Магнитокалорический эффект в окрестности фазовых переходов первого рода в соединениях редкоземельных и переходных металлов (1103600), страница 2

Просмтор этого файла доступен только зарегистрированным пользователям. Но у нас супер быстрая регистрация: достаточно только электронной почты!

Текст из файла (страница 2)

Brück Z{ñ©µ+¶ "°8!± ™µEµ ´·¹#u "°8°<¯•µ+¶¿òó¶· ¸Ÿ²æ¸Ÿ»"¸b°HZj®”¯•· ¸Ÿ°<$± µH¯«&Z %('°) °<*¸ '°8*± ´µ+¶ ·<s_tÈD"?M9:8IfBHcH:N=IbhECM^;gYh«>@?+BH:<G=?+FCHc•=I<iC+FnE5<CEcE?OF=Ifn•IfCH:f^=;:8;="aF e2 P= F eAs Z“DCHBHCHGg~:ÁcE>':MIfB+:KIÁIfCECHB+cE:<BHI<B+cH7%]›`=>'=}D%C+F=9:8I<B+cE?E>'=m>':<BO?OFF=9:8I<DCEA<C2>@?+GAf?+;¡?«=˜L6CEI8L6CHG?×=58>':<Fn[9?OF=Ifn2c†?HGCHcEgYhU>':fFnH;=¡?Ohš^Cš>':fFD%CM^=Ifi:<GI<;CHA8CIfCIfB+Cpa;="aZ?•58?HB+:8>c?+BE>'CEI<L6:8G:W?+GA8CH;?¢5M?+i:89?+B+g~c?OF=Ifn¢c>'CHF=\M^:<;CHcH7%]oBHG7%\HD7=™cHg_^:8GE—•=c?OF=I<n×iG=™BH:8>'i:8G?+B+7%G:¬p+ OÉ×T€c2B+:<9:8;=:¬MÂHÃ9?HI<CHcsË6C+F79=cH†=:8Ibac2G:85<7MFnpBO?+B+:•Bp?HDCHkB+cH:8GH^CEB+:fFnH;CEk™G:8?HD¡==CH\EG?+58¡g}iC8^cH:<GA[?+F=Ifn«cEiCEIfF:[^I<B+cH==Æ<A C>'CHA<:8;=58=G7%]›`:8>'7‡CEBO—•=A<7ÈcKBH:<9:8;=:¬pÂ+ÃÅ9?EIfCEcÁiG=àB+:8>'i:<G?HB+7%G:˜­Â+ÉÁT¢s”Ë6C^?+;;g”>G:8;B+A<:8;CELN?H5<CEc+CHA<C?H;?OF=58?ZiC+F79=cH†=:8IbaiC+F=DG=I<Bp?OFFgyI<C8^:8GE—“?+F=;:\HCHF:<:NÂÍqiCH\HCE9;CEk×LN?H5<gNZIfG:f^;=k2G?H58>':<G2DG=I<Bp?OFF=Bp? ,š¬8ÃEÃW;RsË6CHF=DG=IfBp?+FF=9:8IfD=k CH\EG?+58:<¡ Sm Sr M nO I<=;B+:85<=GCHcE?H; ;?0.550.453h"=>'=9:MIfDC> LN?+D7MFnOB+:<B+:l/R .10 i7%B+:M> iG:8I<I<CHc?+;="aŒCI<?O^D%?Z,cHg_^:<F:<;;CHA8CŠcG:<587MFnOBp?HB+:h"=>'=9:MIfDCEk}G:8?HD¡==ZW=}iCI[F:f^7%]›`=>,I<i:<D"?+;=:8>,iG=mB+:8>'i:8G?+BH7G:¬<2ì OÉTmc¢B+:<9:<;=:£†W:8I<B+;?O^¡?+BH=«9?EIfCEcsË6Ga>'g~: =5M>':<G:8;="a >@?HA<;=BHCHD%?+FCHG=9:8I<DCEA<C J8LNL6:8DBp? iGCEcHCM^="F=Ifn cDcE?H5<=?O^=?H\H?+B+=9:8I<D="h7EI[FCEcH="a"hcj>@?+A8;=B+;gYh–iCHFa"hj^C¬<ìdDV0Z2=–^=?+i?+5<CE;:B+:8>'i:<G?HB+7%3G +4,‚É Æ Ã T¢sÁϞI<CH\E:<;;CEI<B+=’7EIfBp?H;CHcED=’iCE5<cHCHFa"F=’iC+F7%9?HB+n D"?+DB+:8>'i:<G?HB+7%G;g~:HZ‘Bp?HD¥=¥iCHF:<cEg~:ª58?+cE=If=>'CEIfBH=ŽcH:<F=9=;g RUTWV0soRš?+A8;=B+;CE:iC+F:ŽIfCH5f^?+c?OFCEIfn¨JfF:<DB+GCE>@?+A8;=B+C>YîÔh?+G?+DB+:8G;CE:ˆcHG:8>a =58>':8;:<;="a iC+FaCHBÃ,^Cª¬<ì‘DV¨IfCEI<Bp?Hc+Fa"FCƒÂ–I+s œ:M>'i:<G?+B+7%G?CH\EG?+58¡?DCH;B+GC+F=GCHc?OF?EIfn>':[^nHu„D%CH;I<Bp?H;Bp?H;CHcEC+kŽB+:8G>'CHi?+GCEks Ë6CHA8G:<†;CEI<B+n¿CHiG:[^:<F:<;=ax?+\IfC+F]›B+;CEkB+:8>'i:<G?HB+7%Gg¿5M?+cE=If:<F?mCEBqB+CH9;CEIfBH=jA<G?p^7%=GCEcHD=d=,I<CEIfBO?+cHFa"F?mCEDCHFCzÃs Æ T¢sœCE9;CEI<B+nrCHiG:f^:fF:<;="aoCHBH;CEI<=B+:fFnH;CEA<C‡=58>':8;:<;=aoB+:M>'i:<G?HB+7%Gg\HgYF?‡;:˜h"7—:Ãs¾¬•T¢sÏ0BH;CEI<=B+:fFnH;?+aÀiCHA<G:<†W;CEIfBHn«=5M>':<G:8;="acE:fF=9=;gz>@?+A<;=B+CHD"?OFCEG=9:MIfD%CHA<CJ8LNL6:8DBp?¢IfCEI<Bp?Hc+Fa"F5? EÍsßN?E>@?+A<;=9:<;;CEI<B+nÔ= >@?+A8;=B+;?+a cECEIfiG==>'9=cHCEI<B+nÔCE\HG?H5<¡CEc =58>':8GEa"F?EIfniG=¥iC>'CH`=ŽDC>@>':<G9:MIfD=hŽ>'CM^:fF:8k¥J<D%I<B+G?HD¡=CE;;gYhŽ>@?+A8;=B+C>':<B+GCHc µ 6E°7ê 'ºE±Ÿ°K9= 80»µ+¶¸Ÿ»;¯ :0°8·Ÿ²¾éH¶s <w?OacHF:<;;?Oa}iGCH=58cHCM^=BH:fFa>'=qB+CH9;CEIfBHnà=5M>':<G:8;=kIfCIfBp?Hc+Fa"F?= ,™É%ÍsšË6CHA8G:<†;CEIfBHn2=5M>':<G:8;=kB+:8i"FCE:8>'DCIfB+=;:iG:8cHg~†“?OF?¬p͖c^=?Hi?+58CH;:žB+:8>'i:8G?+BH7GÉs Æ ,Â+ÓT}=2Ãs Æ Íqc“CH\HF?HI<B+=×B+:8>'i:8G?+BH7G2CHB•ÂHÃTQ^C•É Æ ÃT¢st "Ó'-E"&Ç- 8$@#"ÜÇ-ŒiG=cH:[^:<;g G:85<7MFnpBO?+B+g =I<I[F:[^CEcE?+;="a¥>@?HA<;=B+;gYhx=>@?+A8;=B+CED%?OFCHG=9:8IfD="h{IfcHCEkIfBHcqIfCH:f^=;:8;=k HoAl = Gd In ZšAŸ^:Q;?+\HF]…^Ç?OF=I<n22>@?+A8;=B+;g~:£LN?H5<CEcHgY:ži:8G:fhECM^gyi:<GcECHA8CGCM^?“B+=i?“iCHGa%^CHD"uviCEGEa%^CEDst >8¬iG:[^I<Bp?+cHF:<;gzG:<5<7pFnpBO?+B+geiGCHcE:[^:8;;gYhcU;?HI<B+Cpa`W:<kG?H\HCHBH:=5M>':<G:8;=k&B+:8>'i:<G?HB+7%G;gYh£=iC+F:8cHgYh65M?+cE=If=>'CIfB+:8k£;?E>@?+A<;=9:<;;CEI<B+=WiC+F=DG=I<Bp?OFF=9:MIfDCEA<CCH\EG?+58¡? Gd In Z“?‡BO?+D"—:ÁcHi:8GcHg~:cEg~iC+F;:<;;gYhy^Fa}J8B+CHk}A8G7%iig4IfCE:[^=;:<;=k2=58>':8G:<;=k’B+:8i"FCH:M>'DCIfB+=’c >@?HA<;=B+;gYhªiC+Fa"h‚;?+iGEa"—:<;;CEI<B+nH]Ô^C’¬MÃHÑDV0sÄ A@ ^=?+\E?HB+=9:MIfD%CH:=58>':<;:<;=:ÅB+:8>'i:8G?+BH7Gg c^:<kI<B+cH=:M>Á>@?HA<;=B+;CHA8C¢iC+Fas?Gd2 IniC8^6Ë C J<BH=> ^?+;;g”> \HgYF= G?HI8If9=Bp?+;g cH:<F=9=;g >@?+A<;=B+CHD"?OFCEG=9:MIfD%CHA<CJ8LNL6:8DBp?Z~cECH5<;=D%?H]›`W:8A<Cc˜^=?Hi?+58CH;:šBH:8>'i:8G?+B+7%Gyìs ÂB,É Æ ÃT iG=r7%cH:fF=9:<;==;?+iGEa"—:<;;CEI<B+=2>@?HA<;=B+;CHA8C¢iC+Fa×CEB¢ÃW^C2¬MÃHÃDV0s365879:<;;g~k CH\HG?+5<:8¡ c cEg”IfCHD%CHB+:M>'i:<G?+B+7%G;CEk LN?H5<:ØuŒi?+G?E>@?+A<;=B+;g~ksœ:M>'i:<G?HB+7%G;?+aQ5M?+cE=If=>'CIfB+nCH\EG?+BH;CHkQ>@?+A<;=B+;CEkQcHCEI<iG==>'9=cHCIfB+=QcHCH58G?HI<Bp?H:<BF=;:8k;CšiG=BH:8>'i:8G?+B+7%G?+h™cHg~†:Â+ÊEëT¢sV…D"IfB+G?+iCHFa¡="aÀ^Ci:8G:8I<:<9:8;="a˜I¢CIfnH]?+\If¡=I8I×iCH58cHCHF="F?U;?+kB+=i?HG?H>@?HA<;=BH;7%],B+:8>'i:<G?HB+7%G7ÁT6]›G=Z…G?+cH;7]–Â+ÉEÃs ì™T¢sï…CHCEB+cH:8BHIfB+cE7%]›`W=klJMLNL6:<DBH=cH;g~k>@?HA<;=BH;g~kŠ>'C>':<;BªIfCEI<Bp?Hc+Fa:8B­s ÃE­ µ cBi:<G:8If9:<B+:;?‡?+BHCE>dAf?p^CHF=;=aZN9B+CÈ5M?H>':<BH;C‡iG:<cEg~†?+:8BB+:<CEG:<B+=9:8I<D7%]4CE¡:<;D7cH:<F=9=;g¤>@?+A<;=B+;CEA<C>'CE>':8;Bp?‘B+G:<h"cE?OF:<;B+;CHA<CIfcHCE\HC8^;CHA<C=CE;?Af?p^C+F=;="aZG ?+cE;CHA8CB"s ­Hì µ s™ßN?+\HF]_^?+:M>'g~:•JMLNL6:<DBHgzCE\CwaI<;"a]›BHIbaZ'iCHu„cE=%^=>'C>'7HZ'BH:8>YZ©9B+CB5<CE;;g~:6J<F:<DB+GCH;gyac+Fa]0BHIba«9?HIfBH=9;C•iCHFaG=58CHc?+;;g”>'=«=×^Ç?+]›B•cHD"F?p^c•CH\E`W7%];?H>@?HA<;=9:<;;CEIfBHn“CE\HG?H5<¡?sË6G= iCH;="—:<;== BH:8>'i:8G?