Таблица 1.53.Сглаженные значения теплопроводности монокристалловтройных гетеровалентных твердых растворов Sr1-x-yLaxNdyF2+x+yТеплопроводность k, Вт/(м К), при содержании La x, Nd y, ф.е.Т, Кх = 0.003y = 0.007х = 0.005y = 0.005х = 0.015y = 0.005х = 0.09y = 0.035026.029.019.95.796022.423.917.25.607019.720.615.25.438017.518.113.75.279015.916.112.55.1210014.514.711.54.9811013.413.610.74.8512012.512.610.24.7313011.711.89.674.6114011.011.29.214.5015010.410.68.834.4010.18.514.301609.881709.449.658.224.211808.969.257.924.131908.748.847.634.062008.378.507.403.992108.208.207.183.922207.927.926.943.862307.637.636.753.802407.407.406.583.752507.207.206.433.692607.017.016.313.642706.856.856.203.602806.696.696.093.552906.546.546.003.513006.426.395.93.47499Таблица 1.54.Сглаженные значения теплопроводности монокристалловтройных твердых растворов Ca1-x-ySryRxF2+xТеплопроводность k, Вт/(м К)Т, КCa0.85Sr0.10La0.05F2.05Ca0.77Sr0.07La0.16F2.16Ca0.70Sr0.11Ce0.19F2.19505.282.031.87604.901.911.79704.611.831.76804.391.781.75904.191.771.741004.071.771.741103.971.771.741203.901.781.741303.851.791.751403.801.801.761503.761.811.781603.711.831.791703.671.841.801803.631.861.811903.591.881.832003.571.891.852103.551.901.882203.541.901.932303.541.912.002403.551.922.052503.581.942.102603.621.982.152703.662.022.202803.702.062.252903.742.112.303003.782.162.37500Продолжение таблицы 1.54Теплопроводность k, Вт/(м К)Т, КCa0.65Sr0.15Pr0.20F2.20Ca0.628Sr0.171Pr0.200F2.200Ca0.56Sr0.26Sm0.18F2.18501.311.441.284601.351.431.285701.381.431.287801.421.431.293901.451.441.3041001.481.451.3181101.511.461.3341201.541.481.3501301.571.501.3661401.591.521.3821501.611.541.3991601.631.561.4161701.651.591.4341801.671.621.4521901.691.651.4702001.721.681.4882101.741.711.5072201.771.751.5272301.801.781.5472401.821.821.5672501.851.861.5892601.871.891.6132701.901.931.6372801.921.971.6632901.942.011.6893001.962.041.714501Продолжение таблицы 1.54Теплопроводность k, Вт/(м К)Т, КCa0.560Sr0.295Tb0.145F2.145Ca0.545Sr0.281Tb0.174F2.174Ca0.567Sr0.279Dy0.154F2.154501.070.950.88601.111.010.96701.141.061.02801.171.111.07901.211.161.121001.241.211.171101.271.251.211201.301.291.251301.331.341.291401.361.381.341501.381.421.391601.411.461.431701.431.501.471801.451.541.511901.471.581.552001.501.621.592101.521.671.632201.551.721.672301.571.771.722401.591.821.772501.611.871.822601.621.921.862701.641.981.912801.652.041.962901.672.092.003001.692.152.04502Продолжение таблицы 1.54Теплопроводность k, Вт/(м К)Ca1-х-ySrxHoyF2+x+yТ, Кх = 0.269; y = 0.121 х = 0.32; y = 0.12Ca0.560Sr0.325Er0.115F2.115Ca0.57Sr0.33Tm0.10F2.1050601.161.251.041.091.091.141.361.39701.321.141.191.42801.381.191.231.44901.441.231.271.471001.491.281.311.501101.531.321.361.521201.571.361.401.551301.621.391.431.581401.661.421.451.601501.691.451.481.621601.731.481.501.641701.771.501.531.661801.811.531.551.671901.861.551.571.692001.911.571.581.712101.961.591.591.732202.001.611.601.742302.051.631.621.752402.101.651.641.772502.151.671.661.782602.201.691.681.792702.251.711.701.802802.301.721.721.812902.341.741.731.823002.391.751.741.833501.161.041.091.364001.251.091.141.394501.321.141.191.425001.381.191.231.445501.441.231.271.476001.491.281.311.506731.571.361.401.55503Продолжение таблицы 1.54Теплопроводность k, Вт/(м К) Ca0.995-xSrxNd0.005F2.005Т, Кх = 0.245х = 0.295х = 0.445506.156.155.35605.275.174.47704.644.433.93804.164.003.53903.803.633.201003.543.402.971103.333.202.791203.173.022.641303.042.882.521402.932.782.431502.842.702.351602.772.632.281702.702.572.221802.642.512.171902.592.452.122002.552.402.092102.522.362.062202.492.322.042302.462.292.012402.432.271.982502.402.251.952602.382.231.932702.352.211.922802.332.191.912902.322.171.903002.32.161.89504Таблица 1.55.