Отзыв ведущей организации (1103867), страница 2
Текст из файла (страница 2)
ABTOP O ~ ' ~ R C H R HiVIHYHe~TCJIOHCTHbIX KyIIpaTOB.OIIpeAeJIeHHRABYXH,meJIefiCYmeCTBylOmHM IIpeACTaBJIeHHRMYpOBeHb AOIIHpOBaHWI BHYTPeHHHX C U ~ ~ - I I J I O C K O C BT ~C~B~e P X I I P O B O m m e M ~ J I O K B~C e r A aocTaeTcxmxe,YeMAOIIHPOB~HHRypoBeHbBHeruHHxCu02-nnoc~oc~eii.n o c n e ~ ~ e eO ~ ' ~ R C H R ~ TCHJIbH0fiCR~ K P ~ H H P O B KBHYTpeHHHXO~C U ~ ~ - I I J I O C K O CBHeIIIHHMHT~~~IIJIOCKOCTIIMH,KOTOPbIe MeTaTInH3HPylOTCR IIpH AOIIHpOBaHHH.rna6a 4 IIOCBIIIIIeHa CJIOHCTbIMT 1 2 B a 2 C a n - ~ C u n 0 2 , + 4 + ~ , KOTOpbIe,csepxperueTKaMH T m aKJTIPaTHbIM CBePXIIPOB0,QHHKaM B i 2 S r 2 C a n - l C ~ n 0 2 n + 4 + FHK ~ KHS-I-S-I ..., me SH g B a 2 C a n - l C ~ n 0 2 n + 2 +IIPHPOAH~IMHF,~~~~~~~- c s e p x n p o B o m m H e ~ J I O K H ,c o n e p x a m H e O A H ~anu6onbrue C U 0 2 - I I J I O C K O C T ~ ~HHTepKiVIHpOBaHHbIX~,c n a 6 o ~ AOIIHpOBaHHHIIPOHCXOAHTIIepeXO.4KUbqHeM,I - H3OIIEITOPbI (CIIefiCepb1).
n p ~AH3JIeKTpHK-MeTiVIJI(~HTH@~PPoM~~HHTH~IIOPWIOK H C Y e 3 a e ~ )H 0 6 p a 3 y e ~ C I IAbIpOYHEM OTKPbITEM IIOBePXHOCTb @ ~ P M H C YPOBHeM @ ~ P M HB OKPeCTHOCTH I I P O T I I X ~ H H O ~O C O ~ ~ H H O C TBaHHIIJIOTHOCTH COCTORHH~~.n p HCHJIbHOCBR3aHHbIXHmpaBJIeHHH,HX O BC~rHraHTCKHMHT<Tc AOIIHpOBaHHbIe BTCnAXO~~@COHOBCKEIX KOHTaKTOBII03TOMYHMeIoTpe3yJIbTaTbI O ~ ' ~ R C H MOAeJIbIo~ H ~ IIIHKaMH K B ~ ~ H Y ~ c T H Y H OKpHCTaJIJIbI B e n y TCOce6xCBePXIIPOBOmmHM, L Q K o ~ ~ @ c o H o B c K ~ ~ OIIPHPOAY.KaK CTOIIKaTOKOMBC-~ O J I Y Y ~ H HaBTOPOM~ I ~A.A. A 6 p ~ ~ o c o ~ a .AJIII HCCJIeAOBaHHbIX B A H C C ~ P T ~ ~ H O H Hpa6o~eO ~ ~ KJTIpaTOBTI-2212CuO2 -Bi-2201, T1-2201C 0 ~ ~ 0 f iIIJIOCKOCTbIoCu02, Bi-2212TpeMII C U 0 2- IIJIOCKOCTIIMH OKa3bIBaeTCII m H H a C B O ~ ~ A H Onpo6era~OH O C H T ~ J I 3~a~p X~ A a kl(a-paAEiyCK O H T ~ K T ~ ) , YTOHCOOTBeTCTBYeTO C O ~ ~ H H O C TKOTOPbIe~~~,COCTaBJIIIIOTKOHTaKTOB B AOIIHPOBaHHbIXC AByMRIIJIOCKOCTIIMH HOrpaHHYeHHOMyCrC.
