Отзыв официального оппонента А.Л. Васильева (Комплексное оборудование и технологические процессы промышленного производства анолита и феррата)

oT3bIB OOI,IqITAJIbHOTO OITIOHEHTAAorffopa rexH[rrecKrrx HayK Bacn.rrena Anercceq Jlrson[qa Ha Ar.rcceprarlrtoAparcueena Enreurs Hnroraennqa <KOMIInEKCHOE OBOPyAOBAHI4E I4IIPOMbIIIJIEHHOf OIIPOIIECCbITEXHOJIOf I4IIECKI4E(DEPPATA>>,upegcraBrreHHyro Ha colrcKturueIIPOI43BOACTBA AHOJII4TA I4yrenofi crerreHn KaHALrAara rexur,rqecK[x HayK rro creq[aJrbHocrrl 05.02.13 Mamnnrr, arperarbr n npoqeccbr (norurpa$r4qecKr.re 14 ynaKoBotlHbleTexHoJrorr{rE r,r o6opy,uoBaHrre, xrrMr{rrecKas [poMbrmJrerrHocrr) (rexHr,IuecKuenayr<u)AKTYAJIbHOCTb PAEOTbICeroAns oqeub ocrpo crolaT npo6reua fio]rcKa s(fSerrunnoro, 4eIu€noro, 6esonacHoropealeHTa Ans o6essaprDKrrBaHlr{ BoAbr r4 croKoB.

Bce npunreHseMble peareuTbl I{ MeroAbIo6naAaror prAoM HeAocrarKoB r.r He Moryr 6rrrs npusHaHbl a6comotno s$(lexrunnblMll u6egonacsrnrru.Ha ceroAuxrll.un{t AeHb [pr,rMeHeHlre xJropcoAepxarqfix peareHToB, HecMorpt Ha pflAHeAocrarKoB, flBlrflercfl. ocnoBHbrn,t MeroAoM o6eseapaxuBarrnfl. Ha KoMMyHanbHbrxBo,qolpoBo rax u craHrltrf,x no o6pa6orKe [por43BoAcrBeunbrx lr ropoAcKrlx croqHbD( BoA.Ognaxo, .{o cr4x rrop cyrqecrByror [porr,rBopequs. C oanoft cropoubl, B coorBercrBllu crpe6onannrnu CaufIuH 2.I.4.1074-01, nr.rrbeBarl BoAa AoJD(Ha coAepxarb He MeHee 0.3-0.5ur/n ocrarorrHoto xJropa, c 4pyrofi cropoHbr, c cagllTapHo-rurrleHll.recroft TorrKI,I 3peHrlg,xJroprrpoBaHr.re []rrbeBofi noArr He xeJrareJrbHo.

Cro.rHrre BoAbI He AoJI]ItHbI coAepx(arb xJlopa,TaK KaK ero ry6ureJrbHo cKrBbrBaercr na $nope u SayHe BoAoeMoB, Ho xnop[poBaul'IeAerudsHfi MSTOA O6essapaNilBa6v1fl CTOTIH6IX BOA.flpuueneurre raKrrx MeroAoB o6essapaxvrBalt4s. n[mesofi BoAbI, KaK yJlbrpaSuoler,o3oH, yJrbrpa3ByK ue s(p(femr.rBnbr Lr3'3a orcyrcrBllfl npoJlouplpoBaHHoro o6essapaxl{BaloqeroAeficrnus. O6pa6orxa BoAbr, coAepxarqeft opranrqecKl4e 3atps3HeH[.f,, xJIopoM IpLIBoALIT Knau6Olee 4OcryuurrfiI,Io6pa.:onauHro HeKoroporo KoJrrrqecrBa ranqeporeHnoft xJIopopraHLIKn, Koropa"fl nary6noB1rufler Ha opraHr,I3M qeJroBeKa.