Сглаженные значения теплопроводности монокристалловтройных твердых растворов (Ba,Sr)1-хRxF2+xТеплопроводность k, Вт/(м К)Т, КBa0.54Sr0.16La0.30F2.30Ba0.555Sr0.170Ce0.275F2.275Ba0.565Sr0.185Pr0.250F2.250500.950.790.84600.950.800.85700.950.820.87800.950.840.88900.950.860.891000.950.870.911100.950.890.921200.950.910.941300.960.930.951400.970.940.961500.980.950.971600.990.970.991701.000.981.011801.011.001.031901.031.021.042001.051.041.062101.071.051.082201.091.071.112301.111.091.132401.141.101.162501.161.121.182601.191.141.212701.221.161.242801.251.181.272901.281.201.303001.311.221.32505Продолжение таблицы 1.55Теплопроводность k, Вт/(м К)Т, КBa0.58Sr0.20Nd0.22F2.22Ba0.60Sr0.22Sm0.18F2.18Ba0.64Sr0.23Gd0.13F2.13500.881.052.02600.891.071.95700.911.081.89800.931.101.83900.951.121.791000.961.131.741100.981.151.711200.991.161.681301.001.181.661401.011.191.641501.021.201.621601.031.221.611701.041.231.601801.051.251.601901.061.261.602001.081.271.602101.091.291.602201.111.311.612301.131.321.612401.161.341.622501.181.361.632601.211.381.632701.241.401.642801.261.421.642901.291.451.653001.311.471.65506Продолжение таблицы 1.55Теплопроводность k, Вт/(м К)Т, КBa0.65Sr0.26Tb0.09F2.09Ba0.66Sr0.27Dy0.07F2.07Ba0.66Sr0.27Ho0.07F2.07502.963.474.72602.793.224.31702.653.063.98802.532.903.65902.422.773.401002.322.663.161102.242.592.971202.182.512.841302.132.452.741402.102.392.651502.082.322.581602.052.272.501702.042.232.441802.022.202.391902.002.182.352001.982.152.322101.972.142.282201.952.122.262301.942.112.242401.932.102.232501.922.092.212601.912.072.202701.902.062.182801.902.052.182901.892.052.173001.882.042.16507Продолжение таблицы 1.55Теплопроводность k, Вт/(м К)Т, КBa0.66Sr0.29Er0.05F2.05 Ba0.66Sr0.30Tm0.04F2.04 Ba0.32Sr0.64Yb0.04F2.04 Ba0.325Sr0.645Yb0.03F2.03505.516.935.486.38604.895.954.765.53704.375.284.264.87803.964.713.874.40903.624.263.584.061003.393.963.363.761103.193.713.203.531203.013.513.063.371302.873.322.943.221402.783.152.843.111502.703.022.753.001602.632.902.662.901702.572.812.582.821802.512.732.522.761902.462.672.472.702002.422.632.422.642102.382.592.382.602202.352.562.342.562302.322.532.302.522402.302.502.272.482502.282.482.242.442602.272.462.212.402702.252.432.202.372802.252.412.182.342902.242.402.172.313002.232.382.162.28508Таблица 1.56.Сглаженные значения теплопроводности монокристаллов LiRF4 (R = РЗЭ)Теплопроводность k, Вт/(м К) в направлении,Т, Кперпендикулярном оси сLiYF450139параллельном оси сLiYF4:1%Nd3+ LiYF4:1%Nd3+76124LiLuF4:<0.3%Се3+140LiYbF4:0.3%Се3+86.06086.4528194.058.47061.5396469.641.88045.730.55053.431.59035.024.83941.024.410028.320.73132.819.311023.117.626.526.916.112019.615.322.522.713.913017.013.520.219.512.014014.912.018.016.910.315013.410.916.015.29.0716012.210.014.713.88.1717011.29.313.312.47.4418010.38.712.111.36.9810.46.551909.588.211.32008.927.810.59.686.262108.457.49.89.125.972207.967.049.28.585.672307.556.718.628.155.472407.236.428.247.775.302506.946.177.997.375.112606.695.957.726.944.942706.465.737.406.624.782806.235.527.026.354.662906.035.346.736.104.583005.845.186.445.94.5509Продолжение таблицы 1.56Теплопроводность k, Вт/(м К) в направлении, перпендикулярном оси сТ, КLiLuF4:1%Nd3+LiY0.3Yb0.7F4LiY0.3Lu0.7F4:1%Nd3+LiY0.8Lu0.2F4:1%Nd3+LiY0.3Lu0.7F4:1%Ce3+, 1%Bi5081.817.817.418.216.86059.113.813.815.013.57045.311.411.712.611.48036.29.810.110.99.859029.28.58.889.78.6410024.17.47.898.77.7211020.06.67.097.97.0012017.16.06.507.36.4013014.85.55.996.835.9214013.05.15.566.425.5315011.74.85.246.095.2016010.74.554.955.774.921709.84.354.715.514.681809.14.224.545.274.501908.44.104.385.084.352007.844.004.244.924.212107.333.904.134.774.072206.923.784.044.633.952306.603.713.954.503.852406.333.663.874.383.762506.093.593.794.283.672605.863.553.724.203.582705.643.503.654.113.492805.433.463.594.033.422905.253.433.543.973.363005.13.413.53.913.3510Продолжение