Заключение организации, где выполнялась работа (Синтез и физико-химические характеристики электродных катализаторов платины и палладия на основе пористого кремния)
Описание файла
Файл "Заключение организации, где выполнялась работа" внутри архива находится в следующих папках: Синтез и физико-химические характеристики электродных катализаторов платины и палладия на основе пористого кремния, Документы. PDF-файл из архива "Синтез и физико-химические характеристики электродных катализаторов платины и палладия на основе пористого кремния", который расположен в категории "". Всё это находится в предмете "химия" из Аспирантура и докторантура, которые можно найти в файловом архиве РТУ МИРЭА. Не смотря на прямую связь этого архива с РТУ МИРЭА, его также можно найти и в других разделах. Архив можно найти в разделе "остальное", в предмете "диссертации и авторефераты" в общих файлах, а ещё этот архив представляет собой кандидатскую диссертацию, поэтому ещё представлен в разделе всех диссертаций на соискание учёной степени кандидата химических наук.
Просмотр PDF-файла онлайн
Текст из PDF
YTBEPX,IIAIO:;.: jl;'t ;,r(D|FOYBOg npopeKropS,Ep,,'ttMo'd.!ipp,cxuirrexHoJroruqecxuiayHr4Bepcr4Ter). * . : r r ' . ,1' i ,, , .ijr.iii',a\'ii ' , n:i.t!o :ir;'i:jtjH.VI.llporouon2017r.3AKNIOIIEHI,IEQe4epanrHoro rocyAapcrBeHHoro6ro4xernoro o6pasoBareJrbHoroyqpelxAeHraf,Bblclrrero o6pasonaHl4fl((MocKoscrufi TexHoJloriz.recruft yHr4Bepcurer>)rro AvaaeprarJuu3eH.IeHro Bnrarus, Orerosu.Ia Ha collcKaHr{eyueuofi crerreHz KaHAr4AaraxrzMI4qecKHXHayK rlo creIII4€lJIbHocrI{02.00.04 - <<@Hsla.IecKa-flxI{MLrfl) (xzrrazuecrcnenayrcu)fiucceptaryw<<Czsre: v Susut<o-xl,IMllr{ecK?rexapaKTepkrcrtrKvr gJreKTpoAHbrxKaraJII43aTOpOB ITJIaTHHbI 14 ilaJrnAALrfl HA OCHOBe rrOpr4CTOfO KpeMHr{fl)BbrrIoJrHeHa Harca$e4pe Su:nuecr<ofi xvMnu HM.
-q.K. Cuprzna HHcrr{ryra roHKLrx xurMr4r{ecKraxrexHoJlorlafiutuenu M.B. IouoHocona Se4ep€LnbHororocyAapcrBeHHoro6ro4xeuroroo6pa:oaareJlbHoro yqpelxAeHr4trBbrclrero o6pasoBaHraf,<<MocrconcrufiTexHoJrorizqecrufiyHZBepcr4TeT).B 2013 r. 3eH.reHIcoB.O. oKoHtII4JIMarLlcrparypy MI4TXT uu.