O.qlraro pt,rcK 3apaxenl,Is KIiIrreqHbM]t I,Iu$erquruu uBr,rpycttMr.r BbrHyxAaer ncd-raxr.r upr,rMeHrrrb rroBblrueHHbre Ao3bI xJlopcoAepxalqux peareHToB.aBTopoM TeMa Ar{cceprallnouuofi pa6orbl, rIocBtIIIeHHuuIpa-:pa6orxe rexHoJrora[ v o6opyAonannx, Iro3Bontrcurx B eA[HoM KoMnJIeKcHoMoneKTponr43HoM arperare (4a-nee K3A) c oAsoft cropoHbl rlonfrarb peareHT, o6na.qaroquftMorrIHbM o6essapaxl,IBaloultlM e(p$enrorrl, rpu sToM He o6paeyroUzfi B BoAexnopopraHr{qecKr,rx coe4uHeuuft, c apyrofi cropoHbl o6ecneqr,rearctrlfix cHI4xeHI{e Ao3BBoAr.rMoro B nr{TbeByro BoAy Anr o6essapaxuBant4s. xJlopa, tBJUIerc.s BecbMa arctyalrnofi.Iloerouy us6panuaxTb r4 O E O C HO BAHH O C Tb HAyTIHbIX rIO JIO )KEHVrn,BbIBOAOB I4 PEKOMEHAAIII{fillpe4cranlegHbre Haf{Hbre floJroxeHr,rr, BbIBoAbI rro pa6ore v peKoMeHAaII[lIo6ocuosaurr KoppeKTuocrbro [ocraHoBKI,I 3a,qau n nrt6opou MeroAoB I'Ix peureHu.fl,npfiMeHeH[eM coBpeMeHHbrx MeroAoB r,rccneAoBarlilt, B ToM qI,IcJIe: Soroxolop[MerpuqecKoroMeroAa olpeAeJreHlrfl KoHrIeHTparIuu $eppata B pacrBope, aMnepoMerpl'IqecKoro Mero,4aonpeAeJIeHI,I.f, coAepxaHr4.fl xJropa B BoAe, [oTeHIIlIOMeTpLIqecKoro TI'ITpOBaHut; MacccrreKTpoMerputti BoJrbraMrrepoMerpulr cocraBa npoMbrruJreHHbrx croKoB' la6oparopurxxurrruqecKoro n 6uonornqecKoro cocraBa npo6 nurresofi soArr N xogsficrseHHo"acrraAo"u"zfi6rrrosrx cToKOB IIocJIe o6eaSapaxk1BaHufl aH6JII'IT6M u (f eppatoru.,{octonepnocrr nonfIeHHbIX pe3ynbTaTon pa6otu noATBepXAeHa errcoroftcxoAr{MocTblo pacqeTHbrx u gKclepI{MeHTaJrbHbrX AaHHbx' anpo6aUnefi n npoublllrireHHbrxycnoBr.r_sx aHoJrlrra u (feppara lr rexur,rqecKr.rx cpeAcrB Ant I{x rloJlyqeH}rg' noJIoxrITeJIbHbMAOCTOB Ep HOC)orrbrToM BHeApeHr.rr pa3pa6oTaHHbx rexHr,rtrecKr.rx peureHr,Ifi IIo o6e33apa)KHBaHHIO BOAbI rIcroKoB Ha crarrqr.rflx BoAocHa6xe:cli/ls.

pr KarraJll,I3arlvw p'.!la ropoAoB.PerouenAarlvru u BbrBoAbr Ar.rcceprarlrEonnoft pa6orrr rIoATBepx.4eHbI p$yJlbraraMu3Kcrrepr.rMeHTaJr6H6D( r4ccJreAoBaHuit u arrpo6aquefi paspa6orannbrx rexHI,IqecKI4x peueuuft u[poMbrrfineHHbrx ycJroBnrx Ans o6eesapaxuBaHufl BoAbI, xosxfictneHno-6rrrosrx croKoB,KoaryJrrqur,r ToKcI,MIrbrx oTxoAoB I,I JII,IBHeBbX BOA.3HAqI4MOCTb An,fl HAyKr4 r4 rrPAKTI4Ktr rrOJIvr{EHHbIX PE3yJIbTATOBK3A, TexHr{qecKr,Ie lr TexHoJIorHqecKLIe peureHrltarperara v eto uogyleft He r{Melor orerrecrBeHHbD( vI sapy6exnrx aHarloroB, qronoArBepxAaercs.