таблицы 1.56Теплопроводность k, Вт/(м К) в направлении, перпендикулярном оси сТ, КLiY0.3Lu0.7F4:3%Nd3+LiY0.4Lu0.6F4:2%Nd3+LiY0.3Lu0.7F4:1%Pr3+LiY0.3Lu0.7F4:2%Pr3+5016.215.217.717.46013.112.414.314.27011.010.511.911.8809.59.0610.210.2908.48.018.99.041007.577.157.958.001106.876.487.267.191206.265.986.616.531305.805.606.105.991405.415.275.655.571505.074.975.305.271604.804.725.025.001704.574.504.794.761804.374.324.604.571904.214.134.434.432004.073.984.304.312103.963.854.174.182203.863.734.054.082303.763.633.953.982403.673.543.863.882503.583.453.783.782603.493.373.713.692703.423.313.643.612803.363.253.583.542903.313.203.533.483003.273.153.493.43511Таблица 1.57.Сглаженные значения теплопроводности монокристаллов КY3F10Теплопроводность k, Вт/(м К)Т, ККY3F10КY3F10: Се3+, Yb3+509.48.03608.87.67708.27.34807.686.96907.216.581006.786.221106.265.871205.905.581305.645.311405.305.061505.104.831604.844.621704.674.461804.504.291904.324.122004.173.972104.053.862203.963.742303.853.652403.773.562503.703.512603.653.462703.613.422803.583.382903.553.353003.533.33512Таблица 1.58.Сглаженные значения теплопроводности монокристаллов семейства NYFТеплопроводность k, Вт/(м К)Т, КNa4Y6F22Na4Y6F22:Yb139Na0.4Yb0.5995Er0.0005F2.16140Na0.42(Lu0.99Er0.01)0.58F2.165012486.0608186.494.058.4706461.569.641.8805045.753.431.5903935.041.024.41003128.332.819.311026.523.126.916.112022.519.622.713.913020.217.019.512.014018.014.916.910.315016.013.415.29.0716014.712.213.88.1717013.311.212.47.4418012.110.311.36.9819011.39.5810.46.5520010.58.929.686.262109.88.459.125.972209.27.968.585.672308.627.558.155.472408.247.237.775.302507.996.947.375.112607.726.696.944.942707.406.466.624.782807.026.236.354.662906.736.036.104.583006.445.845.94.5513Таблица 1.59.Сглаженные значения теплопроводности монокристаллических икерамических материалов на основе LaF3Теплопроводность k, Вт/(м К)Т, К5060LaF3монокристалл16.212.3La0.975Nd0.025F3монокристалл9.547.80LaF3керамика9.37.8LaF3-SrF2керамика2.092.01709.686.736.71.95808.005.855.861.89906.895.225.221.831005.974.714.661.791105.344.314.301.761204.864.023.971.731304.483.793.741.711404.193.613.551.691503.953.453.341.671603.743.303.181.651703.583.173.021.631803.433.052.891.611903.282.942.771.602003.152.852.651.592103.052.762.561.572202.962.672.461.552302.862.592.371.552402.772.512.301.532502.692.442.241.522602.602.372.181.512702.522.302.121.502802.452.242.051.492902.392.182.001.483002.342.141.951.47350––1.731.43400––1.641.39450––1.571.35500––1.511.31550––1.471.29600––1.471.29673––1.51.35514Таблица 1.60.Сглаженные значения теплопроводности гамма-облученных монокристаллов LiFТеплопроводность k, Вт/(м К)Т, Кбез ОН–с ОН–2×106 радотжиг 2×106 рад505755432455106032330719230270213205148200801551461201449011811010011010093898388.311077737072.912065636162.313057555353.814050484746.915044.5434241.816039.9383837.717036.034.53533.918033.031.53330.619030.429.130.328.120028.326.928.126.021026.225.125.424.222024.423.523.622.723022.722.021.821.524021.420.820.720.325020.319.719.519.326019.318.718.218.127018.417.617.317.128017.516.816.516.329016.916.215.915.630016.515.715.415.0515Продолжение таблицы 1.60Теплопроводность k, Вт/(м К)Т, К2×107 рад2×108 рад5×108 рад2×109 рад5053.81189253.86051.51139951.57049.41009249.48047.482.58347.49045.369.27345.310043.060.164.443.011041.051.755.941.012038.846.248.838.813036.642.343.936.614034.538.239.134.515032.534.235.532.516030.531.432.330.517028.829.029.428.818026.927.027.126.919025.225.225.125.220023.723.323.423.721022.521.821.922.522021.320.520.721.323020.319.519.520.324019.218.618.619.225018.317.717.718.326017.516.917.017.527016.816.216.316.828016.215.715.716.229015.615.215.215.630015.214.814.815.2516Таблица 1.61.Сглаженные значения теплопроводности NaFТеплопроводность k, Вт/(м К)Т, Кбез ОН–после отжигаоблуч.