B pa60l.eBi-2223, TI-2223naHApeeBCKHXBAXZiHApeeBCKHXYHCJIy06HapyXCeH0,'YTOCBi-220 1, Bi-22 12 H T1-22 12 AeMOHCTPHPylOT CrC, THIIH'YHylO AJIX0 , 4 ~ 0 m e J I e ~ O f i CBepXIIpOBOAHMOCTH.~ H ~ ~ ~ H mHe In HI ,nOn~eHH0fi ~ H A P ~ ~ B C K Oc I I ~ K T ~ o c K o I I HH~ ~~ ~y H ~ e J I b H 0 Cf i ~ I ~ K T ~ O C K OHaXOmTCXI I H ~ ~ ~ , B IIpeAeJIU ~ K c I I ~ ~ H M ~ H T U ~IIO~eIIIHOCTH.CIIOMOmbIOm ~ p e e ~ c K 0 f iH~yHHeJIbH0fiCIIeKTPOCKOIIHHIIOKa3aH0,'YTOCBepXIIpOBOAHMOCTb B O,QHOCJIO~BO~~H A B ~ X C J I O ~ B@a3UO ~ ~ KyIIpaTOB B i 2 S r 2 C a , - l C ~ ~ 0 2 ~ + 4 H+sT12Ba2Can-lCun02H4+s(Tc=110k5 K)HHMeeT 0 ~ ~ 0 m e J I e ~ Xo af pia K T e p .TI-2223 (Tc=118*5 K),CorJIacHoBfi0IIHpOBaHHbIx K y I I p a ~ a x Bi-2223H3MepeHHaM,HMeeTCII ABe ( E ~ H TPH)C B e p X I I p O B O m ~ H X WeJIH, TO e C T b CBepXIIpOBOAHMOCTb H M e e T M H O ~ O ~ ~ J Ix~a pB aO~~~ ~e pB.A H C C ~ ~ T ~ ~ H O pa60~eH H O ~ ~3 T 0 O ~ ~ X C H R ~ T Cpa3JIHYHbIMIIYPOBHeM AOIIHPOB~HHX ~ H ~ p e H H e f i(IP) H ~ ~ e r u ~(OP)e f iCu02- n n o c ~ o c ~ eBf ci s e p x n p o B o m m H x ~ J I o K U .B rJa6e 5 AkICCepTaUHEl nPEIBeAeHb1 HCCJIeAOBaHkIRKOHTaKTOB MOHOKPElCTaTInOBYBa2C~307-xI?T ~ ~ B ~ ~ C ~ ~C CIIOMOwbK)U ~ O ~ ~OH-A~P ~ ~ B C KMO T~ Y H H ~ J I ~ H O CneKTPOCKOnMI?.~~ a 6 J E o ~ a T I a cAOnOnHMTeJIbHasIbT O H K m CTPYKTYPa, K O T O P m BB n e p ~ b ~ epa6o~eo ~ % R c H R ~ T c R ~ M H C C I ? ~ ~JIeTTelTOBCKEIX nJIa3MOHOB.T a ~ x eMCCJIeAOBaHbIMElKPOTPeaHHeB3JIeKTpOMarHHTHbIe C B O ~ C T BA~X O ~ ~ @ C O H O B C K H XKOHTaKTOB H aT 1 2 B a 2 C a 2 C ~ 3 0 1 0 - 6B.A X O ~ ~ @ C O H O B C K O MP e X H M e(SIS-THII)H3YYeHbI3aBMCMMOCTM KPMTkIIIeCKOrO TOKa OT MarHHTHOrO IIOJZII M reOMeTpMgeCKMe p e 3 0 H a H C b I @ M c K ~ .O n p e ~ e n e ~@a y~ ~ m e ~ ~ racTn o bT a~p me3B TYHHenbHOMAOBaHbI3aBHCHMOCTHICB0cqMJImqMfiYacToTax(SIS-KOHT~KT)Y T 1 2 B a 2 C a 2 C u 3 0 1 0 - g - ~B~ pa6o~e~ ~ a K ~MCCJIe~~PeXElMeKPMTHgeCKOrO TOKaMarHHTHOMo ~ a ~ sc oC K~O P O C T ~C ~ ~ x a p ~ a .none=IcOT MarHHTHOrO3,8 raycc.IIOmB.~ o J I ~ Y nepMOA~ H, @ K O ~ ~ @ C O H O B C KKOHTaKTU~H a BbICOKHXo6nanae~C B O ~ ~ C T B ~ Mc BH e p x n p o B o m w e r o pe3o~a~opa.ABTOPYy ~BHeLUHeM MarHHTHOMcTyneHeK Q H C K ~H anoneBAXHam o c bB C J I ~ ~ O MKOHTaKTa ~ a 6 n K ) ~ aCTYIIeHbKI?~ bQ E I C K ~ .