ceMbro nareHraMr.r P@: Jtlb 113735 or 03.05.2011; l\b 2471891ot 15.03.2011;Ns 142205 or 05.12.2013; J',1b160773 o'r 08.09.15; llbl62651 or 09.11.15; J\! 165201or 08.09.15;]\b 169435 or 04.07.2016, n roropbrx rrprrBeAeHbr r.rcrroJrb3oBaHHble B ArIcceprarII{LI peuIeHLIt.Hay.ruofi nonr,rsHoft rr 3HaqrrMocrbrc o6ra,{arot cneAylou}Ie pe3ynbrarrr pa6orrr:- paspa6otaHHafl aBTopoM KoHrleuqur nonfreurrr aHoJII4Ta Ia $eppara lr'arpvrs. ryreMueu6pauHoro gneKTpoJIrBa B e,qI,IIroM K3A;- cxeMHbre H KoncrpyKTlrBnbre pemeHr.rr K3A u ero Mo.{ynefi !.ns npI{MeHeHI4tpeareHToB B [poMbIItrJIeHHbX ycroBnsx;TexHoJrorntlecKllx napaMeTpoB Ilpoqecca- gKCnepuMeHTaiIbHbIe'IccneAoBaHIItgJreKTpoirlra aHoJrr{Ta u (peppara Harpus.

B K3A Ha BoAoKanane u rpoMhllrrneHHoroflpe.unoNeHHbre aBTopoM KoHrlerrrlllrrIpr.rMeHeHI{s [oJrrreHHbrx peareHToB.rlp arrnuecKyro 3HaqrlMocrb cocraBJr{ror cne,4yroqne pe3yJlbrarbl pa6orrr :- anpo6auur B rrpoMbrrrrJreuHbrx ycnoBrlsx arperaroB AJII nonfreHl,It tu{oJlvra u Qepparat crouHbx BoA;o6ocuonanne sronoruqecroft vr sronoMrl.recroft e([(ferruruocru [peAnoxeHHbD(TexHlIqecKI,Ix peureHllfi no o.rzctre BoAbI lI crorlHbrx BoA.- peKoMeuAaqr,rn ilo lrcflonb3oBaHuro peyJrbraron pa6orrt B cldcreMbl o6essapaNvBanuflnurreeoff Lt rexnil.recxoft BoAbr, rrpoMbrruJreHHhx pt 6rrroerrx croKoB Ha pa3nI'IqIrbIXHapoAHoxogsftcrseHHrx o6rexrax, TaKr{x KaK ropoAcKr,Ie BoAoKaHaJIbI I{ npoMbIrlJIeHHbIerrpeA[p[tTllt.4lao6e::apannvtBaelvIs. BoAbI-COAEPXAHI,IE PABOTbIfir.rccepraq]rouHar pa6ora Aparueena E.H.

cocro]IT I43 BBeAeHHs, rrflTvt rJIaB,3aKJrrotreHu.rr, BbrBoAoB, crrrrcKa nureparypbl LI flpl{Jloxenufi. O6uuft o6leu pa6orrr cocraBJlter192 crpauurlbr MarrrrrHorurcHoro reKcra, coAepxllT 54 pucynra,2T ra6twJ, cnl4coK nllTeparyphl lrx1 3 1 sauuen oBaHvIA, 2 npur,oxeuut.Bo eneAeguu o6ocnoBaHa aKTyaJrbHocrb reMbl Al,IcceprallnoHHoft pa6oru, BhInoJIHeHaHarw3 cocrorHr4r npo6leurr, cQopuynrapoBaHbl Ilenb HayqHofi pa6oru v sal;aqu IaccJIeAoBaHI'IrI'Hay{Hat HoBI43Ha I,I npaKTllr{ecKat IIeHHOCT6'BbmoJrHeH aHaJrr,r3 npr,rMeHteMrx 4esr,rnlpeKTarlToB Anfl oqucrKl'Inu6esoft BoAbr r,r croKoB, MeroAoB 3neKTponr{3a r{ cyuecrByforqrlx Ha pbIHKe ycrpoftc'rn glafloJryqegr.rr xnopcoAepxarq[x peareHToB u ([epparos.