+B+7%Gg c CH\EG?+58¡: cHCE5<;=D"?+:8B L6:8GGC>@?+A<;=B+;CE:7%iCHGa%^CH9:8;=:Es œ:M>'i:<G?HB+7%G?‘T6]›G=ZCEiG:[^:fFa:M>@?Oa D%?HD B+CE9D%?–>@?+D"If=>@?+FnH;C\Hg”I<B+GCHA8C =58>':<;:<;="a ;?H>@?HA<;=9:<;;CIfB+=Z IfCIfBO?+c+Fa:<B ¬8­Hì T¢s’Ì?OFnE;:<k†W:<:7">':<;nE†W:<;=:ÈBH:8>'i:8G?+B+7%GgiG=cHCM^=B}D€i:<G:<hEC8^7|c|I[F?+\HC>@?+A<;=B+;CE:ÈI<CEIfBHCMa;=:HZIfcHa58?+;;CH:‡I‡cECH58;=D;CEcH:<;=:8>ƒ?+;B+=L6:<GGC>@?+A8;=B+;CEkeI<B+G7%DB+7%GgNs¤t‚CEBHIf7%BHI<B+cH=:iC+Fa2i:<G:<hEC8^U=5L6:<GGC>@?+A8;=B+;CEA<C•c?+;B+=L6:<GGCE>@?HA<;=BH;CH:WIfCIfB+Cpa;=:£iGCH=IbhEC8^=BiG=àBH:8>'i:8G?+B+7%G:­EÃÁT¢s”Ë6CM^y^:<kIfB+cE=:8>d>@?HA<;=BH;CHA8CKiCHFaà?+;B+=L6:<GGCE>@?HA<;=BH;CH:7%iCHGa%^CH9:8;=:o>@?+A8;=B+;gYh,>'CE>':<;B+CHcz;?+G7%†?H:<BHIbas ßN?qiC+F:<cHgYh{58?HcH=I<=>'CEI<B8a"h;?H>@?HA<;=9:<;;CEIfBH=x;?H\+F]_^?+]0BHIbaxCEIfCE\H:8;;CEIfBH=Zh?HG?+DBH:<G;g~:’^Fa¦>@?+A<;=B+;CEA<CLN?+58CHcHCHA<C˜i:8G:fhECM^?˜i:<GcECHA<CGC8^?s|Ë6G=rÃÁTƒDG=B+=9:MIfD%CH:ÀiCHF:À>':8Bp?H>@?HA<;=B+;CHA8Ci:<G:fhECM^?È^CIfB+=Af?+:8BQ>@?+D"If=>@?+FnH;CHA<Cà5<;?M9:8;="azÊs Æ DÇV0sV…D"IfB+G?+iCHFa¡="aqiCHF:<cECHk58?HcH=I<=>'CEI<B+=Œ;?E>@?+A<;=9:<;;CEI<B+=Œc¿CH\HF?HI<B+=Œ;?EIfg~`W:8;="aŒDŽ;7pF:<cECHkŒcH:<F=9=;:;?+iGEa"—:<;;CEI<B+=˜iC+FaiG=˜B+:8>'i:<G?HB+7%G: Æ Te^Ç?+:<Bš>@?+A8;=B+;g~k>'CE>':8;B;?HIfg~`:<;=a%s Â+É;?¢?HB+CE>ÅAf?p^CHF=;=asµBRš?HD%I<=>@?OFnE;g~:Å58;?p9:<;=amRUTWV;?H\+F]_^?+F=I<nÈcyCEDG:MIfB+;CIfB+=|B+CE9D=qT6]›G=mu¬8­HìˆT¢sq365<CEB+:<G>'=9:8I<DCE:‰=58>':<;:<;=:ŠJ8;B+GCEi==¤iG=¤cHD"F]09:<;== >@?+A<;=B+;CEA<CiC+Fa,;?+iGEa"—:8;;CEI<B+nH]¤¬MÃHÃqDV‰^CIfB+=A[?+FC 60 · 104 IKJ DFEHG s ^=?H\E?+BH=9:8I<DCE:=58>':8;:<;=:ÈB+:M>'i:<G?HB+7%GgliG=eGCEI<B+:‡;?+iGa"—:<;;CEIfBH=e>@?HA<;K=BH;CHA8CoiC+FaeCHBoÃà^C¬8ÃEÃ×DV}I<CEI<Bp?+cHFa"FC^BC %s ìT¢st_:fF=9=;gzRšTWV0ZG?EI<If9=Bp?H;;g~:¢;?«CEI<;CHcE:“iC+F:<cHgYh58?HcH=I<=>'CEI<B+:<k,;?H>@?+A8;=9:8;;CIfB+==B+:8i"FCH:M>'DCIfB+=Z™hECEGCH†CeIfCEAbF?HIf7%]0BHIŸa>':<—^7IfCE\HCHkst CH\+F?HIfBH= B+:8>'i:8G?+BH7G ;="—: ­Hà T cHD"F]09:<;=: >@?HA<;=BH;CHA8C iC+Fa;?+iGEa"—:<;;CEI<B+nH]zÂ+ÃDVyiG=cHCM^=BDUiCH;=—:<;=]qB+:8>'i:8G?+BH7Gg}=ZwIfCECHB+cE:<BHI<B+cH:8;;CZD GCIfB+7 J8;B+GCEi==sœ?+D=: 5<;?p9:8;="a >@?+A8;=B+CED%?OFCHG=9:8IfD%CHA8C JMLNL6:<DBO?h?+G?HDB+:8G;g ^Fa ?+;B+=L6:<GGC>@?+A8;=B+;gYh >@?HB+:<G=?OFCEcsï F:[^CEcE?HB+:fFnE;CZiC+F79:<;;g~:,J<D"Ifi:8G=>':8;Bp?+FnH;g~:d^Ç?+;;g~:,iC cH:<F=9=;:>@?+A<;=B+CHD"?OFCEG=9:MIfD%CHA<CJ8LNL6:8DBp?§iCM^B+cE:<GE—“^?H]›BŒI<7`:8I<B+cHCEcE?+;=:‰?H;B+=L6:8GGCE>@?HA<;=B+;CHk¤IfB+G7%DBH7Gg cÊ3;=58DCHBH:8>'i:8G?+B+7%G;CHkŒLN?H5<:EZ€9B+C;?+hEC8^=BHIba§cŠIfCECHB+cE:<BHI<B+cH==ŒIG:85<7MFnpBO?+Bp?E>'=;:<kB+GCH;CHA<G?HL6=9:MIfD=h=I8I[F:f^CHc?+;=kst€\HC+F:<:«cHg”I<CHD="hÅiC+Fa"hÁ?p^=?H\E?+BH=9:8I<DCE:×=5M>':<;:8;=:B+:8>'i:8G?+BH7GgjI<Bp?+;CHcH=BHIŸaiC+FCM—•=B+:<FnH;g”>Ys V…B+CzCH+\ CwaIf;"a:8BHIba{B+:8>YZU9BHCziC+F:o>':<Bp?E>@?+A8;=B+;CEA<Czi:<G:<hECM^?CHB+;CEIf=B+:fFnE;C;:8cH:fF=DCZ{=ŒciCHFa"h§;?+iGa"—:<;;CEI<B+nH] \HC+F:<: Æ Ã‰DV cED"F?p^c¤>@?HA<;=BHCHD%?+FCHG=9:8I<D=k‹JMLNL6:<DB¨CEB¦i?+G?HiGCE¡:8I8I<?¨L6:<GGCE>@?+A8;=B+;CHA<C¦B+=i?iG:8cHCEIbhECM^=B×cHD"F?O^CHB«G?H5<G7%†W:8;="a™?+;B+=L6:<GGCE>@?HA<;=BH;CHk™I<B+G7%DB+7%GgNs•Rš?HD%I<=>'7">;?|DG=cHgYh€cqG?+kCE;:|¬M­HÃ|TŒI<c+a58?H;dIyG:85<D=>47%cH:<F=9:8;=:M>4cHCEI<iG==>'9=cHCIfB+=CH\EG?+58¡?Ôc‹CEDG:8I<B+;CIfB+= BH:8>'i:8G?+B+7%Gg T6]›G=Zˆ9B+C ac+Fa:8BHIŸa h?+G?HDB+:8G;CHkCEI<CH\H:8;;CEIfBHnH]ài:8G:fhECM^CHc“cEB+CHGCEA<C“GCM^?¢L6:<GGC>@?+A8;:<B+=D"u„i?+G?E>@?+A<;:8B+=Dst >úÂiG:[^I<Bp?+cHF:<;gzG:<5<7pFnpBO?+B+geiGCHcE:[^:8;;gYhcU;?HI<B+Cpa`W:<kG?H\HCHBH:=5M>':<G:8;=k&B+:8>'i:<G?HB+7%G;gYh¿=¿iCHF:<cEgYh‰5M?+cE=If=>'CIfB+:8kŠ;?H>@?+A8;=9:8;;CIfB+=¿=ÑB+:<iFCH:M>'DCEI<B+=iC+F=DG=I<Bp?+FF=9:MIfD%CHA<C˜CE\HG?H5<¡? HoAl Z~?Bp?HD"—:šcHg~9=I[F:8;;gYhÁiC˜J<B+=>m^?+;;g”>2cH:<F=9=;RšTWV0sRš?HA<;=B+CH7%iCEGEa%^CE9:<;;CH:IfCIfB+Cpa;=:cECH58;=D%?H:<B c HoAl iG=‰CEB+;CEI<=B+:<FnH;C2;=58D="hrB+:8>'i:8G?+BH7G?Ohws{œ:8>'i:8G?+B+7%G?T6]0G=Z0CEiG:f^:fFa:M>@?OarD"?+DrBHCH9D"?Åi:<G:8A<=\?;?zDG=cECHk,B+:<i"FCH:8>'D%CEI<B+=Z™iC+F7%9?H:<BHIbajG?HcH;CEkjɬoT¢s λuvCH\HG?+5<;g~kjcH=%^–DG=cECHkczCHDG:MIfB+;CEIfBH=,>@?+D"If=>'7">@?q7%D"?+5<g~c?+:<B|;?qB+CZU9B+C€LN?+5<CEcHg~k{i:8G:fhECM^jacHFa:<BHIbai:<G:fhECM^CE>ÅcHB+CEGCHA8CGC8^?sϞI<B+Gg~kZq7%5<D=k¿>@?+D"If=>'7">YZq;?H\+F]_^?H:8>'g~kiG=ÑÂ+ÂT ;?4BH:8>'i:8G?+B+7%G;CHk58?HcH=I<=>'CEI<B+= B+:8i"FCE:8>'DCIfB+=Z¤=5M>':<G:8;;CHk c CHBHI<7BEIfB+cE=: >@?HA<;=B+;CHA8C iC+FaZIfCECHB+cE:<BHI<B+cH7H:8B iGCE=IbhEC8^a`:8>'7 c HoAl iG= J8B+CHk BH:8>'i:8G?+B+7%G: I<i=;"u2i:<G:<CHG=:<;BO?+¡=CH;;C>'7ŠLN?+5<CEcHCE>'7li:<G:<hEC8^7Es Ë6G=ÑCMh%F?+—“^:<;==¿;="—:‚Â+ÒTiGCE=IŸhECM^=B =58>':8;:<;=: ;?+iG?+cHF:<;=a F:<A8DCEA<C ;?H>@?+A8;=9=cE?+;="a CHB CEI<=Zi?+G?OFF:<FnH;CHk G:<\EG7 D7%\H=9:8IfD%CHk DG=IfBO?OFF=9:8I<DCHk a9:<kD= L¾¬8ÃEà MvZ§D CEI<=Zi?+G?OFF:<FnH;CHk^=?HA<CH;?OF=×A8G?+;N= Læ¬E¬8à Mvst{CEBHIf7%BHI<B+cH=:U>@?HA<;=BH;CHA8C˜iC+Fa‡LN?+5<CEcE?Oa^=?HA<G?E>@>@?D7%\H=9:8IfD%CHA8C˜>@?+A<;:<B+=D"?ZiC+F79?+]›`“?OaIbai7BH:8>K>'=;=>'=58?+¡==2cEg~G?O—:8;="a^Fa2I<cHCE\HC8^;CHk×J<;:<GA8==äΦ=1[K1 sin2 2ϑ + (K1 + K2 cos2 ϑ)sin2 2ϕsin4 ϑ],4­P ¬MX;:KIfCM^:<G—¢=BÈ7%AúFCHcECHk}LN?+5<gNZW=|IfiCE;Bp?H;;g~kmI<i=;"uvi:<G:<CHG=:<;BO?