M.B. Iouonoconano Ha[paBJIeHHIo<<Xuuns>>,ycrlellrHo 3arlraruB Aracceprarlr4roHa reMy <llonyveHvre uKarzilIHTLItIeCKataKTT4BHOCTbSneKTpOAHbrXMarepuanoB Ha qCHOBeTTOpHCTO|OKpeMHI4r)Ha coLrcKaHtzrecrerreHlr Marr4crpa rro clerlr4€lJrbHocrLr<<Xuuus].B nepuoA rIoAroroBKH AI{ccepraIIIlI4 cor4cKareJrb3eu.reHro Buranufi Oreroeu.{flBrflncfl.oqHbIMacnr{paHrovr ra$e4pu Sz:uuecrofi xtrvrvrvruvr. -f,.K. CuprcraHauHcrLrryraToHKr4x xI{MLrqecKr'TX rexnolorufiLrMeHr.r M.B.JIon4oHocoea MocroncKoroTexHoJrofr,rqecKofoyHlrBepcuTeTa.Hayuurrfi pyKoBoALITeJIb- -f,rurynoe HuKorafi An4peeBr4rr, AoKTop xr4Mr4rrecKlrxHayK, npoSeccop raQeapbl oHeprerl4qecKl4xrexHoJroruit, cucreM LrycraHoBoK r4HcrrrryraT0HKLIXxllMIiIrIecKIiIXrexnolorufiI4MeHI{M.B.JloruoHoconaSe4epanrHororocyAapcrBeHHoro6roAxernoro o6pasoBareJlbHorof{pexAeHr4r Bbrcrlero o6pasoeaHrar<<MocKoscr<2fiTexHoJroria.recrzfiyHr4Bepcurer).Ha sace4 aHvrvrra$ e4p rr S z:u.r ecx oit xutvtuu [p]r cyrcrB oB€uru :sae.
rcaQeqpoir,A.X.H., npo$. Onu4 B.P. - npeAceAareJrb3aceAanvrfl.,K.x.H., AorI.Mznuna H.E.ceKperapb 3ace4aHLrfl,A.X.H., npo$. .flunynon H.A.Hay.trufipyKoBoAr4reJrb,K.x.H., aoq. 3o6:n:aHaA.H., A.X.H.,rpo$. Ilolenon E.A., A.x.H., AorI.flecroe C.M., A.X.H.,npo$. KaqnaauE.A.
(raQeApao6rqefi xuMr{qecKofirexsolorun),rexnoloruu), K.x.H.,c.H.c.A.X.H.,upo$.Epyx JI.f. (san.xa$e4pofio6qefi xr{Mr4qecKofiB.fl.,K.x.H.,KprrnonA.8.,K.x.H.,4oq.4oq. Mopo3oBaT.A., A.X.H.,,{anroruencrcnfi,B.H.c.l[alacues P.C.,K.x.H.,AorI.TrcaqeHKoO.IO.,K.x.H.,AorI.EenqenE.A.1Cryrualu:1.,{orna4 3enqenr<oB.O. no KaHAl4garcrofiAr{cceprarluu'<<Currre3r4 Sz:unogJreKTpoAHbrxxuMl4qecKplexapaKTepI{cTI4Kr{Kar€Urr43aropoBrrJrarr4Hbr14IJ.anral'vrflHaocHoBerroplrcTofoKpeMHLT')>.2. Coo6ueHne HaflHoro pyKoBoA?IreJItAoKTopaxr4MuqecKr4xHayK, npo$eccopa,flrurynonaH.A., AaBIrIefononortlrreJrbHyroxapaKTepr,rcrLrKycorrcKarenro.B xo4e o6cyN4envrfl,AucceprarllroHHofipa6orrr 3eH.reHroB.O.
6unu 3aAaHbrcJreAyrour4eBorrpocbr:,{.x.H., AoII. ilecron C.M. C rarofi ToqHocrblo Bu olpeAeJltrnr4 3HaqeHI4ggneKTpoKararLrrvqecrofiaKTlrBHocrno6pasqon?Oreer: llo HaITILIMorIeHKaM, Koropble coorBercrByror rracloprubrM AaHHbrMupz6opon u nnreparypHblM AaHHrIM, TorlHocrb orrpeAeneHr{-flKaranr4TLrqecKlrarrueHofio6lacru cocraBJlter He 6onee 5-10% or LI3Mep.se\aofiBeJrlrrrr{Hbr,ArrflrrJrorHocrrl ToKa,lponopqnonamnofi cKopocrr{ sneKTpoxr{MlrrrecKoronpoqecca, He 6olee 2 Alvrz.K.x.n.o AoII.