Hau6oree nepcrIeKTLIBHbIM peareHToMBnepnofr HraBeKOMMyHrUrbHbx BoAOIIpOBOAaX tBJIteTCt aHOJII'IT' nOlyraeuuficroKoB HaSJreKTpoJrr,r3oM HacbrrqeHuoro pacrBopa noBapeuHofi colz B BoAe' a Nw, otIlIcrKI'I.ru"rtr"* no o6pa6orKe rexulrqecKr{x ?r croqHbrx BoA flBntercx (feppat (VI). Kax naz6oneeNtL OqucTKfi BOAbr Hailpor,r3BoAr,rtan""itft r{ 3KogoMr,r.mrd MeroA Ant rroJrfreul{fl aHoJlura vI Qepparon BbIAeneHrr,rlnr6panuuft enerrponr{3 c rarraosoo6uennofi ureu6paunofi, o6ecne'il'rearcIquft 6omuytogHepronoTpe6lenueeArrHrqHyIO torrlrrort" 1,ro4yneft K3A u no3BoJltloqnft perynupoBaTbnpoqecca gJreKTpoJrlr3a B 3aBr4crrMocrr.r or tpe6yer'roft npousroAllTeJlbHoctu. Ha ocHoBaHI4rIiu?'Iluzu oro6panutx Jrr.rreparypHbrx r,I rrareHTHbx LIcrotIH[KoB He BbUIBJIeHo I43BecrHbIxpeueuuft uO o6esSapaXI'IBaHI'IIOOTeqecTBeHHbIx 14 rapy6eXnrx 1pOTOTI{IOB KoMnJIeKCHbxgJIeKTpoJIHga AIIsnonrIeHI{s aIIOJIHTa Ia seppara'BOAbr r.r cToKoB ,rp"ra"a""rt rar6paHHoro"3CsopuynupoBaHbr rpe6onauur r pa:pa6arbrBaeMoMy K9A rporI3BoALIreJIbHocrbIo Ao 25rr/cyrrrE xJropa npr{ oHepro3arparax ne 6oree 3,0 rBr'v/rr }I Ao ao 10 xr/cyrxu $eppara npngHepro3arparax He 6olee 6 xBr'./xr.Bo nropofi r.lrase [peAcraBJreuo r,r o6ocnosaHo KoHllelryanbHoe peIueHLIe K3A, uaocHoBaHr,ru Teopuu gneKTpoxr,rMtru paccq[TaHbr ocHoBHbIe TexHoJloruqecKrle flapaMeTpbl[poqeccoB gneKTpoJrr,Ba aHoJrr.rra r,r (peppara Harp]It, paspa6otauu npI,IHIIHIruaIIbHbIe uKoMrroHoBoqnble peIueHI,It rvroAylefi arperara.B rpersefi rJraBe Ha ocHoBaH?rr{ BbrloJrneHHbrx pacqeroB [poI43BoAI,ITeJIbHocrI'I ugHepro[orpe6lenus paspa6orauu cxeMHbre v KoHcrpyKTI,IBHbIe perueHlls rraonylefi Arrs[por.r3BoAcrBa aHoJrlrra n tfepparoB !r onpeAeJreHbl pexl,IMbr nx (fymqr,roHl,IpoBaul,It B cocraBeK!A.