+¡=CH;;g~koi:<G:<hEC8^Læ¬MÃHà Mæ$u Læ¬H¬8à M6ac+Fa:<BHIbaQLN?H5<CHcHg”>€i:8G:fhECM^C>€i:<GcECHA<CGC8^Ç?sï…D"?M9CEDàJ<;B+GCHi==oiG=i:<G:fhECM^:N>'CM—:8B¢\Hg~B+n¢cEg~9=I[F:<;«iC•L6CEG>'7MF:Eä4S =1 dK14 dTPíÂHX.ï =IfiCHFnH58CHcE?+;=:M>rF=B+:<G?+B+7%G;gYh^?+;;gYhCšBH:8>'i:8G?+B+7%G;CHkÅ58?+cE=If=>'CEIfBH=˜i:8GcHCEk|DCE;IfBO?+;B+gQ?+;=5<CHBHGCHi==«\HgYF=«iCHF7%9:<;grcE:fF=9=;gNä J<GA J<GA PSÉEX444S = 10.4 · 10 I8> T4Q = 208 · 10 I<>,3T =Ttr3u IfDGg~Bp?+a«B+:<iFCHBO?“i:<G:<hEC8^?sRšTWV\HgYF}G?HI<I<9=BO?+;};?ÈCEIf;CHcH:˜J8D%I<i:<G=>':<;BO?OFnE;gYhQiC+F:8cHgYhà5M?+cH=If=>'CIfB+:8k;?H>@?HA<;=9:<;;CEIfBH= = i7%B+:8> =;B+:<A8G=GCEcE?H;="a B+:<iFCH:M>'DCEI<B+=sË6CHF7%9:<;;g~:G:<587MFnOBp?HB+g hECEGCH†C‰IfCHAúF?EIf7%]›BHIbaˆ>':f—“^7§IfCE\HCEks Rš?HD%I<=>@?OFnE;g~:5<;?M9:8;="aRšTWV ;?+\HF]_^?OF=Ifn‰cCEDG:8I<B+;CIfB+=ŒB+CH9D=ŽT6]›G=ˆujɬ4T¢sà365<CHBH:<G>'=9:8IfD%CH:=58>':8;:<;=:J<;B+GCHi==liG=‰cHD"F]09:<;==‰>@?+A8;=B+;CEA<C iC+Fa’;?HiGEa"—“:<;;CIfB+nE] Æ ÃDV¥^CEI<B+=Af?OFC 160 · 104 IKJ DFEHG s ^=?H\E?+BH=9:8I<DCE:d=58>':8;:<;=:jB+:M>'i:<G?HB+7%GgiG=oGCIfB+:;?+iGa"—:<;;CEIfBH=o>@?HA<K;=BH;CHA8C‡iC+FaQCEB‡ÃÁ^CrÂHÃKDVIfCEI<Bp?Hc+Fa"FCÁ^CÈìOs T¢Qs P0?HG?+DBH:<GÑ;?H\+F]_^?H:8>'gYhŠB+:8>'i:<G?HB+7%G;gYhÑ58?+cE=If=>'CEIfBH:<kÑRšTWV clCH\HF?HI<B+=Ifi=;"u„i:<G:8CHG=:8;Bp?H¡=CE;;CHA8CqLN?+5<CEcHC+A8Cmi:<G:fhECM^?mCE\EIf7—“^?H:<BHIba{Ià=I<iC+FnE5<CEcE?O;=:8>>'C8^:fFnE;gYh LN?H5<CEc+gYh ^=?+A8G?H>@>Ysï…CHCEB+cH:8BHIfB+cE7%]›`W=k B+:<G>'CM^=;?H>'=9:MIfD=kiCHBH:<;¡=?OFI<C8^:<GE—•=B¢9"F:8;gyG?+5fFCM—:8;="a×c•GEa%^šJ<;:8GA<==?+;=5<CHBHGCHi==«D7%\H=9:MIfD%CHA<C>@?+A8;:<B+=D%?m^Cz†W:MIfB+CEA<CqiCEGEa%^D"?|cHDF]›9=B+:fFnE;CZU=jJ<;:<GA8=]§cE58?+=>'C8^:8kIfBHcH="ajI>@?+A8;=B+;g”>KiC+F:M>Yst Ú-"ÜÇ-EÓ) 8$@#"Ü- iG=cH:f^:<;g G:85<7MFnOBp?HB+g =5<7%9:8;="a >@?+A8;=B+;gYh =>@?+A8;=B+CEB+:<i"FCHcHgYhlIfcHCEkIfBHcIfCE:[^=;:<;=kZoc4DCHBHCHGgYh’;?+\HF]_^?+]0BHIŸa‰>@?HA<;=B+;g~:LN?+58CHcHg~:0i:<G:<hEC8^gyi:<GcHCHA8C“GC8^Ç?BH=i?¢iCHGa%^CHDu„\E:8IfiCHGEa%^CHDst >M¬‘iG:f^IfBO?+cHF:<;g J<D"Ifi:8G=>':<;Bp?OFnH;CªiC+F79:<;;g~:c‚;?HIfBHCMa`:<kG?H\HCHBH:B+:8>'i:<G?HB+7%G;g~:2=ÁiC+F:<cHg~:×5M?+cE=If=>'CIfB+=Å;?H>@?+A8;=9:8;;CIfB+=ÁiC+F=DG=I<Bp?+FF=9:MIfD=hCH\EG?+58¡CHc M nF e(P As ) Z M nF e(P As ) = M n F e (P As ) =0.450.550.470.531.10.90.470.53cH:<F=9=;gKRšTWV0Z+cHg~9=I[F:8;;g~:~iC6J8B+=>š^Ç?+;;g”>Ys@œ?HD"—:~iG:[^I<Bp?Hc+F:8;gÁG:85<7MFnOBp?HB+giGEa>'gYh«=58>':8G:<;=k2B+:8>'i:<G?HB+7%G;gYh«=«iC+F:8cHgYh58?+cE=If=>'CEIfBH:<k«RUTWV0sAŸ^:4Q3¬8ÃWè¶SRT°Eî ð¬Eî ÆEƬEî Æ É E¬ s ÂEÂ"î Æ ÉµPS®0XÄs¾¬UOÉH­ØÄs¾¬8ÄÂ+ʳEPS®0XÉs ì Æ ¬H¬¨És ìE­HìEijUROµÃs ÆHÆ ­HÃØÃs Æ Ä7OÃP V£XÉHÃEÄÂH­HÉ+ Ê7TC7X@ZY[@ ËN?+G?E>':<B+GgyCH\EG?+58¡CHc M nF e(P1−x Asx )sNß ?6B+:M>'i:<G?+B+7%G;gYh•58?+cE=If=>'CEIfBMa"h;?E>@?+A8;=9:8;;CEI<B+=ZE=58>':<G:<;;gYh¢c£iC+F:£¬8ÃEãV0ZCHB+9:<B8F=cHC¢cH="^;C“G:<5<D%CH:67%cH:fF=9:<;=:6>@?HA<;=BH;CHA8C¢>'C>':<;BO?“CH\EG?+58¡CHcZcECH58;=D%?H]›`:<:iG=È7">':<;nH†W:8;==‡BH:8>'i:8G?+B+7%GgNs|œCE9D=yT6]›G=Z”CHiG:[^:<Fa:8>'g~:UD%?HD‡B+:M>'i:<G?HB+7%Gg>@?+D"If=>@?+FnH;C\Eg”IfB+GCHA<C=5M>':<;:8;="a’;?H>@?HA<;=9:<;;CIfB+=Zy7%D%?H58?+;g¦cƒBp?+\HF=¡:ƒ¬EsTN?+D¤iCHD"?+5M?OF=¤=58>':8G:<;=aZ47EIfBp?H;CHcHF:<;=:ŠL6:8GGC>@?+A<;=B+CHA8CŒ7%iCHGa%^CH9:<;="a¤cJ<B+=h‰CE\HG?H5<¡?Oh’iG=cHCM^=B‚D¿IfD"?M9D%CHCE\HG?+5<;CH>'7’=5M>':<;:8;=] i?+G?E>':<B+GCHc4a9:<:8DA<:8D%I<?HA<CE;?OFnH;CHklDG=IfBp?+FF=9:8IfD%CHkŠIfBHG7%DB+7%GgNs Ë6G=9:8>YZ|? uq7%cH:fF=9=c?+:<BEIŸaiG=>':8G;Cd;? 1% Z˜?{IouK7">':<;nH†?H:<BHIbac{Bp?HDCH:}—:|DC+F=9:8I<B+cHC{G?+5Es œ?+D=>CH\EG?+58CE>YZY;:MI<>'CEB+GEaÈ;?˜=5M>':<;:8;=:ÀCH\ECH="hKi?HG?H>':8B+GCHcZ~=58>':8;:<;=:ÀCH\ C:8>@?™a9:8kD=iG?HDB+=9:MIfD=2G?+cH;C“;7MF]sû':<5<D%CH:=58>':8;:<;=:;?E>@?+A8;=9:8;;CEI<B+=Z|i?+G?E>':<B+GCEc4a9:<:8DDG=IfBO?OFF=9:8I<DCHkIfB+G7DB+7%Gg{=ÁBH:8>'i:8G?+B+7%G;g~kKA<=I<B+:<G:85<=I«†W=G=;CHkÁCEDC+FCŬ2T7%D%?+58g~cE?H]›BU;?ÀB+CZ9B+Càcà=I8I[F:f^CHc?+;;gYhoCE\HG?H5<¡?OhocyB+CE9D:‡T6]›G=|iGCH=IbhECM^aByLN?H5<CEc+g~:Åi:<G:<hEC8^gi:<GcHCHA8CGC8^Ç?s|Ë6G=r\HC+F:<:š;=5<D="hÈB+:8>'i:8G?+BH7G?OhK^CEiC+F;=B+:<FnH;gYh‡CEI<CH\H:8;;CEIfBH:<k;?eBH:8>'i:8G?+B+7%G;gYh58?+cE=If=>'CEIfBMa"hj;?H>@?HA<;=9:<;;CEIfBH=ZDCHBHCHGg~:|>'CHAúF=\EgÑ\Eg~B+nIfcHa58?+;grI6=58>':8;:<;=:8>K>@?HA<;=BH;CHA8C•IfCEI<B+Cpa;="aZ"CE\H;?HG7—:<;C“;:6\EgYFCs365M>':<G:8;=:¿iC+F:8cHgYh¦58?HcH=I<=>'CEI<B+:<k ;?H>@?HA<;=9:<;;CIfB+=ÔiG=ÔB+:M>'i:<G?HB+7%G?OhwZiG:8cHg~†?H]›`="h I<CHCHBHcH:<BEIfB+cE7]0`W=: BH:8>'i:8G?+B+7%Gg T6]0G=Z iCED%?H58?OFCZ 9B+CiG=¤7%cH:fF=9:<;==¦;?+iGEa"—:8;;CEI<B+=¦iC+FaZƒ;?M9=;?Oa¤I‰;:8DCHBHCHGCEA<CˆiCHGCHA<CEcHCHA<C5<;?p9:8;="a H ZiGCE=IbhEC8^=B“G:<58DCH:6cECH5<G?HIfBO?+;=:ž>@?HA<;=B+;CHA8C•>'CE>':<;Bp?¢CH\EG?+58¡CHcs'ßN?criC+F79:<;;gYh‡DG=cEgYh;?H\+F]_^?+:8BHIba‡†W=GCHD=kÈiC+F:<cHCEk‡A<=I<B+:<G:85<=IHsqË6CHJ<BHCE>'7K\HgYFI ^:fF?H;2cEg~cHCM^Z9B+Cc•=5<7%9?+:M>'gYh2IfCH:f^=;:8;="a"h2>@?HA<;=BH;CH:£iC+F:£cHg~58g~cE?+:8B¢LN?H5<CEcHgYki:<G:fhECM^2i:<GcECHA<C“GCM^?“=5Ni?+G?E>@?+A8;=B+;CEA<C“c•L6:8GGCE>@?HA<;=B+;CH:NIfCIfB+Cpa;=:Es¬H¬ \w Rš?+A8;=B+CED%?OFCHG=9:8IfD=k JMLNL6:<DBpZ =5M>':<G:8;;g~kcECH58G?HI<Bp?+;==«>@?+A8;=B+;CEA<C¢iCHFa«CHB¢Ã^C2¬<ìs Æ DV0s?iG=t_:fF=9=;?‹=5<CHBH:<G>'=9:8IfD%CHA8C‹=58>':<;:<;="a J<;B+GCHi== \EgYF?ØG?HI<I<9=BO?+;?‹;?CEI<;CHcE:€=58>':<G:<;;gYh‚iC+F:<cHgYh58?HcH=I<=>'CEI<B+:<k‚;?E>@?+A<;=9:<;;CEI<B+=s T6GC>':{BHCHA<CZcH:<F=9=;?ŽIfD%?p9D"?