Kpu"non A.C. Ha KaKoM npn6ope u c rarofi TorrHocrbro BuI43Mep{JII{ pinMep nanouacuEq? Kar npono4urocrLr3MepeHpre gJrJrrrrrcoBr{AHbrxHaHoqacrzq? Karyro $oprnry rrMeJrr,r6uuerarrzqecKue HaHoqacrnrlu? Ha xaxux AaHHbrxBrr ocnoBhlB€ullacbrlprr yrBepx{AeHr{u, rrro HaHoqacrr4rlbrpaBHoMepHopaclpeAenenbr Bruy6une [oprlcroro rcpeuHux?Orner:Zccne4onalnfl,HaHoqacrl4rl npora3BoAvrrrr4cbHa aroMHo-crrJroBoMMlrKpocKore NTegra Prima. Ha cr'airile 2I rpeAcraBneH nplrMep rr{crorpaMMbrpacilpeAeJleHl4t rlo pa3Mepy roryr{er{Hbrx HaHoqacrr{rl Pt-Pd, [oryqeHHbrx B pacrBopeo6parunx euymcufi rpu LrcrroJrb3oBaHvruHeraoHoreHHoro IIAB TpuroH X-100.To.rnocru npl4 I{3MepeHVprcocraBlrJra 0,2 nnd.
I4sl,repeHr4egJrJrr.IncoBr{AHbrxHaHoqacrLrrlrIpoBoAI{JIocb IIo oolrruefi ockl SJIJILIIoa. BnnaerallnqecKr4e HaHoqacrlrrlbr nMeJII4oJIJILIIcoBI{AHyIo$op*y c 6omurvM coorHorxeHlreM rrrarofi u 6onrruofi ocefi, qeM AntHaHoqacrI4II nalrIra4krfl. lloAaHHhrM BbIcoKo paspeuraroqefi npocBerrrrnaroqefigJleKTpoHnofivrurpocKorrl{Ia cKona 6uro o6HapyNeHo, rrro pacilpeAeJreHlreHaHoqacrLrrlBruy6raHerroAJroxeKrropkrcroro KpeMHLrrpaBHoMepHo.K.x.H.o 4oq. KpuJroB A.C. Ha cnafip.e32 npeAcraBJreHacrpyKrypa C(OH)2, qrooHa I43 ce6x npeAcraBJl.fler?9err,rnoATBepx4aeras. [pr{BeAeHnrrfi uexaHr43M[poreKaHratpear<quu?Orner: llpe4crauleHHa.l na cnair e 32'Mcrraqa C(OH)2 f,BJrfleru 6upagtrK€uroM,roroprrfi o6paryercfl. Ha rperrefi craquu peaKrlr.ru rrprMoro oK?rcJreHrlsMypaBbunofiKLICJIOTrI,V pACnAg:aeTCfl.Ha yrneKrACrUfi ra3, ABa npOTOHaVr ABa gJreKTpOHa.laUnUfiMexaHI{3M TIOATBepXAeH,qaHHbrM?rHa IrOTeHrIr{OALTHAMVTTIeCKLTXKpLTBbIXB peaKrllllroKI{cJIeHLItMypaBbzuofi Kl{cJrorbrkr corJracyercr c JrzreparypHbrMr,rr{crorrHlrKaMr4.K.x.H., c.H.c.
[aHroruencnnfi B.fl.. Karue KoHrleHTpar\vunJIarI4HoBbrxMeraJrJIoB6uru Ha [oBepxHocTI'I nopklcTofo KpeMHLItI4 KaKyroMaccoByroAonro oHtr cocTantsttu?Orner. 3arpy:ra [Jlarr4HoBbrx MeTEUIJIoBHa [oBepxuocrr4 vr B rropncroM cJroeo6paeIIa BapbkIpoBaJlacbB rrpeAeJraxor 0,05 4o 0,15 vr/cvr'. MaccoBafl.AoJrr rrJrarr4HoBbrxMeTaJIJIOBCOCTaBLTJTa2-5Yo OT MaCCbr rrOpr4CTOfOCJrOr, rrro rIOATBepXAaerc{ AaHHbrMIrEDAX.K.x.H.,aoq.
