prilogeniya (739540), страница 2
Текст из файла (страница 2)
a = 23.007(2), b = 6.2670(6), c = 10.0814(12) Å, V = 1453.6(3) Å3. Пространственная группа Pna21.
Z = 4, Dc = 1.422 г/см3, R = 0.0302 для 1245 I > 2(I).
Таблица 5. Данные рентгеноструктурного анализа соединения 105.
| Атомы | Длины и углы | Атомы | Длины и углы |
| P(1)-O(2) | 1.4806(14) | N(1B)-C(2)-C(7) | 86.9(6) |
| P(1)-C(17) | 1.792(2) | N(1)-C(2)-C(7) | 120.2(3) |
| P(1)-C(11) | 1.802(2) | N(3)-C(2)-C(7) | 107.8(2) |
| P(1)-C(4) | 1.806(2) | N(1B)-C(2)-C(8) | 138.3(6) |
| O(1)-N(3) | 1.281(2) | N(1)-C(2)-C(8) | 107.6(3) |
| N(1)-C(6) | 1.450(10) | N(3)-C(2)-C(8) | 109.3(2) |
| N(1)-C(5) | 1.473(3) | C(7)-C(2)-C(8) | 111.1(3) |
| N(1)-C(2) | 1.477(3) | O(1)-N(3)-C(4) | 127.78(19) |
| N(1B)-C(2) | 1.440(10) | O(1)-N(3)-C(2) | 118.97(17) |
| N(1B)-C(6B) | 1.51(3) | C(4)-N(3)-C(2) | 113.18(17) |
| N(1B)-C(5) | 1.605(11) | N(3)-C(4)-C(5) | 110.90(18) |
| C(2)-N(3) | 1.497(3) | N(3)-C(4)-P(1) | 122.87(16) |
| C(2)-C(7) | 1.503(4) | C(5)-C(4)-P(1) | 125.87(15) |
| C(2)-C(8) | 1.508(4) | N(1)-C(5)-C(4) | 100.81(17) |
| N(3)-C(4) | 1.298(3) | N(1)-C(5)-C(9) | 118.6(2) |
| C(4)-C(5) | 1.504(3) | C(4)-C(5)-C(9) | 109.83(19) |
| C(5)-C(9) | 1.521(3) | N(1)-C(5)-C(10) | 105.6(2) |
| C(5)-C(10) | 1.523(4) | C(4)-C(5)-C(10) | 113.1(2) |
| C(11)-C(16) | 1.385(3) | C(9)-C(5)-C(10) | 108.9(2) |
| C(11)-C(12) | 1.392(3) | N(1)-C(5)-N(1B) | 33.8(4) |
| C(12)-C(13) | 1.376(4) | C(4)-C(5)-N(1B) | 96.6(4) |
| C(13)-C(14) | 1.371(4) | C(9)-C(5)-N(1B) | 89.6(5) |
| C(14)-C(15) | 1.368(4) | C(10)-C(5)-N(1B) | 135.6(5) |
| C(15)-C(16) | 1.378(4) | C(16)-C(11)-C(12) | 118.5(2) |
| C(17)-C(22) | 1.375(3) | C(16)-C(11)-P(1) | 116.63(17) |
| C(17)-C(18) | 1.383(4) | C(12)-C(11)-P(1) | 124.84(19) |
| C(18)-C(19) | 1.376(4) | C(13)-C(12)-C(11) | 119.8(3) |
| C(19)-C(20) | 1.365(5) | C(14)-C(13)-C(12) | 121.1(3) |
| C(20)-C(21) | 1.359(6) | C(15)-C(14)-C(13) | 119.5(3) |
| C(21)-C(22) | 1.396(4) | C(14)-C(15)-C(16) | 120.3(3) |
| O(2)-P(1)-C(17) | 112.76(10) | C(15)-C(16)-C(11) | 120.8(2) |
| O(2)-P(1)-C(11) | 111.75(10) | C(22)-C(17)-C(18) | 118.8(2) |
| C(17)-P(1)-C(11) | 110.40(10) | C(22)-C(17)-P(1) | 123.1(2) |
| O(2)-P(1)-C(4) | 109.68(9) | C(18)-C(17)-P(1) | 117.69(19) |
| C(17)-P(1)-C(4) | 106.49(10) | C(19)-C(18)-C(17) | 121.5(3) |
| C(11)-P(1)-C(4) | 105.35(10) | C(20)-C(19)-C(18) | 119.1(4) |
| C(6)-N(1)-C(5) | 118.3(5) | C(21)-C(20)-C(19) | 120.7(3) |
| C(6)-N(1)-C(2) | 114.3(5) | C(20)-C(21)-C(22) | 120.5(3) |
| C(5)-N(1)-C(2) | 110.5(2) | C(17)-C(22)-C(21) | 119.5(3) |
| C(2)-N(1B)-C(6B) | 114.9(12) | N(1B)-C(2)-N(1) | 36.0(5) |
| C(2)-N(1B)-C(5) | 105.4(7) | N(1B)-C(2)-N(3) | 99.5(4) |
| C(6B)-N(1B)-C(5) | 106.5(13) | N(1)-C(2)-N(3) | 99.93(17) |
Кристаллы соединения 105 моноклинной сингонии:
a = 12.4029(8), b = 8.9187(5), c = 17.7928(12) Å, V = 1967.9(2) Å3.
Пространственная группа P21/с, Z = 4.
Dc = 1.203 г/см3, R = 0.0456 для 2653 I > 2(I).
![](https://s.studizba.com/z.php?f=/templates/si/i/noavatar.png&w=100&h=100&t=1"){kind=avatar}