ˆJ8;B+GCEi==Z4cECH5<;=D%?H]›`W:8A<CŒcEI[F:[^I<B+cH=:¿LN?H5<CEc+CHA8Cˆi:<G:<hECM^?i:<GcHCHA8C‡GCM^?ZW\HgYF?‡CH¡:<;:8;?ÈIiCE>'CE`WnH]47%G?+cE;:<;="aoTžF?+ki:8GCH;?OuvTžF?M7%5<=7EI<?Z£=IfCIfBp?HcH="F? ∆S = 14 · 104 DFGFEH] G ^Fa M nF e(P As ) Z ∆S = 13.2 · 104 DFGFEH] G ^Fa0.450.55FDHEG=^FasM nF e(P0.47 As0.53 ) ∆S = 13.4 · 104 GF]M n1.1 F e0.9 (P0.47 As0.53 )365iGCHcE:[^:8;;gYhà=I8I[F:f^CHc?+;=kocH=%^;CZ£9B+Cr7cE:fF=9:<;=:ÅIfCM^:8GE—“?+;="ao®0·UiG=;:<=58>':<;;CE>IfCHCEB+;CE†W:<;==2è^¶ RT°NiG=cHCM^=B•D27%cH:<F=9:8;=]oB+:M>'i:<G?+B+7%GgoT6]›G=s…tB+C“—:NcHG:M>aZ>@?+D"If=>@?+FnH;?+acE:fF=9=;?¢>@?+A8;=B+CED%?OFCHG=9:8IfD%CHA8CJ8LNL6:8DBp?=«†=G=;?i=D"?ÀiG?HDB+=9:8IfD=K;:2>':8;"a]›BHIba_s 0›cE:fF=9:<;=:2IfCM^:8GE—“?+;="aÁè¶Z cI<cHCE]dCH9:<G:f^nZ¬MÂiG=cEC8^=B‚D¿7">':<;nE†W:<;=] B+:M>'i:<G?+B+7%Gg T6]0G=Zq;Cl>@?+D%I<=>@?OFnH;g~:5<;?M9:8;="a>@?+A8;=B+CED%?OFCHG=9:8IfD%CHA8CqJ8LNL6:8DBp?eIfBp?H;CHcHaBHIbaj;:8I<DCHFnHD%Cz\HC+FnH†W:Es Ï0\If7—“^:<;=:CH\E;?+G7—:8;;gYh“58?+D%CH;C>':<G;CEIfBH:<k¢\EgYFC£iGCEcH:[^:<;C£c£G?H>'D"?Oh•>@?+A8;=B+CIfB+G=D¡=CE;;CHk>'C8^:fF=LN?+5<CEcHgYhi:<G:<hEC8^CHc¢_=;?OuvûCM^\E:fF?sË67%B+:M>riGa>'gYhÀ=5M>':<G:8;=k\EgYFC27EIfBO?+;CEc+F:8;CZ9B+Cc2=I<I[F:[^CEcE?+;;gYhšCE\HG?H5<¡?Oh>@?+D"If=>@?+FnH;gYho58;?p9:<;=k|RšTWV‘^CEI<B+=Af?+:<BycyCHDG:MIfB+;CEIfBMa"hoBH:8>'i:8G?+B+7%GgªT6]0G=sT6G=cEg~:UiCHF:<cEgYh58?HcH=I<=>'CEI<B+:<kyRšTWV0Z_=5M>':<G:8;;g~:™iG=yB+:8>'i:8G?+BH7G?Ohr>':<;nH†W=hZ";?HI<g~`?H]›BHIbaZ%;C“cH:<F=9=;grRUTWVKc“J<B+CEk×CH\HF?HI<B+=B+:8>'i:8G?+BH7G2>':8;nH†:Hs'û':<58D=kTCGCEI<BKcH:<F=9=;gRUTWV0Z~=58>':8G:<;;CHA8CKiG=QB+:M>'i:<G?HB+7%G?OhycEg~†W: T Z6;?M9=;?+:8BHIbaycCiC+Fa"hiG:8cHg~†“?+]›`="hDG=BH=9:8I<DCE:6iC+F:NLN?+5<CEcHC+A8CWi:<G:fhECM^?s@Ë6CHJ<BHCE>'7•\HgYF2IŸ^:<F?+;cHg~cEC8^Z9BHCdc{=587%9:<;;gYhCH\HG?+5<¡?OhjcHg”I<CHD=:m58;?M9:<;="a>@?+A<;=B+CHD"?OFCEG=9:MIfD%CHA<CJ8LNL6:8DBp?×CH\ CaIf;"a]0BHIŸaÀcHg_^:<F:<;=:8>ÈB+:8i"F?«iG=LN?+58CHcHgYhi:8G:fhECM^?Ohši:<GcHCHA8C×GC8^Ç?ZcHg~58cE?+;;gYh¢^:<kIfB+cE=:8>K>@?+A8;=B+;CEA<C¢iCHFast >[iG:f^IfBO?+cHF:<;g J<D"Ifi:8G=>':<;Bp?OFnH;CªiC+F79:<;;g~:c‚;?HIfBHCMa`:<kG?H\HCHBH:B+:8>'i:<G?HB+7%G;g~:¥= iCHF:<cEg~:ˆ5M?+cE=If=>'CIfB+= ;?E>@?+A<;=9:<;;CEI<B+=Z‰BH:8>'i:8G?+B+7%G;g~:58?HcH=I<=>'CEI<B+=ˆi?+G?E>':<B+GCEcŠDG=I<Bp?OFF=9:MIfDCEk¥IfB+G7%DBH7Gg iC+F=DG=I<Bp?+FF=9:MIfD=hCH\EG?+58¡CHc LaF e Si Z LaF e Co Si =‚cE:fF=9=;g RšTWV0Z™cHg~9=I[F:8;;g~:11.71.311.20.71.1iCÑJ8B+=> ^?H;;g”>Ys œ?+D"—:‰iG:[^ÇIfBp?Hc+F:8;g G:85<7MFnOBp?HB+g iGa>'gYhŽ=5M>':<G:8;=kB+:8>'i:<G?HB+7%G;gYh«=«iCHF:<cEgYh5M?+cE=If=>'CIfB+:8k«RUTWV0sœ:8>'i:8G?+B+7%G;g~:45M?+cH=If=>'CIfB+=§;?H>@?HA<;=9:<;;CIfB+=§\HgYF=Ñ=58>':<G:<;g c‰iC+Fa"h¬8ÃE`à ,ÂHÃHÃÅV0s_t{CE\HCH=hÁCH\HG?+5<¡?OhÁi:<G:<hEC8^r=5ÀL6:<GGCE>@?+A8;=B+;CHA<C˜ci?HG?H>@?HA<;=B+;CH:IfCIfB+Cpa;=:EZ¦cEg~5<cE?H;;CH:Ø;?HA<G:8cE?H;=:8>YZ¤I<CHiGCHcHCp—“^?+:<BHIba G:85<D=> =58>':8;:<;=:8>;?H>@?HA<;=9:<;;CEIfBH=ocÈ7%58DC>{^=?+i?+5<CE;:B+:8>'i:8G?+BH7Gs‚œ:8>'i:<G?HB+7%G;g~kmA8=IfBH:<G:85<=I;?H>@?HA<;=9:<;;CEIfBH= LaF e Co Si ZyC8^;?+D%CZÈ;:jiG:8cHg~†?+F‚CM^;CHA8C‘A<G?O^7EI<?s11.20.71.1œCE9D%? T6]0G=ZØCEiG:[^:fFa:M>@?Oa D%?+D iCHFCM—:8;=: >@?HD%I<=>'7">@? BH:8>'i:8G?+B+7%G;CHkiGCE=5<cEC8^;CHke;?H>@?HA<;=9:<;;CEIfBH=Z«CED%?H58?OF?HIfnoG?HcH;CEk¬8ÊEÊ}TŠ^Fa LaF e Si =11.71.3+ OìÈT‚^Fa sWÌG%78A"=oh@>+?<A;=+B;YgohiG8:HcGH?W`8:;=ok‡c^=+?i+?5<CE;:LaF e11.2 Co0.7 Si1.1B+:8>'i:<G?HB+7%G2CHB T ^C¢ìs “TmCH\H;?+G7—:<;C;:N\HgYFCsCœ:8>'i:8G?+B+7%G;g~: 5M?+cH=If=>'CIfB+= i?+G?E>':<B+GCEc DG=I<Bp?+FF=9:MIfD%CHk a9:8kD=CHiG:[^:<Fa"F=I<njiG=ƒiC>'CH`=G:<;B+A<:8;CHA8G?HL6=9:8IfD%CHA8C{=I8I[F:f^CHc?+;=a‘iCHGCE†WD%CHcHgYh¬8É ba œ:8>'i:8G?+B+7%G;g~:Œ58?HcH=I<=>'CEI<B+=‹RšTWV0Z€=5M>':<G:8;;g~:ˆcCEDG:MIfB+;CIfBMa"h{LN?H5<CHcHgYhei:8G:fhECM^CHc|iG=j7%cH:<F=9:8;==j>@?+A8;=B+;CHA<CiC+FaqCEBQÃy^Cz¬8ìàDV ^Fa LaF e Si =zCHBoÃr^Ce¬H¬DV ^Fa11.71.3sLaF e Co Si?11.20.71.1CH\EG?+58¡CHcsœCE9D=Z"cDCHBHCHGgYh•;?H\+F]_^?H:<BHIba>@?+D%I<=>'7">˜B+:M>'i:<G?HB+7%G;CEkiGCE=5<cECM^;CHki?+G?H>':<BHG?àa9:8kD=Z×G?HI<iC+FCM—:8;gªiG=¬8ÊE­QT‰^Fa LaF e Si ={+ +ÉàT^Fa11.71.3=<IHCEcip?^+?0],BeIfIECHC+BEc<:HB<I+BHc%70]W`='> =+BM:'>i<:G?HB+7%G?H>'=4T6]0G=sLaF e11.2 Co0.7 Si1.1Ë6:<G:<hEC8^àcÁi?+G?E>@?+A8;=B+;CE:ÀI<CEI<B+Cpa;=:ÀiG=cEC8^=BÅDyG:85<DC>'77">':8;nH†:<;=]ƒCH+\ C:8>@?JfF:M>':<;BO?+G;CHkQa9:<kD=ZWIfF:[^CHcE?HB+:fFnH;CZ6cÈ7%iCHGa%^CH9:8;;C>dIfCIfB+Cpa;==Qc‡CE\HG?H5<¡?Oh;?+\HF]_^?+:8BHIŸa2IfiCE;Bp?H;;?+a×CH+\ C:8>';?Oa×>@?HA<;=B+CEI<B+G=D¡="asË6CHF:<cEg~:,58?HcH=I<=>'CEI<B+=l;?E>@?+A8;=9:8;;CEI<B+=ZmiC+F7%9:8;;g~:–;="—:‘B+:M>'i:<G?HB+7%GgT6]›G=Z–=>':<]0BÑcH="^Z,h%?+G?HDB+:<G;g~kŒ^FaxL6:8GGCE>@?HA<;:8B+=D%CHcs ϔ^;?+DCÑcHg~†W:B+:8>'i:<G?HB+7%Gg T6]›G=àiCEcH:f^:<;=:™;?E>@?+A8;=9:8;;CEI<B+=àcJ8B+="hàCH\EG?+58¡?OhrIf7%`W:MIfB+cE:<;;C¬<ìG ?+5<F=9?H:<BHIbas t LaF e Si >@?+A<;=B+;CE:4iC+F:‚cHg~5<g~c?+:<B>':<BO?H>@?+A8;=B+;g~k11.71.3i:<G:fhECM^m=5Ái?+G?H>@?+A8;=B+;CHA<CÈcyL6:<GGCE>@?+A8;=B+;CH:ÅI<CEI<B+CMa;=:HZI<CHiGCEcHCp—^Ç?+]›`W=kIbaiC+F:<cHg”>‚A8=IfB+:8G:<58=IfC>Ys ïGCEI<B+CE>ªB+:8>'i:8G?+BH7GgÑDG=B+=9:MIfDCE:oiC+F:oi:<G:<hECM^?F=;:8k;C¿7%cH:<F=9=cE?+:8BHIbaŒIfC¿I<DCEGCEI<B+nH] ìs欂DcV R+T¢sàt LaF e Co Si ;:11.20.71.1;?+\HF]_^?+:8BHIŸa€i:<G:<A<=\HCHc};?}DG=cHgYheiC+F:8cHCEkz5M?+cE=If=>'CIfB+=€;?H>@?HA<;=9:<;;CEIfBH=Z2?Bp?HD"—:NCHBHI<7BEIfB+cE7H:<B¢iC+F:<cHCEk×A<=I<B+:<G:<5<=I+sRš?HA<;=B+CHD"?OFCEG=9:MIfD=keJ8LNL6:<DBQcà^=?