flpune4enu cocraB rraogyleft K3A, flapaMerpbl rexHoJloruIqecKoro rpoqecca IroJIyqeHLItanonr.rra u Seppara, cocral il nporpaMMHo-a[naparuat peanll3arlut cl{creMblaBTOMaTU3T4pOBaHHOTO ylpaBJreHur npoqeccaMll [poI{3BoACTBa UpOI'I3BOACTBa peareHTOB.flora3auo, wo paspa6oraHHbre KoHcrpliKTr{BHbIe I,I TexHoJIot}IqecKLIe peIrIeHLIf, tr,toAyneft An-[lporr3BoAcrBa aHoJrrlTa n Sepparoe o6ecueq[earor [oBbImeHI4e gHeproo(!(ferrurnnocrlr u6esonacHocrv rexuoJroruqecKoto [poqecca rroJrfreHl,It ilr{oJuTa u (feppar4 a raKxe Bo3Moxuocrbpa3AenbHoro SyHrqraoulrpoBaHr4r xJroparopa vr $epparopa.

Parpa6oranu crpyrrypa vIlporpaMMHo-annaparHafl peuvlr,arJLrr a4urwrsHofi clacreMbl ylrpaBlrcllvfl' gneIcrpoxLIMI,IqecKI4Mcr.rnTe3oM zuromara u (feppara :aarpvs., o6ecnewrearc[u.Ie noBbtrrleHl{e gnepros$(lerrrnuocrll I'I6egonaorocrlr rexuoJroruFrecKoro npoqecca noJrfrenlls arIoJIr,ITa I,I $eppara. Paspa6orau 14Lr3roroBJreH K3A rpor.r3BoAlrreJrbHocrblo Ao 1040 rl.r. xJlopa (ao 25 rr/cyrxu) rpLIeHepro3arparrx Ao 3,0 rBr'.r/rr xnopa u to 420 rlq tpeppata (ao l0 m/cytxu) ,npuoHepro3arparrx Ao 6 rBr..r/Kr (feppara, no3BoJUIroIItu o6essapaxl'IBarb Ao 300 vr'/qacnprrresoft BoAbr (ns pacueraao 3,i *ilo; lo 2100 *3lta" crotlHblx soa (It3 pacqera Ao 0,2"rrlr/rr).ruraBe [plrBeAeHbr pe3ynbrarbl ncnrrrallraft K3A sa BoAooqlacrHblx.{sepNnucx vt gKcuepr,rMeuTaJlbuhle vccJIeAoBaHHt o6e:sapaNuBanilfi.aHoJrlrroM ra QepparoM Harplrfl.

K3A npeacralJlter co6oft He3aBI4clIMo rfynrqraoullpyrolql4egneKTpoJrra3Hbre MoAynr,r c r.rHAlrBr,rAyarrbublMI,r CAY - xJloparoprr nrrpa6atblBttror aHoJIHT AntxJroplrpoBaHur BoAbr u rqerorrb, Qepparop [poLI3BoAtIT (feppar HarpLIt u3 gJleKTponusHofi1qenoqu u pacxoAyeMoto aHoAa. B pesynbrare ucnrrranr.rft [poll3BoAr{TeJlbHocrb xJloparopa HaJtvrnupt BTopr4rrHoro xiroprrpoBanufl B nepecqeTe Ha oAHy gneKTponll3Hylo KaMepy cocTaBpIJIa1060 rl'a xnopa (25,43 rr/cyrrn) rpn oHepro3arparax 2,72 rBt''/xr xnopa.flpousnoAureJrbHocrb 2-x anoAslrx KaMep (peppatopa B cpeAHeM cocraBllJla I73 rlT $eppara(4,150 xr/cyrrur) npr,r sHepro3arparax 5,98 xBr'q/xr (peppara, rlro B repecqere na 5 anoAnrxKaMep coorBercrByer 432,43 rl'a tfeppata (10,38 ru/cyrrcu).