KpuJroB A.C. KaKgaszclrrpa3MepHaHoqacrr,rqor prcrroJrmyeMoroIIAB?BunaerarruqecKlae HaHoqacrI4IIbI sBnslorcroAHopoAHbrMr4urrvr Ha6mo4arorcxoTAenbHbreyqacTKr,rc rrJraTl4Hofi14[annanvreM^?OrBer.llprzr4cnoJrb3oBanuz Her4oHoreHHoro NAB(Tpuron X- 100),HaHorracrl{rl[pokrcxoALrrBnanqenrxpnofi oSoloure, n orruque orQopMIlpoBaHLIeaHI4oHHoroIIAB (AOT), rpLI IdcrloJlb3oBaHrrr4Koroporo SopvrupoBaHneHaHoqacrnrlIIpoI4cxoIrIT BHyrpI4BoAHofo nyna. 3a c.Ier 3Tofo, Brr{.rrHHecrerreHracomo6unkr3ar\uuHapa3Mep HaHoqacrl4l{ Anfl HeI,IoHoreHHoronAB 3HaqI{TeJrbHoHr/DKe.(DopvrupoBaHr{e6zuerallu.{ecrofiHauoqacrI4IIbI B Mr,rqenJlenpozcxoAr4T rryreM oAHoBpeMeHHoroBoccraHoBJIeHI,ItrIoHoB MeraIIJroB,rIo3ToMy He ua6ruo4aerc-f,orAeJIbHbIXHaHoqacruuIIJIaTI4HbI LI rlannAl.lIfl.
HA IIOIIOX{Ke.K.x.n., c.H.c. [auromescrc[fi B.fl,. Ha crafige rrpeAcraBJreHbrHecKoJrbKo$rzsur<oxHMLIqecKI4xMeroAoB I{ccneAosaHuil kr arrecral{uI'r HaHorIacrrIII I4 KoMno3I{ToB.KarurraukI3orr,rxMeroAoBBu ueuocpeAcrBeHnoua4eere?Orser. Henocpe4crBeHHo vruofi npoBoAr{nacb[oAroroBKa oSpa:qon) a*arrtr3 HI{HTepnpeTaIII4-f,nonyqeHHblx AaHHbrx Antr BCex MeTOAOB SneKTpOHHOfOkrpeHTreHoBcKoro analrLr3a. Ocranrnrre Mero.4br r4ccneAoBaHLrflrrpoBoArlnr{cb MHoro.t'caMocTo.flTeJIbHO.B noHrrr4e <SnuerarJrr4r{ecKatA.x.n.o rlpoQ. Illanupo 8.I4. r{ro Bu BKna.qbrBaereHaHorlacruga>>?lloveuy B KarlecrBe noAnoxKr{ r4crronb3yerc-f,uopncmrfi xpevtrnfi?Kaxuira o6p a: ovr npou cxoArar $ z rc arr4fl .c'acrur{Ha rropzcroM rp euHzra?Oreer. B 4anHofi paSore SvIrraera-urkIrlecKa-fiHaHorracrr,rqa[peAcraBJrrer us ceSxcIrJIaBbI C paBHOMepHbIMpaclpeAeJreHr4eMaroMoB rrJraTHHbrkr rranna4r4fl, KoTopbre-f,BJltrIorc.flaKTIzBHbIMvrKaraJrr43aropaMrrB peaKl{r4r4oKr{cJreHzf MypasrzHofi Kr.rcJlorbr.T.e.
HIasenl{pyercflHerarLIBHoeno:4eficrBne MoHooKcr4AayrnepoAaHa aroMbr rrJrarrHbr,npl43TOM HAnIdI{I|Ie aTOMOB TIJIaTI{HbI B HaHOqaCTHIIe yBenI4qI4BaeTAKTHBHOCTbKOMIIO3VITA.KaTa[LITI4TIeCKyIOI4cnolrgoBa:r.kre[opl4croro KpeMHrrflrro3BoJrrer HHTerpzponarb Mr4KpoMorqnufiucrorIHI4KToKaHa ocHoBenopr{croro KpeMukrfl.B 3neKTpoHHyroannaparypy. B rou qlrcJrerrr4rraco3AaHI{e Ua O4UOfrXpeUUUenOfirrJracTkrHec oAHofi ;cropoHbr, 14 TofrJrraBHofo3JIeMeHTac 4pyroft 4nx aBToHoMHofipa6orbr AaHHoro arperara.