+i?H5<CE;:BH:8>'i:8G?+B+7%G–¬<ìdà ,qÉHÉHÃoT¿\HgYFG?HI8If9=Bp?+;Ñ;?’CEI<;CHcE:=58>':8G:<;;gYhŠiC+F:8cHgYh58?HcH=I<=>'CEI<B+:<k¿;?H>@?+A8;=9:8;;CIfB+=sT6GCE>':yB+CEA<CZ2cH:<F=9=;?|IfD%?p9D"?}J8;B+GCEi==ZšcHCE5<;=D"?+]0`W:<A8C}cI[F:f^IfB+cE=:àLN?+58CHcHCHA<Ci:<G:fhECM^?{i:<GcHCHA8C{GC8^?Z\HgYF?{CH¡:8;:<;?{;?dCEI<;CHcE:|IfCECHB+;CH†W:8;="aTžF?+ki:<GCE;?OuTžF?p758=7EI<?s ßN?+=\EC+FnH†W=:5<;?M9:8;="a¿=5M>':<;:8;="aÑJ<;BHGCHi==ÑiG=ÑcHCE5<G?EIfBp?H;==>@?+A8;=B+;CEA<CiC+Fa2CEBÃ^C×Â+âDVyI<CEIfBO?+cE="F= ∆S = 25 · 104 e GFEf] G ^Fa LaF e Si11.71.3= ∆S = 12.5 · 104 e GF]EHG ^Fa LaF e Co Si sÔï‚GCEI<B+CE>ƒ;?+iGa"—:<;;CEIfBH=11.20.71.1>@?+A8;=B+;CEA<CàiC+FamCH\HF?HI<B+nr\EC+FnE†W="ho58;?M9:<;=kqRšTWV ;?yDG=cECHkmBH:8>'i:8G?+B+7%G;CHk58?HcH=I<=>'CEI<B+=ˆ>@?HA<;=B+CHD"?OFCEG=9:MIfDCEA<C‰J8LNL6:8DBp?’^FaŽIfCH:f^=;:8;="a LaF e Si11.71.3G?HI<†W=Ga:<BHIba‡cÅIfB+CEGCH;7Á\EC+F:8:cHg”I<CHD="hKB+:8>'i:<G?HB+7%Gs}t{BHC˜—:šcEG:8>aZ~cE:fF=9=;?>@?+D"If=>'7">@?RšTWVoG?HIfBH:<B2;:<5<;?M9=B+:fFnE;CZ9B+C2h?HG?+DB+:<G;C×^Fa˜I<=IfB+:M>YZcDCEB+CHGgYh>@?+A8;=B+;CE:qiCHF:qcHg~5<g~c?+:<BdLN?H5<CHcHg~k–i:<G:<hEC8^ i:<GcHCHA8C{GCM^?s ûCIfBj5<;?p9:<;=k>@?+A8;=B+CED%?OFCHG=9:8IfD%CHA8CdJ8LNL6:8DBp?jc,I<CH:f^=;:8;== LaF e Co Si iGCH=IbhEC8^=B11.20.71.1If=>@>':8B+G=9;CžCEB+;CIf=B+:<FnH;C›B+:M>'i:<G?+B+7%GgÁT6]›G=ZOiG=9:8>šcE:fF=9=;?0>@?+D"If=>@?+FnH;CHA<CRšTWV‘=5M>':<;"a:8BHIba}cO^cECH:Esœ?+D%?+a}58?+cE=If=>'CEIfBHn‡=5M>':<;:8;="a}J8;B+GCEi==}CE\HG?H5<¡?CEBcH:<F=9=;g iG="FCp—:<;;CHA<C‰>@?+A<;=B+;CEA<CliC+Fa¿h?+G?+DB+:8G;?4^Fa§>@?+B+:8G=?+FCHcZzcDCEB+CHGgYh×;?+\HF]_^?+:8BHIŸa2>@?+A8;=B+;g~kšLN?+5<CEcHg~ki:8G:fhECM^cHB+CEGCHA8C“GC8^Ç?sœ:8>'i:8G?+B+7%G;g~: 58?HcH=I<=>'CEI<B+= RšTWV0ZŽ;?H\+F]_^?HcH†W=:8Iba iG= 7%cH:fF=9:<;==>@?+A8;=B+;CEA<CdiC+Fa‘CHBdÃe^C¬<ì{DVŠ^Fa LaF e Si =‘CHBdÃe^C¬H¬mDVŠ^Fa11.71.3jZiG[:^<IpB+?HcF<:;g;?G=HIàsÉsœ:8>'i:8G?+BH7G;g~kŽA8=IfBH:<G:85<=ILaF e11.2 Co0.7 Si1.1LN?+58CHcHCHA<C6i:<G:<hECM^?6c LaF e Si IfCIfBO?+c+Fa:<B£ÂNT¢ZH9B+CIfCECHB+cE:<BHI<B+cH7H:8B6A<=I<B+:<G:<5<=If711.71.3B+:8>'i:<G?HB+7%G;CHky5M?+cE=If=>'CIfB+=r;?E>@?+A8;=9:8;;CEI<B+=s€T6G=cHg~:™>@?+A<;=B+CHD"?OFCEG=9:MIfD%CHA<CJ8LNL6:8DBp?ZEiCHF7%9:<;;g~:›iG=;?+A8G:<c?+;==•=CphF?O—“^:<;==CH\EG?+58¡? LaF e Co Si Z11.2¬Æ0.71.1fI CEcHi?O^?+]›B¢c•iG:f^:fF?Oh«iCHA8G:<†;CEI<B+=2=58>':8G:<;=kPS;?¢G=I+sɕiG=cE:[^:8;gàG:85<7MFnOBp?HB+g=58>':8G:<;=k2iG=2;?HA<G:8cE?+;==X[s ;?OF=5«DG=cHgYhiC+F:8cHCHkÅ58?HcH=I<=>'CEI<B+=KRšTWVqcIfcE=%^:<BH:fFnIfB+cE7H:<BLaF e11.7 Si1.3CB+CE>YZY9B+C>@?+A8;=B+CED%?+FCHG=9:8I<D=kKJ8LNL6:8DB™cCH\HF?HI<B+=Ái?HG?+iGCH¡:MI<I8?U58;?M9=B+:fFnH;C>':<;nE†W:‡=5M>':<;:8;="azB+:M>'i:<G?+B+7%GgNZ×iGCH=IŸhECM^a`W:8A<Cà5M?QI<9:<BocHg_^:<F:<;=azIfDGg~B+CHkB+:<iFCHB+g i:<G:fhECM^?s ßN?lA<G?HL6=D"?OhwZ€iCHF7%9:<;;gYhÑiG=ˆBH:8>'i:8G?+B+7%G?+h§cHg~†W:Zà\Hg”IfBHGg~kªGCEI<BƒRšTWVx;?p9=;?+:<BEIŸaªciCHFa"hwZyiG:8cHg~†?H]›`="hDG=B+=9:MIfD%CH:TCiC+F:yLN?+58CHcHCHA<Coi:8G:fhC8^?s‹ï F:f^CHc?+B+:<FnH;CZc LaF e Si cHg”I<CHD=:r5<;?M9:8;="a11.71.3>@?+A8;=B+CED%?OFCHG=9:8IfD%CHA8C‡J8LNL6:<DBp?‡CH+\ CwaIf;a]›BHIbaocHg_^:<F:<;=:8>,B+:<i"F?ÈiG=mLN?H5<CEcHCH>i:<G:fhECM^:ei:<GcECHA<CGCM^?ZcHg~5<c?+;;CE>‰^:8kIfBHcH=:M>§>@?+A8;=B+;CHA<C–iCHFas Ë6C+F:<cHg~:58?HcH=I<=>'CEI<B+=>@?HA<;=B+CHD"?OFCEG=9:MIfDCEA<CeJ8LNL6:<DBp?zc LaF e Co Si Z;?+iGCHB+=cZ11.20.71.1F=;:8k;CÈG?HIfBH7BrI˜7%cH:fF=9:<;=:8>j;?+iGEa"—:<;;CEI<B+=}>@?+A8;=B+;CHA<CÈiC+FaZ£;:^CIfB+=Af?Oa;?HI<g~`W:8;="aslïGCEIfBHCE>,B+:M>'i:<G?HB+7%Gg4;:Á;?H\+F]_^?+:8BHIba}I<>':8`W:8;="a}DG=B+=9:8IfD%CHA8CiC+FaZ£;CÈ7">':8;nH†“?+:<BEIŸao;?+D"FCH;oiC+F:<cHgYhàDG=cHgYhoRšTWV0s6V…B+CyIfcE=%^:<BH:fFnIfB+cE7H:<B‡CB+CE>YZw9B+C×J8;B+GCEi="aUCE\HG?H5<¡?•iF?+cE;C×>':<;"a:8BHIbaÀI=58>':8;:<;=:8>ÈiC+FaU=UB+:M>'i:<G?+B+7%GgNsß6:2;?+\HF]_^?+:8BHIŸaIfD"?M9DCHc™J8;B+GCEi==Z~IfcHa58?H;;gYhÅI2cHg_^:fF:8;=:8>|I<DGg~B+CEkB+:<i"FCHB+gi:<G:fhECM^?sœ?HD=>mCH\HG?+5<CE>QcE;:<†;:<:«>@?HA<;=BH;CH:«iCHF:HZ©iC+uvcH=%^=>'CE>'7EZ@;:«cEg~5<g~cE?H:<B>':<BO?H>@?+A8;=B+;CHA<C•i:<G:<hEC8^Ç?c•IfCE:[^=;:<;== LaF e Co Si s11.20.71.1t >bÉØiG:[^I<Bp?+cHF:<;g G:<5<7pFnpBO?+B+g =I<I[F:[^CEcE?+;="a >@?HA<;=B+;gYh 7%iG7A8="h =B+:<iFCHcEgYh IfcHCEkIfBHcxIfCH:f^=;:8;="a Gd (Si Ge ) st hC8^:ÑG?H\HCHBHg \EgYF=51.952.05cHg~iCHF;:8;g =58>':8G:<;="aØB+:8i"FCE:8>'D%CEIfBH=Z’DCEJ8LNL6=¡=:<;BO?ŽF=;:8k;CEA<C¨B+:<i"FCHcHCEA<CG?HI<†W=G:<;="aZK;?E>@?+A<;=9:<;;CEI<B+=ƒ=^=;?E>'=9:8I<DCEk >@?+A8;=B+;CEk cHCEI<iG==>'9=cHCIfB+=c^=?Hi?+58CH;:˜B+:M>'i:<G?+B+7%G}ìs g ,àÉHÃHÇT¢sžË6C+F:8cHg~:˜58?+cE=If=>'CEIfBH=Q;?E>@?+A<;=9:<;;CEI<B+== >@?+A8;=B+CIfB+G=D¡== Bp?+D—:Œ=5M>':<Ga"F=Ifn¤c¤=>'i7pFnEI<;gYh‹>@?HA<;=BH;gYh‹iC+Fa"h;?+iGEa"—:<;;CEI<B+nH]q^C˜¬ Æ Ã×DÇV0sT6GCE>':•B+CEA<CZcEi:<GcHg~:^FaJ8B+CHA8C2D"F?HI<I8?2I<CH:[^=;:<;=k\HgYF=cEg~iC+F;:<;gdiGa>'g~:š=58>':8G:<;=acH:<F=9=;g,RšTWVe=‡=I<IfF:[^CEcE?H;C™=5M>':<;:8;=:IfcECHkI<B+c“CH\EG?+58¡?Wc“hECM^:6B+:8G>'CH¡=D"F=GCEcE?H;="asϞI<B+Gg~k–>@?HD%I<=>'7">’;?eDG=cHgYhjBH:8>'i:8G?+B+7%G;CHk–58?HcH=I<=>'CEI<B+=,B+:8i"FCE:8>'DCIfB+=ZIfCECHB+cE:<BHI<B+cH7%]›`=koLN?H5<CEcHCH>'7yi:<G:<hEC8^7HZ£;?H\+F]_^?+:8BHIbaQiG=}B+:M>'i:<G?+B+7%G:KÂHÄEÂT’=I<>':8`?+:8BHIbacdCH\+F?HIfBHne\EC+F:8:}cHg”I<CHD=hjB+:M>'i:<G?+B+7%G‘c{iG=If7%BHI<B+cH==ƒ>@?+A<;=B+;CEA<C¬8ÄiC+Fas Ë6CEI<DCHFnHD7Šc‰CEDG:MIfB+;CIfB+=¥Â+Ä’T F=;:<k;CH:4B+:8i"FCHcECH:G?HIf†=G:8;=:=58>':8;"a:<BEIŸaIfD"?M9D%CHCE\HG?