E13 ~ o J I o X ~ H M ~ ~BAX MM p a c c s a T a H a C K O P O C T ~C ~ ~ x a p ~ a .~ak16oneefl0ArepKHeMC.B.Kynb6a.1~1~c~oro.CBaXHbIeA M C C ~ ~ T ~ ~ M O H Hpa60~b1O~~pe3yJIbTaTbInOMOwbK) ~ H A ~ ~ ~ BCneKTpocKonMMC K O ~YCTaHOBJIeH O A H O ~ ~ ~ ~ B OyX a p a K T e p CBepXnpOBOAEIMOCTHOnTHMalIbHO AOIIHpOBaHHbIX PTYTHbIX KYnPaTOBHg-1201I?Hg-1212.Am ~pexcnoe~oii@a3b1 Hg-1223 0 6 ~ a p y m e ~ b 1AsecsepxnpoBomuHeCOOTBeTCTBJW~Me0 ~ ~ 0B H2J ' T P ~ H H(IP)~ ~ ~MCBepXIIpOBOJWrrleM6no~e.C ~ I Q ~ C T B O B ~ H MMH~ O ~ O I Q ~ J I ~ B OCBepXnpOBOAHMOCTH~?KJTIpaTaXBHeIIIHMXHgBa2Can-lCun02,+2+sCn 23WenH,(OP) C U ~ ~ - ~ ~ O C K O CB T I I MABYM BHeLUHEIMB PTYTHbIX0 6 a R c ~ a e ~ cp as 3 n H Y H e M B YPOBHRX AOnHPOBSLHHR(OP) M BHYTPeHHMX (IP) C U 0 2 - I I J I o c K o c T ~ ~ .0 6 H a p y X e ~ b 1nPH3HaKM H e y I I p y r H X MHOrOKPaTHbIX 5LHnPeeBCKEIX O T P ~ X ~ H BM SCS~HaHOKOHTaKTaXPTYTHbMKylTpaTOB,OnTEI~eCKHX@OHOHOB C 3HeprI?ei?OTHOLIIeHEiR2A/kTcCOCTaBmeTm14YTOCBR3bIBaeTCRM ~ By.CM3JIyYeHHeM@a3 Hg-1201 Id6.5k1.0.
n o ~ a 3 a H 0 ,YTOHg-1212AJIX @a3b1HepaBHOBeCHbXCpeAHRSI BeJ'IHYHHaHg-1223BenHYHHbI2alkTcB H J ' T P ~ HMH BHeIUHElX~~~CUO2 -~ J I O C K O C CTW~ ~e C~ T B e H H O pa3JIHYSLIOTCR.B AOIIMpOBaHHbIX 06pa3qax p - T H n a Bi-2223 H TI-2223 aBTOPOMTI?)C B e P X n P O B O m w H X IJJeJIEl.MaTepMmax,KaKsBC Y I Q ~ C T B O B ~ H M ~H O T O I ~ ~ J I ~CBePXnPOBOAHMOCTHBO~B 3TMXcnygaeAOnMpOBaHMX B H ~ I I I H(OP)~ ~ I?H ~ ~ J ' I ~ A ~ J IABeE I C(HnM~PTYTH~IX K y n p a T o B ,O ~ ~ I C H ~ ~ TpCa 3Rn m H e Mypo~~ejiB H J ' T P ~ H (IP)H ~ ~C U O 2 - I'IJIocKocT~~~.0 6 H a p y X e ~ JIerrelTOBCK2i%aMonaY A X O ~ ~ @ C O H O B C K MKOHTaKTOBXH a 6a3e Y B ~ ~ C U ~ O ~C B R 3 a H H B C A B y X q e J I e B b I M X a p I c T e p O M CBepXnpOBOAHMOCTH B 3TOM M a T e p H m e .Ha BAXA X O ~ ~ @ C O H O B C K ~KOHTaKTOBIXB T 1 2 B a 2 C a 2 C ~ 3 0 1 0 - 60 6 H a p y X e H b 1 p a 3 M e p H b I e CTYneHbKkI ( D H C K ~u O n p e n e n e H a C K O P O C T ~ C ~ ~ x a Bp~~T Ha XKOHTaKTaX.AmO~%XCH~HHX3KCnepkIMeHTaJIbHbIX p e 3 y J I b T a T O B nkICCepTaqkIkI a B T O p npkIBJIeKaeT@OHOHHY~OMOAeJIb CnapkIBaHkIR 3JIeKTpOHOB A.A.AGp~~ocosa.KaKyXeJ'IIOMkIHaJIOCb,HeAaBHO 0 6 H a p y X e H a CBepXIIpOBOnkIMOCTb CepOBOAOpOAa n p k Ip e K o p n H o B ~ I C O K OT~e ~M n e p a T y p eBHyIIIaeT60nbmpn p k I B ~ I C O K O MAaBneHkIkI.Ta~ofip e 3 y n b ~ a ~H m