@urcaqH{ qacrr,rrlnpozcxoArar 6laro4ap.rr xeMopSrywt B ropax Marpr,rrlbrKpeMHr4.rr.npono4LrJrocbAnr oAHoro r{Jrr4A.x.n.o rlpoQ. @.nuA B.P. lIpoBeAeHLIeI{3MepeHr4fiHecKoJrbKraxo 5p asqoB c oAr4HaKoB6rMr{rrapaMerpawu?Orner: ,{rtl raN4oro rl{rla o6pa":qon[poBoAr{Jraabaepkrflu:uepenzfi.A.*.u., rpo+. @.nuA B.P. Cefiqac ilpoBoAllTc.fl MHolxecrBo rrccJreAoBarrufiro3aMeIrIeHI4IO rIJrarI4HbI B KaralrkrtlarlecKoMcJroe rorIJII{BHbIX 3JIeMeHTOB, IIOqeMy B CSOefipa6ore Brr ucnoJlrcyere I4MeHHourarnHy? lloverray s ceoefi pa6ore Bu ue nonyqaereHaHorIacrI{I{bIMeHbllrero pa3MepaAntr yBenr4qeHvrflKaraJrr4Tr{.recrofiar<rranuocrz?Oreer.
[a, ua ceroAH.alunnfi4enr cyqecrByer MHo]Kecrnopa6or rro 3aMerqeHr4roTIJIaTI{HbIBKATaJTT4TkHeCKOMCJIOe,HOAOCTI4TIbBbTCOKI4XyAenbHbIXSneKTpoKuraJrkrrvrqecKl4xxapaKTepzcrkrK cpaBHr4Mbrxc rrJrarulaoit B AaHHbrxpa6orax ueyAaercf,. I-{enr 4anuofi pa6orrr 3aKrloqaerc-fl B Mr4Hr{arroprnarpukrrorurr4BHoro3IreMeHTa,3a crler yBennrreHut yAenbHbIX xapaKTepr4crlrK oneKTpoAHoro Marepr4ana.
llpupa3MepaHaHoqacrr4rlilpoucxoAr,rr zx 6ucrpoe ((BbrropaHr4e)),4alruefrueM yMeHbIrIeHI4I,IT.e. np oz cxoAr.rTS:f'lcT'pax Aefp aAarlkrfl Kut ailu3aTopa.Hayvnrrfi pyKoBo.{HreJrbconcKareJr{ A.X.H., npo6. -furrynon H.A. B cBoeMcoo6tqeuuln AanIroJIoxI4TeJIbHyroxapaKTepr,rcrlrKyac[]rpaHTy 3euueuxo B.O.llpu o6cylKAeHI4I{c oIIeHKofi npe4cranrenuofi pa6oru BbrcrynnJrrr:A.x.H., npo$(Dnz4 8.P., A.X.H.,npoQ. Fpyn JI.f, 4.x.n., Aou.