+5<;C=ZBO?+DU—:¢D%?+DÀ=ÀB+:8i"FCE:8>'D%CEIfBHnZw=>':<:<B«BH:8>'i:8G?+B+7%G;g~kA<=I<B+:<G:<5<=I+Zš>'Cp—¢;CqI ^:fF?HB+n|cHg~cEC8^Z«9B+CqiG=€^?+;;CHk{B+:8>'i:<G?HB+7%G:àiGCH=IbhEC8^=BLN?+58CHcHg~k™i:8G:fhECM^Åi:<GcECHA8C2GCM^?s«û':<5<D%CH:=5M>':<;:8;=:×>@?+A8;=B+;CHkcHCEI<iG==>'9=cHCIfB+=7%D%?+58g~cE?+:8B;?‡BHCZ9B+Cri:8G:fhECM^|I<CHiGCHcHCp—“^?+:<BHIbaoI8>':<;CEk}>@?HA<;=B+;CHA8CrI<CEI<B+CMa;="ast F=B+:<G?+B+7%G:CEi7%\+F=DCHc?O;g ^?H;;g~:‘G:8;B+A<:8;CHcIfD=hl=I8I[F:f^CHc?+;=kI<CEIfBO?+cECHc= Gd (Si Ge ) Z =>':<]0`W="h iG= D%CE>';?HB+;CHk B+:8>'i:8G?+BH7G:Gd5 (Si1.8 Ge2.2 )522?+;?+FCHA8=9;7%]mDG=IfBO?OFF=9:8I<D7%]zIfBHG7%DB+7%G7EsÏ0\H;?+G7—:<;CZ9B+C«iG=ÀCMh%F?+—^:<;==UcJ<B+=hKCH\EG?+58¡?OhÅCM^;CHcEG:8>':8;;CiGCH=IbhEC8^=B˜>@?+A8;=B+;g~k}PSËNR2#u RUX¢=‡I<B+G7%DB+7%G;g~kPS>'CE;CHD"F=;;?+aeu™CEGB+CHGCE>'\H=9:8I<D%?Oa€IfBHG7%DB+7%G?EXÁLN?+58CHcHg~:Èi:<G:<hEC8^gNhs 009=B+g~c?OaIŸhECp—:MIfB+nqi:<G:89=I[F:<;;gYhjIfCIfBO?+cHCEcZ2\EgYF,IŸ^:<F?+;jcHg~cHCM^Z9B+CzCE\H;?HG7—:<;;g~kdc>@?+A8;=B+CIfB+G7%DBH7G;g~k4LN?+5<CEcHg~k‘i:8G:fhECM^B+Cp—:eI<CHCEB+cH:8BHIfB+cE7H:<BGd5 (Si1.95 Ge2.05 )I<>':8;:–IfCEI<B+Cpa;=kä ËNR2Ku R˜ZÅ>'CH;CED"F=;;?Oa"uvCHGBHCHGC>'\H=9:MIfD%?OaªDG=I<Bp?OFF=9:MIfD%?+aIfB+G7DB+7%G?sÌ£Fa˜\HCHF:<:¢^:<BO?OFnE;CHA8C=5<7%9:8;="aIfcECHkI<B+cš>@?HB+:<G=?OF?\EgYF=˜=58>':8G:<;gziCHF:<cEg~:58?HcH=I<=>'CEI<B+=d;?H>@?+A8;=9:8;;CIfB+=j=>@?+A<;=B+CEI<B+G=D¡==cz=>'i7MFnIf;gYhj>@?+A8;=B+;gYhiC+Fa"hW;?+iGa"—:<;;CEI<B+nH]Á^C¢¬ Æ Ã›DÇV0s+Ë6G=“B+:M>'i:<G?+B+7%G?+hÇZHiG:<cEg~†?+]0`W="h T PíÂHÄEÂ0T£X[ZCGCEI<B;?+iGa"—:<;;CIfB+=À>@?+A8;=B+;CHA<C×iC+FašiG=cHCM^=BDÀIfD%?p9D%CHCH\EG?+5<;CE>'7«7cE:fF=9:<;=];?H>@?HA<;=9:<;;CEIfBH=mCH\HG?+5<¡?‡=|IfCEiGCEcHCM—“^?H:<BHIbao5<;?M9=B+:fFnE;CHk|>@?+A8;=B+CIfB+G=D¡=:8kZ;CEIba`W:8kƒCE\ C:M>';g~kh?+G?HDB+:8GlPSiGCM^C+FnH;?+aƒ>@?+A8;=B+CIfB+G=D¡="aiG=\+F=5<=BH:fFnE;CG?+cE;?ÈiCEi:<G:<9;CEkX[sßN?H\+F]_^?H:<BHIba}Bp?+D—:KiC+F:8cHCEk}A<=I<B+:<G:85<=IÁiCHGEa%^D%?àÂ+ÃrDV0sÏ0\H;?HG7—:<;;g~:CEIfCE\H:<;;CEIfB+=À7D"?+58g~cE?+]0B;?«I<7`:8I<B+cHCEcE?+;=:“>@?+A8;=B+CIfB+G7%DBH7G;CHA8CLN?+58CHcHCHA<C˜i:<G:<hEC8^Ç?˜i:<GcECHA<CÅGC8^Ç?iG=àjœ i›ÂHÄEÂT¢Z_iGCE=IbhEC8^a`:<A8CiC8^r^:8kIfB+cE=:8>>@?+A8;=B+;CEA<C¢iCHFasϞI<CH\H:8;;CEIfBHnH] =58>':8G:<;=k cH:fF=9=;g >@?HA<;=BHCHD"?OFCEG=9:MIfDCEA<C JMLNL6:<DBO?ZIfCEiGCHcECM—“^?+]0`W:<A8C >@?+A8;=B+CIfB+G7DB+7%G;g~k LN?+58CHcHg~k i:<G:fhECM^Z CED%?H58?OF?HIfn58?HcH=I<=>'CEI<B+nàiCHF7%9?+:M>'gYhmG:<587MFnOBp?HB+CHcQCHBo>':<B+CM^=D=eiGCEcH:[^:<;="aqJ<D"Ifi:8G=>':8;Bp?sÌ£Fa€I<G?+cE;:<;="aZ×5<;?M9:8;="a{RšTWV‚\EgYF=eG?HI<I<9=BO?+;gIÈ=IfiC+FnE5<CHcE?+;=:8>‘^?+;;gYhiC}B+:8i"FCH:M>'DCIfB+=€=e=58>':<G:<;g‰;:<iCIfG:f^IfBHcH:<;;Cà^cE7">azG?+5fF=9;g”>'={>':<B+CM^?E>'=s¬U -k œ:8>'i:<G?HB+7%G;g~:Å58?HcH=I<=>'CEI<B+=oRšTWV Gd (Si Ge ) c51.952.05iC+F:”¬<ì~DÇVšiC+F7%9:8;;g~:©c~G:<5<7pFnpBO?+B+:©G?EIf9:8Bp?~=NiGa>'gYh6=58>':8G:<;=ks?t’i:8GcHCEk€I<:<G==€J8D%I<i:<G=>':<;B+CEc|CH\EG?+58:<¡€If;?M9?+F?o;?+A<G:<cE?+FIba|^C|ÉÂ+Ã}T¦PíËNR2uIfCIfB+Cpa;=:pXÅ=d5M?+B+:M>4i"F?+cH;C|CMh%F?+—“^?OFIbae^9C OÊqTŽIàL6=D"I<?+¡=:<kdB+:M>'i:<G?HB+7%Gg9:<G:<5|D"?O—“^g~:zÂ{T¢s2tÑ7EIfBO?+;CHcH=cH†W:8>@Iba–I<CEIfBHCMa;==–iGCH=58cHCM^="FCIfn€=5M>':<G:8;=:RšTWV0st_CzcHB+CEGCHk,I<:<G==,J8D%I<i:<G=>':<;B+CEceCH\EG?+58:<¡d;?HA<G:8cE?OFIŸa€^C€ÉEÂHÃqTŽiCEIfF:D%?+—^CHA<CcHD"F]›9:8;="ar>@?+A<;=B+;CEA<CiCHFa}Pö=58>':<G:<;="arCH9:8G:[^;CHA<C˜58;?p9:<;="aÈRšTWVYX[sË6C+F7%9:8;;g~:eG:85<7MFnpBO?+B+g¨iG:[^ÇIfBp?Hc+F:8;gx;?,G=I+sUìs T6G=cHg~:eBH:8>'i:8G?+B+7%G;CHk58?HcH=I<=>'CEI<B+=eRUTWVŠP ∆H = 14 DVYX˜=>':8]›B}acH;CocHg~G?O—:8;;g~k€>@?+D%I<=>'7"> iG=B+:8>'i:<G?HB+7%G:HZjiG:8cHg~†“?+]›`:<kŒÂHÄEÂlT¢ZrAŸ^:4iCM^§^:<kI<B+cH=:M>‹>@?HA<;=BH;CHA8C‰iC+FaiGCE=IŸhECM^=B€i:<G:<hEC8^‘=5|ËNR lc WRuvI<CEIfBHCMa;=:Hs ßN?+=\EC+FnH†W:8:Q58;?M9:<;=:mRUTWV0Z¬8Êi C+F79:<;;CE:2ci:8GcHCEkKI<:<G==J8D%I<i:<G=>':<;B+CEcÈP ∆T ' 2 K XfZ_;:MIfD%C+FnEDC>':8;nH†:max9:8>€cHCÅcEB+CHGCHkmP ∆T ' 3 K Xfs{V…B+CIfcHa58?+;CÅIUB+:M>YZ09B+CÁiG=r=5M>':<G:8;="a"hÈ\E:<5maxCHB+CEA<G:8cE?zPöi:<Gc?Oae>':<B+CM^=D"?EX=5fuv58?QiC+F:<cHCEA<CQA<=I<B+:<G:85<=I8?QCE\HG?H5<:<¡q;?+hEC8^="FIbaqc^cH7hLN?+58;CE>KIfCEI<B+Cpa;==s iCEI<DC+FnHD7×B+:8i"FCZcEg_^:fFa]0`W:8:8Iba2ciGCH¡:MI<I<:WLN?+58CHcHCHA<Ci:<G:fhECM^?Z^?H:<BmcHD"F?O^dcmCE\H`W:8:È=5M>':<;:8;=:yBH:8>'i:8G?+B+7%GgŠCH\HG?+5<¡?Z×;?+=\HC+FnH†W:<:5<;?p9:8;=:}RšTWV0ZiCHF7%9:<;;CH:oczi:<GcECHk,I<:<G==,J<D"Ifi:8G=>':<;B+CHc{>':<;nE†W:HZÀ9:M>ªcECcHB+CEGCHksË6GCE¡:8I8IfgNZ¿IfCEiGCEcHCM—“^?H]›`W=:¥>@?+A<;=B+CEI<B+G7%DB+7%G;g~k LN?H5<CEc+g~k i:8G:fhECM^ cIfCE:[^=;:<;="a"h Gd (Si Ge ) Z_\HgYF=KiGCE?+;?OF=58=GCEcE?+;g€;?™CEI<;CHcE:F=B+:<G?+B+7%G;gYh5x1−x^?+;;gYh‚C DG=IfBO?OFF=9:8I<D="hlIfB+G7DB+7%G?Oh’cEIf:<h‚B+G:fhlLN?+5EZà;?+\HF]_^?+]0`W="hIbaªcIf:M>':<kI<B+cH:I<CEI<Bp?+cECHc Gd (Si Ge ) Z£iG=QG?+5fF=9;gYhàDCH;¡:<;BHG?+¡=a"hyDG:8>';="aoc5x1−xCHBHI<7%BHIfB+cE=:£>@?+A8;=B+;CEA<C¢iCHFasÌ£FaxCH+\ CwaIf;:8;=:’cH5M?+=>'CIfc+a58=¥>@?+A8;=B+;gYhx=¨IfB+G7DB+7%G;gYh¥iG:<cEG?+`:<;=k\HgYF=x=IfiCHFnH58CHcE?+;g F=B+:8G?+BH7G;g~:ª^?H;;g~:EZ‘IfCHAúF?EIf;C¿DCEB+CHGg”>YZ–=5M>':<;:8;=:DCE;¡:<;B+G?+¡==IfcHCE\HC8^;gYh‚58?HGEa%^CEcZQcECH5<;=D%?H]›`W:8:,iG=‰G?H5<Gg~cE:,D%CHc?OF:8;B+;gYhIfcHa5<:<kZq=ÑIfCEiGCEcHCM—“^?H]›`W:8:IfBHG7%DB+7%G;g~kÑi:<G:<hEC8^§CHB+;CIf=BH:fFnE;CH:ƒI8>':<`:<;=:=CH;CHcšA[?O^C+F=;="a>'Cp—:<BUiG=cHCM^=B+nUD"?