e m y H a CO3naHkIe CBepXnpOBOAHkIKOB n p k I K O M H ~ T H OT~e ~M n e p a T y p e kIT a m e o z t ~ a r a e ~r T, ooremIIpOCTbIX COeAkIHeHkIXX,BbIcoKHe T e M n e p a T y p b IKOTOPbIM RBJIXeTCRC.B.Kynb6a=u1~c~oro3TkIeAkIHCTBeHHbIh4( o ~ o n oTc-200K)AZiHHbIeB03MOXHbIMnepexonaAJIH A E I C C ~ P T ~ ~ E I O H Hpa60~b1O~~CePOBOAOPO,&~ p a f i ~B aeX H b I ,MeXaHkI3MOMM O ~ Y T6b1~bA O C T H ~ H ~ Tu~ IBT a K KaK nJIR C e p O B O n O p O n a n O A A a B n e H k I e MCBePXIIPOBOAkIMOCTkI,KaKCWiTSlIOTMHOrkIepa60~b1M O X H OOTHeCTElCIIe~kIaJIkICTbI,RBJIReTCR @ O H O H H ~ MeXaHkI3M.I~~Pa6o~a H eKC B O ~ O ~ OTH ~ HeAOCTaTKOB.HeAOCTaTKaMcnenymuee:1.
B pa6o~e H e06cymnae~c%, noseMyYBa2C~307-x.M3C B e p X I I p O B O m ~ e M KylTpaTe3KCnepHMeHTaJIbHbIenerrerroBcKarrn0nbITKkIMonaTeKCTa0 6 H a p y X k I ~ b 3TkIMOAbI~a6monae~cxT o n b K oHeRCHO,B6b1nk1APJTkIXIIkIKynpaTaXBCAeJIaHbICABYMIICBepXIIpOBOmQkIMkI UeJIJIMkI.2. B pa60~eBCTpegSlIOTCROIIeraTKkI.K p o ~ eTOrO,B IIOnnkICRX K HeCKOJIbKkIM PkICYHKaM H e TIIoJIHo~~~IH@oPM~u~0I ~IIPkIHRTbIXIO ~ O ~ H ~ Z I ~ H HZUIpkIMep~IXX,H a PHC.3. Bce kI3MepeHkIRTeMnepaTypHbIenpOBeAeHbI npkIT=4..2K, kI B TeKCTe H e T O ~ % X C H ~ H HIIOYeMy~~,H e IIPHBOmTCXO C O ~ ~ H H O C BAX.T~~~3aBkICkIMOCTkI3.9,5.7,5.10.IIpOBeCTkI TaKkIe kI3MepeHH2, KOTOPbIe n03BOJIHJIkIBA ~ J I ~ H ~ ~ 6bmo~ I I I ~6b1M HenJIOXO6b1 n O J I p k I T bAOnOJIHkITeJIbHYfO H H @ O P M ~ ~ H I O0 n p k I p O n e CBepXIIpOBOnkIMOCTH B kICCJIeAOBaHHbIX K y n p a T a X .3 m e r a ~ k 1 1 1 c K o p e e RBJIJIIOTCR n o m e n a H u a M u ~I n pIo B e n e H mu H M c K o n b K o H e YM~TIIIIOTo64efi B~ICOKOEoqeHni AmcepTauuuA H C C ~ ~ T ~ ~C.B.HII@ ~ H A ~ M ~ H T ~ J IH~ aHy S~ HI YOI oTeMnepaTyp.BAAOCTOBepHOCTbMeTOAkIK,B qenoM.K y J I b 6 a ~ k I ~ c ~ o r o npenCTaBIIIIeTpa6o~ykIBHOCHTnaJIb~eErnuxu c c n e n o ~ a ~ ~ f ico6ofiCYII@CTB~HH~IEBKnm3aKOHYeHHYfOB @ k I 3 k I ~ y HkI3KkIX~ I C C ~ ~ T ~ ~ ~pa6o~eI O H HIIOJIJYeHO ~ ~p R n HOBbIX kI H H T e p e C H b I X pe3YJIbTaTOB.06ycno~neaaBOClTpOkI3BOAkIMOCTbK)kICIIOJIb30BaHHeMX I ~ O ~ H ~ O B Z ~ H H 3KCnepkIMeHTaJIbHbIX~IX3KCnepkIMeHTaJIbHbIXn e p e K p e C T H b I h 4 X a p a K T e p O M n p O B e n e H H b I X OnbITOB.MXpe3yJIbTaTOBkInO,4TBepmaeTCXABTOP~@~kI Po ~I IT~ ~ J I ~ I K o B ~ Hpa60~b1H~I~IIOJIHOCTbIO COOTBeTCTBYIoT COnePXZiHkIIO AkICCepTaUkIkI.O C H O B Hpe3YJIbTaTbI~I~AHCCePTauEIEI C .