llecron c.M., K.x.H.,4oq. Kprrnos A.B.Bce nucryrrarolr1lze 4:anrlnoJroxr4TenbHyroorIeHKy npeAcraBneHnofi ArrccepraqrioHHofipaSorrr.flo rarorau o5 cyx4en vrn npvrnflTocJre.qyroqee 3aKnrorreHrre:Arcryanruocrb pa6oru.B Hacrof,ulee BpeMn co3.qaHl4e KuraJrkrrr4qecKll aKTI{BHbrx Lr cra6anrnrrxHaHoKoMrIo3I{THbIXMarepuaJloB, o6raAaroulux rroBbrrueHHbrMr4SyHrcquoHarrbHbrMr4cnofictnauu, [peAcraBJlfler co6ofi npr4Hrlr{[uarrbHyro HayqHyro 3atraqy conpeuenuofiQizsrauecxofixnuuu, HaHorexHoJrorrrvra gHepferraxu.HecoMHeHHbrfiunrepec Bbr3brBaernopucrufi rperrtrzfi (|ff(), Ha ocHoBe Koroporo pazpa1arbrBarorc.fl KaraJrnrtrqecKlreKoMlo3I,ITbI c BblcoKopa3nuroft amzsHofi noBepxHocrbro.
ConpeueHnue $usurcoxlIMuqecKue MeroAbI I{ IroAXoAbI K cr4HTe3yrro3BoJrflror HalpaBJreHHo SopuuponaruKaraJrkr3aropblB nopl4crofi vrarpzqe c xourporzpyeMbrMr4 pa3MepaMrav Sopvrofi 4lrKoHcrpyl4poBaHkIt MI{KpoMouIHbIX ucroqHr,rKoB gHeprr4r4. B cB.rr3?rc 3Tr4M rrotrcKOIITIIM€LIIbHbIXCOCTaBOBKaTaJII4TLIqeCKUaKTLIBHbIX HaHOKOMIIO3I{TOBHa OCHOBeIIJIaTHHoBIIXMeraJIJIoB,rlpo6reua nuSopa Marpr{rlbr-rroAJro)KKu,paspaSorKa cnoco6osMarepu€uroBHaSopnaupoBaHtrfl.u cra6uttu3ar\kru HaHopa3MepHbIXrroJrlrMeraJrJrr4rrecKr4xgaAa.{efi.SyurcqzoH€ulbHblxHocuren{x -sBrf,ercr aKTyaJrbuofinayuHofiHayvnar HoBrr3Ha.B pa6ore BIrepBbIenonyqeHbl o6pa:qrr HaHoKoMrro3HToBrroprrcroro KpeMHr4.rrcHaHorIacrI4UaMLIntatu]Flalnantalluft ilpLI MonbHbIX coorHorrreHr{.rrxMeraJrJroBor 5:1 Ao1:8, Koropble cI4HTe3I4poBaHbrB BoAHo-opraHr4qecKHXpacrBopax oSparqenuuxMrrKpooMyttscuitco creneHrro colro6prnkr3ar\vprcoor 1.5 ao 8.Irlccre4onaHa 3aBl4cl{Mocrb Me}KAy xapaKTeprrcrr,rKa-\4r{HaHoKoMrro3r4ToBkrcnoficreaN,rraMarepnana Ha vrx ocnobe v ycraHoBJreHo,qroSvI:uxo-xI'IMuqecKI4MI,IHaHOqacrI,IIIbIUJIarUHbr ?r ilAilnAAVrfl C Mr4Hr4M€rrrbHbrMr4pa3MepaMr4H paBHoMepHbrMpaclpeAeJleHl4eMoSpa-:yrorcx KaK Ha IloBepxHocrr4, TaK Lr B o6reue xpeuHvenofiMarpI4IIbI npI4 ynbrpa3ByKoBoM Bo3Aeitctsuu B rrplrcyrarBr4v Her,roHoreHHoronAB Tpr.ruoHX-100.Bnepnue rloKa3aHo, qro KaralrvrvqecKar aKTHBHocrb cLIHTe3LIpoBaHHbIX3neKTpo.qHbIXMaTepl4anoBHa ocHoBe [opncrofo KpeMIJkrfla HaHorIacTI4IIaMHrrJraTIrHbII,rrranna4vrflBo3pacTaeTc yMeHblrreHrreMpa3MepaHaHorracTr{qB peaKrllr_f,xBoccTaHoBJreHr4tKucnopoAa, oKI4cJIeHI4tBoAopoAa w MypaBbuHofi rracnoru.