+DD=5M>':<;:8;=]d5<;?+D"?Z'Bp?+DÅ=D5M?H>':<BH;CE>'7CEIfF?+\HF:<;=]àcH:<F=9=;gyCH\>':<;;gYhcE58?H=>'CM^:<kI<B+cH=kstÅ)Õ*+n! mÀù©-(ÝݚiG=cH:f^:<;gÁG:85<7MFnOBO?+B+gÁG?EIf9:8Bp?žcH:<F=9=;gÅG?+5fF=9;gYhcHD"F?O^CHccàRUTWV0Z6cHCH58;=D"?+]›`=kmcEIfF:[^ÇIfB+cE=:ÁcEg_^:fF:8;="aqIfDGg~BHCHk|B+:8i"FCEB+g‚iG=qLN?H5<CHcHgYhi:<G:fhECM^?OhNi:8GcHCEA<C0GC8^Ç?st…g~9=I[F:8;="aiGCEcHCM^="F=Ifn›cžG?E>'D%?Oh£B+:8G>'CM^=;?E>'=9:8I<DCEA<C>':<B+CM^?ZNIfCEAbF?HIf;CKDCHBHCHGC>'7HZ6=5M>':<;:8;=:˜J8;B+GCEi==Q=QB+:8>'i:<G?HB+7%GgƒiG=oLN?H5<CEcHCH>i:<G:fhECM^:6i:<GcECHA8CGC8^?“G?HcH;gNZI<CHCHBHcH:<BEIfB+cE:<;;Cä∆Str = −∆TtrT=−C∂∆Eex∂∆Eme∂∆Ea∂∆I,++− Hcr∂T∂T∂T∂T∂∆Eex∂∆Eme∂∆Ea∂∆I.++− Hcr∂T∂T∂T∂Tû'?EIf9:8BŠ>'CM—•;CiGCHcE:8IfBH=Zd=IfiC+FnE5<7+a§J<D"Ifi:8G=>':8;Bp?+FnH;g~:‚cE:fF=9=;gs∆I, ∆E , ∆Emea¬8­PöìXPÆ XHcr (T )Z po û@?HIf9:<B+;g~:¥B+:8>'i:<G?HB+7%G;g~:¥58?+cE=If=>'CEIfBH= =58>':8;:<;=a>@?HA<;=B+;CHk«9?HIfBH=«J<;B+GCHi==2=«G?+5<F=9;gYhJ8;:<GA<:<BH=9:8I<D="h×cHDF?p^CEcc¢CE\+F?EIfB+=2>@?+A8;=B+;CEA<C•LN?H5<CHcHCHA<Ci:<G:<hEC8^?“c Gd (Si Ge ) s?51.952.05Nß ?mG=I+s Æ iG:[^ÇIfBp?Hc+F:8;gB+:8>'i:<G?HB+7%G;g~:Q58?+cE=If=>'CEIfBH=€G?H5fF=9;gYh€cHD"F?O^CHcc =5M>':<;:8;=:–J<;B+GCHi==‰iG=‰LN?H5<CEc+CE>Œi:8G:fhECM^:,i:<GcECHA<C GCM^?ƒcI<CH:[^=;:<;==s<Ç;?p9:<;="a i?HG?H>':8B+GCHc= ∆I iCHF7%9:<;g =5Gd5 (Si1.95 Ge2.05 )Hcr (T )J<D"Ifi:8G=>':<;Bp?OFnH;gYhU^Ç?+;;gYhws«Rš?HA<;=BHCH7%iG7%Af?Oa™J8;:<GA8="a E \HgYF?2cHg~9=I[F:8;?2iCmeL6CHG>'7pF:HäEme =Â+Ã1 2ω ,2κPSÄEXDFEfGTtr (K) −∆Str · 10−4 ( Gq] )ÂOìÃÂ+ĬMÂHÊÂH¬ÆìÆÃGd5 (Si1.95 Ge2.05 )Gd5 (Si1.7 Ge2.3 )Sm0.55 Sr0.45 M nO3TbErT b0.5 Dy0.5Â+ʬ8ÊÆÃs ì¬8ÃÂ"s Æ∂∆Eex∂T−Hcr ∂∆I∂T∂∆Eme∂T≥ 90%≤ 5%≤ 1%≥ 90%≤ 3%≤ 1%≥ 80%≤ 15%≤ 1%≥ 76%≤ 5%≤ 19%≥ 80%≤ 12%≤ 5%≥ 82%≤ 5%≤ 15% 7X@rY4\ Ï0¡:8;D%?cH:<F=9=;QG?H5fF=9;gYhàcHD"F?O^CHccÈRšTWV–iG=LN?H5<CEcHg_hi:<G:<hEC8^?+hi:8GcHCEA<C“GCM^?sWŸA ^: ω u~CEB+;CIf=B+:<FnH;?Oa^:8L6CHG>@?+¡="aZ? κ u›IŸ—•=>@?H:8>'CIfB+ns¢Ï0¡:8;D%?×BH:8>'i:8G?+B+7%G;CHk58?HcH=I<=>'CEI<B+= ω iC+F7%9:8;?4=5J<D"Ifi:8G=>':8;Bp?+FnH;gYhDG=cHgYh>@?HA<;=BHCEIfBHG=D¡==sœCE9;CH:Œ5<;?M9:8;=:ŒIb—•=>@?+:M>'CEIfBH= κ ZlD I<CM—“?+F:<;=]WZl;:ˆ=58cH:MIfB+;CZ’iCHJ8B+CE>'7=IfiC+FnE5<CHc?pF?+I<njcE:fF=9=;? 0.77 · 10−12 ( suIKJtfv ) Zac+Fa]0`?OaIbaƒh?+G?HDB+:<G;CHk^FaIfCE:[^=;:<;=k{^?+;;CHA8C|D"F?EI<I8?s V…;:<GA8="aj?H;=58CHB+GCEi==dBO?+D"—:Q;:<=58cH:8I<B+;?Z;CqcCHDG:8IfBH;CEI<B+=’B+:M>'i:<G?HB+7%Gg‹T6]›G=’CE;?ZàiCHu„cE=%^=>'C>'7HZà;:8cH:fF=D%?ƒ=’:<kl>'Cp—•;CiG:8;:<\EG:<9nsû@?+5<;CEIfBHn•J8;B+GCEi=kULN?+5HZcECH5<;=D%?H]›`?+a«cEIfF:[^I<B+cH=:£I<D%?p9D%? ∂E iG=i:<G:<hEC8^:HZiCHD"?+5M?+;?«;?cEI<Bp?+cED:•G=IHs Æ s2TN?+DcH="^;C=5G=If7%;D"?ZJ<Bp?šI<CEIfBO?+∂TcHFa]›`“?Oa>@?OF?iCIfG?HcH;:8;=]’IÁCH\E`W=>=58>':8;:<;=:8>–J8;B+GCEi==|=|7%\Hg~cE?H:<BrIÁGCEI<B+CE>B+:M>'i:<G?+B+7%GgNsRš?+D"If=>@?+FnH;CHkqcH:<F=9=;glIfD"?M9CEDqJ8;B+GCEi==q^CEI<B+=Af?+:8BQiG=eB+:8>'i:<G?HB+7%G:rT6]›G=PíÂHÄE›T£XfZO=“;?+=\HC+FnH†W=kWcED"F?O^¢c6RšTWVÀ^?H:<Bž=58>':8;:<;=:YB+:M>'i:<G?+B+7%G;CEk“iGCE=5<cECM^;CHkCH\>':<;;CEk×J<;:<GA8== ∂E iG=2i:8G:fhECM^:Es∂T ;?OFCEA<=9;g~:¨cHg~9=I[F:8;="a \EgYF= cHg~iC+F;:8;g ;?ØCEI<;CHcE:ŽF=B+:<G?+B+7%G;gYh^?+;;gYh™^FaÁI<CH:f^=;:8;="a Sm Sr M nO Z©cÀDCEB+CHGC>o>@?HA<;=BH;g~kÁi:<G:<hEC8^KiG=0.550.453B+:8>'i:<G?HB+7%G:T6]0G=2acHFa:<BHIbašLN?+58CHcHg”>Ái:<G:<hEC8^CE>Ái:<GcECHA<C•GCM^?Z?•BO?+D"—:N^F`a :›ëEZ%(Z ç ±=IfiF?+cECHcZZ_c™D%CHB+CEGgYhÅ=;"^7%¡=GCEcE?+;;g~kK>@?HA<;=BH;g”>T bx Y1−x T bx Dy1−xiC+F:8>Œi:<G:<hECM^’CHBA<:<F=D%CH=%^Ç?OFnE;CHkª?+;B+=L6:<GGC>@?+A8;=B+;CEk‚D’L6:8GGCE>@?HA<;=B+;CHk2meexÂ"¬fI B+G7DB+7%G: cª;:8DCHBHCHGCEkŠCH\HF?HI<B+=ŠB+:8>'i:8G?+BH7G¿ac+Fa:<BHIba¿LN?H5<CHcHg”>¨i:8G:fhECM^C>i:<GcHCHA8C“GC8^Ç?sû':<5<7pFnOBp?+BHg€G?HIf9:<B+CEcUiG=cH:f^:<;g€c™Bp?+\HF=¡:ÂsßN?U="hÅCEI<;CHcE:×>'CM—•;CIŸ^:fF?HB+ncHg~cEC8^Z9B+C×c†=GCHD%CE>KDF?HI8If:IfCH:f^=;:8;=kZcDCEB+CHGgYh2iC8^š^:8kIfB+cE=:8>È>@?+A<;=B+;CEA<CiC+FaUiGCH=IbhECM^aB«>@?+A8;=B+;g~:•LN?+5<CEcHg~:Wi:8G:fhC8^gmi:<GcHCHA8C×GCM^?ZwCIf;CEcH;CEkšcED"F?p^cRšTWVK^?+:8B“=5M>':<;:8;=:NCE\E>':<;;CHk×J8;:<GA<==s“ÿ'qwÿWUyxz7X|{"Çew}wÇý'P ¬MX×365879:<;g >@?+A<;=B+;g~: = >@?+A8;=B+CEB+:<i"FCHcHg~: I<cHCHkIfB+c? I<CH:[^=;:<;=kZZZM nF e(P0.47 As0.53 )M nF e(P0.45 As0.55 )M n1.1 F e0.9 (P0.47 As0.53 )= LaF e Co Si Z Gd (Si Ge ) Z HoAl Z Gd In cLaF e11.7 Si1.311.20.71.151.952.0522CE\+F?EIfB+=>@?HA<;=B+;gYhLN?H5<CEcHg_hNi:8G:fhECM^CEc›i:<GcECHA<C0GCM^?Z+IfCEiGCHcECM—“^?+]0`W="hIba\EC+FnE†W=>Å>@?+A8;=B+CED%?+FCHG=9:8I<D=>ÅJ8LNL6:8DB+CE>yPSRšTWVYXfsË6GCHcE:[^:8;C=5M>':<G:8;=:B+:M>'i:<G?+B+7%G;gYh = iC+F:<cHgYh 58?HcH=I<=>'CEI<B+:<k RšTWV0Z;?H>@?+A8;=9:8;;CIfB+=ZcECEIfiG==>'9=cHCEI<B+=Z B+:8i"FCE:8>'DCIfB+= = i?+G?H>':<BHGCHc DG=IfBO?OFF=9:8I<DCHkI<B+G7%DB+7%Gg c ^=?Hi?+58CH;:BH:8>'i:8G?+B+7%GŠìs ~ ,’ÉEÃHÁT¢ZÁc‚IfBO?+¡=CH;?HG;gYh>@?HA<;=BH;gYhiC+Fa"hU^C˜¬MÃHëDVm=˜=>'i7MFnEI<;gYh™iCHFa"hU^C¬ Æ Ã2DV0sË6CED%?H58?+;CZ9BHCQcQJ<B+="hqI<CH:[^=;:<;="a"hmiG=9=;CHkziCpac+F:8;="a|\HCHFnH†="h}cH:fF=9=;zRšTWVc|CEDG:MIfB+;CIfB+=j>@?+A8;=B+;gYh{LN?H5<CHcHgYhzi:8G:fhECM^CEc}i:<GcECHA<CmGC8^?}acHFa:<BHIbaG:85<D%CH:K=5M>':<;:8;=:‡CH\E>':8;;CEkmJ8;:<GA8==qiG=zi:<G:<hEC8^:HZ¢iGCH=IbhEC8^a`W:8>–iCM^^:8kIfBHcH=:M>Á>@?HA<;=BH;CHA8C¢iC+FasP„ÂHX×t_i:8GcHg~: iGCHcE:[^:8;g iGEa>'g~: =58>':8G:<;="a RšTWV c IfCE:[^=;:<;=a"hZZZM nF e(P0.47 As0.53 )M nF e(P0.45 As0.55 )M n1.1 F e0.9 (P0.47 As0.53 )= LaF e Co Si Z Gd (Si Ge ) s 0©IfBO?