B . K y n b 6 a r ~ ~ c ~ oOr o~HaysHbIx xypHanax,B TOMwcne3B83~ ~ ~ H K OB B4 ~CTaTbRXH ~ I Bcnmxa BAK (WebofScience),EIAonoxeHbI Ha 7OTeYeCTBeHHbIX H 3apy6e~HbIXKOH@epeHIJEIXX.I I o n y s e ~ ~ bpe3ynb~a~b1,~enoMmo@ ~ H A ~ ~ H T ~ T MHTepeca,~ ~ H O ~ Ononesab~ EIHnRlIpaKTElreCKElX IJeJIeii. Pe3yJIbTaTb1 PeKOMeHAyeTCR EiCnOJIb3OBaTb B aKaeMEIYeCKEIX ElHCTHTYTaXEIyspex,qeHlim sb~crueiirueonbr:BMOII PAH, MOO PAH, MOTT PAH, MTO EIM.JI.JIa~nay PAH, O E I ~ E I Y ~ C KElHCTHTyTeOMEIM.II.
H. JIe6e~esa PAH,~ O C ~ A ~ ~ C T B ~ HyHEIBepCEITeTe,HOMMP3 PAH,BHOBOCEI~EI~CKOn a 6 0 p a ~ o p ~MI'Y,~ x Cn6rY, HHTY, HI/Iu" K ~ P Y ~ T O B CE KIHE~C~T~~ THkiJIY",MMOM, MMET PAH, HMBHM~oJIox~HEIR,BbIHeCeHHbIe Ha 3awHTy,A.lIOJIHOCTbIoHM.A.A. Eossapa.AOKa3aHbI pe3J'JIbTaTaMH pa60Tb1. B ~ I B O A ~ Ixopomo O ~ O C H O B ~ H ~ I .AEICC~PT~~EIOHH%~p a 6 0 ~ a ((M~oroIqenesm CBepXIIpOBOAEiMOCTb AOnEIpOBaHHbIXKylIpaTOB)) YAOBJIeTBOPReTT ~ ~ ~ O B ~ HlIyHKTaHIIM9( ( ~ o J I o X ~ H E I R0c~eneseii))BAK Pocc~liic~oiiO e ~ e p a u mnpeaaxsmeMbIM,KIIpHCYWeHEIH JTeHbIXKmAEIAaTcKm AEIccepTaqEIRM, a,Kynb6asEi~c~EIii,~~~~CJIOs aBc nHyOm,s a e ~npacyyqesm eMy p e ~ o i cTeneHHiee m ~ o p C.B.KaHAHAaTa@EI~HKO-M~T~M~TEIY~CKEHayKIXlI0ClIeuHaJIbHOCTH 01.04.09- @ E I ~ E I K ~HH3KEIXTeMnepaTyp.A o ~ CI.
B~. K y n b 6 a r ~ ~ c ~ noo r o~ H C C ~ ~ T ~ ~ E I O pH aH6Oo ~~ e3acnyrua~EI 06cym~eH HaCeMEIHape ~ ~ H C T E ~ T06weiiYT~C ~ H T X ~20~ 16R rOAa,@EI3EIKFiHM. A.M.~ ~ O X O ~P oOc cB~ ~i i c ~ oAK~H~MEIEIiihay^lIpOTOKOJI N2 2004.@e~epaJIbHOerOCyAapCTBeHHOe 6Io~Xe~HoeJTpe~eHHeHayKEI MHCTEIT~T06weii @EI~EIKEIEIM. A.M. IIpoxoposa PAH,O ~ n e n~ o n e 6 a ~ ~ i i119991, M o c ~ s ayn., Bas~nosa,38Tene@o~:+7(499)503-82-22, E-mail: galina@,kapella.a~i.run0~lIEIcbT.H.M~xafino~oiiyAOCTOBepXIoY s e ~ b ~ceKpeTapbiiMOO PAHAOKTOP @ E ~ ~ E I K O - M ~ T ~ M ~ T H Y ~HCaYKKI I X(C . H . A H A ~ ~ ~ B )26.
![](https://s.studizba.com/z.php?f=/templates/si/i/noavatar.png&w=100&h=100&t=1"){kind=avatar}