+;CEc+F:8;CZLaF e11.7 Si1.311.20.71.151.952.059BHC G:85<7MFnpBO?+B+g iGa>'gYh =5M>':<G:8;=k hECEGCH†C IfCEAbF?HIf7%]0BHIŸa IB+:8G>'CM^=;?E>'=9:8I<D=>'=G?HI<9:<BO?H>'=ZcEg~iC+F;:<;;g”>'= ;? CEIf;CHcH:J8D%Ifi:<G=>':8;Bp?+FnH;gYh^?+;;gYhiC¢BH:<i"FCE:8>'D%CEIfBH=2=«;?E>@?+A8;=9:8;;CEI<B+=sPíÉEX•Ì£FaNI<CH:[^=;:<;="a Gd (Si Ge ) cEg~iC+F;:<;g™=58>':8G:<;=a6;?E>@?+A8;=9:8;;CEI<B+=51.952.05=e>@?+A8;=B+CIfB+G=D¡==eco=>'i7MFnEIf;gYh|>@?HA<;=B+;gYhqiC+Fa"hm;?+iGa"—:<;;CIfB+nE]^Cz¬ Æ ÃrDV0}s 0©IfBO?+;CEc+F:8;CZ¢9BHCQcr^Ç?+;;C>‘IfCE:[^=;:<;==Z•iG=zB+:8>'i:8G?+BH7G:ÂHÂ6T ]0G=Z"IfCIf7%`W:MIfB+cE7%]›BW>@?HA<;=BH;g~k×=×IfB+G7%DBH7G;g~k«LN?+58CHcHg~:”i:8G:fhECM^gNs@Ë6G=\EC+F:8:›cHg”I<CHD=h¢BH:8>'i:8G?+B+7%G?+hiCM^^:8kIfB+cE=:8>Å>@?+A8;=B+;CHA<C“iC+FaiGCH=IbhEC8^=BLN?H5<CHcHg~k|i:<G:<hEC8^ec}IfCIfB+Cpa;=:È?+;?+FCHA8=9;CE:K;=58DCEB+:8>'i:8G?+BH7G;CHkeLN?H5<:EsË67%B+:M>,iGEa>'gYh}=58>':8G:<;=k}CEiG:f^:fF:8;Crc+F="a;=:ÅB+:8G>'CH¡=D"F=GCEcE?H;="a};?cE:fF=9=;7=×h?HG?+DBH:<G«B+:M>'i:<G?HB+7%G;gYh«=«iC+F:8cHgYh58?+cE=If=>'CEIfBH:<k2RšTWV0sPSìX×Ë6GCEcH:f^:<;C =5879:<;=:Ô>@?+A8;=B+CEB+:<i"FCHcHgYh IfcECHkI<B+c IfCE:[^=;:<;=a HoAl2cªCHDG:8IfBH;CEI<B+=¿Ifi=;i:<G:<CHG=:<;BO?+¡=CH;;CEA<CªLN?+58CHcHCHA<C4i:<G:<hEC8^Ç?4=‰^?+;?=;B+:<GiG:<BO?+¡="a iCHF7%9:<;;gYhØJ<D"Ifi:8G=>':8;Bp?+FnH;gYhØ^?+;;gYhØ;?¤CEIf;CHcH:>'CM^:fFnH;CEk LN?H5<CHcHCHk ^=?+A8G?H>@>'g D7\E=9:MIfDCEA<C L6:<GGCE>@?HA<;:8B+=D%? c>@?HA<;=BH;CE>‰iC+F:Es ßN?€CIf;CEcH:}B+:M>'i:<G?+B+7%G;gYh‘58?+cE=If=>'CEIfBH:<k–DCE;IfBO?+;B>@?HA<;=BH;CHk2?H;=5<CEB+GCEi==×G?HI<I<9=BO?+;?cE:fF=9=;?“I<DGg~B+CEk«B+:<iFCHB+gài:<G:<hECM^?iG=IfiCH;BO?+;;CEk˜I<i=;CEcHCHki:8G:<CEG=:<;Bp?H¡==˜=˜iCED%?H58?+;CZ9BHCšJ<BHCš5<;?p9:8;=:I<CHAúF?HI<7H:<BHIba«IžJ8D%Ifi:<G=>':8;Bp?+FnH;g”>'=2G:<587MFnOBp?HBp?H>'=sj€'Ç_€Zz2X'ZYrg€'Åy‚0ý@Ç"qY…P ¬MX×蚵HéH¶°<¸Ÿº"³8µ¾ºH±Ÿ²¾³°„ƒÇ°8³f¸b·¢²¾¶ M nF eP As …u µH·Ÿf° ų<ºH¯¢½ºH»¶·8s ç s‡†_±Ÿ»³ˆ6ÇZ…è˜s1−xxFò ¾ë%¶Z®£sè˜s %Y²´*· '²æ¶µ+¶ Š‰s%°8éH»·8Zåèšèšè˜ZÂ+­EÃOu¹ÂO­¬“P„Â+ÃHÃ Æ X ½½ÊOuú¬8ÉsP„ÂHX×蚵HéH¶°<¸Ÿº"³8µ ¾ºH±Ÿ²¾³N½±bºH½°8± ¸b²æ°M·”º ‹@ˆ¸ '° LaF e Si µ+¶ LaF e Co Si ·Ÿë"·¹u11.71.311.20.71.1¸b°<¯•·×蚵 ŒFò æë%¶Z›®£s 蘍s %Y²´*· '²æ¶ŽZ T_s ðs ›»Z›ås 6µHºZ~ås NsYê%»¶rµ+¶ †0s‘“sYê7'°8¶Zåèšèšè˜ZÂH­HÃOu¹Â+­"¬“P„Â+ÃEÃ Æ XfZ%½`½ %¬pÂpKu %¬<ìsPíÉEX×蚵HéH¶°<¸Ÿº"³8µ ¾ºH±Ÿ²¾³ „° ƒÇ°8³f¸ ²¾¶ ² ¸b²æ¶°<±úµ+¶E¸ f° æ°M³[¸Ÿ±bºH¶ ¯¢°f¸úµ+¯•µ+éE¶°f¸b²¾³ ·Ÿë"·¹¸b°<¯•·T_sðWs ”»Z2ås 6µHºZ×蚵 ŒqFò ¾ë%¶Z«®£s“蘒s %Y²´*· '²æ¶ZðsLa(F e1−x Cox )11.9 Si1.1s 80²´µ+¶Z2ås £s¢ê"»¶{µH¶ 9†ž“s “s•7ê '°<¶Z2ås“®”½y½ í•s ”–'%ë"·<sØ­ zP„Â+ÃHÃ Æ X[Z×½½ 5¬MÃHèšÉEÃHÉpuú¬<ÃHèšÉHÃ Æ sPSì=X :0²æ±b°8³f¸Q¯“°MµH·Ÿ»±b°<¯¢°<¶¸b·yº ‹Å¯•µ+éE¶°f¸bº"³<µ æºH±Ÿ²´³}„° ƒÇ°8³[¸Q²¾¶‘*¸ '˜° —±b· ¸ uvºH$± "°<±à· ë"· ¸Ÿ°8¯T…sðWZs ”»Zè˜sFò ¾ë%¶Z®£sè˜qs %Y²´*· '²æ¶Zåqs Nsê%»¶|Z “så1s ™µH¶é1Z ™“sLaF e11.7 Si1.3T_sš¼ '°<¶qZ T_Ss µ+¶éZZ "ns £sš¼ '°8¶é1Z †ž1s “s7ê '°<¶Zåsw®”½½ í›s ”–'%ë"·<s­HÉÀPíÂHÃHÃEÉEX[Zǽ½ÆEÆ ÃHÉOu Æ+Æ ÃHÄsP Æ X×Rš?HA<;=B+;g~:HZ>@?+A<;=B+CHBH:<i"FCEcHg~: =>@?+A8;=B+CE7iG7%A<=: IfcECHkI<B+cE?c CHDG:MIfB+;CEIfBH= >@?HA<;=B+CEI<B+G7%DB+7%G;CEA<C LN?+58CHcHCHA<CGd (Si Ge )51.952.05Â+Éi:8G:fhECM^?s s"ï0sÐ6:8G;g~†WCEcZOÌs s2W="F=iiCHcZ%R˜s3¢sE3žFnE=;ZEû's7<'sEõN:<cE=B+=;Z®W|s ‰qs ”'°8$³ 'µ+±ú·#6%ëEZñWsœV¢sq”°M³ˆ'µ+±ú·#6%ëEZrV¢s®Wsœ6·b³ˆ'¶°<²"¶°<±“åH±MZ'tžstžs@ï…;:<A8=G:<cZ sR˜sœ_=†W=;SZ RšR ­HÉ¢· »½y½ ©¬•PíÂHÃHÃEÂEX[Z Æ ¬8­+u Æ ÂOÉsPíÄEX×蚵HéH¶°<¸ŸºH*¸ '°8±Ÿ¯•µ +½±bºH½°8± ¸b²æ°M·wº ‹"½º ¾ë%³<±Ÿë"· ¸bµ ¾²æ¶° Gd In sè˜s8ò[s<Fò ¾ë%¶ZO®£sMè˜us %Y²¾*· '²¾¶Z2V¢s®£œs 6·bˆ³ '¶°<² "¶°<±MZ'åH±Ms×ñWrs V¢qs ”°Mˆ³ 'µH±b*· 6%ëHZ®£|s ‰qs ”°Mˆ³ 'µH±b*· 6%ëHZ@¼…±bëHº"³fº%º æ°8±b·<Z ¬E¬P„Â+ÃHìMX[Z"½½s@ì Æ pu„ìEÄ+ìsPž+X×Rš?HA<;=B+CHD"?OFCEG=9:MIfD=k J8LNL6:<DBÔ= Ifi=;i:8G:<CEG=:<;Bp?+¡=CH;;g~k i:<G:<hEC8^i:8GcHCEA<C6GC8^Ç?6cND7%\E=9:8I<DC>™>@?+A<;:<B+=D%: HoAl s'R˜s3¢sE3žFnH=;ZE3¢sEߢs <Ç7%\HD%CHcZ2Rš3Wï_RuvÃ Æ Z"RCIfDc?ZÂ+ÃEÃ Æ sPíÊEX×Rš?HA<;=B+CHD"?OFCEG=9:MIfD=kƒJ8LNL6:8DBjc,?H;B+=L6:8GGC>@?+A<;=B+;gYhƒ>@?+B+:8G=?OF?Oh‘cCEDG:8I<B+;CIfB+=|>':8Bp?H>@?HA<;=B+;gYhmLN?+58CHcHgYhài:<G:<hEC8^CEcÈi:8GcHCEA<CÈGCM^?s’3¢s6ߢs<Ç7%\EDCHcZ"R˜s3¢s3žFnE=;Z"õNC>'CH;CIfCHc+uvÃ Æ Z"RšCEIfDcE?ZÂHÃHÃ Æ sPí­EX×Rš?HA<;=B+CHD"?OFCEG=9:MIfD=k¦J8LNL6:<DB§cˆiC+F=DG=IfBO?OFF=9:8I<D="h¦IfCE:[^=;:<;=a"h= T bAl ZRsž3¢sž3žFnH=;Z sžRsžœ_=†W=;Z“ñWs V¢s ”'°8$³ 'µ+±ú*· 6ëEZW®£}s ‰sHoAl22”'°8$³ 'µ+±ú#· 6%ëµ+¶ ÀZ V¢s®£s 6·bˆ³ '¶°<² "¶°8±8ZåH±MsæZßNRURšR2uóÃ+ìZ"RšCEIfDcE?ZÂ+ÃHÃHìsP ¬8ÃXRš?HA<;=B+CHD"?OFCEG=9:MIfD=:lIfcECHkI<B+cE?F:8A<=GCEcE?H;;gYhˆi:<GCEcEIfD=B+CHc AM nO Z3Ÿ s 3¢s ï…i=9D=;Z s…ï0s Ð6:<G;g~†CHcZ R˜s©3¢s©3žFnE=;Z s©Rs©œ_=†W=;Z”Ïs Ÿ s.%CEG\H:8;DCZ©R˜s ï0s©TN?+GBO?+cH¡:<cE?Z s@û's©TN?M7MFnZ©tžs s >':fF=9:<cZ…ßNRšRšRuvÃHìZRCIfDc?ZÂHÃHÃHìsP ¬H¬pXRš?HA<;=B+;g~:HZ>@?+A<;=B+CHBH:<i"FCEcHg~: =>@?+A8;=B+CE7iG7%A<=: IfcECHkI<B+cE?c CHDG:MIfB+;CEIfBH= >@?HA<;=B+CEI<B+G7%DB+7%G;CEA<C LN?+58CHcHCHA<CGd5 (Si1.95 Ge2.05 )i:8G:fhECM^?s s"ï0sÐ6:8G;g~†WCEcZOÌs 2s W="F=iiCHcZ%R˜s3¢sE3žFnE=;ZEû'7s <'sEõN:<cE=B+=;Z®W|s ‰qs ”'°8$³ 'µ+±ú#· 6%ëEZñWœs V¢qs ”°Mˆ³ 'µ+±ú#· 6%ëErZ V¢s®Wœs 6·bˆ³ '¶°<² "¶°<±“åH±MZ'tžstžs@ï…;:<A8=G:<cZ sR˜sœ_=†W=;ZßNRšRšRuvìHZ"RCIfDc?¢Â+ÃHìHsÂOì.

Характеристики

Список файлов диссертации